• 제목/요약/키워드: solvent engineering

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무용제형 저기포성 정련제의 제조 및 정련특성 (Preparation of Solvent-Free Low Foaming Scouring Agents and Their Scouring Characteristics)

  • 박홍수;안성환;심일우;조혜진;함현식;김영찬;김성길
    • 한국응용과학기술학회지
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    • 제23권1호
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    • pp.37-44
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    • 2006
  • Solvent-free low foaming scouring agents (LFSC) were prepared by blending of 2-ethylhexylaminoethyl sulfate (2-EHAS), POE(10) octadecylbenzyl- ammonium chloride (POBAC) and Sedlan FF-200 (FF-200). As the results of several tests, 2-EHAS/POBAC/FF-200/water (8g/12g/20g/60g) mixture (LFSC-5) showed good cleaning power, penetrating ability and stability to alkali, and gave less problem in water pollution. The foaming power of LFSC-5 measured by Ross and Miles method was 8mm foam height immediately after foaming, and that measured by Ross and Clark method was less than 300mm foam height at $30^{\circ}C$, and 18mm at $80^{\circ}C$. As a result, LFSC-5 proved a good low foaming scouring agent for fiber.

용제형 저기포성 정련제의 제조 및 정련효과 (Preparation of Solvent-Type Low Foaming Scouring Agents and Their Scouring Effect)

  • 유혁제;정동진;;함현식;박홍수
    • 한국응용과학기술학회지
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    • 제21권2호
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    • pp.156-163
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    • 2004
  • Low foaming scouring agents (LSSA) were prepared by blending of amine salt of dodecylbenzene sulfone, poly (PO-b-EO) glycol, Newpol PP-2000, MJU-100, ethylene glycol and organic solvent. As the results of several tests, LSSA-2 showed good scouring effect, penetrating ability and emulsifiability, and showed not much water pollution. The foaming power of LSSA-2 measured by Ross & Miles method was 11mm foam height immediately after foaming. And the foaming power of LSSA-2 measured by Ross & Clark method were less than 310mm foam height at $30^{\circ}C$, 17mm at $80^{\circ}C$. As a result, LSSA-2 was proved as a good foaming scouring agent.

A Study on Composites of Ethylene-Vinyl Acetate Copolymer and Ethylene-Propylene-Diene Rubber with Aluminum Hydroxide as a Fire Retardant

  • Lee, Yu Jun;Lee, Su Bin;Jung, Jae Young;Lee, Dam Hee;Cho, Ur Ryong
    • Elastomers and Composites
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    • 제51권2호
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    • pp.93-98
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    • 2016
  • The composites of EVA/EPDM including aluminum trioxide (ATH) as a fire retardant were manufactured for the purpose of improving low temperature property and flame resistance in the rubbery materials. The ratio of EVA to EPDM didn't affect the flame resistance of the rubber composites. The addition of ATH resulted in increase of the flame resistance. In the evaluation of the cold resistance, the increasing EPDM content showed enhancement of cold resistance in the composites due to increasing low Tg EPDM. It was found out that tensile strengths of the composites showed a maximum value at 100 phr of ATH by reinforcing effect, but a minimum value at 200 phr of ATH owing to slippage between the flame retardant by the external stress. In the measurement of solvent resistance in tetrahydrofuran, the increasing ATH content yielded enhancement of solvent resistance by reducing swelling of the composite, and increasing EPDM content also resulted from increase of the solvent resistance by reduction of polarizability as well as increase of crosslink in the composites.

Removal of Potassium from Molasses by Solvent Extraction and Ion Exchange

  • Wang, Lingyun;Nam, Sang-Ho;Lee, Manseung
    • Bulletin of the Korean Chemical Society
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    • 제35권9호
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    • pp.2711-2716
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    • 2014
  • The high content of potassium in molasses limits its usage as a raw material for stock feed. Moreover, its high viscosity makes it difficult to develop an efficient removal process. In this study, ion exchange and solvent extraction experiments have been performed to investigate the removal of potassium from a mixture of molasses with water. Cationic exchange resins (AG50W-X8 and Diphonix) showed a high loading percentage of potassium but the occurrence of breakthrough in few bed volumes was a drawback to the industrial application. Among the cationic extractants (D2EHPA, PC 88A, Cyanex 272) tested in this study, saponified PC 88A was found to be the best extractant for the removal of potassium. Batch simulation studies on a three stage counter current extraction confirmed that 85% of potassium was removed from 50 wt % molasses solution in water by using saponifed PC 88A.

수용액(水溶液)에서 코발트와 니켈 분리(分離) (Separation of Cobalt and Nickel from Aqueous Solution)

  • 류양;이만승
    • 자원리싸이클링
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    • 제22권1호
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    • pp.11-19
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    • 2013
  • 코발트와 니켈에 대한 수요가 증가함에 따라 다양한 자원으로부터 순도가 높은 상태로 이 금속들을 회수하는 것은 중요하다. 고순도 코발트와 니켈을 얻기 위해서는 다른 금속이온과의 분리가 필요하다. 본 총설에서는 순수한 코발트와 니켈용액을 얻을 수 있는 용매추출, 이온교환 및 침전법을 소개하고 비교하였다. 특히 용매추출에 대해서는 기존 공정의 장단점과 함께 공정조건을 조사하였다.

Unstable Inverted Phases of Di- and Tri-block Copolymers on Solution-Casting Films

  • Sun Dachun;Huang Lei;Liang Haojun
    • Macromolecular Research
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    • 제13권2호
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    • pp.152-155
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    • 2005
  • A dynamic density functional theory is presented for the observation of the phase revolutions of a solution-casting film of di- and tri-block copolymers under solvent evaporation conditions. With the evaporation of the solvent, the inverted phases, the minor part of the component becomes the continuous phase at the higher solvent evaporation rate, as observed in this experiment. Further simulation revealed that these inverted phases are converted into the normal phase and the major part of the component becomes the continuous phase, implying that the inverted phases observed in this experiment are unstable.

Circular Dichroism of Optically Active Poly(dialkylsilane) Aggregates in Microcapsules

  • Terao, Ken;Kikuchi, Noriaki;Sato, Takahiro;Teramoto, Akio;Fujiki, Michiya;Dobashi2, Toshiaki
    • 한국고분자학회:학술대회논문집
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    • 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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    • pp.344-344
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    • 2006
  • Poly(n-hexyl-(S)-3-methylpentylsilane) aggregates confined in microcapsules to keep the aggregation number and ranging in average polymer mass in a microcapsule from $2{\Box}10^{-16}\;to\;2{\Box}10^{-14}g$. were studied by circular dichroism measurements in ethanol (a non solvent) and tetrahydrofuran (an associative solvent at low temperature) at varioustemperatures. The size of each aggregate did not affect the optical activity because the circular dichroism was proportional to the aggregation number at the same condition. Moreover, the circular dichroism appreciably reflected the prepared method, i.e. temperature and solvent.

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Investigation of Solvent Effect on the Electrical Properties of TIPS Pentacene Organic Thin-film Transistors

  • Kim, Kyung-Seok;Chung, Kwan-Soo;Kim, Yong-Hoon;Han, Jeong-In
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2006년도 6th International Meeting on Information Display
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    • pp.1150-1153
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    • 2006
  • In this paper, we investigated the effect of solvent on electrical properties of triisopropylsilyl (TIPS) pentacene organic thin-film transistors (OTFTs). The TIPS pentacene was spin coated by using chlorobenzene, p-xylene, chloroform and toluene as solvent. Fabricated OTFT with chlorobenzene showed field-effect mobility of $0.01\;cm^2/V{\cdot}s$, on/off ratio $4.3{\times}10^3$ and threshold voltage of 5.5 V. In contrast, with chloroform the mobility was $5.8{\times}10^{-7}\;cm^2/Vs$, on/off ratio $1.1{\times}10^2$ and threshold voltage of 1.7 V.

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자동차 냉각 시스템에 사용되는 thermostat용 wax의 제조 및 분석에 관한 연구 (Studies on the Manufacturing and Analysis of Wax for Thermostat for use in Cooling System of Automobile)

  • 박경석;정석진
    • 공업화학
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    • 제7권1호
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    • pp.1-8
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    • 1996
  • 자동차 엔진용 thermostat에서 냉각수 온도제어를 위해 사용되는 wax의 제조 및 성분 분석을 실시하였다. 제조된 시료에 대해 lift 실험을 실시해 본 결과, 용제 추출법에 의해 제조된 시료가 자동차 엔진용 thermostat으로 사용 가능한 범위내에 있게 됨을 볼 수 있었다. 또한, 원유의 pitch를 용제 추출한 후 감압 증류 및 산처리를 하면 보다 정밀한 wax를 제조 할 수 있음을 알 수 있었다.

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Preparation of tungsten metal film by spin coating method

  • Lee, Kwan-Young;Kim, Hak-Ju;Lee, Jung-Ho;Sohn, Il-Hyun;Hwang, Tae-Jin
    • Korea-Australia Rheology Journal
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    • 제14권2호
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    • pp.71-76
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    • 2002
  • Metal thin films, which are indispensable constituents of ULSI (Ultra Large Scale Integration) circuits, have been fabricated by physical or chemical methods. However, these methods have a drawback of using expensive high vacuum instruments. In this work, the fabrication of tungsten metal film by spin coating was investigated. First of all, inorganic peroxopolytungstic acid (W-IPA) powder, which is soluble in water, was prepared by dissolving metal tungsten in hydrogen peroxide and by evaporating residual solvent. Then, the solution of W-IPA was mixed with organic solvent, which was spin-coated on wafers. And then, tungsten metal films, were obtained after reduction procedure. By selecting an appropriate organic solvent and irradiating UV, the sheet resistance of the tungsten metal film could be remarkably reduced.