• Title/Summary/Keyword: spectrum gap

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Temperature Driven Phase Transition of Organic-Inorganic Halide Perovskite Single Crystals

  • Byun, Hye Ryung;Kim, Hyo In;Byun, Su Jeong;Park, Dae Young;Jeong, Mun Seok;Byeon, Clare Chisu
    • Journal of the Korean Physical Society
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    • v.73 no.11
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    • pp.1729-1734
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    • 2018
  • Organic-inorganic halide perovskite single crystals undergo phase transition of being cubic, tetragonal, or orthorhombic depending on the temperature. We investigated the $CH_3NH_3PbBr_{3-x}I_x$ single crystals grown by the inverse temperature crystallization method with temperature-dependent UV-Vis absorption and photoluminescence. From the temperature-dependent absorption measurement, the optical band gap is extracted by derivation of absorption spectrum fitting and Tauc plot. In our results, $CH_3NH_3PbBr_{3-x}I_x$ single crystals show that an abrupt change in optical band gap, PL peak position and intensity appears around 120 K - 170 K regions, indicating the phase transition temperature.

Optical Properties of ZnHgGa4Se8 and ZnHgGa4Se8:Co2+ Single Crystals

  • Lee Choong-Il
    • Korean Journal of Materials Research
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    • v.15 no.10
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    • pp.657-661
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    • 2005
  • [ $ZnHgGa_4Se_8\;and\;ZnHgGa_4Se_8::Co^{2+}$ ] single crystals were grown by the Bridgman-Stockbarger method. The single crystals crystallized into a defect chalcopyrite structure. The optical energy band gap of the single crystals was investigated in the temperature range 11-300K. The optical energy band gap of the $ZnHgGa_4Se_8:Co^{2+}$ single crystal was smaller than that of the $ZnHgGa_4Se_8$ single crystal. The temperature dependence of the optical energy band gap of the single crystals was well fitted by the Varshni equqtion. The impurity optical absorption spectrum of the $ZnHgGa_4Se_8:Co^{2+}$ single crystal was measured in the wavelength region 300-2300 m at 80 K. Impurity absorption peaks in the spectrum were analyzed within the framework of the crystal field theory and were attributed to the electron transitions between the energy levels of $Co^{2+}$ sited in the Td symmetry point.

Modal Analysis of Point and Discretized Continuous Spectra for Metal-Insulator-Metal Waveguides in the Terahertz Region

  • Hur, Jun;Choo, Hosung;Park, Jong-Eon
    • Journal of Electrical Engineering and Technology
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    • v.13 no.4
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    • pp.1644-1654
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    • 2018
  • Eigenvalue distributions for a periodic metal-insulator-metal waveguide, classified into the point spectrum and the discretized continuous spectrum (DCS), are investigated as functions of frequencies, gap widths, and periods. Muller's method is suggested for solving exact eigenvalues, and we propose the scheme for finding proper initial values in the Muller's method by considering only ${\Re}e({\varepsilon}_r)$ in the dispersion equation. We then find that anti-crossing behavior, repulsive effect between the point spectrum and the DCS, becomes stronger when the real parts of the roots in the point spectrum have smaller values. Finally, we examine the transmittances of a single subwavelength slit for real metals using the mode matching technique. The transmittances in real metals similarly follow those of the perfect electric conductor (PEC) at low frequencies, while the patterns at higher frequencies begin to differ from the PEC.

The Growth Characteristics of ${\beta}\;-FeSi_2$ as IR-sensor Device for Detecting Pollution Material : The Usage of the Ferrocene-Plasma

  • Kim, Kyung-Soo;Jung, II-Hyun
    • Journal of environmental and Sanitary engineering
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    • v.15 no.2
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    • pp.102-111
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    • 2000
  • As IR-sensor for detecting pollution material, the iron silicide has a fit band gap, high physicochemical stability at high temperature and good acid resistance. The growing film was formed with the Fe-Si bond and the organic compound because plasma resolved the injected precursors into various active species. In the Raman scattering spectrum, the Fe-Si vibration mode showed at 250 {TEX}$cm^{-1}${/TEX}. The FT-IR peak indicated that the various organic compounds were deposited on the films. The iron silicide was epitaxially grown to β-phase by the high energy of plasma. The lattice structure of films had [220]/[202] and [115]. The thickness of the films increased with the flow rate of silane. But rf-power increased with decreasing the thickness. The optical gap energy and the band gap were shown about 3.8 eV and 1.182∼1.194 eV. The band gap linearly increased and the formula was below: {TEX}$E_g^{dir}${/TEX}= 8.611×{TEX}$10^{-3}N_{D}${/TEX}+1.1775

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Comparison of Performance of Models to Predict Hardness of Tomato using Spectroscopic Data of Reflectance and Transmittance (토마토 반사광과 투과광 스펙트럼 분석에 의한 경도 예측 성능 비교)

  • Kim, Young-Tae;Suh, Sang-Ryong
    • Journal of Biosystems Engineering
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    • v.33 no.1
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    • pp.63-68
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    • 2008
  • This study was carried out to find a useful method to predict hardness of tomato using optical spectrum data. Optical spectrum of reflectance and transmittance data were collected processed by 9 kind of preprocessing methods-normalizations of mean, maximum and range, SNV (standard normal variate), MSC (multiplicative scatter correction), the first derivative and second derivative of Savitzky-Golay and Norris-Gap. With the preprocessed and non-processed original spectrum data, prediction models of hardness of tomato were developed using analytical tools of PLS (partial least squares) and MLR (multiple linear regression) and tested for their validation. The test of validation resulted that the analytical tools of PLS and MLR output similar performances while the transmittance spectra showed much better result than the reflectance spectra.

C 1s photoelectron energy loss spectra of organic electroluminescent materials

  • Lee, J.W.;Kim, T.H.
    • Journal of Korean Vacuum Science & Technology
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    • v.4 no.1
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    • pp.1-5
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    • 2000
  • The C 1s photoelectron energy loss spectra of tris (8-hydroxy-quinoline) aluminum (Alq$_3$) and N,N'-diphenyl-N,N'-bis (3-methyl phenyl)-1,1'-bi-phenyl-4,4'-diamine (TPD) thin films have been investigated. Two major loss structures, namely the plasmon dominated loss lines and shake-up satellites, have been observed. The shake-up spectrum of the C 1s photoelectron line is directly related to the $\pi$-$\pi$$\^$*/ energy gap of the molecule which plays an important role in organic electroluminescent materials. The molecular orbitals of Alq$_3$ and TPD and their major components, quinolime and benzene, have been calculated with the AMI semi-empirical method. The amount of the plasma-dominated loss of Alq$_3$ and TPD, which has to do with the delocalization of electrons through the molecule, was about 24 eV, alike in both cases. The main peak of the C 1s shake-up spectrum of Alq$_3$ and TPD, however, was 5.2 eV and 6.8 eV respectively. It was found that the main shake-up peak reflects more the local $\pi$\longrightarrow$\pi$$\^$*/ transition of quinoline and benzene component rather than the excitation of the whole molecule of Alq$_3$ and TPD. The C 1s shake-up spectra, however, revealed some correlation with the optical energy gap of the organic eletroluminescent materials.

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Trichel Pulse in Negative DC Corona discharge and Its Electromagnetic Radiations

  • Zhang, Yu;Liu, Li-Juan;Miao, Jin-Song;Peng, Zu-Lin;Ouyang, Ji-Ting
    • Journal of Electrical Engineering and Technology
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    • v.10 no.3
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    • pp.1174-1180
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    • 2015
  • We investigate in this paper the radiated electromagnetic waves together with the discharge characteristics of Trichel pulse of negative DC corona discharge in air in pin-to-plate and wire-to-plate configurations. The feature of the current pulse and the frequency spectrum of the electromagnetic radiations were measured under various pressures and gas gaps. The results show that the repetition frequency and the amplitude of Trichel pulse current depend on the discharge conditions, but the rising time of the pulse relates only to the radius of needle or wire and keeps constant even if the other conditions (including the discharge current, the gas gap and the gas pressure) change. There exists the characterized spectrum of electromagnetic waves from negative corona discharge in Trichel pulse regime. These characterized radiations do not change their frequency at a given cathode geometry even if the averaged current, the gas gap or the air pressure changes, but the amplitude of radiations changes accordingly. The characterized electromagnetic radiations from Trichel pulse corona relate to the formation or the rising edge of current pulse. It confirms that the characterized radiations from Trichel pulse supply information of discharge system and provide a potential method for detecting charged targets.

A half subcarrier guard band spectrum assignment scheme for multi-user FBMC systems

  • Huang, Wei;Xu, Hongbo;Li, Zhongnian
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.16 no.1
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    • pp.350-364
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    • 2022
  • Traditionally, in multi-user multi-carrier systems, the neighboring subband will be gapped by one subcarrier, which is set as guard band to reduce multiple access interference (MAI) between neighboring subbands. The empty subcarrier for guard band will degrade the spectral efficiency of the whole system. In order to enhance the spectral efficiency of multi-user filter bank multiple carrier (FBMC) systems, a new subband allocation method is introduced, in which the neighboring subband is gapped by half subcarrier instead of one subcarrier. Meanwhile, in order to implement the proposed resource allocation scheme, an optimized FBMC prototype filter is designed to decrease the inter-subband interference to the neighboring subband. The detailed simulations about the comparison between the proposed spectrum assignment and traditional FBMC are given, as well as the performance in the different interference scenarios. The simulation results show that the combination of the proposed spectrum assignment scheme and the optimized filter has better performance compared to the traditional scheme. The proposed scheme can be used in the system which serves massive users to get higher spectrum efficiency.