• 제목/요약/키워드: spectroscopic methods

검색결과 638건 처리시간 0.03초

Two Alkaloids from Ephedra aphylla growing in Egypt

  • Abdel-Kader, Maged S.;Kassem, Fahima F.;Abdallah, Rokia M.
    • Natural Product Sciences
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    • 제9권2호
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    • pp.52-55
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    • 2003
  • The aerial parts of Ephedra aphylla afforded two alkaloids belonging to two different classes. The first alkaloid, ephedradine C, belonging to the spermine alkaloid, a group characterized by its hypotensive effect. The other alkaloid, hordenine is a phenylalkylamine alkaloid isolated for the first time from Ephedra Species. The structures were elucidated by spectroscopic methods and the assignment of some carbons in ephedradine C was achieved based on 2 D-NMR experiments.

Flavan-3,4-diol Derivatives from the Heartwood of Robinia pseudoacacia

  • Bae, Young-Soo
    • Journal of the Korean Wood Science and Technology
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    • 제29권3호
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    • pp.99-103
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    • 2001
  • Three flavan-3,4-diol derivatives were isolated from the heartwood of Robinia pseudoacacia and characterized by spectroscopic methods including $^1H$ and $^{13}C$ NMR and positive FAB-MS. The structures were identified as 4,4'-dimethoxy-, 4-ethoxy- and 4-ethoxy-4'-methoxy-2,3-trans-3,4-cis-(+)-leucorobinetinidin.

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황촉규 지상부의 성분분리 및 항산화활성 (Phytochemical Constituents and Antioxidant Activities of the Aerial Parts of Hibiscus manihot)

  • 박은영;양기숙
    • 약학회지
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    • 제54권3호
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    • pp.164-167
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    • 2010
  • Column chromatographic separation of the MeOH extract from the aerial parts of Hibiscus manihot led to the isolation of four compounds. Their structures were characterized to be hentriacontane (1), palmitic acid (2), daucosterol (3) and 3-dihydrocaffeonyl-5-p-coumaroylquinic acid (4) by spectroscopic methods. The compounds (1~4) were for the first time reported from this plant. The solvent fractions were tested for their antioxidant activities by free radical scavenging and superoxide dismutase (SOD).

Removing Telluric Absorbtion lines for IGRINS spectra

  • Jeong, Gwanghui;Han, Inwoo;Lee, Byeong-Cheol
    • 천문학회보
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    • 제41권1호
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    • pp.78.2-78.2
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    • 2016
  • There are many telluric absorption lines which are laid on the science spectrum in ground based spectroscopic observations. In especial, the IR region spectra are considerably contaminated by telluric lines. Therefore, many scientists have a difficulty in removing the telluric effect. We thus tried removing telluric lines with IGRINS data by two methods. One is using the standard stellar spectrum as telluric lines. The other adopt calculated synthetic telluric spectrum. Here we present the results of test for precise removing telluric lines on IGRINS spectra.

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Novel and Efficient Synthesis of Tetrazolo[1,5-b]-1,2,5-oxadiazepines as Antibacterial Activities from Ethyl 1-aminotetrazole-5-carboxylate

  • El-Badry, Susan M.;Taha, Mamdouh A.M.
    • 대한화학회지
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    • 제55권6호
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    • pp.974-977
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    • 2011
  • Ethyl 1-aminotetrazole-5-carboxylate (1) has been utilized to construct a variety of novel tetrazolo [1,5-b]-1,2,5-oxadiazepine derivatives which repesent a relatively little explored group with interesting antibacterial activities. The synthesized compounds were elucidated using IR, $^1H$ NMR and mass spectroscopic methods, besides elemental analyses.

Antioxidant Polyphenol Glycosides from the Plant Draba nemorosa

  • Rahman, Md. Aziz Abdur;Moon, Surk-Sik
    • Bulletin of the Korean Chemical Society
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    • 제28권5호
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    • pp.827-831
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    • 2007
  • Bioassay-directed fractionation of Draba nemorosa led to the isolation of two new phenolic glycosides, 1-O- (sinapoyl)-glucitol (2) and 1,3-disinapoylgentiobiose (5) along with five known phenolic glycosides (1, 3, 4, 6, and 7). Their structures were characterized based on spectroscopic methods (2D NMR, HRTOFMS, IR, and UV). The isolated compounds showed antioxidant activities (IC50) in the range of 14-98 mM which were estimated by DPPH radical-scavenging assay.

섬쑥부쟁이의 테르페노이드 성분 (Terpenoids from the Aerial Parts of Aster glehni)

  • 민용득;권학철;최상진;이강노
    • 약학회지
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    • 제48권1호
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    • pp.65-69
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    • 2004
  • The chromatographic separation of MeOH extract of the aerial parts of Aster glehni (Compositae) led to the isolation of three sesquiterpenes, two sterols and four terpenes. Their structures were determined to be $\beta$-amyrin acetate (1), phytol (2), alismol (3), $\alpha$-tocopheryl quinone (4), $\alpha$-spinasterol (5), 10-O-methyl alismoxide (6), alismoxide (7), and 3-O-(6'-O-palmitoyl-$\beta$-D-glucosyl)-spinasta 7,22-diene (8) by physicochemical and spectroscopic methods . These compounds (1-8) were first isolated from the Aster glehni.

Structural and Spectral Characterization of a Chromium(III) Picolinate Complex: Introducing a New Redox Reaction

  • Hakimi, Mohammad
    • 대한화학회지
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    • 제57권6호
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    • pp.721-725
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    • 2013
  • Reaction between 2-pyridinecarboxylic acid (Hpic) and $K_3[Cr(O_2)_4]$ give complex $[Cr(pic)_3].H_2O$ (1) which is characterized by elemental analysis and spectroscopic methods (FT-IR, Raman) and X-ray crystallography. In the crystal structure of 1, chromium atom with coordinated by three nitrogen and three oxygen atoms has a distorted octahedral geometry. Also a water molecule is incorporated in crystal network. Each water molecule acts as hydrogen bond bridging and connects two adjacent complexes by two $O-H{\cdots}O$ hydrogen bonds.