• Title/Summary/Keyword: spherical morphology

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Fabrication of Biodegradable Polyphosphazene Microparticles by Electrohydrodynamic Atomization (전기분무에 의한 생분해성 폴리포스파젠 마이크로입자의 제조)

  • Xue, Li-Wei;Cai, Qing;Ryu, Seung-Kon;Jin, Ri-Guang
    • Polymer(Korea)
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    • v.35 no.5
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    • pp.424-430
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    • 2011
  • Biodegradable poly[(glycine ethyl ester)-(phenylalanine ethyl ester) phosphazene](PGPP) microparticles were fabricated by electrohydrodynamic atomization to apply drug release test. Atomization parameters such as applied voltage, polymer concentration, and molecular weight were investigated to inspect their effects on the size and morphology of microparticles. The average diameter of PGPP microparticles decreased as increasing applied voltage and solution flow rate. Dichloromethane/dioxane mixture shows better results for the preparation of microparticles than single solvent owing to the different PGPP solubility in solvent. Blending PGPP polymers with proper molecular weights not only favored the production of spherical PGPP microparticles via electrohydrodynamic atomization, but also provided a way to adjust drug (rifampicin) release behavior. Drug-loaded biodegradable polyphosphazene microspheres can be fabricated via electrohydrodynamic atomization, which has potential use in biomedical applications.

The Characteristics of Resonant Stimulated Raman Scattering in the water droplet (미세 물방울에서의 공명 유도라만산란의 특성)

  • 문희종;김광훈;임용식;고춘수;이재형;장준성
    • Korean Journal of Optics and Photonics
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    • v.6 no.4
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    • pp.337-344
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    • 1995
  • We have detected the resonant stimulated Raman scattering signal when the Q-switched Nd:YAG laser beam are incident on the $35~62{\mu}m$ sized water droplet as pump beam. The signals appeared as uniformly spaced peaks and the intervals between peaks become narrow as the droplet size increases. Also we have confirmed the morphology dependent resonances (MDR's) characteristic of the stimulated Raman scattering signal when the water droplet becomes nearly spherical shape after two water droplets are coupled to a droplet. The error in the measured intervals between MDR's of same mode order is about 5%.out 5%.

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Preparation of Nanosized WO3 Powder by Chemical Vapor Condensation Process

  • Kim, Jin-Chun;Kim, Byoung-Kee
    • Journal of Powder Materials
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    • v.10 no.3
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    • pp.186-189
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    • 2003
  • A chemical vapor condensation (CVC) process using the pyrolysis of metal-organic precursors was applied to produce the nanosized $WO_3$ powders. Morphology and phase changes of the synthesized $WO_3$ powder as a function of CVC parameters were investigated by XRD, BET and TEM. The agglomerated nanosized monoclinic $WO_3$ powders with nearly spherical shape and 10-38 nm in mean diameter could be obtained. Conditions to produce the $WO_3$ nanopowders are presented in this paper.

Characterization and Modification of Low Molecular Water-Soluble Chitosan for Pharmaceutical Application

  • Jang, Mi-Kyeong;Nah, Jae-Woon
    • Bulletin of the Korean Chemical Society
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    • v.24 no.9
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    • pp.1303-1307
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    • 2003
  • The low molecular water-soluble chitosan nanoparticles (LMWSC-NPs) were prepared, which was modified with hydrophilic and hydrophobic moieties to evaluate the potential for pharmaceutics application. The synthesis of LMWSC-NPs was identified by FT-IR and $^1H$-NMR spectra. Also, we measured the photon correlation spectroscopy (PCS), transmission electron microscope (TEM) and atomic force microscope (AFM) to investigate the characteristics and morphology of the LMWSC-NPs. At the PCS measurement, the more increase the number of substitutive group, the more decrease the positive charge of LMWSC-NP surface. From the results of TEM and AFM, spherical morphologies were observed, and their sizes were 30-150 nm. Resultantly, LMWSC-NPs prepared in this experiment will be expected as a suitable device for the drug targeting system.

EVOLUTIONARY MODELS OF ROTATING DENSE STELLAR SYSTEMS WITH EMBEDDED BLACK HOLES

  • FIESTAS, JOSE A.
    • Publications of The Korean Astronomical Society
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    • v.30 no.2
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    • pp.345-347
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    • 2015
  • We present evolutionary models of rotating self-gravitating systems (e.g. globular clusters, galaxy cores). These models are characterized by the presence of an initial axi-symmetry due to rotation. Central black hole seeds are included in our models, and black hole growth due to the consumption of stellar matter is simulated until the central potential dominates the kinematics of the core. Our goal is to study the long-term evolution (Gyr) of relaxed dense stellar systems which deviate from spherical symmetry, and their morphology and final kinematics. With this purpose in mind, we developed a 2D Fokker-Planck analytical code, and confirmed its results using detailed N-Body simulations, applying a high performance code developed for GPU machines. We conclude that the initial rotation significantly modifies the shape and lifetime of these systems, and cannot be neglected in the study of the evolution of globular clusters, and the galaxy itself. Our models give a constraint for the final intermediate black hole masses expected to be present in globular clusters.

Morphological Note of Zygnema cruciatum (Zygnemataceae, Chlorophyta) in Korea

  • Kim, Jee-Hwan;Kim, Young-Hwan
    • ALGAE
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    • v.24 no.2
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    • pp.57-60
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    • 2009
  • We described a freshwater filamentous zygnematacean species, Zygnema cruciatum (Vaucher) Agardh in Korea,based on light microscopy and scanning electron microscopy. Zygnema cruciatum is characterized by unbranched fil-amcnts of short cylindrical cells, two stellate chloroplasts per cell, a pyrenoid in each chloroplast. Cells are 32-39 $\mu$m in width and 35-50 $\mu$m in length, Conjugation is scalariform and female gametangia are cylindrical or slightlyenlarged. Zygospores are yellow-brown, spherical or broadly ovoid, 35-44 $\mu$m wide and 40-47 $\mu$m long. Under SEM, wall of zygospore has pitted mesospore and pits are 1.4-1.8 $\mu$m in diameter and 3-4 $\mu$m apart from each other.

Synthesis of Ag Nanopowder for Low Temperature Heat Treatment Prepared by Liquid Phase Reduction Method (액상환원법에 의한 저온 열처리용 Ag 나노분말의 합성)

  • Lee, Jong-Kook;Choi, Nam-Kyu;Song, Dae-Sung;Yang, Gon-Seung;Seo, Dong-Seok
    • Journal of the Korean Society for Heat Treatment
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    • v.18 no.4
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    • pp.242-246
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    • 2005
  • Silver nanoparticles were synthesized by liquid phase reduction method from aqueous silver nitrate solution and borohybride as a reduction agent. The morphology, particle size and shape were influenced by the reaction conditions such as the concentration of $AgNO_3$, a reduction agent and addition of surfactant. The particle size decreased with decreasing the concentration of silver nitrate and using a borohydride. The obtained Ag particles showed the spherical shape with the range of 10-20 nm.

Organic-Inorganic nani-Composite of PMMA-Forsterite Doped with $Eu^{+3}$

  • Park, Dong Gon;Gang, Jin;Gwon, Hae Yeong
    • Bulletin of the Korean Chemical Society
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    • v.21 no.6
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    • pp.604-610
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    • 2000
  • Drying-step in sol-gel processing was bypassed by exchanging alcoholic solvent in forsterite alcogel directly with MMA. By in-situ polymerization of the MMA, organic-inorganic nano-composite of PMMA-forsterite was prepared. As porous nature of inorganic networks in the gel was preserved and fixated in the composite, spherical morphology of PMMA was resulted. The PMMA-forsterite composite was optically transparent, machinable,mechanically sustainable, and thermally more stable than pristine PMMA. When doped with $Eu^{+3}$, inorganic moiety in the composite provided site environment that is very different from that in pristine PMMA. Prominent $^{5}D_0$$^{7}F_0$ transition at 578 nm, broken degeneracy in $^{5}D_0$$^{7}F_1$ and $^{5}D_0$$^{7}F_2$ transitions suggested that $Eu^{+3}$ was exclusively doped in the inorganic moiety of the composite, which had lower symmetry than the organic counterpart.

New Record of Ciliates, Blepharisma undulans and B. steini (Ciliophora: Heterotrichida: Blepharismidae) from Korea

  • Lee, Eun-Sun;Shin, Mann-Kyoon
    • Animal Systematics, Evolution and Diversity
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    • v.25 no.1
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    • pp.41-47
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    • 2009
  • Two ciliate species of Blepharisma were collected from the riverine wetland and mountain peak soil in Korea, Blepharisma undulans Stein, 1867 and B. steini Kahl, 1932, which are reported for the first time from Korea. The description was based on the observations of live and protargol impregnation specimens. Diagnostics of these species (Blepharisma undulans vs. B. steini) are as follows. Body length/width ratio in vivo about 6/1 vs. 2/1, shaped in spindle vs. pyriform to ellipsoid and colored in pinkish vs. reddish. Macronuclei 2 vs. 1, with 4-9 vs. 4-7 spherical micronuclei. Adoral zone of membranelles extends from anterior end to 1/3 vs. 1/2-2/3 of body length, with 47-56 vs. 33-45 adoral membranelles. The numbers of somatic kineties are 22-27 vs. 18-22.

Ultrastructure of the fertilized egg envelopes in Ancistrus cirrhosus, Loricariidae, Teleostei

  • Dong Heui Kim
    • Applied Microscopy
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    • v.50
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    • pp.13.1-13.7
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    • 2020
  • We examined the morphology of fertilized egg and ultrastructures of fertilized egg envelopes of Ancistrus cirrhosus belong to Loricariidae using light and electron microscopes. The fertilized eggs formed a mass on the spawning place and were yellowish, spherical, non-transparent, demersal, adhesive, and a narrow perivitelline space. But, the adhesiveness of fertilized eggs was disappeared after spawning excluding contact parts. The micropyle with funnel shape was surrounded by 15-19 furrow lines of egg envelope in a spoke-like pattern. The outer surface of egg envelope has smooth side and inner surface of egg envelope was rough with grooves. Also, the total thickness of the fertilized egg envelope was about 32.58 ± 0.85 ㎛ (n = 20), and the fertilized egg envelope consisted of three layers, an outer adhesive electron-dense layer, a middle layer with low electron density and an inner electron-dense layer with grooves in counter structure from other most teleost. Collectively, these morphological characteristics and adhesive property of fertilized egg, and ultrastructures of micropyle, outer surface, and section of fertilized egg envelope are showed species specificity.