• 한국분말재료학회지
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• 제12권2호
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• pp.112-116
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• 2005

In the present study, the focus is on the analysis of carbothermal reduction of oxide powder prepared from waste WC/Co hardmetal by solid carbon under a stream of argon for the recycling of the WC/Co hard-metal. The oxide powder was prepared by the combination of the oxidation and crushing processes using the waste $WC-8 wt.\%Co$ hardmetal as the raw material. This oxide powder was mixed with carbon black, and then this mixture was carbothermally reduced under a flowing argon atmosphere. The changes in the phase structure and gases discharge of the mixture during carbothermal reduction was analysed using XRD and gas analyzer. The oxide powder prepared from waste $WC-8wt.\%Co$ hardmetal has a mixture of $WO_{3} and CoWO_{4}$. This oxide powder reduced at about $850^{\circ}C$, formed tungsten carbides at about $950^{\circ}C$, and then fully transformed to a mixed state of tungsten carbide (WC) and cobalt at about $1100^{\circ}C$ by solid carbon under a stream of argon. The WC/Co composite powder synthesized at $1000^{\circ}C$ for 6 hours from oxide powder of waste $WC-8wt.\%Co$ hardmetal has an average particle size of $0.3 {\mu}m$.

• 한국대기환경학회지
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• 제26권6호
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• pp.657-665
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• 2010

Carbon dioxide ($CO_2$) is known to be a major greenhouse gas partially emitted from waste combustion facilities. According to the greenhouse gas emission inventory in Korea, the quantity of the gas emitted from waste sector in 2005 represents approximately 2.5 percent of all domestic greenhouse gas emission. Currently, the emission rate of greenhouse gas from the waste sector is relatively constant partly because of both the reduced waste disposal in landfills and the increased amounts of waste materials for recycling. However, the greenhouse gas emission rate in waste sectors is anticipated to continually increase, mainly due to increased incineration of solid waste. The objective of this study was to analyze the property of Municipal Solid Waste (MSW) and estimate $CO_2$ emissions from domestic MSW incineration facilities. The $CO_2$ emission rates obtained from the facilities were surveyed, along with other two methods, including Tier 2a based on 2006 IPCC Guideline default emission factor and Tier 3 based on facility specific value. The $CO_2$ emission rates were calculated by using $CO_2$ concentrations and gas flows measured from the stacks. Other parameters such as waste composition, dry matter content, carbon content, oxidation coefficient of waste were included for the calculation. The $CO_2$ average emission rate by the Tier 2a was 34,545 ton/y, while Tier 3 was 31,066 ton/y. Based on this study, we conclude that Tier 2a was overestimated by 11.2 percent for the $CO_2$ emission observed by Tier 3. Further study is still needed to determine accurate $CO_2$ emission rates from municipal solid waste incineration facilities and other various combustion facilities by obtaining country-specific emission factor, rather than relying on IPCC default emission factor.

• 한국폐기물자원순환학회지
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• 제35권7호
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• pp.606-615
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• 2018

Over the past two decades, the options for solid waste management have been changing from land disposal to recycling, waste-to-energy, and incineration due to growing attention for resource and energy recovery. In addition, the reduction of greenhouse gas (GHG) emission has become an issue of concern in the waste sector because such gases often released into the atmosphere during the waste management processes (e.g., biodegradation in landfills and combustion by incineration) can contribute to climate change. In this study, the emission and reduction rates of GHGs by the municipal solid waste (MSW) management options in D city have been studied for the years 1996-2016. The emissions and reduction rates were calculated according to the Intergovernmental Panel on Climate Change guidelines and the EU Prognos method, respectively. A dramatic decrease in the waste landfilled was observed between 1996 and 2004, after which its amount has been relatively constant. Waste recycling and incineration have been increased over the decades, leading to a peak in the GHG emissions from landfills of approximately $63,323tCO_2\;eq/yr$ in 2005, while the lowest value of $35,962tCO_2\;eq/yr$ was observed in 2016. In 2016, the estimated emission rate of GHGs from incineration was $59,199tCO_2\;eq/yr$. The reduction rate by material recycling was the highest ($-164,487tCO_2\;eq/yr$) in 2016, followed by the rates by heat recovery with incineration ($-59,242tCO_2\;eq/yr$) and landfill gas recovery ($-23,922tCO_2\;eq/yr$). Moreover, the cumulative GHG reduction rate between 1996 and 2016 was $-3.46MtCO_2\;eq$, implying a very positive impact on future $CO_2$ reduction achieved by waste recycling as well as heat recovery of incineration and landfill gas recovery. This study clearly demonstrates that improved MSW management systems are positive for GHGs reduction and energy savings. These results could help the waste management decision-makers supporting the MSW recycling and energy recovery policies as well as the climate change mitigation efforts at local government level.

• 유기물자원화
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• 제17권2호
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• pp.101-111
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• 2009

본 연구에서는 강원지역의 도시 생활 쓰레기의 성상 및 물리 화학적 조성을 연구하였다. 생활 쓰레기 자원화시설 설치 및 자료확보 차원, 매립장 관리차원에서 본 연구는 필요한 연구이다. 폐기물의 평균 밀도는 $101.8{\sim}199.8kg/m^3$ 범위내의 결과를 얻었다. 생활 쓰레기는 30.7%의 음식물류, 36.3% 의 종이류, 15.８%의 플라스틱 및 비닐류, 1.9%의 섬유류, 3.2%의 목재류 1.５%의 고무 및 가죽류 등으로 구성되어 있다. 생활쓰레기의 대부분은 음식물, 종이류, 플라스틱류 등으로 이루어져 있으며 9０% 정도가 가연 성분이다. 삼성분 분석에서는 44.6%의 수분 및 47.4%의 가연분 그리고 7.7% 의 회분으로 이루어져 있었다. 원소분석결과는 탄소, 산소, 수소 순으로 많았다. 생활쓰레기의 저위 발열량은 2,631kcal/kg 이며 고위 발열량은 3,310 kcal/kg 이었다.

• 대한전자공학회:학술대회논문집
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• 대한전자공학회 2001년도 The 6th International Symposium of East Asian Resources Recycling Technology
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• pp.415-420
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• 2001

Water usage in the semiconductor industries is dramatically increased by not only using bigger wafer from 8 inches to 12 inches but also by adapting new process such as Chemical Mechanical Planarization (CMP) process invented by IBM in late '80. However, The document published by International Semiconductor Association suggests the decreasing ultra pure water (UPW) use from 22 gallon/in$^2$in 1997 to 5 gallon/in$^2$ in 2012. The criteria will possibly used as exporting obstacle in the future. Generally, Solid content of CMP slurry is about 15wt%. The slurry is diluted with UPW before fed to a CMP process. When the slurry is discharged from the process as waste, it contains 0.1~0.6wt% of solid content and 9~10 at pH. The CMP waste slurry is discharged to stream with minimum treatment. In this study, to find optimum condition of coagulation for water recovery from the waste CMP slurry various condition of coagulation were examined. After coagulation far 0.1 wt% solid content of waste CMP slurry, the sludge volume was 10~15% after 30 min of sedimentation time. For the 0.5 wt%, sludge volume was 50~55% after one hour of sedimentation time. For more than 80% of water recycling, the solid content should be in the range of 0.1 to 0.2wr%. Based on the result of the turbidity removal, the Zeta Potential and the analysis of heavy metals, the optimum condition for 0.1 wr% of waste CMP slurry was with 20 mg/L of PACI at 4 to 5 of pH. The result showed that the optimum conditions fer the 0.1 wt% waste CMP slurry were 100mg/L of Alum at 4~5 of pH, 100 mg/L of MgCI$_2$at pH 10 to 11 and 100 mg/L of Ca(OH)$_2$at pH 9 to 11, respectively.

• 유기물자원화
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• 제24권4호
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• pp.39-48
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• 2016

본 연구에서는 폐기물매립지 운영자, 관계 공무원 및 지역주민들에게 폐기물매립에 관한 정보 제공은 물론 실시간으로 폐기물매립지의 운영 및 관리를 최적화할 수 있는 매립 정보관리 시스템을 개발하였다. 매립 정보관리 시스템은 두 개의 시스템 (폐기물 매립이력 관리 시스템 및 매립 진척상황 관리 시스템)로 구성되어 있다. 자동화된 RFID / LPR 방식에 의한 고형 폐기물 매립이력 관리 시스템은 폐기물 수거 차량과 반입폐기물의 정보를 관리하며, 또한 폐기물매립지 외각에 설치된 추적 카메라를 이용하여 폐기물의 매립위치 및 매립시간 등의 정보를 3차원으로 DB화하여 향후 매립폐기물의 자원화 및 사후토지 이용 시 필요한 매립이력을 제공할 수 있도록 하였다. 매립진척상황 정보관리 시스템은 레이저 스캐너를 이용하여 실시간으로 매립지 부피 및 용량을 3차원으로 관리하여 매립진척상황을 실시간으로 산정할 수 있도록 하여 향후 매립지 잔여용량 분석을 통한 수요예측이 가능하도록 하였다.

• 자원ㆍ환경경제연구
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• 제24권4호
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• pp.747-761
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• 2015

본 연구에서는 2006-2013년 기간의 생활폐기물 관련 자료를 사용하여 종량제봉투 가격이 각 처리유형별 생활폐기물의 수거서비스 수요에 미치는 영향을 조사하였다. 생활폐기물 수거서비스 수요에 영향을 미치는 다른 변수들을 통제하고 관찰되지 않는 지역 및 시간적 특성들의 영향을 통제하기 위해 지역 및 시간 고정효과모형으로 각 처리유형별 수거서비스 수요함수를 추정하였다. 추정결과 종량제봉투 가격의 상승은 비탄력적이지만 종량제봉투에 의한 비음식물류 생활폐기물의 수거서비스 수요를 감소시키는 것으로 나타났다. 또한 종량제봉투 가격의 상승은 음식물쓰레기 배출량을 증가하도록 하고 상대적으로 다른 수거서비스 수요에 비해서 재활용품 배출량의 증가에 강하게 영향을 미치는 것으로 나타났다. 이러한 결과는 종량제봉투 가격의 상승에 따른 비음식물류 생활폐기물에 대한 수거서비스 수요의 감소는 음식물쓰레기와 재활용품의 분리수거의 증가에 기인하는 것임을 시사한다. 그러나 종량제봉투 가격의 상승이 1인당 총생활폐기물 발생량을 증가시키는 것으로 나타나고 있어 음식물쓰레기 및 재활용품의 분리배출 증가와 잠재적인 불법투기 및 소각을 고려한 피드백 효과로 인해 생활폐기물의 발생을 원천적으로 감소하도록 하기보다는 오히려 증가하도록 하는 결과를 낳고 있는 것으로 보인다.

• 환경위생공학
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• 제13권3호
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• pp.93-101
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• 1998

This study was carried out to investigate and analyze the citizen's attitude for the issue of the municipal solid wastes in Miryang city. The waste generation rate was decreased by 56% compared with 1991, and 71.8% of generated wastes were treated by landfill method. 61.6% among respondents were contacted waste problem by TV and the majority of respondents felt seriousness of food-waste problem. The majority of people felt that waste discharge decreased after "volume-base charge system" and 71% of total respondents were burdened down with use of volume-base charge envelope. The greater part of citizens answered that they experienced damage due to wastes and satisfied with the collection system but they recognized the necessity of the establishment of collection system and increase of cleaners must be nessary.

• 경영과학
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• 제20권1호
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• pp.65-76
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• 2003

The increased environmental concerns and the emphasis on recycling are gradually shifting the orientation of municipal solid waste (MSW) management. This paper is designed to evaluate regionalization programs for MSW management system. We developed a mixed intiger network programming (MIP) model to identify environment-friendly, cost-effective expansion plans for regionalization scenarios considered. The MIP model is a dynamic capacity expansion model based on the network flow model that depicts the MSW management cycle. In particular, our model is designed to determine the optimal form of regionalization using binary variables. We apply this model to assess the regionalization program of Seoul Metropolitan City, which includes three scenarios such as 1) districting, 2) regionalization with neighboring self-governing districts, and 3) g1obalization with all districts. We demonstrate how our model can be used to plan the MSW system. The results indicate that optimal regionalization with nearby self-governing districts can eliminate unnecessary landfills and expansions if jurisdictional obstacles are removed.

• 상하수도학회지
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• 제24권5호
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• pp.561-572
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• 2010

The efficiency of biological hydrolysis at $80^{\circ}C$ on municipal solid waste mixed with anaerobic digestion sludge was investigated in 100L batch reactors. The hydrolysis effect was observed within a day, when the hydrolysis reactor used for a pre-treatment reactor for methanogenesis, and the effect was observed during two days, When the reactor used for post-treatment reactor. For both configurations, methane production rate decreased, when hydrolysis was carried out more than a day. Gaseous ammonia in the hydrolysis reactors was successtully removed by the ammonia stripping system. Microbial diversity analysis on the hydrolysis reactors indicated dependency of microbial diversity on the configuration of the hydrolysis reactors. Carbohydrate and lactate degrading microbes dominated in the hydrolysis reactor, when the hydrolysis reactor used for a pre-treatment reactor for methanogenesis, while protein degrading microbes dominated in the post-treatment reactor.