• Journal of the Korean Wood Science and Technology
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• 제19권3호
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• pp.62-71
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• 1991

An evaluation of bending test of composite I and Box beams for determining the ultimate strength limit design criteria was presented. Maxium loads of composite I beams were found in beams composed of thicker upper flanges and/or vertical LVL flanges. These loads of plywood web beams were greater than those of PB web beams. Maximum loads of unsymmetrical box beams were less than those of symmetrical box beams. Thus, it took on different phase in box type beams. Ultimate loads of composite beams were greater than those of solid. The failure of composite beams were abrupt and failure mode was classified into following categories; Edgewise shear failure in web, delamination in flange-web joint, tension failure and tearing in LVL flanges, and web delamination. These failures of composite beams were appeared at the mixed mode. The influence factor affecting the performance of tested composite beams was shear strength of PB-web composite beams and compressive strength in plywood-web composite beams. It was also assumed that the influence factors on structural performance on composite beams were flange quality, web material and geometry of cross section. As one of the design methods resisting to compressive stress that was required in the case of small span to depth ratio and deep beams. composite I-beams composed of thicker upper flanges comparing to lower flanges were very effective in structural performance.

• Journal of Advanced Marine Engineering and Technology
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• 제29권8호
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• pp.891-898
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• 2005

Inertia welding is a solid-state welding process in which butt welds in materials are made in bar and in ring form at the joint race, and energy required lot welding is obtained from a rotating flywheel. The stored energy is converted to frictional heat at the interface under axial load. The quality of the welded joint depends on many parameters, including axial force, initial revolution speed and energy amount of upset. working time, and residual stresses in the joint. Inertia welding was conducted to make the large exhaust valve spindle for low speed marine diesel engine. superalloy Nimonic 80A for valve head of 540mm and high alloy SNCrW for valve stem of 115mm. Due to different material characteristics such as, thermal conductivity and flow stress. on the two sides of the weld interface, modeling is crucial in determining the optimal weld geometry and Parameters. FE simulation was performed by the commercial code DEFORM-2D. A good agreement between the Predicted and actual welded shape is observed. It is expected that modeling will significantly reduce the number of experimental trials needed to determine the weld parameters. especially for welds for which are very expensive materials or large shaft. Many kinds of tests, including macro and microstructure observation, chemical composition tensile , hardness and fatigue test , are conducted to evaluate the qualify of welded joints. Based on the results of the tests it can be concluded that the inertia welding joints of the superalloy exhaust valve spindle are better properties than the material specification of SNCrW.

• Advances in Energy Research
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• 제5권2호
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• pp.91-105
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• 2017

Thermal hydraulic (TH) analysis of nuclear power reactors is utmost important. In this way, the numerical codes that preparing TH data in reactor core are essential. In this paper, a subchannel analysis of a Russian pressurized water reactor (WWER1000) core with enhanced numerical code is carried out. For this, in fluid domain, the mass, axial and lateral momentum and energy conservation equations for desired control volume are solved, numerically. In the solid domain, the cylindrical heat transfer equation for calculation of radial temperature profile in fuel, gap and clad with finite difference and finite element solvers are considered. The dependence of material properties to fuel burnup with Calza-Bini fuel-gap model is implemented. This model is coupled with Isotope Generation and Depletion Code (ORIGEN2.1). The possibility of central hole consideration in fuel pellet is another advantage of this work. In addition, subchannel to subchannel and subchannel to rod connection data in hexagonal fuel assembly geometry could be prepared, automatically. For a demonstration of code capability, the steady state TH analysis of a the WWER1000 core is compromised with Thermal-hydraulic analysis code (COBRA-EN). By thermal hydraulic parameters averaging Fuel Assembly-to-Fuel Assembly method, the one sixth (symmetry) of the Boushehr Nuclear Power Plant (BNPP) core with regular subchannels are modeled. Comparison between the results of the work and COBRA-EN demonstrates some advantages of the presented code. Using the code the thermal modeling of the fuel rods with considering the fission gas generation would be possible. In addition, this code is compatible with neutronic codes for coupling. This method is faster and more accurate for symmetrical simulation of the core with acceptable results.

• Bulletin of the Korean Chemical Society
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• 제29권10호
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• pp.1905-1910
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• 2008

The reaction of 3,14-dimethyl-2,6,13,17-tetraazatetracyclo[16.4.0$0^{1.18}.0^{7.12}$]docosane ($L^1$) with formaldehyde in warm methanol yielded 3,14-dimethyl-2,6,13,17-tetraazatetracyclo[16.4.$1^{2.6}.0^{1.18}.0^{7.12}$]tricosane ($L^7$) containing one 1,3-diazacyclohexane subunit. In methanol, $L^7$ readily reacts with $Cu^{2+}$ ion to form [$CuL^7(H_2O)$]$^{2+}$ which is extremely inert against methanolysis. In the solution containing $Ni^{2+}$ ion, however, $L^7$ reacts with methanol to yield [$NiL^3$]$^{2+}$ ($L^3$ = 2-(methoxymethyl)-5,16-dimethyl-2,6,13,17-tetraazatricyclo[16.4.$0^{1.18}.0^{7.12}$]- docosane), in which one N-$CH_2OCH_3$ pendant arm is appended. The copper(II) complex [$CuL^7(H_2O)$]- $(ClO_4)_2{\cdot}3H_2O\;(I{\cdot}3H_2O)$ has a severely distorted trigonal bipyramidal coordination geometry with a 4-5- 6-5 chelate ring sequence. The crystal structure of [$NiL^3$]$(PF_6)_2{\cdot}2H_2O$ (IIb) shows that the N-$CH_2OCH_3$ pendant arm is not coordinated to the metal ion in the solid state. In various solvents (S), however, the nickel(II) complex exists as a mixture of [$NiL^3$(S)]$^{2+}$, in which the N-$CH_2OCH_3$ group as well as S is coordinated to the metal ion, and [$NiL^3$]^{2+}.

• Bulletin of the Korean Chemical Society
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• 제31권8호
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• pp.2309-2314
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• 2010

Design and syntheses of four red phosphorescent heteroleptic cationic iridium(III) complexes containing two substituted phenylquinoxaline (pqx) or benzo[b]thiophen-2-yl-pyridin (btp) main ligands and one 2,2'-biimidazole (H2biim) ancillary ligand are reported: [$(pqx)_2$Ir(biim)]Cl (1), [$(dmpqx)_2$Ir(biim)]Cl (2), [$(dfpqx)_2$Ir(biim)]Cl (3), [$(btp)_2$Ir(biim)]Cl (4). Complex 1 showed a distorted octahedral geometry around the iridium(III) metal ion with cis metallated carbons and trans nitrogen atoms. The absorption, emission and electrochemical properties were systematically evaluated. The complexes exhibited red phosphorescence in the spectral range of 580 to 620 nm with high quantum efficiencies of 0.58 - 0.78 in both solution and solid-state at room temperature depending on the cyclometalated main ligands. The cyclic voltammetry of the complexes (1-3) showed a metal-centered irreversible oxidation in the range of 1.40 to 1.90 V as well as two quasi reversible reduction waves from -1.15 to -1.45 V attributed to the sequential addition of two electrons to the more electron accepting heterocyclic portion of two distinctive cyclometalated main ligands, whereas complex 4 showed a reversible oxidation potential at 1.24 V and irreversible reduction waves at -1.80 V.

• 한국철도학회논문집
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• 제14권3호
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• pp.240-247
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• 2011

본 연구에서는 콘크리트 궤도 침목 내에 설치되는 인서트에 예기치 못하게 침투된 수분의 결빙압이 앵커볼트의 인발강도에 미치는 영향을 유한요소해석을 통해 고찰하였다. 3차원 유한요소해석모델은 콘크리트 침목의 현장실험 결과, 도면 및 레일체결장치의 제원 실측치를 기반으로 수립되었으며, 비선형구성방정식과 파괴 모델은 측정된 압축강도로부터 CEB-FIP 1990 모델코드를 이용하여 추정하였다. 해석모델의 적정성은 철도기술연구원에서 수행한 현장 인발시험 결과 및 실내시험 결과와의 비교를 통해 확인하였다. 다양한 인자, 즉 결빙위치, 앵커볼트 초기 체결력의 크기 및 콘크리트 압축강도에 따른 해석을 수행하였으며, 그 결과를 제시하였다. 해석결과에 의하면, 매립전내 침투수의 결빙력은 균열손상의 가장 가능성 있는 직접적인 원인 중 하나로 간주될 수 있음을 확인하였다. 또한, 외측매립전의 결빙력이 내측 매립전 보다 작은 것으로 나타났으나 그 차이는 크지 않았다.

• 한국우주과학회:학술대회논문집(한국우주과학회보)
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• 한국우주과학회 2004년도 한국우주과학회보 제13권2호
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• pp.347-350
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• 2004

A space radiation analysis has been used to evaluate an ability of electronic equipment boxes or spacecrafts to endure various radiation effects, so it helps design thicknesses of structure and allocate components to meet the radiation requirements. A comparison study of space radiation dose analysis programs SPENVIS Sectoring Tool (SST) and SIGMA II is conducted through some structure cases, simple sphere shell, box and representative satellite configurations. The results and a discussion of comparison will be given. A general comparison will be shown for understanding those programs. The both programs use the same strategy, solid angle sectoring with ray-tracing method to produce an approximate dose at points in representative simple and complex models of spacecraft structures. Also the particle environment data corresponding to mission specification and radiation transport data are used as input data. But there are distinctions between them. The specification of geometry model and its input scheme, the assignment of dose point and the numbers, the prerequisite programs and ways of representing results will be discussed. SST is a web-based interactive program for sectoring analysis of complex geometries. It may be useful for a preliminary dose assessment with user-friendly interfaces and a package approach. SIGMA II is able to obtain from RSICC (Radiation Safety Information Computational Center) as a FOR-TRAN 77 source code. It may be suitable for either parametric preliminary design or detailed final design, e.g. a manned flight or radiation-sensitive component configuration design. It needs some debugs, recompiling and a tedious work to make geometrical quadric surfaces for actual spacecraft configuration, and has poor documentation. It is recommend to vist RSICC homepage and GEANT4/SSAT homepage.

• Bulletin of the Korean Chemical Society
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• 제32권3호
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• pp.894-898
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• 2011

The first example of lead compound from $Pb(NO_3)_2$ and $H_3L$ N-heterocyclic ligand $(H_3L\;=\;(HO_2C)_2(C_3N_2)(C_3H_7)CH_2(C_6H_4)(C_6H_3)CO_2H)$, $[Pb_4(L')_4]{\cdot}5H_2O$ 1 (L' = OOC$(C_3H_7)(C_3N_2)CH_2(C_6H_4)(C_6H_3)COO)$, has been obtained under hydrothermal condition by decarboxylation, and characterized by elemental analysis, IR, TGDTA, and single-crystal X-ray diffraction. Compound 1 possesses a rare two-dimensional upper-lower offset terrace-like layer structure. In 1, crystallographic distinct Pb(II) ion adopts five-coordination geometry, and two lattice water molecules occupy the voids between 2-D layers. Results of solid state fluorescence measurement indicate that the emission band 458 nm may be assigned to $\pi^*-n$ and $\pi^*-\pi$ electronic transitions within the aromatic systems of the ligand L', however, the emission bands centred at 555 nm, 600 nm and 719 nm may be derived from phosphorescent emission ($\lambda_{excitation}$ = 390 nm).

• Steel and Composite Structures
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• 제20권1호
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• pp.167-184
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• 2016

This paper presents the details of Finite Element (FE) analysis carried out to determine the limiting deformation capacity and failure mode of Laced Steel-Concrete Composite (LSCC) beam, which was proposed and experimentally studied by the authors earlier (Anandavalli et al. 2012). The present study attains significance due to the fact that LSCC beam is found to possess very high deformation capacity at which range, the conventional laboratory experiments are not capable to perform. FE model combining solid, shell and link elements is adopted for modeling the beam geometry and compatible nonlinear material models are employed in the analysis. Besides these, an interface model is also included to appropriately account for the interaction between concrete and steel elements. As the study aims to quantify the limiting deformation capacity and failure mode of the beam, a suitable damage model is made use of in the analysis. The FE model and results of nonlinear static analysis are validated by comparing with the load-deformation response available from experiment. After validation, the analysis is continued to establish the limiting deformation capacity of the beam, which is assumed to synchronise with tensile strain in bottom cover plate reaching the corresponding ultimate value. The results so found indicate about $20^{\circ}$ support rotation for LSCC beam with $45^{\circ}$ lacing. Results of parametric study indicate that the limiting capacity of the LSCC beam is more influenced by the lacing angle and thickness of the cover plate.

• 대한조선학회논문집
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• 제50권1호
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• pp.1-7
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• 2013

The high-skewed and/or composite propellers of current interests to reduce the ship vibration and to increase the acoustic performance are likely to be exposed to the unexpected structural problems. One typical example is that the added mass effect on the propellers working in the non-uniform wake field reduces the natural frequency of the propeller leading to the resonance with the low-frequency excitation of the external forces. To avoid this resonance problem during the design stage, the technique of fluid-structure interaction has been developed, but the higher-order effect of the blade geometry deformation is not yet considered in evaluating the added mass effects. In this paper the fluid boundary-value problem is formulated by the potential-based panel method in the inviscid fluid region with the velocity inflow due to the body deformation, and the structural response of the solid body under the hydrodynamic loading is solved by applying the finite element method which implements the 20-node iso-parametric element model. The fluid-structure problem is solved iteratively. A basic fluid-sturcture interaction study is performed with the simple rectangular plates of thin thickness with various planform submerged in the water of infinite extent. The computations show good correlation with the experimental results of Linholm, et al. (1965).