• Title/Summary/Keyword: solution synthesis

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Modified Component Mode Synthesis Method Using Ritz Vectors (Ritz 벡터를 이용한 수정 분할구조해석법)

  • 이인원;김동옥
    • Journal of KSNVE
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    • v.3 no.1
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    • pp.77-82
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    • 1993
  • In general, the dynamic analysis with FEM(Finite Element Method) of large structures requires large computer memory space and long computational time. For the purpose of economical dynamic analysis of large structures, most of engineers want to use an efficient solution algorithm. This paper reports the modified CMS(Component Mode Synthesis) method which uses more efficient algorithm than the classical CMS method. In this paper, it is shown that Ritz vector sets can play the role of normal mode vector sets of substurctures in the CMS algorithm. The modified CMS method has good convergence performance compared with that of the classical CMS method.

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Synthesis and Characterization of Poly(alkyl $\alpha$, L-glutamate-co-ethylene oxide)

  • Kim, Gunwoo;Kim, Jin-Yeol;Daewon Sohn;Lee, Youngil
    • Macromolecular Research
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    • v.10 no.1
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    • pp.49-52
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    • 2002
  • Rod-coil amphiphilic block copolymers, PALG-PEOs, poly(alkyl $\alpha$, L-glutamate-co-ethylene oxide)s, were successfully synthesized in three steps: 1) esterification of L-glutamic acid, 2) synthesis of ${\gamma}$-alkyl L-gultamate N-carboxyanhydride, and 3) polymerization of NCA monomers. These molecules form polymeric micelles with the hydrophobic core and hydrophilic corona in aqueous solution, which were characterized by light scattering and static fluorescence measurement.

Synthesis of Multiple Constant Multiplication Circuits Using GA with Chromosomes Composed of Stack Type Operators

  • Isoo, Yosuke;Toyoshima, Hisamichi
    • Proceedings of the IEEK Conference
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    • 2000.07b
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    • pp.623-626
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    • 2000
  • The purpose of this paper is to find an efficient solution for multiple constant multiplication (MCM) problem. Since the circuit structure can be represented as a directed acyclic graph, evolutionary computing is considered as an effective tool for optimization of circuit synthesis. In this paper, we propose a stack type operator as a chromosome element to synthesize a directed acyclic graph efficiently. This type of chromosome can represent a graph structure with a set of simple symbols and so we can employ the similar method to a conventional GA.

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Sol-gel Synthesis and Properties of Phosphate Ceramics

  • Lee, Burtrand I.;Cao, Zhicheng;Samuels, Willam D.;Exarhos, Gregory J.
    • The Korean Journal of Ceramics
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    • v.6 no.4
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    • pp.390-395
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    • 2000
  • Silicon, titanium, zirconium phosphates were synthesized by starting with appropriate chemical precursors in a solution. The synthetic procedure, chemical and physical structures were examined by FT-IR, liquid and solid state NMR, TGA, SEM, XRD, etc. The phosphates were examined for thermal and electrical properties. Advantages of the synthesis technique and the data on unique structures and thermal properties are reported.

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Synthesis of Poly(enaryloxynitriles) Containing Schiff Bases and Their Thermal Properties

  • 김상곤;한양규;공명선
    • Bulletin of the Korean Chemical Society
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    • v.16 no.4
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    • pp.326-331
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    • 1995
  • Poly(enaryloxynitriles) containing Schiff bases were prepared from p-bis(1-chloro-2,2-dicyanovinyl)benzene (2) and various aromatic diols having Schiff base moiety by interfacial polymerization. The chemical structure of the polymers was confirmed through synthesis of their corresponding model compounds. All the polymers were soluble in polar aprotic solvents and their brittle films were cast from DMF solution. They showed a large exotherm around 340 ℃ attributable to the chemical change of dicyanovinyl group. Especially, curing of azomethine group was observed to occur at 390 ℃ by differential scanning calorimetry. According to the thermogravimetric analyses, they exhibited excellent thermal stability with 60-90% residual weight at 500 ℃ in nitrogen.

The Effect of the Binder to Zeolite Thin Film Coating by Heat Treatment (열처리를 통한 제올라이트 박막 코팅 시 바인더의 영향)

  • Yoo, Young-Seok;Jo, Jun-Ho;Kim, I-Tae
    • Journal of the Korean institute of surface engineering
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    • v.46 no.6
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    • pp.277-282
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    • 2013
  • This study is an experimental attempt to confirm the binder effect of zeolite coating on glass plate by heat treatment. As a result, zeolite was successfully formed with low concentratios of pressure, whose concentration was effective in 10% or more for thin film zeolite coating. And as the content of the binder (TEOS) in mixed coating solution was higher, the zeolite was fastened better on the surface. Above 5% content of the binder in the coating solution, TEOS hindered zeolite synthesis of the precursor and brought to zeolite capacity decrease. Furthermore, when the concentration of the precursor, sedimentation rate of the precursor was higher and the coating efficiency is reduced thereby. Therefore, the most effective concentrations of the precursor and TEOS in the coating solution was 10% and 5%, respectively. It was concluded that zeolite coating is produced by heat treatment method after dipping without hydrothermal synthesis.

Facile Synthesis of Hydroxyapatite by Hydrothermal and Solvent Combustion Methods

  • Bramhe, Sachin N;Lee, Hyun Chul;Chu, Min Cheol;Ryu, Jae-Kyung;Balakrishnan, Avinash;Kim, Taik Nam
    • Korean Journal of Materials Research
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    • v.25 no.9
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    • pp.492-496
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    • 2015
  • Hydroxyapatite (HA), which is an important calcium phosphate mineral, has been applied in orthopedics, dentistry, and many other fields depending upon its morphology. HA can be synthesized with different morphologies through controlling the synthesis method and several parameters. Here, we synthesize various morphologies of HA using two simple methods: hydrothermal combustion and solution combustion. The phase purity of the synthesized HA is confirmed using X-ray diffractometry. It demonstrates that pure phased hydroxyapatite can be synthesized using both methods. The morphology of the synthesized powder is examined using scanning electron microscopy. The effects of pH and temperature on the final powder are also investigated. At $140^{\circ}C$, using the hydrothermal method, nano-micro HA rods with a hexagonal crystal structure can be synthesized, whereas using solution combustion method at $600^{\circ}C$, a dense cubic morphology can be synthesized, which exhibits monoclinic crystal structures.

X-ray Photoelectron Spectroscopy Study of LaFeO3 Powders Synthesized by Solution Combustion (용액연소법으로 제조한 LaFeO3의 XPS 특성)

  • Hwang, Yeon;Kang, Dae-Sik;Park, Mi-Hye;Cho, Sung-Baek
    • Korean Journal of Materials Research
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    • v.18 no.6
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    • pp.313-317
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    • 2008
  • [ $LaFeO_3$ ] powders were synthesized using a method involving solution combustion, and the surface properties of these powders were examined by x-ray photoelectron spectroscopy. As the amount of fuel increased during the synthesis, the $LaFeO_3$ powders became amorphous with a large plate-like shape. It was found that the O 1s spectra were composed of two types of photoelectrons by deconvolutioning the spectra. Photoelectrons with higher binding energy come from adsorbed oxygen ($O^-$) whereas those with lower energy come from lattice oxygen ($O^{2-}$). The ratio of adsorbed and lattice oxygen increased as the ratio of the fuel and nitrate (${\Phi}$) increased. The binding energy of both types of oxygen increased as ${\Phi}$ increased due to the formation of carbonates.

Solution Structure and Backbone Dynamics of the Biotinylation Domain of Helicobacter pylori Biotin-carboxyl Carrier Protein

  • Jung, Jin-Won;Lee, Chul-Jin;Jeon, Young-Ho;Cheong, Chae-Joon;Lee, Weon-Tae
    • Bulletin of the Korean Chemical Society
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    • v.29 no.2
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    • pp.347-351
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    • 2008
  • Acetyl-CoA carboxylase (ACC) is an excellent candidate for antibiotics drug target, which mediates malonyl-CoA synthesis from acetyl-CoA through acetylation process. It is also involved in the committed step of fatty acid synthesis which is essential for living organisms. We have determined the three dimensional structure of C terminal domain of HP0371, biotin-carboxyl carrier protein of H. pyroli, in solution state using heteronuclear multi-dimensional NMR spectroscopy. The structure of HP0371 shows a flatten b-sheet fold which is similar with that of E. coli. However, the sequence and structure of protruding thumb are different with that of E. coli and the thumb shows different basis of structural rigidity based on backbone dynamics data.

Mobility Reduction Scheduling for High-Level Synthesis (상위수준합성을 위한 배정가능범위 축소 스케줄링)

  • Yoo, Hee-Jin;Yoo, Hee-Yong
    • Journal of KIISE:Computer Systems and Theory
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    • v.32 no.7
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    • pp.359-367
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    • 2005
  • This paper presents a scheduling approach for synthesizing pipelined datapaths under resource constraints. The proposed approach evaluates whether or not a scheduling solution can exist in case an operation temporarily is assigned to the earliest or latest control step among the assignable steps for the operation. If a solution cannot be found, it is impossible to assign the operation to that control step due to a violation against resource constraints, and so we can eliminate that control step among candidate assignable control steps. The proposed algorithm builds up a schedule based on gradual mobility reduction and finds a solution that yields high performance by evaluating on the impact on register assignment. Experiments on benchmarks show that this approach gains a considerable improvement over previous approaches.