• 제목/요약/키워드: solution resistance

검색결과 1,861건 처리시간 0.028초

거품 제어에 의해 형성된 무정형 그물망 구조의 니켈이 코팅된 은나노와이어 유연 투명전극의 특성 분석 (Characterization of Nickel-coated Silver Nanowire Flexible Transparent Electrodes with a Random-mesh Structure Formed by Bubble Control)

  • 박종설;박태곤;박진석
    • 반도체디스플레이기술학회지
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    • 제19권3호
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    • pp.36-42
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    • 2020
  • Silver nanowire (AgNW) random-meshes with high transmittance, low sheet resistance, and high oxidation stability and flexibility were fabricated using solution-based processes. The random-mesh structure was obtained by forming bubbles whose sizes and densities were controlled using a corona treatment of polyethylene terephthalate (PET) substrates. To reduce the sheet resistance of the fabricated AgNW electrode, a washing process using ethanol solution was performed. In addition, nickel (Ni) was coated on AgNW to improve resistance to oxidation. The effects of corona treatment and Ni-coating on the transmittance, sheet resistance, oxidation stability, and flexibility of the AgNW electrodes were investigated.

PZT의 무전해 니켈도금의에 미치는 액조현성의 영향 (Effect od solution composition on electroless Ni plating on PZT)

  • 김제경;이명훈;문경만
    • 한국표면공학회지
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    • 제31권4호
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    • pp.209-216
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    • 1998
  • It is well knownthat electroledd plating is the desirable surface treatment method which is being widely used to all kinds of material such as requiring corrosing resistance, wear resistance and conductivity, especially nonconductivity materials' surface plating. However, it is suggested that there are some problems that must be solved, for exaple, rate of plating, corrosion resistance, thickness of plating film etc. Therefore in this paper, when electroless nickel plating was performed on the PZT(Pb(Zr,Ti))with varying of solution composition such as NaOH, and $H_2NCH_2COOH$, the effect of the rate of plating and corrosion resistance were investigated.

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(1-x)$CaMnO_{3}-xCaTiO_{3}$계 세라믹스의 전기적 특성 (Electrical Properties of (1-x)$CaMnO_{3}-xCaTiO_{3}$Ceramic System)

  • 안순영;윤상옥;윤종훈;장성식
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2000년도 하계학술대회 논문집
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    • pp.865-868
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    • 2000
  • It was examined that the relationship between microstructures, electrical properties and crystal structure of (1-x)CaMnO$_3$-xCaTiO$_3$solid solution system which was made by mixing a semiconducting material CaMnO$_3$of low resistance and a dielectric material CaTiO$_3$of high resistance with variable ratios (x=0, 0.1, 0.3, 0.5, 0.7, 0.9, 1.0). As the CaTiO$_3$increased, the resistance, B constant and lattice constant were increased, but the grain size was decreased. On particular, above 50wt% of CaTiO$_3$, the resistance at 2 5$^{\circ}C$ was rapidly increased due to the correlation in connectivity of the lattices between the conductive Mn$^{+4}$ octahedron and the insulative Ti$^{+4}$ octahedron.ron.

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소금용액에 포함된 글루코오스 농도의 전기화학적 측정 (Electrochemical Determination of Glucose Concentration Contained in Salt Solution)

  • 김영한
    • 한국항만학회지
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    • 제14권4호
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    • pp.475-479
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    • 2000
  • A possibility of the implementation of a quartz crystal sensor to the determination of chemical oxygen demand is examined by checking the electrochemical behavior of the sensor in a glucose solution. Since the surface of a quartz crystal has to be oxidized, a relatively active metal is coated on the surface of a usual 9 MHz AT-cut crystal. The electrochemical behavior is investigated by measuring the changes of current, resonant frequency and resonant resistance while a constant potential is applied. The crystal is installed in a specially designed container, and a quartz crystal analyzer is utilized to measure the frequency and resistance simultaneously. The variations of the measurements are examined at different concentrations of glucose solution, and a proper relation between the concentrations of glucose solution, and a proper relation between the concentration and the measurements is analyzed. As a result, it is found that a linear relation between the concentration of less than 900 ppm and the peak current when a constant potential of -180 mV (SSCE) is applied. The relation can be utilized for the determination of glucose concentration in sea water, and considering a direct relation between gluose concentration and chemical oxygen demand tells a possibility of the measurement of chemical oxygen demand using quartz crystal oscillators.

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국산동판을 사용한 리드프레임 도금기술에 관한 연구 (Electroplating on the Lead Frames Fabricated from Domestic Copper Plate)

  • 장현구;이대승
    • 한국표면공학회지
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    • 제19권3호
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    • pp.92-108
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    • 1986
  • An electroplating on the lead frame fabricated from domestic copper plate was studied experimentally. In this study, nickel was plated on the thin copper lead frame and silver layer was coated on the nickel film in the cyanide electrolyte. The effect of process variables such as current density, plating time, coating thickness and flow rate of electrolytic solution on the properties of coating was investigated. Some samples on each step were fabricated during electroplating. The results obtained from polarization measurement, observation of SEM photograph, adhesion test of coating and microhardness test are as follows. On silver plating, polarization resistance of potentiostatic cathodic polarization curve is reduced as the flow rate of Ag electrolytic solution increases. And above resistance is also reduced when the minor chemicals of sodium cyanide and sodium carbonate are added in potassium silver cyanide bath. The reduced polarization resistance makes silver deposition on the cathode easy. An increase in the current density and the coating thickness causes the particle size of deposit to coarsen, and consequently the Knoop microhardness of the coating decreases. On selective plating an increase in the flow rate of plating solution lead to do high speed plating with high current density. In this case, the surface morphology of deposit is of fine microstructure with high Knoop hardness. An increasing trend of the adhesion of coating was shown with increasing the current density and flow rate of electrolytic solution.

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Effects of Inhibitors on Corrosion Resistance of Steel in CaCl2 Solution Based on Response Surface Analysis

  • Park, Tae-Jun;Jang, HeeJin
    • Corrosion Science and Technology
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    • 제20권3호
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    • pp.129-142
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    • 2021
  • Effects of corrosion inhibitors (i.e., sodium nitrite, sodium hexametaphosphate, trimethylamine (TEA), sugar, and urea) on the corrosion resistance of carbon steel in CaCl2 solution were investigated. The test solution was designed with response surface methodology of design of experiments (DOE) in the range of 0 ~ 50 ppm for NaNO2, 0 ~ 200 ppm for (NaPO3)6, 0 ~ 2000 ppm for TEA, 0 ~ 3000 ppm for sugar, 0 ~ 200 ppm for urea with 3 wt% CaCl2. The corrosion potential and the corrosion rate were measured with potentiodynamic polarization tests and analyzed statistically to find main effects of inhibitor concentrations and interactions between them. As a result, hexametaphosphate was the most effective compound in reducing the corrosion rate. Sugar also reduced the corrosion rate significantly possibly because it covered the surface effectively with a high molecular weight. The inhibiting action of sugar was found to be enhanced by adding trimethylamine into the solution. Nevertheless, trimethylamine did not appear to be effective in inhibiting corrosion by itself. However, urea and sodium nitrite showed almost no inhibition on corrosion resistance of steel.

그라우팅 영역이 선형열원 해석에 미치는 영향에 관한 연구 (A Study of the Effect of Grouting Region on the Solution of Line Source Analysis)

  • 이세균;우정선;노정근
    • 에너지공학
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    • 제19권3호
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    • pp.143-150
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    • 2010
  • 선형열원 해석은 열원 주위가 완전히 균일한 매질로 이루어져 있다는 가정 하에 성립되는 해석이나 실제 보어홀 시스템의 경우 그라우팅 영역은 주위토양과 매우 다른 열물성치를 가진 물질로 이루어져 있다. 본 연구에서는 이러한 그라우팅 영역이 선형열원 해석에 어떠한 영향을 미치는가를 연구하였다. 연구방법으로는 먼저 수치모델을 개발하고 이 수치모델에 의하여 시간에 따른 보어홀 유체온도를 생성한 후 이 유체온도를 선형열원법에 이용하여 지중열전도도와 보어홀 전열저항을 구하며 이렇게 구한 해를 수치모델의 입력조건과 비교함으로서 그 차이점을 규명한다. 이러한 해석결과 선형열원법의 해인 지중열전도도와 보어홀 전열 저항은 수치모델 입력조건에 비해 대략, 86%와 91%의 수준으로 나타났다. 선형열원 해로부터 수치모델의 입력조건을 역산해 나가는 Chart법이 본 연구에서 개발되었으며 시험용 보어홀의 열응답시험 결과와 비교해 본 결과 이 Chart법은 신뢰성이 있는 것으로 나타났다. 그라우트 영역의 열물성치를 변화시켜가며 선형열원해의 특성이 어떻게 변하는지도 검토하였다.

1액형 광촉매를 아스팔트 포장에 적용하기 위한 기초연구 (Fundamental Study on Applying an Integral TiO2 Solution to Asphalt Pavement)

  • 박재영;김영;김혁중;황용경;이재준
    • 한국도로학회논문집
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    • 제19권1호
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    • pp.53-62
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    • 2017
  • PURPOSES : This research was a fundamental study on the application of an integral $TiO_2$ solution to asphalt concrete pavement. The integral $TiO_2$ solution was produced in pilot production equipment; application of the integral $TiO_2$ solution to asphalt pavement was conducted to examine the pollution-reducing capability of photocatalytic compounds such as $TiO_2$. The photocatalytic $TiO_2$ reacted with air pollutants, converting them into small amounts of relatively benign molecules. METHODS : In this study, laboratory experiments were conducted using five various testing methods. Tensile strength ratio (TSR) and British pendulum test (BPT) were conducted in order to evaluate the properties of asphalt pavement subsequent to the integral $TiO_2$ solution coating. In addition, methylene blue testing, a measurement of nitrate on the coated pavement, and nitrogen oxide (NOx) reduction testing were conducted in order to evaluate photocatalytic reaction. Lastly, a UV-A lamp was used as a light source for photocatalytic reactions. RESULTS : Test results indicated no change in the properties of asphalt pavement following the integral $TiO_2$ solution coating. In order to evaluate the performance of asphalt pavement as a function of $TiO_2$, the moisture susceptibility and skid resistance were investigated. The moisture susceptibility and skid resistance satisfied there quirements related to pavement quality and safety specification. Furthermore, the effects of reduction of air pollution were significantly improved as determined via the methylene blue test and NOx reduction test. The $TiO_2$-paved asphalt specimen exhibited approximately 43% reduction of NOx. CONCLUSIONS : This study has suggested that applying $TiO_2$ rarely impacts asphalt pavement performance measures such as moisture susceptibility and skid resistance, and that its application may be a better means of reducing air pollution. Further studies, such as proper $TiO_2$ dosage rates and compatibility with various pavement types, are required to broaden and generalize its application.

Nb 함량에 따른 Ti-Nb계 합금의 내식성에 대한 연구 (A study on corrosion resistance of Ti-Nb alloys by Nb contents)

  • 박근형
    • 대한치과기공학회지
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    • 제28권1호
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    • pp.61-66
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    • 2006
  • Titanium alloys have been used for dental materials due to it's very good biocompatibility. Ti-6Al-4V alloy instead of pure titanium is being widely used as biomaterials has some characteristics such as high fatigue strength, tensile strength and corrosion resistance. But it has been reported recently that the vanadium element expresses cytotoxicity and carcinogenicity and the aluminium element is related with dementia of Alzheimer type and neurotoxicity. The Ti-Nb alloys has designed and examined corrosion resistance. Ti-3wt.%Nb($\alpha$type), Ti-20wt.%Nb(${\alpha}+{\beta}$type) and Ti-40wt.%Nb($\beta$type) alloys were melted by vacuum arc furnace. The corrosion resistance of Ti alloys was evaluated by potentiodynamic polarization test in the solution of 0.9% NaCl and 5% HCl. The results can be summarized as follows: 1) For the corrosion test in the solution of 0.9% NaCl and 5% HCl, the corrosion behaviour of Ti-Nb alloys was similar to ASTM grade 2 CP Ti. 2) The corrosion resistance of Ti-20Nb alloy was better than that of CP-Ti, Ti-3Nb, Ti-40Nb alloy in 0.9% NaCl and 5% HCl, solutions.

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알칼리 활성화 슬래그 시멘트 모르타르의 내황산성 (Resistance of Alkali Activated Slag Cement Mortar to Sulfuric Acid Attack)

  • 민경산;이승헌
    • 한국세라믹학회지
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    • 제44권11호
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    • pp.633-638
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    • 2007
  • The setting time of alkali activated slag cement tends to be much faster than ordinary Portland cement, and its compressive strength had been higher from the 1 day but became lower than that of the cement on the 28 days. According to the results of the surface observation, weight loss, compressed strength, and erosion depth tests on the sulphuric acid solution. It has been drawn that alkali activated slag cement has a higher sulphate resistance than ordinary Portland cement, and in particular, the alkali activated slag cement added 5 wt% alumina cement has little deterioration on the sulphuric acid solution. The reason why the alkali activated slag cement has higher sulphate resistance than other hardened cement pastes is that it has no $Ca(OH)_2$ reactive to sulphate ion, and there is little $CaSO_4{\cdot}2H_2O$ production causing volume expansion, unlike other pastes. And it is supposed that $Al(OH)_3$ hydrates with high sulphate resistance, which is produced by adding the alumina cement increases the sulfate resistance.