• 제목/요약/키워드: solution uptake

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Biosorption of Lead and Cadmium by Fucoidan from Undariafinnatifida (미역 포자엽 fucoidan의 중금속 흡착 특성)

  • KOO Jae-Geun
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.34 no.5
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    • pp.521-525
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    • 2001
  • Screening tests of different fucoidan fractions from Sporophylls of Undazia pinnatifida, Laminaria religiosa, Hizikia fusiforme and Sagassum fulvellum revealed that the highest biosorptive Pb and Cd uptake fraction was Undaria finnatifida Fr-3.0 prepared by dissolving the precipitated complex (crude fucoidan and cetylpyridinum chloride) with 3.0 M $CaCl_2$ solution, The Pb and Cd uptake by Undaria finnatifida Fr-3.0 was quantitatively evaluated using sorption isotherms and Langmuir sorption model. The Pb and Cd uptake by Undaria finnatifida Fr-3.0 increased with increasing pH values at high equilibrium residual concentration. The highest experimentally observed Pb and Cd uptake value in the sorption isotherm for pH 5.5 were 94 mg/g (at $C_f=164\;mg/L$) and 64 mg/g (at $C_f=197\;mg/L$) respectively, and $q_{max}$ of Pb and Cd calculated by Langmuir sorption model were 178 mg/g and 122 mg/g, respectively. In the low equilibrium concentration range, up to 20 mg/L, the Pb uptake remained unchanged in the presence of Cd, but decreased at higher equilibrium concentration range.

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Laboratory Measurements on the Uptake of Carbon Monoxide by Soils (토양의 일산화탄소 제거에 관한 연구)

  • Myung Ja Kim
    • Journal of the Korean Chemical Society
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    • v.27 no.1
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    • pp.31-37
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    • 1983
  • The consumption of atmospheric carbon monoxide by soil was measured under laboratory conditions in different types of soils. Laboratory experiments were performed with humus containing high proportion of organic matter, roadside soils, and humus and roadside soils previously exposed to high concentration of CO by reusing in the experiment. CO concentrations in the 18.2 l-reaction vessel were varied from 2,000 ppm to 24,000ppm to estimate the effectiveness of CO consumption at high level of CO. The uptake of CO by soil was measured by gas chromatography using a TCD detector. The control experiments conducted along with the soil experiments evidently indicated that the potting soil is responsible for CO consumption. Humus showed much higher CO uptake rates compared with the soil taken from roadside. The humus reused in the experiment showed somewhat higher rates(15%) of uptake than the fresh one. The soil's ability to remove CO from the test atmosphere reached a maximum near the CO concentration of 13,000 ppm in the range of $9,000~24,000ppm$. The addition of streptomycin did not influence the removal capacity of soil significantly, whereas 10% saline solution remarkably prevented CO uptake of the humus sample.

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RICE UPTAKE AND LEACHING OF 99TC IN DIFFERENT PADDY SOILS CONTAMINATED ACCORDING TO TWO CONTRASTING SCENARIOS

  • Choi, Yong-Ho;Lim, Kwang-Muk;Jun, In;Kim, Byung-Ho;Keum, Dong-Kwon
    • Journal of Radiation Protection and Research
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    • v.40 no.4
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    • pp.231-243
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    • 2015
  • Four different paddy soils collected around the Gyeongju nuclear site were treated with $^{99}TcO_4{^-}$ solution under the assumption of two contrasting contamination scenarios. Scenario I (SN-I) is for a pre-transplanting deposition of $^{99}Tc$ followed by plowing, whereas SN-II is for its deposition onto the water surface shortly after transplanting. Rice plants were grown in lysimeters in a greenhouse. Plant uptake of $^{99}Tc$ was quantified with the $TF_{area}$ ($m^2{\cdot}kg^{-1}-dry$). The SN-II $TF_{area}$ values for straws and brown rice, having been generally higher than the SN-I values, were within the ranges of $6.9{\times}10^{-3}{\sim}4.1{\times}10^{-2}$ and $5.2{\times}10^{-6}{\sim}7.3{\times}10^{-5}$, respectively. Sorption onto clay seems to have decreased $^{99}Tc$ uptake in SN-I, whereas it may have had an insignificant effect in SN-II. A phenomenon characteristic of submerged paddy soil, i.e., the development of a thin oxic surface layer may have greatly affected the rice uptake of SN-II $^{99}Tc$. The surface-water concentrations of $^{99}Tc$ were much higher in SN-II than in SN-I. For the percolating water, however, the opposite was generally true. At most 1.3% of the applied $^{99}Tc$ were leached through such percolation. The use of empirical deposition time-dependent $TF_{area}$ values was considered desirable in assessing the radiological impact of a growing-season deposition of $^{99}Tc$ onto paddy fields.

Comparison of Soil Testing Methods for Plant Available Phosphate

  • Kim, Myung Sook;Kwak, Han Kang;Kim, Yoo Hak;Kang, Seong Soo;Gong, Myung Suk;Zhang, Yong Seon;Yoon, Hong Bae;Lee, Chang Hoon
    • Korean Journal of Soil Science and Fertilizer
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    • v.46 no.3
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    • pp.153-162
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    • 2013
  • Most test methods for plant available soil phosphate are based on the extraction with a chemical solution. The objective of this study is to evaluate available phosphate of various tests at different soil phosphate levels. Two experiments were conducted as follows: i) Extracting capacities of soil phosphate tests - Mehlich III, Mehlich II, Bray I, Olsen, Kelowna, and Modified Lancaster(Mod. Lancaster) - were compared with that of Lancaster test for the soils collected from 32 paddy and 27 upland fields with various soil chemical properties. ii) Field trials on comparing to phosphate uptake by plant were accomplished by cultivating rice and corn plants in the pots filled with the soils. Available phosphate of Lancaster test was significantly correlated with those of Mehlich III, Mehlich II, Bray I, Olsen, Kelowna, and Mod. Lancaster. In upland soils, available phosphates of all the tests were curvilinearly regressed with phosphate uptake by corn. The determination coefficients ($R^2$) of the regression equation between available phosphate in soils and phosphate uptake by plants were ranged from 0.861 (Mehlich III) to 0.741 (Olsen). In paddy soils, the available phosphate measured by Mehlich III and Lancaster was significantly correlated with phosphate uptake by rice. In conclusion, Lancaster and Mehlich III tests could be used for predicting available phosphate in upland and paddy soils.

Availability of Chicken Feather for Removal of Hexavalent Chromium and Oil (6가 크롬 및 유류 제거를 위한 우모 폐기물의 이용가능성)

  • Jeong, Jin-Ha;Lee, Na-Ri;Park, Sung-Bo;Jeong, Seong-Yun;Park, Geun-Tae;Son, Hong-Joo
    • Journal of Environmental Science International
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    • v.21 no.3
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    • pp.369-375
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    • 2012
  • We investigated usefulness of chicken feather as bioadsorbent for removal of hexavalent chromium[Cr(VI)] and oil from aqueous solution. Chicken feather was chemically treated with DTPA, EDTA, NaOH and SDS, respectively. Among them, EDTA was the most effective in adsorbing Cr(VI). Cr(VI) uptake by chicken feather was increased with decreasing pH; the highest Cr(VI) uptake was observed at pH 2.0. By increasing Cr(VI) concentration, Cr(VI) uptake was increased, and maximum Cr(VI) uptake was 0.34 mmol/g. Cr(VI) adsorption by chicken feather was well described by Freundlich isotherm than Langmuir isotherm and Freundlich constant(1/n) was 0.476. As the concentration of chicken feather was increased, Cr (VI) removal efficiency was increased but Cr(VI) uptake was decreased. Most of Cr(VI) was adsorbed at early reaction stage(1 h) and adsorption equilibrium was established at 5 h. On the other hand, chicken feather adsorbed effectively oils including bunker-A and bunker-C. In conclusion, our results suggest that chicken feather waste could be used to remove heavy metal and oil; it is a potential candidate for biosorption material.

THE IN VITRO STUDY ON FLUORIDE RELEASE AND FLUORIDE UPTAKE TO DENTIN FROM FLUORIDE CONTAINING LINER / BASE CEMENTS (수종 불소함유 이장용 시멘트의 불소 유리량과 상아질로의 불소흡착정도)

  • Ko, Hyo-Jee;Chung, Hyun-Ju;Oh, Won-Mann
    • Restorative Dentistry and Endodontics
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    • v.18 no.1
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    • pp.27-37
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    • 1993
  • The purpose of this study was to determine the fluroide release levels of new fluoride-containing liner/base cements and the fluoride uptake by dentin surfaces. Ten specimens of each brand (Fuji ionomer Type III, Fuji Lining LC, Timeline, Vitrebond and XR ionomer) were made, polymerized and placed in fluoride-free distilled water at $37^{\circ}C$, 100% relative humidity for 24 hours. The extracting solution of specimen was exchanged and fluoride release was measured daily for the 30 days. For fluoride uptake study, twenty-five extracted human lower molars were sectioned longitudinally in the mesiodistal direction with a diamond disc. Five teeth were filled with each material and then stored at $37^{\circ}C$, 100% humidity for 4 weeks. Fluoride uptake by dentin from the test materials was evaluated using electron probe micro X-ray analyzer. The following results were obtained : 1. The amounts of fluoride release showed no significant difference between Fuji ionomer Type III and Fuji Lining LC, but showed significant difference between other groups. XR ionomer released significantly greater fluoride than any other group(P<.001). 2. All the materials have a burst effect which more fluoride released in then first 3 day and showed significant decrease over the test period (P<0.001). 3. XR ionomer group showed fluoride penetration to approximately $50{\mu}m$ deep in dentin. But other material groups showed very little fluoride uptake by dentin.

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Studies on the removal of cd+2 ion in wastewater by plants I. absorption of cd+2 by dock (rumex crispus l.) plants (植物에 의한 廢水 중의 Cd+2 이온 際去에 關한 硏究 1. 소리쟁이 ( Rumex crispus L. ) 의 Cd+2 吸收)

  • Cha, Young-Ⅱ
    • The Korean Journal of Ecology
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    • v.15 no.2
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    • pp.137-145
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    • 1992
  • When exposed to 1, 700 ml of 0.089, 0.445 or 0.890 mM/l cadmius solution, dock (rumex crispus L)plants from heavily polluted chungrangchon site absorbed 0.0404, 0.2244 or 0.4929 mM of cadmium per g dw during the first 4 hours, which were 5.0~30.8 times faster uptake rate than those of water hyacinth (eichhornia crassipes Solm. - laub). Zinc, with which cadmium generally occurs together, did not affect the uptake rate in the concentration range of 0.0306 ~0.0918 mM/l. rumex cripus from chungrangchon site and from less polluted shingalchon site, when exposed to 1, 700 ml of 0.089 mM/l solution for 3 days, removed 68.4% and 63.2%, repectively, of the cadmium initially present in the solution. And when exposed to cadmium solution of the same concentration for the second time after cadmium-free hydroponic culture for three days, these plants removed 76.1% and 66.8% of cadmium, respectively. These removal rates were not significantly different between collection sites or between exposures, but were about 2 times greater for the first exposure, and 2~5 times greater for the second exposure, than those of water hyacinth. these results incate that rumex cripus can absorb, and thus remove, large amount of cadmium ion in wastewater, and so can be used in wastewater treatment, e.g. soil trench method. since there was large difference among the plants in the ability to absorb cadmium, it should be possible to select for strain with greater ability.

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Effects of Sulfate Ion Concentration in Nutrient Solution on the Growth and Quality of Artemisia mongolicar var. tenuifolia (배양액 내의 황산이온 농도가 참쑥의 생육과 품질에 미치는 영향)

  • Lee, Yun-Jeong;Park, Kuen-Woo;Suh, Eun-Joo;Cheong. Jin-Cheol
    • Journal of Bio-Environment Control
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    • v.7 no.1
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    • pp.55-61
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    • 1998
  • This experiment was conducted to evaluate the effects of sulfate ion concentration in nutrient solution on the growth and qualify of Mongolian wormwood (Artemisia mongolica var. tenuifolia). Sulfate ion concentration was treated 0, 0.5, 1, 2 and 3mM using the modified nutrient solution composition for herb plants developed by European Vegetable R & D Center in Belgium. The growth of Mongolian wormwood was good at 3mM treatment and dry weight was best at 3mM treatment, Chlorophyll content increased with sulfate ion concentration. Mineral content did not show any significant difference among treatments. But Ca content in tissue markedly decreased at 3mM treatment. Sulfate ion uptake increased in proportion to sulfate ion concentration in nutreint solution, the higher sulfate ion concentration, the more uptake of sulfate ion by plant. At 1mM sulfate ion treatment, essential oil content was best, but the higher sulfate ion concentration resulted in decrease of essential oil content.

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Heavy Metals Biosorption from Aqueous Solution by Endophytic Drechslera hawaiiensis of Morus alba L. Derived from Heavy Metals Habitats

  • El-Gendy, Mervat Morsy Abbas Ahmed;Hassanein, Naziha M.;El-Hay Ibrahim, Hussein Abd;El-Baky, Doaa H. Abd
    • Mycobiology
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    • v.45 no.2
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    • pp.73-83
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    • 2017
  • The ability of dead cells of endophytic Drechslera hawaiiensis of Morus alba L. grown in heavy metals habitats for bioremoval of cadmium ($Cd^{2+}$), copper ($Cu^{2+}$), and lead ($Pb^{2+}$) in aqueous solution was evaluated under different conditions. Whereas the highest extent of $Cd^{2+}$ and $Cu^{2+}$ removal and uptake occurred at pH 8 as well as $Pb^{2+}$ occurred at neutral pH (6-7) after equilibrium time 10 min. Initial concentration 30 mg/L of $Cd^{+2}$ for 10 min contact time and 50 to 90 mg/L of $Pb^{2+}$ and $Cu^{2+}$ supported the highest biosorption after optimal contact time of 30 min achieved with biomass dose equal to 5 mg of dried died biomass of D. hawaiiensis. The maximum removal of $Cd^{2+}$, $Cu^{2+}$, and $Pb^{2+}$ equal to 100%, 100%, and 99.6% with uptake capacity estimated to be 0.28, 2.33, and 9.63 mg/g from real industrial wastewater, respectively were achieved within 3 hr contact time at pH 7.0, 7.0, and 6.0, respectively by using the dead biomass of D. hawaiiensis compared to 94.7%, 98%, and 99.26% removal with uptake equal to 0.264, 2.3, and 9.58 mg/g of $Cd^{2+}$, $Cu^{2+}$, and $Pb^{2+}$, respectively with the living cells of the strain under the same conditions. The biosorbent was analyzed by Fourier Transformer Infrared Spectroscopy (FT-IR) analysis to identify the various functional groups contributing in the sorption process. From FT-IR spectra analysis, hydroxyl and amides were the major functional groups contributed in biosorption process. It was concluded that endophytic D. hawaiiensis biomass can be used potentially as biosorbent for removing $Cd^{2+}$, $Cu^{2+}$, and $Pb^{2+}$ in aqueous solutions.