• Journal of Electrochemical Science and Technology
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• v.12 no.1
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• pp.74-81
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• 2021

Silicon (Si) is recognized as a promising anode material for high-energy-density lithium-ion batteries. However, under a condition of electrode comparable to commercial graphite anodes with low binder content and a high electrode density, the practical use of Si is limited due to the huge volume change associated with Si-Li alloying/de-alloying. Here, we report a novel core-shell composite, having a reversible capacity of ~ 500 mAh g-1, by forming a shell composed of a mixture of nano-Si, graphite nanosheets and a pitch carbon on a spherical natural graphite particle. The electrochemical measurements are performed using electrodes with 2 wt % styrene butadiene rubber (SBR) and 2 wt.% carboxymethyl cellulose (CMC) binder in an electrode density of ~ 1.6 g cm-3. The core-shell composites having the reversible capacity of 478 mAh g-1 shows the outstanding capacity retention of 99% after 100 cycles with the initial coulombic efficiency of 90%. The heterostructure of core-shell composites appears to be very effective in buffering the volume change of Si during cycling.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 2007.05a
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• pp.1191-1195
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• 2007

Many approximate models for interaction between a flexible structure and an infinite external acoustic medium have been developed for a long time. Among them, Doubly Asymptotic Approximations (DAAs) are very well known approximations. But, it has shortcomings in intermediate frequency range and can't fully describe the acoustic medium. So, this paper presents the modified approximation by applying the retarded and advanced potentials to Kirchhoff's formula. It describes the external acoustic medium more in detail and shows a good result in early time transient responses when it was applied to a spherical shell. Through a spherical shell interacting with external acoustic medium, the transient responses for the proposed model is compared to Huang's exact solution and DAA2.

• Journal of the Korean Ceramic Society
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• v.46 no.2
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• pp.131-136
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• 2009

Radio frequency (RF) plasma treatment is studied for the size reduction and the spheroidization of coarse particles to change them into nano-sized powders of spherical shape in MLCC fields. The uni-nanoadditives manufactured by RF plasma processing for high dispersion have been investigated for the effect on core-shell structure in dielectrics of MLCC. Microstructures have been characterized using scanning electron microscope (SEM), transmission electron microscope (TEM) and Electron Probe Micro Analyzer (EPMA). We compared the distribution of core-shell grains between specimens manufactured using uni-nanoadditive and using mixed additive. In addition, the uniformity of rare earth elements in the core-shell structured grains was analyzed. It was shown, from TEM observations, that the sintered specimen manufactured using uni-nanoadditives had more dense small grains with well-developed core-shell structure than the specimen using mixed additives, which had a homogeneous microstructure without abnormal grain growth and shows broad temperature coefficient of capacitance (TCC) curves in all temperature ranges because of well dispersed additives.

• Bulletin of the Korean Chemical Society
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• v.28 no.12
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• pp.2279-2282
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• 2007

Highly crystalline, uniform Fe nanoparticles were successfully synthesized and encapsulated in zirconia shell using sol-gel process. Two different approaches have been employed for the coating of Fe nanoparticle with zirconia. The thickness of zirconia shell can be readily controlled by altering molar ratio of Fe nanoparticle core to zirconia precursor in the first case where as reaction time was found to be most effective parameter to controlled the shell thickness in the second method. The structure and magnetic properties of the ZrO2-coated Fe nanoparticles were studied. TEM and HRTEM images show a typical core/shell structure in which spherical α-iron crystal sized of ~25 nm is surrounded by amorphous ZrO2 coating layer. TGA study showed an evidence of weight loss of less than 2% over the temperature range of 50-500 °C. The nanoparticles are basically in ferromagnetic state and their magnetic properties depend strongly on annealing temperature. The thermal treatment carried out in as-prepared sample resulted in reduction of coercivity and an increase in saturation magnetization. X-ray diffraction experiments on the samples after annealing at 400-600 °C indicate that the size of the Fe@ZrO2 particles is increased slightly with increasing annealing temperature, indicating the ZrO2 coating layer is effective to interrupt growing of iron particle according to heat treatment.

• International Journal of Naval Architecture and Ocean Engineering
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• v.8 no.6
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• pp.530-536
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• 2016

The number of fabrication shop for spherical type LNG tank is proportional to that of the tank radius to be constructed. Due to limitation of facility investment including building sites, it is practically difficult to fabricate various size tanks with perfectly spherical shape in the yards. The efficient method to be capable of increasing cargo tank volume is to extend vertically the conventional spherical type LNG tank by inserting a cylindrical shell structure. The main purpose of this study is to derive related equations on forces generated on spherical type LNG tank with central cylindrical part under various static loadings in order to establish the simplified analysis method for the initial estimate. In this study, equations on circumferential and meridional force have been derived and verified by relations with the reaction forces per unit length of equator.

• Publications of The Korean Astronomical Society
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• v.11 no.1
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• pp.27-47
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• 1996

We have performed the high resolution computer simulation with 1D spherical hydrodynamic code in order to study the dynamical evolution of supernova ejecta interacting with a pre-existing fast wind structure. The fast wind structure has been calculated with $M_{in}=3{\times}10^{-6}M_{\odot}yr^{-1}$ and ${\upsilon}_{in}=1000km/sec$, which velocity is higher than the critical velocity relating to the initial radiative cooling. The fast wind becomes initially adiabatic. After a shell formation time of ${\sim}4000yrs$, the wind becomes radiative cooling at the shell zone, forming a thin dense radiative shell and an adiabatic wind bubble afterward. When supernova explodes in the wind center at 20,000yrs after the wind evolves, the supernova ejecta, which has a dense distribution of ${\rho}{\propto}r^{-n}$(here we have n = 9), interacts initially with, the understood wind zone, producing forward and reverse shocks. The reverse shock heats the supernova ejecta and its temperature increases. In this study, as the mass of the supernova ejecta is larger than that of the wind shell ($M_{ej}=5M_{\odot}$, $M_{sw}=2M_{\odot}$), we can conform two shell structures: an outer shell by the supernova ejecta and a secondarily shocked wind shell by it. The secondarily shocked wind shell should accelerates in this case to be R-T unstable, consequently producing the knots.

• Proceedings of the KIEE Conference
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• 2003.04a
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• pp.19-21
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• 2003

일반적으로 PMDC모터에 사용되는 자석은 가격과 재질에 따라서 여러 가지로 분류할 수 있다. 그러나 착자방법에는 등방향과 방사형 착자로 나눌 수 있고 용도에 따라서 다극으로 착자할 수 있다. 하지만 그 기본적인 구조에는 원통형, 판형, 육면체형으로 분류할 수 있는데 구형, 반구형 또는 구형 shell에 관한한 아직까지 소개된 문헌이 빈약하다. 본 논문에서는 슬롯리스 구형직류모터에 사용될 반구형 shell형태의 영구자석의 착자기 구조와 착자방법에 대한 가능성을 찾아보고 이론적으로 증명하고자 한다.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 2001.05a
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• pp.85-89
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• 2001

The problem of the transient interaction of a plane acoustic shock wave which has an infinitely steep wave front with a cylindrical or spherical elastic shell has been studied analytically from early fifties based on the integral transform and series solution techniques. Huang adopted an inverse Laplace transform, and used a finite number of terms of the infinite series expansion of the equations for the shells. In the 1990s, the results have been used by many authors for validation of computer codes. The object of this paper is to discuss the interaction between a moving source and submerged spherical shells. Since the center of source is moving the first contact location between the waves and shell changes depending on the source velocity and distance. These are considered in the analysis. Furthermore, constant source strength and decreasing strength are considered in the analysis. Radial velocities at several locations on the structure are obtained and the results are discussed.

• Proceedings of the Korean Vacuum Society Conference
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• 2010.02a
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• pp.92-92
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• 2010

Replacing the existing illumination with solid-state lighting devices, such as light-emitting diodes (LEDs) are expected to reduce energy consumption and environmental pollution as they provide better efficiency and longer lifetimes. Currently, white light emitting diodes are composed of UV or blue LED with down-converting materials such as highly luminescent phosphors White light-emitting diodes (LED) were fabricated with multi-shell nanocrystal quantum dots for enhanced luminance and improved stability over time. Multi-shell quantum dots (QDs) were synthesized through one pot process by using the Successive Ionic Layer Adsorption and Reaction (SILAR) method. As prepared, the multi-shell QD has cubic lattice of zinc-blend structure with semi-spherical shape with quantum yield of higher than 60 % in solution. Further, highly fluorescent multi-shell QD was deposited on the blue LED, which resulted in QD-based white LED with high luminance with excellent color rendering properties.

• The Bulletin of The Korean Astronomical Society
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• v.35 no.2
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• pp.73.1-73.1
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• 2010

Using the spectroscopic data secured with the Hamilton Echelle Spectrograph attached to a 3-m telescope at the Lick Observatory, we derived the expansion velocities from various line profiles in the 3600 $\AA$ to 10,000 $\AA$ based on the full width at half maximum and double peak of the high dispersion line profiles. The symmetrical shapes of the permitted line profiles indicate that the permitted line zone is symmetrical e.g., a spherical shell or bipolar + torus structures, which might be evidence of relatively recent ejection from the central star. Most other stronger forbidden lines might be coming from a main shell which appears as a bilateral symmetrical morphology, seen in HST and other ground-based telescopic images. The overall expansion velocities of this main shell structure that are responsible for most lines, seem to show the Hubble type expansion, i.e., accelerating shell. The faster expansion velocities of the permitted OII, NII, NIII and perhaps CII lines that do not suit to the Hubble type expansion, imply the existence of a somewhat smaller inner shell inside the outer main shell. We conclude that the nebular shell consists of a swiftly expanding inner shell and an outer normal shell excited by a central star of about 55,000K. The former compact zone appears to be responsible for the permitted C, N, and O lines while the latter extended shell appears to be responsible for H, He, and forbidden lines. We present some evidence that NGC 6833 be a member of the Galactic halo.