• 임산에너지
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• 제21권2호
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• pp.17-24
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• 2002

소나무 수피로 부터 수증기 활성화 의하여 활성탄을 제조하였으며, 제조된 활성탄은 세공 구조 및 표면적에 대한 검토를 행하였다. 활성화를 위하여 3종류의 서로 다른 형태의 로(정치식 수직, 수평로 및 회전식 수평로)가 본 실험에 사용되었다. 정치식 수직 및 수평로를 이용하여 수피를 탄화시키고 이를 수증기 활성화시키면, 1,000 ㎡／g이상의 높은 비표면적을 얻기는 어려웠다. 분말상태의 시료를 사용하면 비표면적이 약간 향상되었지만, 여전히 정치식 로의 경우 높은 비표면적의 결과를 얻기는 어려웠다. 로타리식 수평로에서 수피를 수증기 활성화시키면, 시판 1급 활성탄과 유사한 1,000 ㎡／g 이상의 비표면적을 나타내는 활성탄을 제조할 수 있었다. 로타리식 수평로에서 제조된 활성탄은 미세공에서 중세공까지 다양한 공극 분포를 나타내었다.

• Carbon letters
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• 제8권1호
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• pp.30-36
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• 2007

Oxidized PAN (OXI-PAN) fibers were used for the precursors of activated carbon fiber in study. How drying temperature affected the properties of carbon fibers on activating process of carbon fibers was investigated. The specific surface areas of activated carbon fibers have been determined on a series of chemically activated carbons with KOH and NaOH. The experimental data showed variations in specific surface area, iodine and silver adsorptions by the activated carbon fibers. The amount of iodine adsorption increases with increasing specific surface areas in both activation methods. This was because the ionic radius of iodine was smaller than the interior micropore size of activated carbon fibers. Silver adsorbed well in NaOH activated carbon fibers rather than KOH activated carbon fibers in this study.

• Journal of the Korean Wood Science and Technology
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• 제23권1호
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• pp.54-60
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• 1995

This paper reports on the changes of equilibrium moisture contents and specific surface areas of Poplar wood(Populus euramericana) for various steam explosion treatments. Equilibrium moisture contents(EMC) and specific surfaces of steam exploded woods were measured under the moisture adsorption course at 25$^{\circ}C$, and compared with those of other materials and wood meals. The EMCs of steam exploded wood meal were 1~5% less in comparison with that of wood meal. In the case of delignified steam exploded wood meal and delignified wood meal, the same tendency was appeared too. But absolute values of EMCs for delignified wood meals were larger than those of the wood meal. For the changes of EMC by the steam exploded conditions, the EMC decreased with the increase of the steam explosion pressure. On the other hand, specific surface areas were calculated from BET plots based on amounts of monomolecular vapor adsorption of various wood meals. Specific surface areas of the wood meal and delignified wood meal were 90~145, 34~90($m^2/g$) respectively, and which were greater in comparison with those of steam exploded wood meals and delignified steam exploded wood meals. From these results, it is considered that the amount of water vapor adsorption was decreased by the increase of the crystallinity, effect of heat treatment, and coating by melted lignin in during the steam explosion.

• 약학회지
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• 제29권4호
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• pp.176-182
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• 1985

As a part of the studies on adsorptive properties of Korean halloysite clays, Hadong white clays of premium grade were examined for geometric pore structured by mercury porosimetry and for specific surface areas by nitrogen adsorption according to the BET procedure. Three size fractions of the native clay sample were derived from passage BS #100, #200 and #325 meshes, respectively. Several parameters lhus observed in relation to the pore structures are shown below: 1. The size fraction of BS #100, #200 and #325 show internal pore volumes of 25.3, 30.2 and $35.0m^2g^{-1}$, respectively. 2. In the distribution curves of the cumulative pore volume against pore diameter, it has been shown that the larticle sizes, the steeper the distribution over the larger ranges of pore diameters. The converse is true the smaller particles. 3. Internal pore areas increase with decrease in pore sizes. It follows that the pores having diameters of $\leq$0.1$\mu\textrm{m}$ are responsible for more than 90% of the total pore area. 4. The behaviour of nitrogen adsorption can be best described by BET type IV isotherm. Further, the hysteresis loops of the adsorptiondesorption curves become narrower with decresing particle sizes. 5. The specific surface areas observed for the fractions of BS #100, BS #200 and BS #325 are 34.6, 35.4 and 43.2m $^2g^{-1}$, respectively. and the calcined clay of BS #325 has a specific surface area near $30.4m^2g^{-1}$.

• Carbon letters
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• 제4권2호
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• pp.86-92
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• 2003

A series of micro- and mesoporous activated carbons were prepared from two kinds of phenolic resin using a metal treated chemical activation methodology. $N_2$-adsorption data were used to characterize the surface properties of the produced activated carbons. Results of the surface properties and pore distribution analysis showed that phenolic resin can be successfully converted to micro- and mesoporous activated carbons with specific surface areas higher than 973 $m^2/g$. Activated carbons with porous structure were produced by controlling the amount of metal chlorides ($CuCl_2$). Pore evolvement depends on the amount of additional metal chloride and precursors used. From the SEM and EDX data, copper contents were shown to be most effected by the incremental addition of metal chloride.

• 한국응용과학기술학회지
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• 제28권2호
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• pp.225-231
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• 2011

The electrochemical characteristics of electric double layer capacitor(EDLC) were investigated using various carbon materials. The physical properties such as specific surface area and mean pore size of activated carbon were analyzed by BET. The results of the activated carbon used for electrode material showed that the specific surface areas varied from 600 to 1500 $m^2$/g and mean pore sizes from 1.74 to 2.88 nm. A maximum specific capacitance of 0.30 F/$cm^2$ was obtained for the activated carbon with the highest specific surface area and ionic conductivity. Also, it was found that the electrochemical results of the cyclic charge-discharge tests were stable.

• Carbon letters
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• 제4권4호
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• pp.168-174
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• 2003

Silver nitrate ($AgNO_3$) powder was mixed into a reformed pitch precursor. Then, the silver-containing pitch was melt spun to form round and "C" shape fibers. A wire mesh was inserted prior to the nozzle to improve the spinnability of the silvercontaining precursor pitch. Silver particles in the carbon fibers (CFs) were detected by XRD and TEM. These tests showed that silver particles were uniformly distributed and the total amount of silver remained constant during stabilization and carbonization. Next, the silver-containing CFs were activated by steam diluted in nitrogen gas. Silver particles accelerated the activation rate, but the specific surface areas of the silver-containing ACFs were similar to those of non-silver containing ACFs at the same burn-off levels. The specific surface area of the C-shaped activated carbon fibers was larger than that of the round activated carbon fibers. The likely reason is that the surface area of a C-shaped CF is about two times larger than that of a round CF when equivalent cross-sectional areas are compared. A small amount of silver particles in the periphery of the CFs was removed during the activation, but the remainder of silver was stayed within the ACFs.

• The Korean Journal of Ceramics
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• 제4권3호
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• pp.245-248
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• 1998

Porous carbon fiber composites (CFCs) having variable specific surface area ranging 35~1150 $\m^2$/g were reacted to produce silicon carbide fiber composites with SiO vapor generated from a mixture of Si and $SiO_2$ at 1673 K for 2 h under vacuum. Part of SiO vapor generated during conversion process condensed on to the converted fiber surface as amorphous silica. Chemical analysis of the converted CFCs resulting from reaction showed that the products contained 27~90% silicon carbide, 7~18% amorphous silica and 3~63% unreacted carbon, and the composition depended on the specific carbide, 7~18% amorphous silica and 3~63% unreacted carbon, and the composition depended on the specific surface area of CFCs. CFC of higher specific surface area yielded higher degree of conversion of carbon to silicon and conversion products of lower mechanical strength due to occurrence of cracks in the converted caron fiber. As the conversion of carbon to silicon carbide proceeded, pore size of converted CFCs increased as a result of growth of silicon carbide crystallites, which is also linked to the crack formation in the converted fiber.

• 한국세라믹학회지
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• 제28권2호
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• pp.146-152
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• 1991

Ultra fine and homogeneous (Ni0.4Zn0.6)Fe2O4 ferrite powders were prepared by direct-wet, Hydrothermal and coprecipitation methods. In case that specific surface areas of Ni-Zn ferrite powders were over 220㎡/g, 100㎡/g, 30㎡/g individually direct-wet, hydrothermal and coprecipitation methods. The Ni-Zn ferrite magnetic fluids of which Solvents were benzene or kerosene was prepared by making cation surfactant adsorbed on the surface of the (Ni0.4Zn0.6)Fe2O4. The results that measured dispersion and viscosity by making cation surfactant adsorbed were as follows. 1. The adsorption amount of Oleric acid be proportioned the specific surface area of powders. 2. The maximum amount of Oleric acid was 36wt% of dried powders which has 220㎡/g of specific surface area. 3. The stability of fluid by direct-wet synthesis emthod in benzene or kerosene solvent excellent.

• Bulletin of the Korean Chemical Society
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• 제22권7호
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• pp.678-684
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• 2001

Porous silica-pillared montmorillonites were prepared by simultaneous intercalation of dodecylamine-TEOS [tetraethylorthosilicate, Si(OC2H5)4] into the H-montmorillonite and intragallery amine-catalyzed hydrolysis of TEOS. Mixtures of the H-montmorillonite, dodecylamine and TEOS at molar ratios of 1 : 2 : 15-30 and 1 : 2-6 : 20 resulted to swollen and viscous gel once at room temperature, allowing intercalation compounds which dodecylamine and TEOS were simultaneously intercalated into interlayer of H-montmorillonite. The hydrolysis of the gallery TEOS was conducted in water solution for 40 min at room temperature, affording siloxane-pillared H-montmorillonite. Calcination of samples at 500 $^{\circ}C$ in air resulted in silica-pillared montmorillonite with large specific surface areas between 403 and 577 m2 /g, depending on the reaction stoichiometry. The reaction at H-montmorillonite : dodecylamine : TEOS reaction stoichiometries of 1 : 2 : 15 and 1 : 4 : 20 resulted in high specific surface areas and mesopores with a narrow pore size distribution. Result indicates that the intragallery-amine catalyze the hydrolysis of gallery-TEOS and simultaneously have a role of gallery-templated micellar assemblies.