• Title/Summary/Keyword: solution leakage

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Fabrications and Properties of VF2-TrFE Films for Nonvolatile Memory Application (비휘발성 메모리 응용을 위한 VF2-TrFE 박막의 제작 및 특성)

  • Jeong, Sang-Hyun;Byun, Jung-Hyun;Kim, Hyun-Jun;Kim, Ji-Hun;Kim, Kwang-Ho
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.388-388
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    • 2010
  • In this study, Ferroelectric vinylidene fluoride-trifluoroethylene (VF2-TrFE) copolymer films were directly deposited on degenerated Si (n+, $0.002\;{\Omega}{\cdot}cm$) using by spin coating method. A 1~5 wt% diluted solution of purified vinylidene fluoride-trifluoroethylene (VF2:TrFE = 70:30) in a dimethylformamide (DMF) solvent were prepared and deposited on silicon wafers at a spin rate of 2000 ~ 4000 rpm for 2 ~ 30 seconds. After annealing in a vacuum ambient at 100 ~ $200^{\circ}C$ for 60 min, upper aluminum electrodes were deposited by vacuum evaporation for electrical measurement. X-ray diffraction results showed that the VF2-TrFE films on Si substrates had $\beta$-phase of copolymer structures. The capacitance on highly doped Si wafer showed hysteresis behavior like a butterfly shape and this result indicates clearly that the copolymer films have ferroelectric properties. The typical measured remnant polarization ($P_r$) and coercive filed ($E_c$) values were about $5.7\;{\mu}C/cm^2$ and 710 kV/em, respectively, in an applied electric field of ${\pm}$ 1.5 MV/em. The gate leakage current densities measured at room temperature was less than $7{\times}10^{-7}\; A/cm^2$ under a field of 1 MV/cm.

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Fabrications and Properties of Al/$VF_2$/$n^+$-Si(100) Structures by Dip Coating Methode (Dip Coating 법에 의한 Al/$VF_2$-TrFE/Si(100) 구조의 제작 특성)

  • Kim, Ka-Lam;Jeong, Sang-Hyun;Yun, Hyeong-Seon;Lee, Woo-Seok;Kwak, No-Won;Kim, Kwang-Ho
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.20-21
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    • 2008
  • Ferroelectric vinylidene fluoride-trifluoroethylene ($VF_2$-TrFE) copolymer films were directly deposited on degenerated Si ($n^+$, 0.002 $\Omega{\cdot}cm$) using by dip coating method. A 1 ~ 3 wt% diluted solution of purified vinylidene fluoride-trifluoroethylene ($VF_2$:TrFE=70:30) in a dimethylformamide (DMF) solvent were prepared and deposited on silicon wafers using dip coating method for 10 seconds. After Post-Annealing in a vacuum ambient at 100~200 $^{\circ}C$ for 60 min, upper aluminum electrodes were deposited by thermal evaporation through the shadow mask to complete the MFS structure. The ferroelectric $\beta$-phase peak of films, depending on the annealing temperature, started to show up around $125^{\circ}C$, and the intensity of the peak increased with increasing annealing temperature. Above $175^{\circ}C$, the peak started to decrease. The C-V characteristics were measured using a Precision LCR meter (HP 4284A) with frequency of 1MHz and a signal amplitude of 20 mV. The leakage-current versus electric-field characteristics was measured by mean of a pA meter/DC voltage source (HP 4140B).

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A Study on the Synthesis and Characterization of Polymerizable Bolaamphiphiles (중합성 Bolaamphiphile 분자의 합성과 특성에 관한 연구)

  • Jin, Ji Young;Ko, Seuk-Beum;Jeong, Myung Hee;Choi, Kyoung Hee;Lee, Youn-Sik
    • Applied Chemistry for Engineering
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    • v.8 no.1
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    • pp.59-66
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    • 1997
  • Di(10-hemisuccinyloxy)decyl muconate(DDM) and di(6-hemisuccinyloxy)hexyl muconate(DHM) were synthesized, and showed a phase transition in an aqueous solution at 97 and $79^{\circ}C$, respectively. They did not form liposomes by themselves or even in the presence of cholesterol or dioleoylphosphatidylethanolamine(DOPE), but did form liposomes when they were mixed with phosphatidylcholine(PC). DHM molecules in liposome membranes were readily polymerized via 1,2-polymerization process on exposure to 254nm. Liposomes composed of DOPE/dioleoylphosphatidylcholine(DOPC)/DHM(3/3/1) were stable at neutral pH, but leaky at weakly acidic pH. The leakage of entrapped calcein from liposomes in phosphate-buffered saline (PBS, $37^{\circ}C$) of pH 4.8 and 5.8 was complete within 30 and 50 min, respectively. The release of toke entrapped calcein was increased with decreasing pH such that 50% and 100% of the calcein were released at pH near 5.5 and 5.0, respectively.

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The Study of Optimized Combustion Tuning Method for Fossil Power Plant (발전용 보일러의 최적연소조정기법에 대한 실험적 연구)

  • Jung, Jae-Jin;Song, Jung-Il
    • Journal of the Korean Solar Energy Society
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    • v.29 no.5
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    • pp.45-52
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    • 2009
  • Fossil power plants firing lower grade coals or equipped with modified system for $NO_x$ controls are challenged with maintaining good combustion conditions while maximizing generation and minimizing emissions. In many cases significant derate, availability losses and increase in unburned carbon levels can be attributed to poor combustion conditions as a result of poorly controlled local fuel and air distribution within the boiler furnace. In order to develop a on-line combustion tuning system, field test was conducted at operating power boiler. During the field test the exhaust gases' $O_2,\;NO_x$ and CO was monitored by using a spatially distributed monitoring grid located in the boiler's high temperature vestibule and upper convective rear pass region. At these locations, the flue gas flow is still significantly stratified, and air in-leakage is minimal which enables tracing of poor combustion zones to specific burners and over-fire air ports. using these monitored information we can improving combustion at every point within the furnace, therefore the boiler can operate at reduced excess $O_2$ and gas temperature deviation, reduced furnace exit gas temperature levels while also reducing localized hot spots, corrosive gas conditions, slag or clinker formation and UBC. Benefits include improving efficiency, reducing $NO_x$ emissions, increasing output and maximizing availability. Discussion concerning the reduction of greenhouse gases is prevalent in the world. When taking a practical approach to addressing this problem, the best way and short-term solution to reduce greenhouse gases on coal-fired power plants is to improve efficiency. From this point of view the real time optimized combustion tuning approach is the most effective and implemented with minimal cost.

Thermal Stability and Electrical Properties of $HfO_xN_y$ ($HfO_2$) Gate Dielectrics with TaN Gate Electrode (TaN 게이트 전극을 가진 $HfO_xN_y$ ($HfO_2$) 게이트 산화막의 열적 안정성)

  • Kim, Jeon-Ho;Choi, Kyu-Jeong;Yoon, Soon-Gil;Lee, Won-Jae;Kim, Jin-Dong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07a
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    • pp.54-57
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    • 2003
  • [ $HfO_xN_y$ ] films using a hafnium tertiary-butoxide $(Hf[OC(CH_3)_3]_4)$ in plasma and $N_2$ ambient were prepared to improve the thermal stability of hafnium-based gate dielectrics. A 10% nitrogen incorporation into $HfO_2$ films showed a smooth surface morphology and a crystallization temperature as high as $200^{\circ}C$ compared with pure $HfO_2$ films. The $TaN/HfO_xN_y/Si$ capacitors showed a stable capacitance-voltage characteristics even at post-metal annealing temperature of $1000^{\circ}C$ in $N_2$ ambient and a constant value of 1.6 nm EOT (equivalent oxide thickness) irrespective of an increase of PDA and PMA temperature. Leakage current densities of $HfO_xN_y$ capacitors annealed at PDA temperature of 800 and $900^{\circ}C$, respectively were approximately one order of magnitude lower than that of $HfO_2$ capacitors.

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Effect and Issues on the Water Supply Network Management System in Kwangju (광주시 상수도관망관리시스템의 효과 및 문제점에 관한 연구)

  • 오창수
    • Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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    • v.16 no.1
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    • pp.103-110
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    • 1998
  • This study deals with the effective management system on the underground facilities by Geographic In-formation System (GIS). For this purpose,"Management System on the Water Supply Network by GIS in Kwangju" was analylized. Following results were obtained in this study. This system could be practically used for the inquiry of water supply and distribution pipes, check valves, pipe equipments and parcel identification numbers. Inquiry of addresses using the parcel identification numbers were effective for the database management system of the water supply facilities. The poits at issue for the performance of this study were the security and education of experts, the security of revenue source, the discord between GIS companies concerned. Establishments of GIS software technologies and database systems, and the settlement between GIS companies were required for the solution of these poits. Development of computer management systems on the water sup-ply network by GIS enabled the replacement of outworn pipes and the leakage inquiry techniques in pipes. in pipes.

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Measurements of Vibration and Pressure of an Oxidizer Pump for a 7-tonf Turbopump with a Modified Rear Floating Ring Seal (수정된 후방 플로팅 링 실을 적용한 7톤급 터보펌프 산화제 펌프의 진동 및 압력 측정)

  • Bae, JoonHwan;Kwak, Hyun-Duck;Choi, ChangHo;Choi, JongSoo
    • Tribology and Lubricants
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    • v.36 no.5
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    • pp.253-261
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    • 2020
  • In this paper, we present an experimental investigation of the frequency characteristics and a visual inspection of an oxidizer pump with a modified rear-floating ring seal for a 7-tonf turbopump. An oxidizer pump typically operates at high rotational speeds and under cryogenic conditions. Despite its low hydraulic efficiency, the floating ring seal is frequently employed as a leakage control solution for turbomachinery because it effectively reduces abrasion by friction. When the oxidizer pump starts up, the floating ring moves excursively but locks up stably against the pump casing when the contact pressure increases. The compressive force on the floating ring depends on the hydrodynamic forces induced by the flow through the floating ring. This force is controlled by the nose position of the floating ring. Based on a validation test for a 7-tonf turbopump with two types of floating rings, we concluded that the floating ring with a small diameter nose can move easily with a low contact pressure in the cooling path. This leads to instability of the pressure fluctuation around the floating ring. In contrast, a floating ring with a large diameter nose has a high contact pressure and attaches strongly to the casing, which causes wear and frictional oxidation between the contact surfaces of the impeller and the floating ring.

A Study on filament Winding Process of A CNG Composite Pressure Vessel (필라멘트 와인딩 압력용기의 최적설계와 CNG자동차 연료 충진용기 개발)

  • Kim, Eui-Soo;Kim, Ji-Hoon;Park, Yoon-So;Kim, Chul;Choi, Jae-Chan
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2002.10a
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    • pp.933-937
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    • 2002
  • The fiber reinforced composite material is widely used in the multi-industrial field where the weight reduction of the infrastructure is demanded because of their high specific modulus and specific strength. Pressure vessels using this composite material in comparison with conventional metal vessels can be applied in the field where lightweight and the high pressure are demanded from the defense and aerospace industry to rocket motor case due to the merits which are energy cutdown the weight reduction and decrease of explosive damage preceding to the sudden explosion which is generated by the pressure leakage condition). In this paper, for nonlinear finite element analysis of E-glass/epoxy filament winding composite pressure vessel receiving an internal pressure, the standard interpretation model is developed by using the ANSYS, general commercial software, which is verified as the accuracy and useful characteristic of the solution based on Auto LISP and ANSYS APDL. Both the preprocessor for doing exclusive analysis of filament winding composite pressure vessel and postprocessor that simplifies result of analysis have been developed to help the design engineers.

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Hop-by-Hop Dynamic Addressing Based Routing Protocol for Monitoring of long range Underwater Pipeline

  • Abbas, Muhammad Zahid;Bakar, Kamalrulnizam Abu;Ayaz, Muhammad;Mohamed, Mohammad Hafiz;Tariq, Moeenuddin
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.11 no.2
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    • pp.731-763
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    • 2017
  • In Underwater Linear Sensor Networks (UW-LSN) routing process, nodes without proper address make it difficult to determine relative sensor details specially the position of the node. In addition, it effects to determine the exact leakage position with minimized delay for long range underwater pipeline monitoring. Several studies have been made to overcome the mentioned issues. However, little attention has been given to minimize communication delay using dynamic addressing schemes. This paper presents the novel solution called Hop-by-Hop Dynamic Addressing based Routing Protocol for Pipeline Monitoring (H2-DARP-PM) to deal with nodes addressing and communication delay. H2-DARP-PM assigns a dynamic hop address to every participating node in an efficient manner. Dynamic addressing mechanism employed by H2-DARP-PM differentiates the heterogeneous types of sensor nodes thereby helping to control the traffic flows between the nodes. The proposed dynamic addressing mechanism provides support in the selection of an appropriate next hop neighbour. Simulation results and analytical model illustrate that H2-DARP-PM addressing support distribution of topology into different ranges of heterogeneous sensors and sinks to mitigate the higher delay issue. One of the distinguishing characteristics of H2-DARP-PM has the capability to operate with a fewer number of sensor nodes deployed for long-range underwater pipeline monitoring.

Studies on the Sorption and Fixation of Cesium by Vermiculite (II)

  • Lee, Sang-Hoon
    • Nuclear Engineering and Technology
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    • v.6 no.2
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    • pp.97-111
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    • 1974
  • The adsorption mechanism of Cs-137 in low level radioactive solution by vermiculite treated with Na ion is studied in order to investigate its effective utilization for the radioactive effluent treatment. The beneficial role of Na-vermiculite is that Na ion can induce the wider c-axis spacing in which Cs ion can be sorbed in vermiculite. Cation exchange capacity and distribution coefficient of cesium seems to be influenced by the variation of c-axis spacing of vermiculite. Comparative identification and detection with the characteristic analyses of X-ray diffraction and electron diffraction patterns, diffrential thermal analysis and electron microscopy of Na-, K- and Cs-vermiculite are studied for the phemomena of Cs adsorption by vermiculite. This importance of the utilization in terms of adsorption and fixation of cesium involving vermiculite is discussed. It is found that the Na-vermiculite is valuable outside charging material for high level radioactive liquid waste storage tank of underground to protect the pollution of the underground water.

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