• Journal of Soil and Groundwater Environment
• /
• v.16 no.4
• /
• pp.23-30
• /
• 2011

Risk based pollution level of Pb and Cd in metal contaminated soils depending on physicochemical properties of soil in a target site was assessed using biotic ligand model. Heavy metal activity in soil solution defined as exposure activity (EA) was assumed to be toxic to Vibrio fischeri and soil organisms. Predicted effective activity (PEA) determined by biotic ligand model was compared to EA value to calculate risk quotient. Field contaminated soils (n = 10) were collected from a formes area and their risk based pollution levels were assessed in the present study using the calculated risk quotient. Concentrations of Pb determined by aqua regia were 295, 258, and 268 mg/kg in B, H and J points and concentrations of Cd were 4.73 and 6.36 mg/kg in G and I points, respectively. These points exceeded the current soil conservation standards. However, risk based pollution levels of the ten points were not able to be calculated because concentrations of Pb and Cd in soil solution were smaller than detection limits or one (i.e., non toxic). It was because heavy metal activity in soil solution was dominant toxicological form to organisms, not a total heavy metal concentration in soil. In addition, heavy metal toxicity was decreased by competition effect of major cations and formation of complex with dissolved organic carbon in soil solution. Therefore, it is essential to consider site-specific factors affecting bioavailability and toxicity for estimating reliable risk of Pb and Cd.

• Journal of Soil and Groundwater Environment
• /
• v.18 no.6
• /
• pp.38-47
• /
• 2013

This study was performed to identify the optimal operating conditions and to evaluate the xylene removal efficiency, applying in-situ soil flushing with the low concentrated solution of 'Tween 80' at the xylene contaminated site. The pilot scale test site ($5m{\times}5m{\times}3m$), was mainly composed of 'sandy loam', with the average hydraulic conductivity of $9.1{\times}10^{-4}cm\;s^{-1}$. The average xylene concentration of the site was 42.1 mg $kg^{-1}$, which was more than 2.5 times higher than Korea soil pollution warning limit (15 mg $kg^{-1}$). For the soil flushing, 7,800 L of 0.1~0.2% surfactant solution was injected into three injection wells at the average injection time of 9 hr $d^{-1}$ for 10 days, followed by the additional only groundwater injection of 6,000 L. The same amount of the effluent solution was extracted from three extraction wells. From the analysis for xylene concentration of all effluent at 3 extraction wells, total 166 g of xylene was removed by in-situ surfactant flushing. Even though the residual xylene concentrations of 7 soil sampling locations in the test site were different due to the soil heterogeneity, from the comparison of xylene concentration at 7 locations before/after the feasibility test, 53.9% of the initial xylene in the site was removed from three extraction wells (mainly Ext-N and Ext-M well). The results showed that the in-situ soil flushing by using low concentrated 'Tween 80' solution had a great potential to remediate the xylene contaminated site.

• Geomechanics and Engineering
• /
• v.29 no.1
• /
• pp.1-11
• /
• 2022

A semi-analytical solution to responses of overconsolidated (OC) unsaturated soils surrounding an expanding spherical cavity under constant suction condition is presented. To capture the elastoplastic hydro-mechanical property of OC unsaturated soils, the unified hardening (UH) model for OC unsaturated soil is adopted in corporation with a soil-water characteristic curve (SWCC) and two suction yield surfaces. Taking the specific volume, radial stress, tangential stress and degree of saturation as the four basic unknowns, the problem investigated is formulated by solving a set of first-order ordinary differential equations with the help of an auxiliary variable and an iterative algorithm. The present solution is validated by comparing with available solution based on the modified Cam Clay (MCC) model. Parametric studies reveal that the hydraulic and mechanical responses of spherical cavity expanding in unsaturated soils are not only coupled, but also affected by suction and overconsolidation ratio (OCR) significantly. More importantly, whether hydraulic yield will occur or not depends only on the initial relationship between suction yield stress and suction. The presented solution can be used for calibration of some insitu tests in OC unsaturated soil.

• Proceedings of the Korean Institute of Building Construction Conference
• /
• 2019.11a
• /
• pp.145-146
• /
• 2019

In this study, we evaluated the early strength of red clay soil with the polymer aqueous solution at rammed earth construction. In order to satisfy the demolding strength of the formwork be due to the rammed of red clay soil, the polymer aqueous solution was added to evaluate the compressive strength at the early age according to the consolidation level. As a result, a high compressive strength was exhibited with the formulation to which the polymer aqueous solution was added.

• Korean Journal of Soil Science and Fertilizer
• /
• v.43 no.6
• /
• pp.978-980
• /
• 2010

This study was conducted to observe the cause of injury of fig plant. Nitrogen dioxide gas can be evolved at low pH or reduced in soil. Fig plant cultivated with nutrient solution was wilted or withered. Injury symptom for nutrient solution containing nitrous acid was worse as pH of soil decreased. However, increase in pH of nutrient solution treated with increasing $Ca(OH)_2$ solution prevented nutrient solution from producing nitrogen dioxide gas. Recovery of the fig plant by pH increase indicated that the cause of injury was nitrogen dioxide gas.

• Korean Journal of Soil Science and Fertilizer
• /
• v.47 no.1
• /
• pp.23-27
• /
• 2014

Nutrient accumulation in surface soil has become a serious problem for cucumber production in greenhouse. However, still in many cases, soil management practices are only focused on maintaining crop yield, regardless of sustainability related with soil chemical properties. This study was conducted to propose a sustainable soil management practice by investigating the impact of cover crop species and nitrogen rate of fertigated solution on cucumber yield and soil chemical properties in greenhouse condition. Rye and hairy vetch were tested as a fallow cover crop, and each amount of urea (1/2, 3/4, 1 times of N fertilizer recommendations), determined by soil testing result, was supplied in fertigation plots as an additional nitrogen source. The result showed that the yield of cucumber was higher in rye treatment than control and hairy vetch treatment. In addition, rye effectively reduced EC and accumulated nutrients from the soil. Meanwhile, N concentration of fertigated solution showed no significant effect on the growth and yield of cucumber. Consequently, these results suggest that it is desirable to choose rye as a fallow catch crop for sustainable cucumber production in greenhouse.

• The Korean Journal of Ecology
• /
• v.2 no.1
• /
• pp.31-37
• /
• 1978

The salt accumulation on the soil surface can be mathematically described. Although the movement of salts in soil solution is expressed in terms of mathematical model, which has certain limitations in practical application, except the exchangeable and absorbable state salts in soil solution. This model is illustrated by analyticl experiments in which evaporation from the bare soils, transpiration of plants and rainfall are required. Agreement between the model and the measured data was satisfactory, which validating the salt accumulation theory on the soil surface.

• Korean Journal of Soil Science and Fertilizer
• /
• v.37 no.5
• /
• pp.322-328
• /
• 2004

Available nutrients in soil solution play key roles on the growth of plants, but the equilibria in soil solution can be disturbed by acid precipitation. In this study, we investigated the relationships between element concentrations in the needles of Pinus thunbergii and chemical properties of forest soil solutions in the industrial complexes as an effort to find the possible limiting factor(s) causing the forest decline. The Ca/Al molar ratios in needles of Pinus thunbergii collected from the control sites were 18. However, at Onsan and Ulsan industrial complexes, those were decreased to the ranges from 10 to 11 for the one-year old needles and from 9 to 10 for the two-year old needles. The Mg/Al molar ratios showed similar tendencies with the Ca/Al molar ratios of the needles of Pinus thunbergii. In the A horizon, there existed a significant correlation between Mg concentrations in the needles of Pinus thunbergii and Ca/Al molar ratio of forest soil solution. Calcium concentrations in the needles of Pinus thunbergii in the B horizon were also significantly correlated with Ca/Al molar ratios of forest soil solutions. The uptakes of Ca and Mg by Pinus thunbergii were mainly limited by Al in the soil solutions of the A horizon and by Mn and Al in the soil solutions of the B horizon.

• Journal of Soil and Groundwater Environment
• /
• v.15 no.2
• /
• pp.34-39
• /
• 2010

In this study, the remediation of diesel contaminated soil was attempted with ozone treatment and Fenton reaction. About 10% of initial diesel concentration was removed by the ozone saturated solution. The pseudo-first order decomposition constant of diesel contaminated soil in the presence of 5% of hydrogen peroxide with 1.82, 2.82, 4.82, 6.82, and 11.82% of iron contents was 0.0228, 0.0308, 0.0482, 0.0471, and 0.0592 $min^{-1}$ respectively. The decomposition constant of the diesel was 0.0064 $min^{-1}$ with the addition of ozone saturated solution only. On the addition of ozone saturated solution in the presence of 5% hydrogen peroxide and 5% iron, the decomposition constant of the diesel was 0.0850 $min^{-1}$. These results indicated that the decomposition rate was 190% faster than without the addition of ozone saturated solution. Thus, the application of both ozone and the fenton reaction is promising for the remediation of the diesel contaminated soil.

• Geomechanics and Engineering
• /
• v.21 no.6
• /
• pp.527-536
• /
• 2020

An elastic-plastic solution for cavity expansion problem considering strength degradation, undrained condition and initial anisotropic in-situ stress is established based on the Tresca yield criterion and cavity expansion theory. Assumptions of large-strain for plastic region and small-strain for elastic region are adopted, respectively. The initial in-situ stress state of natural soil mass may be anisotropic caused by consolidation history, and the strength degradation of soil mass is caused by structural damage of soil mass in the process of loading analysis (cavity expansion process). Finally, the published solutions are conducted to verify the suitability of this elastic-plastic solution, and the parametric studies are investigated in order to the significance of this study for in-situ soil test.