• Journal of the Korea institute for structural maintenance and inspection
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• v.23 no.3
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• pp.92-95
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• 2019

In this paper, a novel laser-based non-contact and non-destructive stress measurement technique is newly proposed for measuring stress in steel structural members. As the demand of stress monitoring in structural members is increased, various non-destructive techniques are being applied to the field of structural health monitoring. Spectroscopic techniques are non-contact technique and widely used for chemical identification of target materials. Especially, piezospectroscopic technique is a residual stress measurement technique in thermal barrier coatings. Although the piezospectroscopic technique has high possibility of measuring structural stress in steel members, the technique has been rarely applied to this field. In this paper, piezospectroscopy-based stress measurement technique is, therefore, proposed for measuring stress in steel structural member. To do that, alumina particles have been coated onto a specimen of a structural steel rod using a thermal spray coating technique. And then, an uniaxial compression test has been conducted to the specimen to collect each fluorescence spectrum under different loading conditions. Finally, the linear relation of spectral shift and applied compressive stress of the specimen has been experimentally established.

• Natural Product Sciences
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• v.6 no.4
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• pp.193-198
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• 2000

Phytochemical study of the constitutive polyphenolics of the flower aqueous alcohol extract of Tamarix tetragyna was carried out. The new sulphated flavonol, quercetin 3',4'-dimethyl ether $3-O-KSO_3$ as well as the new natural galloyl glucose, $2-O-galloyl-({\alpha}/{\beta})-^4C_1-glucopyranose$ were isolated and characterized. The known sulphated flavonols, kaempferol 7,4-dimethyl ether $3,5-di-O-KSO_3$, quercetin 7-methyl ether $3,3',4'-tri-O-KSO_3$, quercetin 7,4'-dimethyl ether $3-O-KSO_3$ and quercetin $3-O-KSO_3$ and the known sulphated phenolics, isoferulic acid $3-O-KSO_3$ and ellagic acid 4,4'-dimethyl ether $3-O-KSO_3$ were also separated and identified. The structures were established by conventional methods of analysis and confirmed by $^1H-,\;^{13}C-NMR$ and negative ESI-mass spectrometry. 2D-homonuclear chemical shift correlation NMR experiment was applied for the new natural galloylglucose.

• Ocean Science Journal
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• v.42 no.1
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• pp.49-59
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• 2007

Besides empirical algorithms with the blue-green ratio, the algorithms based on fluorescence are also important and valid methods for retrieving chlorophyll-a concentration in the ocean waters, especially for Case II waters and the sea with algal blooming. This study reviews the history of initial cognitions, investigations and detailed approaches towards chlorophyll fluorescence, and then introduces the biological mechanism of fluorescence remote sensing and main spectral characteristics such as the positive correlation between fluorescence and chlorophyll concentration, the red shift phenomena. Meanwhile, there exist many influence factors that increase complexity of fluorescence remote sensing, such as fluorescence quantum yield, physiological status of various algae, substances with related optical property in the ocean, atmospheric absorption etc. Based on these cognitions, scientists have found two ways to calculate the amount of fluorescence detected by ocean color sensors: fluorescence line height and reflectance ratio. These two ways are currently the foundation for retrieval of chlorophyll-a concentration in the ocean. As the in-situ measurements and synchronous satellite data are continuously being accumulated, the fluorescence remote sensing of chlorophyll-a concentration in Case II waters should be recognized more thoroughly and new algorithms could be expected.

• Korean Journal of Pharmacognosy
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• v.27 no.1
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• pp.26-31
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• 1996

A sesquiterpene ortho-naphtpoquinone was isolated from the 80% aqueous methanolic extract of root bark of Ulmus davidiana Planch whose stem and root bark have been used as an oriental medicine for the treatment of edema, mastitis, gastric cancer and inflammation. On the basis of spectral data obtained from UV-vis, IR, HR-EIMS and NMR spectrometry, including the pulse field gradient (PFG) HMQC and HMBC techniques, the structure of this compound was determined as 2,3-dihydro-3-hydroxy-3,6,9-trimethylnaphtho(1,8-b,c)pyran-7,8-dione which has been known as mansonone 1. This compound has been isolated only from the heart-wood of Mansonia altissima Chev, a Sterculiacea from West Africa. Thus, this compound was isolated for the second time from natural source in this study. This is the first report to present the carbon chemical shift assignment of mansonone I.

• Information and Communications Magazine
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• v.16 no.10
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• pp.112-124
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• 1999

본 논문에서는 FTTC/VDSL (Fiber-to-the-Curb/Very High-speed Digital Subscriber Line) 전송시스템의 개발동향과 ANSI, ETSI, ITU등의 표준화 위원회에서 현재 진행중인 VDSL 시스템의 표준화 작업에 대해 기술하였다. 특히, POTS (Plain Old Telephone Service), BA-ISDA(Basic Access Integrated Services Digital Network), HDSL(High-rate Digital Subscriber Line), SDSL (Single-pair HDSL), ADSL(Asymmetric Digital Subscriber Line) 등의 다양한 xDSL (Digital Subscriber Line) 서비스들에서 발생하는 NEXT (Near-end Crosstalk)/FEXT (Far-end Crosstalk)와 같은 crosstalk를 최소화하기 위해 제안된 VDSL시스템의 주파수 대역과 PSD (Power Spectral Density) mask에 관해 설명하고, 순방향(down-stream) 채널과 역방향(upstream) 채널의 데이터 전송률이 대칭적인 VDSL전송시스템과 비대칭적인 VDSL 전송시스템 간의 주파수대역의 호환성 문제, RFI(Radio Frequency Interference) ingress/egress 문제의 해결 방안에 관해 기술하였다. 또한, 현재 VDSL Coalition과 VDSL Alliance 간에 논의 중인 VDSL 전송시스템의 변복조 방식에 관한 표준화 작업과정 및 순방향과 역방향에 할당될 band 개수에 따른 시스템 성능의 장단점 등에 관해 살펴보았다. 끝으로 현재 국내에서 개발되고 있는 FTTC/VDSL 전송시스템의 전체구조를 요약하고, 네트워크에서 가입자쪽으로 순방향 데이터 전송에 사용된 51.84 Mb/s 19-CAP (Carrierless Amplitude/Phase Modulation) 전송시스템과 가입자 댁내에서 네트워크 방향으로 역방향 데이터 전송에 사용된 1.62 Mb/s QPSK (Quadrature Phase Shift Keying) burst-mode TDMA (Time Division Multiple Access) 전송시스템 등의 동작 원리 및 구조를 기술하였다.

• Bulletin of the Korean Chemical Society
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• v.35 no.10
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• pp.3035-3040
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• 2014

A new efficient catalytic method for aza/thia-Michael addition reactions of amines/thiols with higher product yields has been developed. Combining single-walled carbon nanotubes (SWCNT) with triethylammonium hydrogen phosphate (TEAP) ionic liquid (IL) can work as a catalyst. We utilized Raman spectroscopy to gain insight into the interactions between IL and SWCNT. The interactions between SWCNT with TEAP were confirmed by the increasing intensity ratios and spectral shift in wavelength of the Raman D and G bands of SWCNT. Further, the morphology of the resulting composite materials of TEAP and SWCNT was determined by using scanning electron microscopy (SEM). Higher product yield in reduced reaction time is the key advantage of using bucky gel as a catalyst for Michael reaction.

• Current Optics and Photonics
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• v.1 no.4
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• pp.372-377
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• 2017

We demonstrate that the local resonance of metamaterials can be tuned by the effects of organic thin films under photoexcitation. Tris (8-hydroxyquinolinato) aluminum ($Alq_3$) layers are deposited on metamaterial/silicon hybrid structures. By varying the thickness of the $Alq_3$ layer on the subwavelength scale, the resonant peak of the metamaterial becomes very adjustable, due to the effect of a thin dielectric substrate. In addition, under photoexcitation all the spectral peaks of the resonance shift to higher frequencies. This originates from the reduction of the capacitive response generated inside the gaps of split-ring resonators. The adjustability of the electromagnetic spectrum may be useful for developing optical systems requiring refractive-index engineering and active optical devices.

• Bulletin of the Korean Chemical Society
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• v.34 no.10
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• pp.2895-2899
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• 2013

Direction of intercalation to DNA of the planar dipyrido[3,2-a:2',3'-c]phenazine ligands (dppz) of a bis-Ru(II) complex namely, $[Ru(1,10-phenanthroline)_2dipyrido[3,2-a:2^{\prime},3^{\prime}-c]phenazine]^{2+}$ linkered by a 1,3-bis(4-pyridyl)propane, was investigated by probing the behavior of 4',6-diamidino-2-phenylindole (DAPI) that bound deep in the minor groove. Bis-intercalation of DPPZ resulted in a little blue shift and hyperchromism in DAPI absorption band, and a large decrease in DAPI fluorescence intensity which accompined by an increase in the dppz emission intensity. Diminishing the intenisty of the positive induced circular dichroism (CD) and linear dichroism (LD) were also observed. These spectral changes indicated that insertion of dppz ligand caused the change of the binding mode of DAPI, which probably moved to the exterior of DNA from the minor groove and interacted with the phospghate groups of DNA by electrostatic interaction. At the surface of DNA, DAPI binds at the phosphate groups of DNA by electrostatic attraction. Consequently, this observation indicated that the dppz ligand intercalated from the minor groove.

• Korean Journal of Materials Research
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• v.17 no.9
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• pp.489-492
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• 2007

Temperature and injection current dependence of elctroluminescence(EL) spectral intensity of the $In_{0.27}Ga_{0.73}N/GaN$ multi-quantum-well(MQW) have been studied over a wide temperature and as a function of injection current level. EL peaks also show significant broadening into higher photon energy region with the increase of injection current. This is explained by the band-filling effect. When temperature is slightly increased to 300 from 15 K, the EL emission peak showed red-blue-red shift. It can be explained by the carrier localization by potential fluctuation of multiple quantum well and band-gap shrinkage as temperature increase. It is found that a temperature-dependent variation pattern of the EL efficiency under very low and high injection currents show a drastic difference. This unique EL efficiency variation pattern with temperature and current is explained field effects due to the driving forward bias in presence of internal(piezo and spontaneous polarization) fields.

• Journal of Institute of Control, Robotics and Systems
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• v.14 no.2
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• pp.197-204
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• 2008

The purpose of this paper was to develop a rehabilitation training system which is controlled by electric currents to the Magneto-Rheological dampers system. This system provided the function for the training of the unbalance of the lower extremities. 10 subjects executed the tracing and moving exercises which are presented through the display monitor and confirmed own the capability of performance on the task. The electromyographies of the four muscles in lower extremities were recorded and analyzed in the time and frequency domain the muscles of interest were rectus femoris, biceps femoris, gastrocnemius, tibialis anterior. The experimental results showed that subjects had a task under feedback mode then subjects improve the capability of performance, increasing the in time, decreasing the out time and the distance of body shift. The moving average EMG, spectral energy of four muscle is lower the feedback mode than the constant mode. This could aid the hemiplegic patients to train more easily.