• 한국분말재료학회지
• /
• 제25권4호
• /
• pp.291-295
• /
• 2018

A conductive additive is prepared by dispersing multi-walled carbon nanotubes (MWCNTs) on Cu powder by mechanical milling and is distributed in epoxy to enhance its electrical conductivity. During milling, the MWCNTs are dispersed and partially embedded on the surface of the Cu powder to provide electrically conductive pathways within the epoxy-based composite. The degree of dispersion of the MWCNTs is controlled by varying the milling medium and the milling time. The MWCNTs are found to be more homogeneously dispersed when solvents (particularly, non-polar solvent, i.e., NMP) are used. MWCNTs gradually disperse on the surface of Cu powder because of the plastic deformation of the ductile Cu powder. However, long-time milling is found to destroy the molecular structure of MWCNTs, instead of effectively dispersing the MWCNTs more uniformly. Thus, the epoxy composite film fabricated in this study exhibits a higher electrical conductivity than 1.1 S/cm.

• 공업화학
• /
• 제17권6호
• /
• pp.575-579
• /
• 2006

리튬의 삽입과 탈리가 가능한 탄소전극은 첫 싸이클 동안 카본전극 계면에 solid electrolyte interface가 형성된다. 초기 충전과정에서의 용매분해로 형성된 막은 전지의 성능에 영향을 미치게 되며, 이러한 용매분해는 초기 비가역 용량의 주된 요인중의 하나이다. 본 연구에서는 초기 비가역 반응을 억제하기위해 카본 표면 위에 부동태 막 형성을 위한 첨가제로서 $Li_{2}CO_{3}$을 사용하였다. $Li_{2}CO_{3}$ 첨가 효과를 시간대 전압법, 순환 전압-전류법, 그리고 임피던스법을 이용하여 조사하였고, 또한 SEM, EDX 그리고 XRD를 통해 표면 현상과 조성의 변화를 관찰하였다. 1 M $LiPF_{6}$/EC : MA (1 : 3, v/v) 전해질 용액에 $Li_{2}CO_{3}$의 첨가는 전극 표면에서의 용매분해 억제를 통하여 초기 비가역 용량을 감소시킴을 확인하였다.

• 플랜트 저널
• /
• 제10권1호
• /
• pp.34-39
• /
• 2014

본 연구에서는 상용성 공정모사기인 BR&E사의 PROMAX를 사용하여 amine류 흡수제인 30 wt%의 MEA수용액, 30 wt%의 DEA수용액 그리고 50 wt%의 MDEA수용액과 50 wt%의 MDEA에 첨가제로써 3 wt%의 piperazine을 첨가한 공정을 이용하여 천연가스 중에 포함되어 있는 산성가스인 $CO_2$와 $H_2S$ 성분의 제거 성능에 대한 비교 작업을 수행하였다. 공정모사 결과로 MEA는 상대적으로 많은 $CO_2$를 제거 할 수 있는 반면에 DEA, MDEA, MDEA와 첨가제인 piperazine은 $H_2S$를 많이 제거한다는 것을 알 수 있었고, MEA 30 wt%수용액의 경우는 lean amine의 circulation rate가 가장 적은 것으로 나타냈다. 재비기의 heat duty는 MDEA 50 wt%에 첨가제인 piperazine 3 wt% 수용액이 가장 적음을 알 수 있었다. 또한 MDEA 그리고 MDEA와 첨가제인 piperazine을 비교해 보면 첨가제로 인하여 solvent circulation rate가 감소된 것을 알 수 있었다.

• 환경위생공학
• /
• 제13권3호
• /
• pp.66-71
• /
• 1998

This study was investigated to evaluate worker exposures to organic solvents by type of print industry. Results were as follows; 1. Workers were exposed to mixture of toluene, isopropyl alcohol(IPA), methyl ethyl ketone(MEK), n-hexane, ethylacetate(EA), acetone. The components of high exposure solvents were toluene, IPA and MEK. 2. Considering additive effects of the compounds, exposure indices(Em) were calculated. The Mean of exposure indices were 1.79 for Gravere, 0.41 for Screen and 0.14 for Opset workplace. The workers of Gravere workplace were estimated to overexpose for solvents. 3. The highest overexposed solvent was toluene for a single component. The rate of overexposed level for toluene was 7.41% for some print workplace and for mixed solvent was 1.85％. 4. Local exhaust systems were inappropriate and respiratory protective devices were not supplied to the workers. 5. Sound level was over 90dB(A) in Opset print workplace and some measures should be performed to get down the sound level.

• Bulletin of the Korean Chemical Society
• /
• 제34권11호
• /
• pp.3410-3414
• /
• 2013

Atom-economical esterification is of great importance in green chemistry. In this work, we demonstrated the catalyst and additive free esterification of alcohols by their reaction with 2-acyl-4,5-dichloropyridazin-3(2H)-ones without solvent at $100^{\circ}C$. Aliphatic and aromatic alcohols were converted into the corresponding esters in good to excellent yields. It is noteworthy that the reaction is solvent-free, atom-economic, easy-workup, and rapid and that the process is inexpensive.

• 대한화학회지
• /
• 제15권2호
• /
• pp.95-105
• /
• 1971

The apparent molal volumes ${\phi}_v$ of a series of homologous tetraalkylammonium chlorides, $Me_4NCl, Et_4NCl, Pr_4NCl,\;and\;Bu_4NCl$, in a series of isopropanol-water mixtures have been determined at $30^{\circ}C$ from precision density measurements using pycnometers. The values of ${\phi}_v$ extrapolated to infinite dilution give partial molal volumes $\={V}^{\circ}$s which are almost additive for successive homologues and enable one to determine the absolute individual ionic partial molal volumes. The experimental results are discussed in terrns of the varying size and surface charge of the ions and the structure of the binary solvent mixtures. The results indicate that at 0.1 mole fraction isopropanol the maximum structuredness of water causes a minimum in the tetraalkylammonium-cation partial molal volumes, while at 0.2 mole fraction the solvent structure is such that the free volumes is a minimum and the electrostrictive effect of chloride ion is a maximum.

• KSBB Journal
• /
• 제13권2호
• /
• pp.133-140
• /
• 1998

Using rlFN-$\alpha$ and rhGH as the model proteins, the refolding performances of the published processes were evaluated and compared. Key engineering parameters such as the type of denaturant and this concentration, protein concentration in the refolding buffer, and pH and ionic strength of the buffer were experimentally investigated. Furthermore, the role of a co-solvent of surfactant type in aggregation reduction was also studied. Of the denaturants tested (8M urea, 6M guanidine HCI, 0.5% SDS), SDS at alkaline pH (9.5) and ambient temperature gave the highest recovery yield. The SDS process was effective in the refolding of observed where dissolution proceeded better under lower strength (10 mM) but aggregation was suppressed under higher strength (>50 mM.) When PEG-4000 and/or Tween were added as co-solvent or refolding-enhancing additive, 1.6-2 times higher yield was realized. The‘masking’of the hyrophobic patches located on the surface of the protein with the surfactant molecules was believed to be responsible for the considerable reduction in aggregation during refolding.

• 동의신경정신과학회지
• /
• 제3권1호
• /
• pp.84-90
• /
• 1992

Solvent and TLC-fractionations of the root of Salvia miltiorrhiza have yielded the results as follows ; Solvent fractions Petr. ether Ether Ethy1 acetate Water Control 100uL 0 0.2 35.1 41.9 43.0 50ul 0.7 3.7 37.2 42.0 TLC-fractionation and the Cytotoxic activity Fractions I II III IV V VI Petr. ehter Control 100uL13.0 7.1 16.8 1.2 30.9 23.2 0.5 48.3 50uL 37.1 26.1 30.0 20.1 45.7 27.2 29.7 Among the solvent fractions the petroleum ehter fraction corresponding to the concentration of 20ug/ml has showed the strongest Cytotoxic activity. (no cell survived) A double dilution of the fraction(10ug/ml) still showed strong activity.(0.2 cells survived) The ether fraction contained strong activity. Of the fraction which have veen obtained by a prcparative silicagel TLC I, II, III & IV were cytotoxic, but V and VI were inactive Howevcr, it is worthwhile to note that no one of these has no strong Cytotoxicity as the pertoleum ether fraction itself. This observation says that the active fractions could be additive or synergic to each other. The most active fraction, IV, was scrached out from the TLC and its UV-spectrum taken. The absorption maxima were 207 and 272 nm, indicating the presence of a flavanone strucuture.

• Korean Chemical Engineering Research
• /
• 제47권6호
• /
• pp.669-675
• /
• 2009

연질 PVC 대체를 위한 비변색 타입의 무용제형 상온 액상수지를 폴리올을 경화제로 사용하는 폴리우레탄수지 구조제어 설계를 통한 프리폴리머 합성방법을 응용하여 제조할 수 있었다. Macro-glycol, 분자량 및 반응조건의 영향 등을 고찰하여 최적의 작업성과 물성을 가지는 무용제형 상온액상수지를 제조하였으며, 우수한 기계적인 특성과 함께 유색작업을 위한 안료의 분산성 등에서도 우수하였고, Tg가 $-40^{\circ}C$의 값을 나타내었다. 또한 자외선 노출이나 질소산화물에 의한 황변특성도 개선할 수 있었다.

• Bulletin of the Korean Chemical Society
• /
• 제32권9호
• /
• pp.3295-3305
• /
• 2011

Thermal behavior of poly (methyl methacrylate) was analyzed in the presence of tin (IV) chloride. Five different proportions - polymer to additive - were selected for casting films from common solvent. TG, DTG and DTA were employed to monitor thermal degradation of the systems. IR and py-GC-MS helped identify the decomposition products. The blends start degrading at a temperature lower than that of the neat polymer and higher than that of the pure additive. Complex formation between tin of additive and carbonyl oxygen (pendent groups of MMA units) was noticed in the films soon after the mixing of the components in the blends. The samples were also heated at three different temperatures to determine the composition of residues left after the expulsion of volatiles. The polymer, blends and additive exhibited a one step, two-step and three-step degradation, respectively. $T_0$ is highest for the polymer, lowest for the additive and is either $60^{\circ}C$ or $70^{\circ}C$ for the blends. The amount of residue increases down the series [moving from blend-1 (minimum additive concentration) to blend-5 (maximum additive concentration)]. For blend-1, it is 7% of the original mass whereas it is 16% for blend-5. $T_{max}$ also goes up as the concentration of additive in the blends is elevated. The complexation appears to be the cause of observed stabilization. Some new products of degradation were noted apart from those reported earlier. These included methanol, isobutyric acid, acid chloride, etc. Molecular-level mixing of the constituents and "positioning effect" of the additive may have brought about the formation of new compounds. Routes are proposed for the appearance of these substances. Horizontal burning tests were also conducted on polymer and blends and the results are discussed. Activation energies and reaction orders were calculated. Activation energy is highest for the polymer, i.e., 138.9 Kcal/mol while the range for blends is from 51 to 39 Kcal/mol. Stability zones are highlighted for the blends. The interaction between the blended parts seems to be chemical in nature.