• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2001년도 추계학술발표회
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• pp.191-194
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• 2001

The electrokinetic apparatus for remediation of the soil contaminated with Cs$^{+}$was designed. After kaolin clay was compulsorily contaminated by Cs$^{+}$ solution, the remediation characteristics by electrokinetic method were analyzed. After remediation experiment, the pH of the cathode side of the soil column was increased to 12.7 due to the generation of OH in cathode reservoir, but no hydroxide cesium form in the cathode side. Effluent rate from the cathode almost was constant and cesium concentration of effluent decreased with time passage. The 49% of a total of Cs$^{+}$ in the column was decontaminated for 0.4 day, the 72% of a total of Cs$^{+}$ in the column was decontaminated for 0.8 day, the 83% of a total of Cs$^{+}$ in the column was decontaminated for 1.2 days, the 89% of a total of Cs$^{+}$ in the column was decontaminated for 1.6 days, and the 93% of a total of Cs$^{+}$ in the column was decontaminated for 2.1 day Meanwhile, the predicted values of residual concentration by the developed model were quite similar to those obtained from experiments.m experiments.

• 자원환경지질
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• 제56권5호
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• pp.619-628
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• 2023

본 연구에서는 토양 내 비소 및 수은의 안정화제로 황산칼슘비료의 적용 가능성을 검토하였다. 아울러 황산칼슘비료의 물리적 특성(입자상, 미분상, 용액상)에 따른 비소 및 수은의 안정화 특성을 상추 재배 포트실험으로 비교?검토하였다. 34일 간의 상추재배를 통해 확인한 비소 및 수은의 전이감소 효과는 대체적으로 70% 이상인 것으로 나타나 안정화제로서의 적용성을 확인하였다. 다만, 용액상 안정화제 처리조건에서 성장한 상추의 생체량은 대조구의 46% 수준으로 가장 낮았는데, 이는 안정화제로부터 유래된 영양물질의 유효도가 극단적으로 높아 오히려 식물체 성장을 저해한 것으로 판단되었다. 토양 내 비소 및 수은의 분획특성 확인결과 수은에서만 존재형태의 변화가 크게 나타났다. 수은은 안정화 처리된 토양에서 원소수은의 감소와 잔류형/황화물 형태의 증가가 확인되었는데, 이러한 경향은 용액상 > 미분상 > 입자상의 순서로 나타났다. 본 연구를 통해 대형 교반장비의 진입이 어려운 농경지에서는 용액상 처리제의 살포만으로 안정화 효과를 얻을 수 있음을 확인하였다. 다만, 높은 영양물질 유효도로 인해 염해토양의 특성을 보일 수 있으므로, 투여량 조절을 통해 농작물 위해를 사전 제어할 필요가 있다.

• 한국잠사곤충학회지
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• 제20권1호
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• pp.1-4
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• 1978

The root-out of mulberry saplings has been studied by pour into soil and spray on leaves of the plant growth substances. In addition, the effect of "Rutin", a kind of plant growth hormones has been also studied on promoting the rootability of mulberry scions by dipping the scions at the various concentrations. The results are summarized as follows: (1) It is likely to be effective on acceleration of the rootability resulting in increase of rooting ratio by pour into soil at the concentration of 1 ppm and 10 ppm NAA, 10 ppm and 100 ppm Rutin, and 5000 fold solution of Atonic, respectively (2) Growth of branch is only promoted by leaf spray of 0.5% urea, 0.005% and 0.01% Rutin, and 5000 fold solution of Atonic without increasing the root weight. (3) It seems that 0.05% of Rutin is of practical use, and 0.05% to 0.4% of "Rutin" accelerates the root-out of mulberry scions as well as NAA does.

• 한국토양비료학회지
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• 제36권4호
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• pp.225-232
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• 2003

노지에서 분무식 양액재배를 이용하여 감귤나무(Citrus unshiu Marc. cv. Miyagawa Wase)의 무기양분과 물 흡수 실험을 수행하였다. 양액의 농도는 세 수준으로 나누어 공급한 뒤 주기적으로 양액을 채취하여 무기양분과 물 흡수량을 측정하였고, 생체중의 변화를 조사하여 수체 증가량을 알아보았다. 물의 흡수는 감귤나무의 수체와 시간이 경과할수록 증가하였으나, High 처리구에서는 Medium과 Low보다 적게 흡수되었다. 영양생장(5~7월)과 과실형성(8~9월)기에 생체중과 양분흡수 증가가 가장 크게 일어났다. 양분의 흡수는 양액 공급 농도에 따라 차이가 컸으며, 높을수록 더 많이 흡수하는 경향이었고, $NH_4-N$, S, P, Mg, Fe보다 $NO_3-N$, K, Ca가 많았다. 또한 감귤잎 중 무기양분 함량도 공급되는 양액의 농도가 높을수록 증가하였다. 감귤나무의 주요 원소의 양액 농도 조성은 N, P, K, Ca, Mg 경우 각각 27.1, 16.5, 66.0, 80.0, $24.0mg\;L^{-1}$이 적당힌 것으로 사료된다.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2000년도 추계학술대회
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• pp.196-201
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• 2000

The influence of adsorption on cadmium toxicity to soil microorganisms in smectite-rich soils and sediments was quantified as a function of solution and sorbent characteristics. Adsorption and surface complexation experiments were conducted to infer Cd sorption mechanisms to a reference smectite and three fractions of a Veritsol soil, and to elucidate the effects of the surface complexation on Cd bioavailability and toxicity in soils and sediments. Cadmium adsorption isotherms conformed to the Langmuir adsorption model, with adsorptive capacities of the different samples dependent on their characteristics. Equilibrium geochemical modeling (MINTEQA2) was used to predict the speciation of Cd in the soil suspensions using Langmuir and Triple Layer surface complexation models. The influence of adsorption and surface complexation on cadmium toxicity to soil microorganisms was assessed indirectly through the relative change in microbial hydrolysis of fluorescein diacetate (FDA) as a function of total Cd concentration and sorbent characteristics. Adsorption decreased the toxicity of Cd to soil microorganisms. Inner-sphere complexation is more effective than outer-sphere complexation in reducing the bioavailability and toxicity of heavy metals in soils and sediments.

• 생물환경조절학회지
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• 제15권3호
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• pp.264-269
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• 2006

본 실험은 배양액의 농도가 무화과의 생육과 수량에 미치는 영향을 조사하기 위하여 수행하였다. 1차 실험에서 배양액의 농도에 따른 무화과 생육은 1/2농도 처리구에서 초장, 엽수, 경경, 착과수가 양호했으며, 엽장과 엽폭은 1/2농도구를 제외한 다른 처리간에는 차이가 없었다. 배양액의 농도에 따른 과식의 평균과중은 토양재배의 38.4g보다 수경재배에서 50.9g으로 높게 나타났고, 과장, 과경, 당도는 처리간의 차이가 없었다. 수확량은 토양재배보다 수경재배에서 월등하게 많았으며, 배양액 1/2농도보다 2/2와 3/2농도에서 높게 나타났다. 무화과의 수경재배에서 저농도에서 양호한 생육을 나타내었으며, 수량은 높은 농도에서 양호하였다. 본 실험의 결과는 무화과의 수량 및 품질증대에 유용하게 활용될 수 있을 것이다.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2003년도 추계학술발표회
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• pp.356-359
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• 2003

Polycyclic aromatic hydrocarbons (PAHs) are representative hydrophobic organic carbons (HOCs). Surfactant-enhanced electrokinetic (EK) remediation is an innovative in-situ technology that can effectively remove HOCs from low-permeability soils. In this study, the electrokinetic remediation using Tergitol 15-S-12, a nonionic surfactant, was conducted for the removal of phenanthrene from kaolinite. Tergitol 15-S-12 was used at concentrations of 1.5, 2.0, 2.5 and 7.5 g/L to enhance the solubility of phenanthrene. When the surfactant solution was applied to EK system, high electrical potential gradient was maintained and the amount of electroosmotic flow decreased. Removal efficiency of phenanthrene was proportional to the concentration of Tergitol 15-S-12 because the solubility and mobility of phenanthrene was enhanced by surfactant micelle. Therefore, the suitable concentration of nonionic surfactant Tergitol 15-S-12 is expected to improve the removal efficiency of PAHs in EK remediation.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2006년도 총회 및 춘계학술발표회
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• pp.402-406
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• 2006

The physical and chemical characteristics of ALC were analyzed and showed 2.2 of specific gravity and 9.05 of pH. The results of leaching tests with standard method for soil and waste indicated heavy metals(Cu, Cd, Pb, $Cr^{6+}$) were under maximum concentration level. The anaerobic digestion sludge was attached in the surface of ALC within 90 hours. As the results of batch test, pH of the ALC and Bio-ALC were decreased from initial pH of ALC to 8.7 and 7.8 respectively Also, the concentration of heavy metals was rapidly eliminated in the solution with the batch test. The result of column experiment indicates that the removal efficiency of ALC was showed 66% of T-P, 60% of T-N, and 67% of CODcr. Also, removal efficiency of Bio-ALC was slightly higher than that of ALC in T-N (64%) and CODcr (74%).

• 한국산림과학회지
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• 제87권4호
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• pp.611-619
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• 1998

황산용액을 첨가하여 인위적으로 산성화시킨 갈색산림토양에 2년생 소나무 묘목을 온실내에서 120일 동안 생육시킨 후, 묘목의 생장과 영양상태를 조사하였다. 토양용액의 Al 농도는 토양의 $H^+$ 부하량이 증가함에 따라 증가하였으며, 또한 소나무 묘목의 건물생장은 토양의 $H^+$ 부하량이 증가함에 따라 감소하였다. 소나무 묘목 지하부 Al 농도의 증가는 엽내 Ca 및 Mg 등과 같은 식물생장 필수원소 농도의 저하를 초래하였다. 소나무 묘목의 건물생장과 토양용액의 (Ca+Mg+K)/Al 몰비와의 사이에 높은 상관이 있는 것으로 나타났으며(r=0.96, p<0.001), 토양용액의 (Ca+Mg+K)/Al 몰비가 7.0이하로 낮아지면 건물생장이 감소가 발생하고 몰비가 1.0일 때의 건물생장은 대조구에 비하여 약 40% 감소하였다. 이상의 결과를 종합할 때 토양용액의 (Ca+Mg+K)/Al 몰비의 이용은 산성강하물에 대한 임계부하량 평가에 중요한 지표(指標)가 될 수 있다고 생각된다.

• 한국지하수토양환경학회지:지하수토양환경
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• 제26권5호
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• pp.9-19
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• 2021

This study evaluated the feasibility of combined use of physical separation and soil washing to remediate heavy metals (Pb and Cu) contaminated soil in a military shooting range. The soils were classified into two types based on the level of heavy metal concentrations: a higher contaminated soil (HCS) with Pb and Cu concentrations of 6,243 mg/kg and 407 mg/kg, respectively, and a lower contaminated soil (LCS) with their concentrations of 1,658 mg/kg and 232 mg/kg. Pb level in both soils exceeded the regulatory limit (700 mg/kg), and its concentration generally increased with decreasing soil particle size. However, in some cases, Pb concentrations increased with increasing soil particle size, presumably due to the presence of residues of bullets in the soil matrix. As a pretreatment step, a shaking table was used for physical separation of soil to remove bullet residues while fractionating the contaminated soils into different sizes. The most effective separation and fractionation were achieved at vibration velocity of 296 rpm/min, the table slope of 7.0°, and the separating water flow rate of 23 L/min. The efficiency of ensuing soil washing process for LCS was maximized by using 0.5% HCl with the soil:washing solution mixing ratio of 1:3 for 1 hr treatment. On the contrary, HCS was most effectively remediated by using 1.0% HCl with the same soil:solution mixing ratio for 3 hr. This work demonstrated that the combined use of physical separation and soil washing could be a viable option to remediate soils highly contaminated with heavy metals.