• Title/Summary/Keyword: solution casting

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A Study on Development of the Three-Dimensional Numerical Model to Analyze the Casting Process: Mold Filling and Solidification

  • Mok Jinho
    • Journal of Mechanical Science and Technology
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    • v.19 no.7
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    • pp.1488-1502
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    • 2005
  • A three dimensional model was developed to analyze the mold filling and solidification in the casting processes. The model uses the VOF method for the calculation of the free surface and the modified Equivalent Specific Heat method for the treatment of the latent heat evolution. The solution procedure is based on the SIMPLER algorithm. The complete model has been validated using the exact solutions for phase change heat transfer and the experimental results of broken water column. The three-dimensional model has been applied to the benchmark test and the results were compared to those from experiment, a two-dimensional analysis, and another three dimensional numerical model.

Effect of Nonsolvent Additive in Casting Solutions on Polysulfone Membrane Preparation (Polysilfone 막의 제조에 있어 제막용액에 첨가된 비용매의 영향)

  • 한명진
    • Membrane Journal
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    • v.6 no.3
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    • pp.157-165
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    • 1996
  • Polysulfone(PS) membranes were prepared from homogeneous PS solutions by the phase inversion technique. When propionic acid(PA) was added into a casting solution of n-methylpyrrolidone(NMP) and PS, precipitation rate of the solution film was accelerated. This kind of acceleration was consistent, even though a precipitating nonsolvent was changed from water to isopropanol. These phenomena were caused by decrease of nonsolvent tolerance in the casting solution due to addition of PA. PS powder was prepared by precipitation of a 3wt% solution in dimethylformamide(DMF) using ethanol as nonsolvent. Gas adsorption analysis of the powder showed that the capillary condensation sites were found in the powder structure. Membranes prepared from PS solution(15wt%) in NMP had the following characteristics of gas adsorption and water permeation. In gas adsorption analysis, the membrane precipitated using isopropanol showed low uptake of nitrogen gas and the capillary condensation sites were not found. On the contrary, a significant amount of the capillary condensation sites was found in the membrane coagulated by water, which was related to increase of nitrogen uptake. tn the membrane prepared froin the solution including PA, an increase of the Henry's law sites and the Langmuir sites was not found clearly. However, the capillary condensation sites were significantly increased, and the water transport also increased.

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Exposure Assessments of Chemical Risk Factors to Airborne Contaminants in Foundry Process (주물사업장 내 공기중 화학적 유해인자 노출 평가)

  • Bae, Hye-Jeong;Nam, Mi-Ran;Lee, Sang-Man;Jung, Yu-Jin;Shon, Byung-Hyun;Phee, Young-Gyu;Jung, Jong-Hyeon
    • Journal of Environmental Science International
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    • v.24 no.5
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    • pp.699-708
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    • 2015
  • This study was performed to identify the state of the exposure and characteristics of pollutants by each process at 4 casting sites located in Gyeongsang-do from April to November 2013. The concentrations of methanol, crystallized silica glass, formaldehyde and phenol were analyzed by different process - casting process, molding process, core process, and shakeout & finishing process. The highest concentration of methanol was found in casting and molding process, whereas the highest concentration of crystalline quartz(Silica) was observed in core process. The most oxidized steel dusts and the highest concentration of fume were found in shakeout & finishing process. As a result of this study, those labors working at the casting site were found to be constantly exposed to various forms of hazardous chemicals; therefore, it is considered that this is the time to manage and plan how to reduce them. In addition, it is required to thoroughly manage the local exhauster, and improve the process and working environment to reduce various forms of hazardous chemicals.

The Optimization of Continuous Casting Process for Production of Copper Clad Steel Wire (동피복 복합선재 제조를 위한 연속주조공정의 최적화)

  • Cho, Hoon;Kim, Dae-Geun;Hwang, Duck-Young;Jo, Hyung-Ho;Kim, Yun-Kyu;Kim, Young-Jig
    • Journal of Korea Foundry Society
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    • v.25 no.6
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    • pp.259-264
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    • 2005
  • The copper clad steel wire is used extensively as lead wires of electronic components such as capacitors, diodes and glass sealing lamp because the wire combines the strength and low thermal expansion characteristic of Fe-Ni steel with the conductivity and corrosion resistance of copper. In order to fabricate the copper clad steel wire, several processes including electro-plating, tubecladding extrusion process and dip forming process have been introduced and applied. The electroplating process for the production of copper clad steel wire shows poor productivity and induces environmental load generation such as electroplating solution. The dip forming process is suitable to mass production of copper clad steel such as trolley wire. and need expensive manufacturing facilities. The present paper describes the improvement of the conventional continuous casting process to fabricate copper clad steel wire, which its core metal is low thermal expansion Fe-Ni alloy and its sheath material is copper. In particular, the formation of intermetallic compound at interface between core and sheath was investigated in order to introduce optimum continuous casting process parameter for fabrication of copper clad steel wire with higher electrical conductivity. The mechanical strength of copper clad steel wire was also investigated through wiredrawing process with of 95% in total reduction ratio.

Tutorial Review on Membrane Classification and Preparation Methods (멤브레인 분류 및 제조 방법에 대한 튜토리얼 총설)

  • Moon, Seung Jae;Kim, Young Jun;Kim, Jong Hak
    • Membrane Journal
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    • v.32 no.3
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    • pp.198-208
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    • 2022
  • Membrane can selectively separate various substances such as organic substances, liquids, solutes, vapors, gases, ions or electrons according to the separation technology and various uses. Membranes are largely divided into symmetric membranes and asymmetric membranes, and classified into porous and nonporous structure depending on the presence or absence of pores. Also, the interface of the membrane may be molecularly uniform, or chemically or physically non-uniform. Preparation techniques include melt extrusion, stretching, template leaching, track-etching, solution casting, phase inversion, and solution coating method. The prepared membrane can be applied to various applications such as microfiltration, ultrafiltration, nanofiltration, reverse osmosis, gas separation and energy fields. This review provides a tutorial on how to prepare membranes according to the classification and types.

Consolidation of Quartz Powder by the Geopolymer Technique

  • Ikeda, Ko;Nakamura, Yoshinori
    • The Korean Journal of Ceramics
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    • v.6 no.2
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    • pp.120-123
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    • 2000
  • The geopolymer technique may be a future-oriented technology for saving energies and resources. This technique requires 3 fundamental elements so-called filler, hardener and geopolymer liquor being generally an alkaline silicate solution. Quartz powder, water quenched granulated blast furnace slag and sodium silicate solution prepared from $Na_2O\cdot2SiO_2$were chosen for these three elements. After mixing these starting materials in appropriate proportions, monoliths were prepared by casting at room temperature. Strength tests showed the following results for 28d age speciment: 7.9-12.7 MPa in flexural strength and 20.2-32.8 MPa in compressive strength, depending on geopolymer liquor/solid ratio, P/S and fineness of the quartz powders used.

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Tyrosinase-Immobilized Biosensor Based on Ionic Property-Modified MWNTs Prepared by Radiation-Induced Graft Polymerization

  • Ryu, Ha-Na;Choi, Seong-Ho
    • Carbon letters
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    • v.11 no.3
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    • pp.216-223
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    • 2010
  • Two-types of ionically modified multi-walled carbon nanotube (MWNTs) based sensors were developed by radiationinduced graft polymerization using vinyl monomers such as 3-(butyl imidazol)-2-(hydroxyl)propyl methyl methacrylate and 1-[(4-ethenylphenyl)methyl]-3-buthyl-imidazolium chloride with ionic properties, in aqueous solution at room temperature. Subsequently, the tyrosinase-immobilized biosensor was fabricated by a hand-casting of the ionic property-modified MWNTs, tyrosinase, and chitosan solution as a binder onto ITO glass surface. The sensing ranges of the tyrosinase-biosensor for phenol in phosphate buffer solution was in the range of 0.005~0.2 mM. The total phenolic compounds mainly such as caffeine of the tyrosinase-immobilized biosensor for commercial coffee were also determined.

[ $Ag^+$ ]-Chitosan Complex Membranes for Propylene/Propane Separation

  • Kim, Jeong-Hoon;Lee, Soo-Bok;Feng, Xianshe
    • Korean Membrane Journal
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    • v.8 no.1
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    • pp.36-42
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    • 2006
  • We have prepared new water-swollen chitosan-$Ag^+$ complex membranes and studied their permeation and separation behavior for propylene and propane gases. The $Ag^+$ containing chitosan complex membranes were prepared from chitosan and $AgNO_3$ aqueous solution. The $AgNO_3$ and water content in the membrane were controlled by adjusting $AgNO_3$ concentration of casting solution. The permeation properties of propylene and propane were investigated as a function of $AgNO_3$ concentration, and various operation conditions. High permeability of above 17 barrer and high selectivity of above 170 could be obtained with the membranes prepared from 3 M $AgNO_3$ aqueous solution. Periodic regeneration test confirmed these membranes could be very useful for the separation of propylene/propane and other olefin/paraffin separation.

Preparation and Characterization of PVA/SA Blend Nanofiltration membranes

  • Llee, Kew-Ho
    • Korean Membrane Journal
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    • v.1 no.1
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    • pp.86-92
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    • 1999
  • The nanofiltration (NF) membranes based on poly(vinyl alcohol) (PVA) and sodium alginate (SA) were prespared. Homogeneous PVA/SA blend membranes were prepared by casting a PVA/SA (95/5 in wi%) mixture solution on an acryl plate followed by drying at a room temperature and by cros-slinking with glutaraldehyde (GA) for 20 minutes PVA/SA blend composite membranes were also prepared by coating a PVA/SA (95/5 in wi%) mixture solution on microporous polysulfone(PSF) supports. The PVA/SA active layer of the composite membrane was crosslinked at room temperature by using an membranes were characterized with a scanning electron microscopy (SEM) a fourier transform infrared spectroscopy (FTIR) and permeation tests. The permeation properties of the composite membrane were as follows: 1.3{{{{ {m }^{2 } }}}}/{{{{ {m }^{2 } }}}}day of flux and >95% of rejection at 200 psi for a 1000 ppm PEG600 solution.

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Preparation of a Semi-Conductive Thin Film Sensor for Measuring Occlusal Force

  • Yu, Siwon;Kim, Nari;Lee, Youngjin
    • Journal of Sensor Science and Technology
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    • v.24 no.2
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    • pp.88-92
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    • 2015
  • In order to study the semi-conductive characteristics of carbon black-filled ethylene-propylene-diene monomer (EPDM) composite film, which is used for measuring occlusal force, composite samples with volume ratios of carbon black to EPDM ranging from 30% to 70% were prepared. The process of making a composite film consists of two steps, which involve the preparation of a slurry composition and the fabrication of a thin film using solution casting and a lamination process. To prepare the slurry composition, we dispersed carbon black nanoparticles into an organic solvent before mixing with an EPDM solution in toluene. The mechanical and electrical properties of the resulting carbon black-filled EPDM film were then investigated, and the results showed that the electrical resistance of a film decreases with the increase in the carbon black content. Furthermore, improved elastic recovery was observed after cross-linking the EPDM.