• Title/Summary/Keyword: spillover

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Room Temperature Hydrogen Gas Sensor Based on Carbon Nanotube Yarn (상온감지 가능한 탄소나노튜브 방적사 기반의 수소 감지 센서)

  • Kim, Jae Keon;Lee, Junyeop;Kong, Seong Ho;Jung, Daewoong
    • Journal of Sensor Science and Technology
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    • v.27 no.2
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    • pp.132-136
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    • 2018
  • We report the development of a room-temperature hydrogen ($H_2$) gas sensor based on carbon nanotubes (CNT) yarn. To detect $H_2$ gas in room temperature, a highly ordered CNT yarn was placed on a substrate from a spin-capable CNT forest, followed by the deposition of a platinum (Pt) layer on surface of the CNT yarn. To examine the effect of the Pt-layer on the response of the CNT sensor, a comparative sensing performance was characterized on both the Pt deposited and non-deposited CNT yarn at room temperature. The Pt-CNT yarn yielded high response, whereas the non-deposited CNT yarn showed negligible response for $H_2$ detection at room temperature. Pt is a reliable and efficient catalyst that can substantially improve the detection of $H_2$ gas by chemical sensitization via a "spillover" effect. It can be efficiently utilized to increase the sensitivity and selectivity as well as to obtain fast response and recovery times.

Development of Exit-Ramp Control Strategy Avoiding Mainline Spillover for Urban Freeway (과포화 신호제어 기법을 응용한 도시고속도로 진출램프 제어전략의 개발)

  • 김영찬;이철기;허혜정
    • Journal of Korean Society of Transportation
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    • v.19 no.3
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    • pp.89-100
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    • 2001
  • 내부순환로의 진출램프 중 성산, 홍은, 홍제, 길음, 마장 진출램프에서는 램프의 지체가 심각하여, 진출차량의 대기행렬이 내부순환로 본선에까지 이르는 대기행렬 역류현상이 발생하고 있다. 이러한 본선으로의 대기행렬 역류는 본선의 혼잡을 가중시키고 교통사고의 위험도 증가시킨다. 본 논문에서는 이러한 도시고속도로의 진출램프 혼잡을 개선하기 위해 진출램프 제어전략을 개발하였다. 진출램프 제어전략의 목표는 진출램프의 대기차량이 본선으로 역류하지 않도록 하는 것이다. 대기행렬의 역류를 막기 위해서는 진출램프의 차량이 인접한 간선도로로 원활하게 진행하도록 해야 하며, 간선도로와 진출램프의 대기행렬을 제어정책에 따라 관리할 수 있어야 한다. 이를 위해서 진출램프 진출부에 신호를 설치하여 간선도로차량의 흐름을 제어하고, 진출부 하류부 교차로와 연동제어를 하여 진출공간을 확보하였다. 또한, 대기행렬의 관리를 위해서는 대기행렬 관리계수를 정의하고 이 값에 따라 현시를 결정할 수 있는 제어식을 유도하였다. 진출램프 제어전략은 과포화 신호제어 기법을 응용하여 개발하였으며, 그 중 Equity offset과 내부미터링 기법을 연동제어에 응용하였고, Imbalanced split 기법은 대기행렬 관리계수에 따라 현시가 결정되는 제어식의 개발에 응용하였다. 진출램프 제어전략을 평가하기 위하여 진출램프의 혼잡으로 인해 본선으로 대기행렬 역류가 발생하는 내부순환로의 홍은, 홍제 진출램프를 선정하였으며, NETSIM을 통해 진출램프 제어전략의 효과를 분석하였다. 분석결과 진출램프의 혼잡이 크게 개선되며, 운영자의 관리목적에 따라 대기행렬의 관리가 이루어지는 것을 볼 수 있었다. 진출램프 제어전략은 내부순환 도시고속도로뿐만 아니라 진출램프 제어가 필요한 타도시고속도로에서도 적용을 하면 좋은 효과를 얻을 수 있을 것으로 예상된다.

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거시경제변수의 주식시장에 대한 변동성전이효과에 관한 실증연구

  • Byeon, Yeong-Tae;Park, Gap-Je;Im, Sun-Yeong
    • The Korean Journal of Financial Studies
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    • v.14 no.1
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    • pp.97-117
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    • 2008
  • 본 연구의 목적은 AR(1)-GARCH(1, 1)모형을 이용하여 우리나라의 거시경제변수의 변동성으로부터 주식시장의 변동성으로 전이효과(spillover)가 존재하는지를 규명하는데 있다. 본 연구는 자본시장이 개방되기 시작한 1992년 1월부터 2007년 6월까지 186개월치의 KOSPI 지수 및 주요산업지수와 거시경제변수인 정부의 통화정책을 반영하는 콜금리, 미달러환율, 인플레이션의 대용치인 생산자물가지수 자료에 근거하여 거시경제변수의 주식시장에 대한 변동성전이효과를 AR(1)-GARCH(1, 1)모형을 이용하여 분석하였다. 분석결과에 따르면 콜금리의 KOSPI 지수수익률에 대해 변동성전이효과는 통계적으로 비유의적으로 나타나 변동성전이효과가 없는 것으로 나타났으며 환율은 KOSPI에 대해 양(+)의 변동성전이효과가 존재함을 보였다. 이는 미달러환율의 기대치 않은 변동성이 주식시장의 변동성에 양(+)으로 충격을 준다는 것을 의미한다. 또한 인플레이션의 대용치인 생산자물가지수(PPI)는 주식시장에 대해 변동성전이효과가 1% 유의수준에서 통계적으로 유의하여 강한 변동성전이효과가 존재하는 것으로 나타났다. 이러한 결과는 이자율을 나타내는 콜금리를 제외하고 Cumhur, Arslan and Meziyet(2005)의 연구와 동일한 결과를 보였다.

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The Stability Conditions, Performance and Design Methodology for the Positive Position Feedback Controller (양변위 되먹임 제어기의 안정성, 제어 성능 및 설계 방법)

  • Kwak, Moon-Kyu;Han, Sang-Bo;Heo, Seok
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.14 no.3
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    • pp.208-213
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    • 2004
  • This paper is concerned with the theoretical estimation of the single-input single-output(SISO) positive position feedback(PPF) controller and the derivation of the stability conditions for the multi-input multi-output (MIMO) PPF controller. Although the stability condition for the SISO PPF controller was derived in the earlier works, the question regarding the performance estimation of the SISO PPF controller has never been studied theoretically. Hence, the SISO PPF controller for the single degree-of-freedom system was first investigated and then control parameters including gain, the filter frequency, and the damping factor of the PPF controller were analyzed in detail thus providing the design methodology for the SISO PPF controller. In the case of real structure. there are infinite number of natural modes so that some modes are to be controlled by a limited number of actuator and sensor. Based on the theoretical results on the SISO PPF controller, the stability condition for the multi-input multi-output PPF controller was derived when only the few number of modes are to be controlled. The control spillover problem is also discussed in detail.

Study of Synthesis and Magnetic Properties of Ni and Ni-Cu Nano Metal Powders Prepared by the Pulsed Wire Evaporation(PWE) Method (전기폭발법에 의한 Ni 및 Ni-Cu 나노 금속 분말의 제조와 자기적 특성연구)

  • 박중학;엄영랑;김경호;김흥희;이창규
    • Journal of Powder Materials
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    • v.10 no.2
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    • pp.83-88
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    • 2003
  • Nanocrystalline materials of Ni and Ni-Cu alloy have been synthesized by the pulsed wire evaporation (PWE) method and these abnormal magnetic properties in the magnetic ordered state have been characterized using both VSM and SQUID in the range of high and low magnetic fields. Ni and Ni-Cu particles with an average size of 20 to 80 nm were found to influence magnetic hysterisis behavior and the results of powder neutron diffraction patterns and saturation magnetization curves are shown to indicate the absence of the NiO phase. The shifted hysterisis loop and irreversibility of the magnetization curve in the high field region were observed in the magnetic-ordered state of both Ni and Ni-Cu. The virgin magnetization curve for Ni slightly spillover on the limited hysterisis loop ($\pm$20kOe). This irreversibility in the high field of 50 kOe can be explained by non-col-linear behavior and the existence of the metastable states of the magnetization at the surface layer (or core) of the particle in the applied magnetic field. Immiscible alloy of Cu-Ni was also found to show irreversibility having two different magnetic phases.

Uncertainty and Manufacturing Stock Market in Korea

  • Jeon, Ji-Hong
    • The Journal of Industrial Distribution & Business
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    • v.10 no.1
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    • pp.29-37
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    • 2019
  • Purpose - We study the dynamic linkages of the economic policy uncertainty (EPU) in the US on the manufacturing stock market returns in Korea. In detail, we examine the casual link between EPU index in the US and the manufacturing stock indexes in Korea. Research design, data, and methodology - We measure mainly the distribution effect of the US EPU on the manufacturing stock market in Korea of 1990-2017 by the vector error correction model (VECM). Result - In result, we estimate the impact of the US EPU index has significantly a negative response to the manufacturing stock market in Korea such as non-metal stock index, chemical stock index, food stock index, textile·clothes stock index, automobile·shipbuilding stock index, machinery stock index, steel·metal stock index. Also the remaining variables such as electric·electronics stock index, S&P 500, and producer price index in Korea have a negative relationship with US EPU index. Conclusions - We find out that the relationship between EPU index of the US and the manufacturing stock market in Korea has the negative relationships. We determine the EPU of the US has the spillover effect on the industry stock markets in Korea.

The Effects of Methane (CH4) and Nitrous Oxides (N2O) Taxes on the Korean Agricultural Sector (메탄과 아산화질소 배출저감을 위한 과세 효과분석 -한국농업부문을 중심으로-)

  • Lee, Sang-Youp;Kim, Heon-Goo
    • Environmental and Resource Economics Review
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    • v.9 no.5
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    • pp.853-876
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    • 2000
  • The purpose of this paper is to come up with the measures for sustainable development of the agricultural sector in store for the strengthened U.N. Framework Convention on Climate Change. We analyze the spillover effects of Methane and Nitrous Oxides taxes (carbon tax) on the Korean agricultural sector. Unlike the other sectors, the agricultural sector has a unique characteristic generating greenhouse gas in the process of production itself even without consuming much fossil fuel. In order to estimate the impacts of those taxes, non-linear optimization method has been used with various assumed scenarios. The production effect, income and' price effect, and greenhouse gas emission reduction effect in the agricultural sector have been estimated through this method. The empirical results show that the paddy sector has a bigger tax effect than the livestock sector. In the paddy sector, the carbon tax has more impacts in the suburban areas than in the rural areas, while the swine farming section in the livestock sector has a conspicuous income effect in the midst of low greenhouse gas emission effect. These results allude us to apply graded tax rates to the crop, the livestock, and the region of different kind. Even if the agricultural sector has a less tax effect when compared with other industrial sectors, an environmental tax might be an effective measure to prevent global warming.

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The Impact of Asian Economic Policy Uncertainty : Evidence from Korean Housing Market

  • Jeon, Ji-Hong
    • The Journal of Asian Finance, Economics and Business
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    • v.5 no.2
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    • pp.43-51
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    • 2018
  • We study the impact of economic policy uncertainty (EPU) of Asian four countries such as Korea, Japan, Hong Kong, and China on housing market returns in Korea. Also, we document the relationship between the EPU index of those four countries and the housing market including macroeconomic indicators in Korea. The EPU index of those four countries has significantly a negative effect on the housing purchase price index, housing lease price index in Korea. The EPU index in Korea and Japan has significantly a negative effect on the CPI. The EPU index in only Japan has significantly a negative effect on the PPI. The EPU index in Hong Kong and Korea has significantly a negative effect but the EPU index in China significantly has a positive effect on the stock price index in construction industry. The EPU index in only Korea has significantly a negative effect the stock price index in banking industry. This study shows the EPU index of the Korea has the negative relationships on the housing market economy rather than other countries by VECM. And this study has an important evidence of the spillover of several macroeconomic indicators in Korea for the EPU index of the Asian four countries.

Pt/MOF-5 Hybrid Composite Encapsulated with Microporous Carbon Black to Improve Hydrogen Storage Capacity and Hydrostability

  • Yeo, Sin-Yeong;Gwak, Seung-Yeop
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.05a
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    • pp.45.2-45.2
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    • 2011
  • Metal organic frameworks (MOF) have generated considerable interests as a potential candidate for hydrogen storage owing to their extremely high surface-to-volume ratio and low density. In this study, Pt nanoparticles of about 3 nm in size were introduced outside MOF-5 [$Zn_4O$(1,4-benzenedicarbocylate)3], which was then encapsulated with hydrophobic microporous carbon black (denoted CB@Pt/MOF-5) in order to enhance hydrogen uptake capacity without decreasing the specific surface area and hydrostability. To study the chemical composition, morphology, crystal information, and properties of the synthesized material, a variety of techniques is employed, including WXRD, XPS, ICP-AES, FE-SEM, HR-TEM, and N2 adsorption-desorption, confirming the formation of novel hybrid composite designated CB@Pt/MOF-5 with highly crystalline structure, large specific surface area and pore volume. In addition, $H_2$ storage capacity for resulting material was measured using magnetic suspension microbalance at 77 and 298 K under high-pressure condition, and the hydrostability was also tested by exposing the sample to 33% relative humidity at $23^{\circ}C$ and measuring XRD as a function of time.

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A Co-movement Analysis of Housing Purchase Price of Capital and Non-Capital Area (수도권과 지방 주택매매가격의 동조화 변화 분석)

  • Jang, Han Ik
    • Land and Housing Review
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    • v.10 no.1
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    • pp.9-18
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    • 2019
  • This study examined the dynamic change in the co-movement between the house price rates with the network methods of Mantegna (1999). First, Capital area and non-capital area form independent clusters which have the heterogeneous co-movement pattern. In other words, Capital and non-capital areas have low connectivity in the housing market. Also, if the co-movement between capital areas have been strengthened, the co-movement between non-capital areas have been weakened. The results of the dynamic analysis show that the degree of the co-movement in the housing market is continuously increased. The members of the co-movement group in the capital area are strongly steadied by all periods. However, the members in the non-capital area have been changed according to the period. Accordingly, it is necessary to establish policies based on various information for the housing market of the non-capital area rather than policies targeting the capital area. In addition, Apartments in Korea are more likely to be used as investment or speculative assets than other types of houses. It has been confirmed that this is Gangbuk, which is locatied in the northern part of Seoul, appears to be a region where the Spillover Effects of price fluctuation can be triggered in the housing and apartment market. However, the housing market in Gangnam, which is locatied in the southern part of Seoul, was divided into low systematic risk.