• 제목/요약/키워드: solid concentration

검색결과 1,894건 처리시간 0.021초

Sintering Mixtures in the Stage of Establishing Chemical Equilibrium

  • Savitskii, A.P.
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 1999년도 춘계학술대회 및 발표대회 강연 및 발표논문 초록집
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    • pp.5-5
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    • 1999
  • The Principal deficiency of the existing notion about the sintering-mixtures consists in the fact that almost no attention is focused on the Phenomenon of alloy formation during sintering, its connection with dimensional changes of powder bodies, and no correct ideas on the driving force for the sintering process in the stage of establishing chemical equilibrium in a system are available as well. Another disadvantage of the classical sintering theory is an erroneous conception on the dissolution mechanism of solid in liquid. The two-particle model widely used in the literature to describe the sintering phenomenon in solid state disregards the nature of the neighbouring surrounding particles, the presence of pores between them, and the rise of so called arch effect. In this presentation, new basic scientific principles of the driving forces for the sintering process of a two-component powder body, of a diffusion mechanism of the interaction between solid and liquid phases, of stresses and deformation arising in the diffusion zone have been developed. The major driving force for sintering the mixture from components capable of forming solid solutions and intermetallic compounds is attributed to the alloy formation rather than the reduction of the free surface area until the chemical equilibrium is achieved in a system. The lecture considers a multiparticle model of the mixed powder-body and the nature of its volume changes during solid-state and liquid-phase sintering. It explains the discovered S-and V-type concentration dependencies of the change in the compact volume during solid-state sintering. It is supposed in the literature that the dissolution of solid in liquid is realised due to the removal of atoms from the surface of the solid phase into the melt and then their diffusicn transfer from the solid-liquid interface into the bulk of liquid. It has been shown in our experimental studies that the mechanism of the interaction between two components, one of them being liquid, consist in diffusion of the solvent atoms from the liquid into the solid phase until the concentration of solid solutions or an intermetallic compound in the surface layer enables them to pass into the liquid by means of melting. The lecture discusses peculimities of liquid phase formation in systems with intermediate compounds and the role of the liquid phase in bringing about the exothermic effect. At the frist stage of liquid phase sintering the diffusion of atoms from the melt into the solid causes the powder body to grow. At the second stage the diminution of particles in size as a result of their dissolution in the liquid draws their centres closer to each other and makes the compact to shrink Analytical equations were derived to describe quantitatively the porosity and volume changes of compacts as a result of alloy formation during liquid phase sinteIing. Selection criteria for an additive, its concentration and the temperature regime of sintering to control the density the structure of sintered alloys are given.

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High-Solid Enzymatic Hydrolysis and Fermentation of Solka Floc into Ethanol

  • Um, Byung-Hwan;Hanley, Thomas R.
    • Journal of Microbiology and Biotechnology
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    • 제18권7호
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    • pp.1257-1265
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    • 2008
  • To lower the cost of ethanol distillation of fermentation broths, a high initial glucose concentration is desired. However, an increase in the substrate concentration typically reduces the ethanol yield because of insufficient mass and heat transfer. In addition, different operating temperatures are required to optimize the enzymatic hydrolysis (50$^{\circ}C$) and fermentation (30$^{\circ}C$). Thus, to overcome these incompatible temperatures, saccharification followed by fermentation (SFF) was employed with relatively high solid concentrations (10% to 20%) using a portion loading method. In this study, glucose and ethanol were produced from Solka Floc, which was first digested by enzymes at 50$^{\circ}C$ for 48 h, followed by fermentation. In this process, commercial enzymes were used in combination with a recombinant strain of Zymomonas mobilis (39679:pZB4L). The effects of the substrate concentration (10% to 20%, w/v) and reactor configuration were also investigated. In the first step, the enzyme reaction was achieved using 20 FPU/g cellulose at 50$^{\circ}C$ for 96 h. The fermentation was then performed at 30$^{\circ}C$ for 96 h. The enzymatic digestibility was 50.7%, 38.4%, and 29.4% after 96 h with a baffled Rushton impeller and initial solid concentration of 10%, 15%, and 20% (w/v), respectively, which was significantly higher than that obtained with a baffled marine impeller. The highest ethanol yield of 83.6%, 73.4%, and 21.8%, based on the theoretical amount of glucose, was obtained with a substrate concentration of 10%, 15%, and 20%, respectively, which also corresponded to 80.5%, 68.6%, and 19.1%, based on the theoretical amount of the cell biomass and soluble glucose present after 48 h of SFF.

열풍건조 전 감자의 삼투압농축시 물질이동과 공정의 최적화 (Mass Transfer and Optimum Processing Conditions for Osmotic Conditions of Potatoes prior to Air Dehydration)

  • 김명환
    • 한국식품과학회지
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    • 제22권5호
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    • pp.497-502
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    • 1990
  • 삼투압 농축중 설탕용액의 농도와 온도 및 침지시간에 따른 감자 내부의 수분손실, 고형분 증가나 손실 및 몰랄농도를 반응 표면 분석법으로 조사하였고, 이차 다항 회귀 모델로써 예측하였다. 또한 삼투압 농축과 데치기가 6%수분(wet basis)까지 열풍조건시 비타민 C 함량유지에 미치는 효과를 평가하였다. 감자내부의 수분손실, 고형분 증가나 손실, 몰랄농도, 속도 매개변수 및 비타민 C 함량에 가장 크게 영향을 미치는 요소는 설탕농도이었고 그 다음 침지시간과 침지온도 순이었다. 수분손실과 설탕흡수는 초기 10분간 침지과정에서 빠르게 이루어진 후 증가현상이 둔화되었다. 설탕용액 $(60\;Brix,\;80^{\circ}C)$에서 20분간 침지 후 44.6%의 수분손실이 되었다. 삼투압 농축후 건조시킨 감자가 데치기 한 후 건조시킨 감자보다 높은 비타민 C 함량을 유지하였다. 30% 이상의 수분손실과 50% 이상의 비타민 C 함량유지의 관점에서 삼투압농축공정의 최적조건은 $60-70^{\circ}C$의 침지온도와 60 Brix의 설탕농도 및 16-20분간의 침지시간이었다.

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Treatment of High Concentration Organic Wastewater with a Sequencing Batch Reactor (SBR) Process Combined with Electro-flotation as a Solids-liquid Separation Method

  • Choi, Younggyun;Park, Minjeong;Park, Mincheol;Kim, Sunghong
    • Environmental Engineering Research
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    • 제19권4호
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    • pp.395-399
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    • 2014
  • Operation characteristics of the sequencing batch reactor (SBR) process with electro-flotation (EF) as a solid liquid separation method (EF-SBR) were investigated. EF-SBR process showed excellent solid-liquid separation performance which enabled to separate biosolids from liquid phase within 30 min and to extend cyclic reaction time. Although influent organic loading rate was increased stepwise from 5 to 15 g COD/day, food to microorganisms (F/M) ratio could be maintained about 0.3 g COD/g VSS/day in EF-SBR because biomass concentration could be easily controlled at desired level by EF. However, it was impossible to increase biomass concentration at the same level in control SBR (C-SBR) process because solid-liquid separation by gravity settling showed a limitation at higher mixed liquor suspended solids (MLSS) concentration with 60 min of settling time. Total chemical oxygen demand (TCOD) removal efficiency of EF-SBR process was not decreased although influent organic loading rate became 3 times higher than initial value. However, it was seriously deteriorated in C-SBR process after increasing the rate over 10 g COD/day, which was accounted for insufficient organic removal by relatively higher food to microorganisms (F/M) ratio as well as biosolids wash-out by a limitation of gravity sedimentation.

수평 관에서 고체입자 농도가 압력강하 및 마찰계수에 미치는 효과 (Effects of Particle Concentrations on Friction Factors and Pressure Drops in a Horizontal Pipe)

  • 안수환;이병창;강호근
    • 동력기계공학회지
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    • 제11권4호
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    • pp.44-49
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    • 2007
  • Generally, the economic concept of optimized design and operating conditions in fluidized bed heat exchangers can hardly be realized. Because the lack of fundamental knowledge about the particle flows, the optimum design of the fluidized bed heat exchanger is rather limited. In the present work, measurements are made on pressure drops and friction factors in the horizontal circular tube with solid particles in the circulating water. Two different solid particles of diameters of 3mm and 4mm are covered. The Reynolds numbers are ranged from 10,000 to 45,000. It is concluded that the friction factors for the particles of 4mm diameter are much higher than those for the particles of 3mm diameter. And at the lower particle concentration, the friction factors are strongly influenced by the fluid velocity rather than the particle concentration; However, the effect of the particle concentration on friction factors is also significantly higher at a higher particle concentration operating condition.

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정수장 배출수 처리를 위한 Crossflow 관형막 여과 공정의 운전 적용에 관한 연구 (A Study about Applicability of Treatment for Water Treatment Residual Sludge Using Crossflow Tubular Membrane System)

  • 김영훈;김관엽;김지훈;이용수;이의종;엄정열;김형수;황선진
    • 상하수도학회지
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    • 제23권4호
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    • pp.499-505
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    • 2009
  • Many other countries have investigated the residual sludge treatment process to save the existing water resource and produce the high suspended solid concentration sludge. There are various methods for concentrating residual sludge, but the membrane system has received the most interest for its efficiency. The objective of this study was to evaluate the application of membrane filtration system for the residual sludge treatment. The experiment equipment was composed of Lab scale Crossflow tubular membrane filtration system. Generally, crossflow operation mode demands high electric cost mainly for the pump energy. So to cut off electric cost, very low Crossflow velocity was used in this experiment. Results confirmed that suspended solid concentration of residual sludge could be concentrated to 57,000mg/L in low Crossflow velocity tubular membrane system,. This concentration can be directly injected into the dehydrator. Based on the results, we know that the Crossflow tubular membrane system should be replaced conventional residual sludge treatment system.

부유물 침전을 고려한 준설투기장 설계의 적합성 평가 (Suitability Evaluation of Containment Area Design Considering Suspended Solid Sedimentation)

  • 지성현;김찬기;정혁상;천병식
    • 한국지반환경공학회 논문집
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    • 제11권10호
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    • pp.41-48
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    • 2010
  • 본 연구에서는 기존에 적용된 준설투기장 설계에서 준설투기장에서 배출되는 상등수의 부유물 농도 예측에 대한 적합성 평가를 위하여 실제 현장 준설 시 준설투기장 내에서 준설토의 입도분포 및 상등수의 부유물 농도 분포를 측정하여 설계 예측 값과 비교하였으며, 상등수의 유속과 부유물 농도와의 관계를 분석하였다. 평가 결과, 현장 측정값과 설계 예측값이 비교적 유사한 경향을 보였으나, 준설 초기 및 상등수 유속이 증가한 시점에서는 설계 예측값과 상이한 측정값을 보였다. 이는 기존에 적용된 준설투기장 설계법이 준설 기간에 따라 민감하게 변화하는 준설토의 침강 깊이 및 상등수의 유속 등을 반영하지 못하기 때문으로 판단된다. 또한 준설투기장에서 동시에 측정된 유속과 부유물 농도의 분포가 유사한 경향을 보이므로 상등수의 유속과 부유물 침전이 상당히 밀접한 관계가 있는 것으로 관측되었다. 따라서, 현장 준설투기장 상황 변화를 보다 정확히 예측하기 위하여 준설토 계면고, 침강깊이, 상등수 유속에 따라 변화하는 부유물 침전을 고려한 준설투기장 설계법이 필요하다고 사료된다.

Sales Energy Promotion Efficiency and Policy Utilization Plan for Energy Facilities

  • KWON, Lee-Seung;LEE, Woo-Sik;KWON, Woo-Taeg
    • 유통과학연구
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    • 제18권9호
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    • pp.67-75
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    • 2020
  • Purpose: The purpose of this study is to enhance sales promotion efficiency for using solid refuse fuel facilities. Renewable energy technology using Solid Refuse Fuel (SRF) is an economic efficiency technology that recovers waste by burning various wastes. A survey on the pollutants discharged from the solid fuels facilities was investigated so that the SRF facilities could be expanded, distributed and reflected in the policy. Research design, data, and methodology: In this study, 9 business sites using SRF and Bio-SRF as main raw materials were investigated for 2 years. The characteristics of target business sites such as the type of fuel used, combustion method, combustion temperature, daily fuel consumption and environmental prevention facilities were studied. Results: The average pollution & ammonia concentration of Bio-SRF facilities was found to be 88.15% higher than that of SRF facilities. But the average acetaldehyde concentration of SRF facilities was found to be 88.15% higher than that of Bio-SRF facilities. Conclusions: The main issue is how much electric power generation using combustible materials affects air pollution. The waste recycling law provides the standard value according to the fuel property, but there is a considerable gap with the mixed fuel. Therefore, for efficient utilization of facilities using solid fuel products, additional research is needed to improve the distribution structure of exhaust pollutants is needed.

Solid Substrate and Submerged Culture Fermentation of Sugar Cane Bagasse for the Production of cellulase and Reducing Sugars by a Local Isolate, Aspergillus terreus SUK-1

  • Wan Mohtar, Yusoff;Massadeh, Muhannad Illayan;Kader, Jalil
    • Journal of Microbiology and Biotechnology
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    • 제10권6호
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    • pp.770-775
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    • 2000
  • Several process parameters were studied to ascertain the effect on degradation of sugar cane bagasse in relation to the production of cellulase enzyme and reducing sugars by Solid Substrate Fermentation (SSF) and Submerged Culture Fermentation (SCF) of Aspergillus terreus SUK-1. The effect of air-flow rate (0-1.3 v/v/m), of different ratios of substrate weight to liquid volume (1:6, 1:10, 1:20, and 1:30 w/v, g/ml), scale-up effect (10, 20, and 100 times of 1:10 ration, w/v) and the effect of temperature (30, 40, 50, and $60^{\circ}C$) in SSF were studied. Air-flow rate of 1.0 v/v/m gave the highest enzyme activity (FPase 0.25 IU/ml, CMCase 1.24 IU/ml) and reducing sugars concentration (0.72 mg/ml). Experiment using 1:10 ratio (w/v) was found to support maximum cellulase activity (FPase 0.58 IU/ml, CMCase 1.97 IU/ml) and reducing sugar concentration (1.23 mg/ml). Scaling-up the ratio of 1:10(w/v) by a factor of 20 gave the highest cellulase activity (FPase 0.71 IU/ml, CMCase 2.25 IU/ml) and reducing sugar concentration (3.67 mg/ml). The optimum temperature for cellulase activity and reducing sugar production was $50^{\circ}C$(FPase 0.792 IU/ml, CMCase 2.25 IU/ml and 3.85 mg/ml for reducing sugar concentration). For SCF, the activity of cellulase enzyme and reducing sugar concentration was found to be lower than that obtained for SSF. The highest cellulase activity obtained in SCF was 50% lower than the highest cellulase activity in SSF, while for reducing sugar concentration, the highest concentration obtained in SCF was 90% lower than that obtained in SSF.

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포말 농축물에 의한 포말 생성의 영향인자 (The Effective Factors of n Foam Generation Using Foam Condensate)

  • 서근학;신정식;이주화
    • 한국수산과학회지
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    • 제36권5호
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    • pp.509-514
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    • 2003
  • We performed the experiment to determine the effective factors, such as the initial concentration of protein, pore size of air distributor, SAV (superficial air velocity), pH, salts and temperature related to foaming characteristics. The foam height in a foam generator was increased with the increase of the initial protein concentration and the decrease of pore size. As SAV was increased, the foam height was increased, and the optimum SAV was 0.84 cm/sec. The foam height was highest in the acid region and it was increased with the increase of salt concentration of NaCl and $NaHCO_3.$ The removal efficiencies of TSS (total suspended solid) and turbidity decreased with the increase of the initial protein concentration in the batch foam separator.