• Journal of Powder Materials
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• v.28 no.6
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• pp.470-477
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• 2021

Energy storage systems should address issues such as power fluctuations and rapid charge-discharge; to meet this requirement, CoFe₂O₄ (CFO) spinel nanoparticles with a suitable electrical conductivity and various redox states are synthesized and used as electrode materials for supercapacitors. In particular, CFO electrodes combined with carbon nanofibers (CNFs) can provide long-term cycling stability by fabricating binder-free three-dimensional electrodes. In this study, CFO-decorated CNFs are prepared by electrospinning and a low-cost hydrothermal method. The effects of heat treatment, such as the activation of CNFs (ACNFs) and calcination of CFO-decorated CNFs (C-CFO/ACNFs), are investigated. The C-CFO/ACNF electrode exhibits a high specific capacitance of 142.9 F/g at a scan rate of 5 mV/s and superior rate capability of 77.6% capacitance retention at a high scan rate of 500 mV/s. This electrode also achieves the lowest charge transfer resistance of 0.0063 Ω and excellent cycling stability (93.5% retention after 5,000 cycles) because of the improved ion conductivity by pathway formation and structural stability. The results of our work are expected to open a new route for manufacturing hybrid capacitor electrodes containing the C-CFO/ACNF electrode that can be easily prepared with a low-cost and simple process with enhanced electrochemical performance.

• Journal of Electrochemical Science and Technology
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• v.12 no.4
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• pp.458-464
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• 2021

Lithium ion batteries (LIBs) is a kind of rechargeable secondary battery, developed from lithium battery, lithium ions move between the positive and negative electrodes to realize the charging and discharging of external circuits. Zeolitic imidazolate frameworks (ZIFs) are porous crystalline materials in which organic imidazole esters are cross-linked to transition metals to form a framework structure. In this article, ZIF-67 is used as a sacrificial template to prepare nano porous carbon (NPC) coated cobalt nanoparticles. The final product Co/NPC composites with complete structure, regular morphology and uniform size were obtained by this method. The conductive network of cobalt and nitrogen doped carbon can shorten the lithium ion transport path and present high conductivity. In addition, amorphous carbon has more pores that can be fully in contact with the electrolyte during charging and discharging. At the same time, it also reduces the volume expansion during the cycle and slows down the rate of capacity attenuation caused by structure collapse. Co/NPC composites first discharge specific capacity up to 3115 mA h/g, under the current density of 200 mA/g, circular 200 reversible capacity as high as 751.1 mA h/g, and the excellent rate and resistance performance. The experimental results show that the Co/NPC composite material improves the electrical conductivity and electrochemical properties of the electrode. The cobalt based ZIF-67 as the precursor has opened the way for the design of highly performance electrodes for energy storage and electrochemical catalysis.

• Composites Research
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• v.37 no.3
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• pp.190-196
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• 2024

The bipolar plate is a crucial element of the vanadium redox flow battery (VRFB) as it serves as both the electrical conduit and the structural support for the cell within the VRFB stack. Although, the graphite material is primarily used for the bipolar plate due to its excellent electrical conductivity, a significant limitation of performance of the VRFB is present due to high interfacial contact resistance (ICR) arises between the electrode and bipolar plate in the cell stack. This study aims to develop an integrated electrode-bipolar plate assembly that will address the limitations of the ICR. The integrated assembly was constructed using a single carbon felt with thermoplastic and thermoset polymers utilizing hot press method. Experimental results verify that the bipolar plate assembly exhibits reduced area specific resistance (ASR) due to the continuous electrical path. Additionally, from the charge/discharge cell test results, the integrated assembly shows improved cell performance. Therefore, the developed integrated electrode-bipolar plate assembly can serve as a substitute for the conventional bipolar plate and electrode assembly.

• Journal of the Korean Applied Science and Technology
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• v.33 no.3
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• pp.587-592
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• 2016

In this study, flexible acid treated single walled carbon nanotubes (A-SWCNTs) electrodes were fabricated by using gold coated PET substrate and spray coating technique. The acid-treatment method was conducted to introduce functional groups on the SWCNTs wall, which could improve dispersability of the SWCNTs and its electrochemical property. The electrochemical properties of flexible A-SWCNTs electrode were carried out by cyclic voltammetry(CV), electrochemical impedance were carried out by cyclic voltammetry(CV), electrochemical impedance spectroscopy(EIS) and galvanostatic charge/discharge (GCD) cycles. As a results, The specific capacitance value of the unbent A-SWCNTs electrode was $67F{\cdot}g^{-1}$, which decreased to $63F{\cdot}g^{-1}$ (94% retention) after 1000 GCD cycles. Interestingly, the specific capacitance of the unbent A-SWCNTs electrode with application of the 1000 GCD cycles was retained even after 500 bending to $30^{\circ}$ with 6000 GCD cycles.

• Journal of Environmental Impact Assessment
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• v.24 no.6
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• pp.549-560
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• 2015

The priorities of siting restriction was derived from quantification of environmental hazard according to industrial classification based on 'Chemical Ranking and Scoring System(CRS)' which is handling the discharge characteristics of 31 industrial classifications regulated from locating at 'Industrial Complex in Rural Area(ICRA)'. CRS that is utilizing the data of 'Pollutant Release and Transfer Registers(PRTR)' is applied to determine human health risk and ecological risk which are calculated by discharged amount and materials $LC_{50}$ according to water, soil and air media based on industrial classification. From this process, exposure assessment and toxicity assessment for integrating the adverse environmental impact and the mitigation effect of environmental risk according to the development of environmental technologies into establishing the rational landuse management method for the 31 industrial classifications regulated from locating at ICRA was analyzed. From the assessment result of the siting restriction removal at ICRA for 31 industrial classifications, based on 2012 year reference 6 industries that includes Manufacture of Guilt Coloration Surface Processing Steel Materials, Manufacture of Biological Product, Manufacture of Smelting Refining and Alloys of Copper, Dyeing and Finishing of Fibers and Yarns, Manufacture of Other Basic Iron and Steel n.e.c., Rolling Drawing and Extruding of Non-ferrous Metals n.e.c. are calculated as having relatively lower environmental hazards, thus it is judged that the siting restriction mitigation at ICRA is possible for the 6 industrial classifications that are not discharging the specific hazardous water contaminants during manufacturing process.

• Environmental and Resource Economics Review
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• v.18 no.1
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• pp.53-73
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• 2009

This study examines the existence of ${\beta}$-convergence of carbon dioxide emissions in 24 countries over the period 1971~2002. For that purpose, The model of economic growth developed by Barro and Sala-i-Martin (1995) is extended and conducted Dynamic panel analysis and unit root testing by employing the panel stationarity test of Levin et al. (2002) and 1m et al. (2003). A dynamic panel estimation is well known method including capacity to control for both the endogeneity problem and the unobserved country-specific effects problem. Dynamic panel estimation method has been widely used in similar empirical studies. therefore, we also used the dynamic panel estimation method in our estimation. The result show that evidence of ${\beta}$-convergence exists among both the Obligatory GHG reduction countries (Annex) and the Non-obligatory GHG reduction countries (Non-Annex). but China discharge amount of $CO_2$ gas more than any other country. This fact can cause some bias in overall test. and so we reexamined test of convergence for Non-annex countries excluding china. As expected, in the Non-annex countries excluding china, I couldn't find any evidence of convergence.

• Journal of Korea Water Resources Association
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• v.49 no.5
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• pp.451-458
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• 2016

In order to infer regional flood frequency for ungauged watersheds, index flood method was applied for this study. To pursuit this given purpose, annual peak flood data for 22 watersheds located at the upstream of the Chungju Dam watershed were obtained from the spatial extension technique. The regionalization of mean annual flood was performed from extended flood data at 22 points. Based on the theory that flood discharge and watershed size follows the power law the regionalization generated the empirical relationship. These analyses were executed for the full size of the Chungju Dam watershed as one group and three different mid-size watersheds groups. From the results, the relationship between mean annual flood and watershed sizes follow the power law. We demonstrated that it is appropriate to use the relationship between specific flood discharges from the upper and lower watersheds in terms of estimating the floods for the ungaged watersheds. Therefore, not only the procedure of regional frequency analysis but also regionalizaion analaysis using finer discretization of the regions interest with respect to the regional frequency analyisis for the ungauged watersheds is important.

• Journal of Korea Water Resources Association
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• v.44 no.6
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• pp.497-510
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• 2011

A levee height is determined by adding a deterministic freeboard to a flood water level in Korea. In the USA, a levee height is determined by choosing a value conditionally among the freeboard criteria and the levels resulted from a probabilistic method. The probabilistic method adopts a conditional non-exceedance probability (CNP) which is the probability that the target stage will not be exceeded given a specific flood event. The purpose of the study is to compare Korean criterion for levee height estimation with that of the USA. Levee heights were determined according to the above two criteria at twenty-five cross sections in five streams. The results show that Korean criterion on average yields levee heights 20 cm higher than those calculated by the criterion of the USA. The larger the flood discharges become, the higher the levee height differences are usually. It is caused by the freeboard estimation criterion of Korea that the larger design flood is, the higher freeboard is given. Korean criterion, however, resulted in lower levee heights for smaller streams than those by the criterion of the USA. To sum it up, the Korean levee height criteria can result in overestimation or underestimation depending on flood discharge amount, being compared with the criteria of the USA. The Korean freeboard especially needs to be increased for smaller flood discharges.

• Journal of Korea Water Resources Association
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• v.54 no.spc1
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• pp.1095-1105
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• 2021

The advancement of dam operation is further required due to the upcoming rainy season, typhoons, or torrential rains. Besides, physical models based on specific rules may sometimes have limitations in controlling the release discharge of dam due to inherent uncertainty and complex factors. This study aims to forecast the water level of the nearest station to the dam multi-timestep-ahead and evaluate the availability when it makes a decision for a release discharge of dam based on LSTM (Long Short-Term Memory) of deep learning. The LSTM model was trained and tested on eight data sets with a 1-hour temporal resolution, including primary data used in the dam operation and downstream water level station data about 13 years (2009~2021). The trained model forecasted the water level time series divided by the six lead times: 1, 3, 6, 9, 12, 18-hours, and compared and analyzed with the observed data. As a result, the prediction results of the 1-hour ahead exhibited the best performance for all cases with an average accuracy of MAE of 0.01m, RMSE of 0.015 m, and NSE of 0.99, respectively. In addition, as the lead time increases, the predictive performance of the model tends to decrease slightly. The model may similarly estimate and reliably predicts the temporal pattern of the observed water level. Thus, it is judged that the LSTM model could produce predictive data by extracting the characteristics of complex hydrological non-linear data and can be used to determine the amount of release discharge from the dam when simulating the operation of the dam.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.4 no.1
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• pp.103-112
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• 1984

This study is an effort to develop a series of empirical procedure for the determination of design flood for a small watershed based on the unit hydrograph theory. It is shown that a flood discharge of a watershed with a specific return period can be expressed as a product of its watershed area, rainfall factor, runoff factor and flood peak reduction factor. Since the procedures for the determination of rainfall factor and runoff factor were already developed in the previous study (13) a series of step-by-step procedure is devised to empirically determine the flood peak reduction factor in the present study. Using the methodology developed herein the 50-year design flood, which is of concern in the drainage of agricultural lands, is estimated for a watershed on upper Kyungan River and compared with the design floods by the existing methods now in use. The flood peak reduction factor was correlated with the dimensionless parameter consisted of the rainfall duration divided by the basin lag time, which was computed from the derived unit hydrographs by the method of moment. The unit hydrographs of various durations were synthesized by the method of build up and S-curve. A multiple correlation was also made between the basin lag time and the physiographic parameters of the watershed, i.e., the stream length and the average stream slope.