• International Journal of Air-Conditioning and Refrigeration
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• 제17권1호
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• pp.32-36
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• 2009

The ice storage system uses water for low temperature latent heat storage. However, a refrigerator capacity is increased and COP is decreased due to supercooling of water in the course of phase change from solid to liquid. This study investigates the cooling characteristics of the TMA-water clathrate compound including TMA (Tri-methyl-amine, $(CH_3)_3N$) of $20{\sim}25wt%$ as a low temperature latent heat storage material. The results showed that the phase change temperature and the specific heat is increased and the supercooling degree is decreased as the weight concentration of TMA increased. Especially, the clathrate compound containing TMA 25 wt% has the average phase change tempera ture of $5.8^{\circ}C$, the supercooling degree of $8.0^{\circ}C$ and the specific heat of 3.499 kJ/kgK in the cooling process. This can lead to reduction of operation time of refrigerator in low temperature latent heat storage system and efficiency improvement of refrigerator COP and overall system. Therefore, energy saving and improvement of utilization efficiency are expected.

• 대한기계학회논문집
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• 제14권3호
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• pp.694-701
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• 1990

본 연구에서는 열기관의 출력이, 주어진 열원사이에서 구성되는 사이클의 형 태에 의존한다는 점에서 최대출력 사이클이 어떤 형태가 될 것인가하는 문제에 촛점을 맞추어 사이클을 해석하고, 최대출력을 구하고자 한다.

• 공업화학
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• 제35권2호
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• pp.140-147
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• 2024

바이오매스 활용을 높이기 위하여, 열처리 공정을 통해 강아지풀 기반 리튬 이온 이차 전지용 탄소음극재(SV-C)를 제조한 뒤 전기화학적 성능을 고찰하였다. 강아지풀의 열처리 온도가 750 ℃로 낮을 때 낮은 결정성과 높은 비표면적(126 m²/g)과 함께, 표면에 많이 존재하는 산소의 (-) 전하가 리튬을 끌어당김으로 인하여 비정전용량(1003.3 mAh/g, at 0.1 C)이 높지만, 용량 유지율은 61.0% (at 500 cycles and 1 C)로 낮아지는 것으로 여겨진다. 또한, 열처리온도가 1150 ℃로 증가하면 탄소층이 축합되어 배열이 우수해짐에 따라 구조 결함이 감소하여 기공이 크게 줄어 비표면적(32 m²/g)이 감소한 것으로 확인되었다. 또한, 음극재 표면결함이 감소하여 결정성이 높아지게 되면, 용량 유지율은 89.7% (at 500 cycles and 1 C)로 높지만, 결함 정도가 작아 활성점이 줄어들어 비정전용량이 471.7 mAh/g로 매우 낮은 것으로 여겨진다. 본 연구 범위에서, 열처리 온도에 따라 제조된 강아지풀 기반 탄소음극재의 경우, 비표면적에 비해 표면 산소 함량과 결정성 등이 음극재의 전기화학적 특성에 더 높은 신뢰도를 갖는 것으로 나타났다.

• Journal of the Korean Physical Society
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• 제73권9호
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• pp.1211-1218
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• 2018

Within the framework of the modified factorization method, we solve the $Schr{\ddot{o}}dinger$ equation with the modified Yukawa potential. The energy spectrum is obtained using the Pekeris approximation scheme for the centrifugal term. The thermodynamic properties, including the vibrational partition function, vibrational mean energy, vibrational mean free energy, vibrational specific heat capacity and vibrational entropy, are calculated. As a special case, we compare our result with that work of Dong [Int. J. Quant. Chem. 107, 366 (2007)] and find good agreement.

• 설비공학논문집
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• 제13권3호
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• pp.153-159
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• 2001

A system simulation program was developed for a multi-type inverter heat pump. Electronic expansion valve(EEV) was used to extend the capacity modulating range of the heat pump as expansion device. The program was also developed to calculate actual system performance with the building load variation with climate during a year. The performance variation of a multi-type hat pump with two EEV and an inverter compressor was simulated with compressor speed, capacity, and flow area of the EEV. As a result, the optimum operating frequency of the compressor and openings of the expansion device were decided at a given load. As compressor speed increased, he capacity of heat pump increased, the capacity of heat pump increased. Therefore flow area of EEV should be adjusted to have wide openness. Thus the coefficient of performance(COP) of the heat pump decreased due to increasement of compressor power input. The maximum COP point at a given load was decided according to the compressor speed. And under the given specific compressor speed and the load, the optimum openings point of EEV was also decided. Although the total load of indoor units was constant, the operating frequency increased as the fraction of load in a room increased. Finally ad the compressor power input increased, the coefficient of performance decreased.

• Advances in Energy Research
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• 제3권3호
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• pp.167-179
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• 2015

This paper presents a techno-economic analysis of a partial repowering scheme for an existing 210 MW coal fired power plant by integrating a gas turbine and by employing waste heat recovery. In this repowering scheme, one of the four operating coal mills is taken out and a new natural gas fired gas turbine (GT) block is considered to be integrated, whose exhaust is fed to the furnace of the existing boiler. Feedwater heating is proposed through the utilization of waste heat of the boiler exhaust gas. From the thermodynamic analysis it is seen that the proposed repowering scheme helps to increase the plant capacity by about 28% and the overall efficiency by 27%. It also results in 21% reduction in the plant heat rate and 29% reduction in the specific $CO_2$ emissions. The economic analysis reveals that the partial repowering scheme is cost effective resulting in a reduction of the unit cost of electricity (UCOE) by 8.4%. The economic analysis further shows that the UCOE of the repowered plant is lower than that of a new green-field power plant of similar capacity.

• Journal of Electrochemical Science and Technology
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• 제13권3호
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• pp.323-338
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• 2022

Heat generation and temperature of a battery is usually presented by an equation of current. This means that we need to adopt time domain calculation to obtain thermal characteristics of the battery. To avoid the complicated calculations using time domain, 'state of charge (SOC)' can be used as an independent variable. A SOC based calculation method is elucidated through the comparison between the calculated results and experimental results together. Experiments are carried for rapid resistive discharge of a large-capacitive lithium secondary battery to evaluate variations of cell potential, current and temperature. Calculations are performed based on open-circuit cell potential (SOC,T), internal resistance (SOC,T) and entropy (SOC) with specific heat capacity.

• 열처리공학회지
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• 제27권6호
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• pp.295-301
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• 2014

In this study, the relationship between strength and damping capacity of annealed magnesium alloys after hot rolling was investigated. The microstructure of hot rolled magnesium consisted of dendrite structure and $Mg_{17}Al_{12}$ compounds precipitated along the grain boundary. The dendrite structure was dissipated, $Mg_{17}Al_{12}$ compounds was decomposed by annealing, and then its dissolved in ${\alpha}$-Mg. With an increasing the annealing temperature and time, strength was slowly decreased and damping capacity was slowly increased by the growth of grain size and decreasing of defects induced by hot rolling. In annealing treatmented magnesium alloys after hot rolling, damping capacity was decreased rapidly with an increase of strength. There was on proportional relationship between tensile strength, and damping capacity.

• 한국기계가공학회지
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• 제6권3호
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• pp.98-104
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• 2007

The carbon fiber reinforced carbon composite (CFRC) materials are necessary for the advanced industries that require the thermal resistance. And the development and research for CFRC has been in progress in the field of aerospace and defense industry. CFRC have several advantages and special properties such as excellent anti ablation, outstanding strength retention at very high temperature, high heat capacity and thermal transport, high specific stiffness and strength, and high thermal shock resistance. They have been used as aircraft brake, rocket nozzle, nose cones, jet engine turbine wheels, and high speed craft. Since the technology related to CFRC was prohibited from importing and exporting, we developed our own technology to produce F-16 B32 brake disk made out of CFRC, and then we performed various tests to observe the characteristics of CFRC-based brake disk developed in this study in view of density, strength, friction, specific heat, and heat conductivity.

• 대한설비공학회지:설비저널
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• 제7권1호
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• pp.13-19
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• 1978

An experiment has been performed of find a temperature distribution of the circulating fluid in a packed bed thermal storage system when the inlet fluid temperature is constant. The thermal storage system is a specific-heat type in which the circulating fluid, hot air, exchanges heat directly with the heat storage materials, glass balls, in a heat storage bin. An empirical equation which includes two dimensionless variables $t^*\;and\;T_f^*$, is obtained. Also, heat storage efficiency and heat storage capacity are calculated from this equation, The heat transfer coefficient calculated by the suggested equation was compared with the value determined by the existing empirical equation.