• Title/Summary/Keyword: soil organic carbon

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Assessment of Risk Based Pollution Level of Pb and Cd in Metal Contaminated Soils Using Biotic Ligand Model (Biotic ligand model에 근거한 중금속 오염지역의 Pb 및 Cd 위해오염도 평가기법 개발)

  • An, Jin-Sung;Jeong, Seul-Ki;Moon, Hee-Sun;Nam, Kyoung-Phile
    • Journal of Soil and Groundwater Environment
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    • v.16 no.4
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    • pp.23-30
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    • 2011
  • Risk based pollution level of Pb and Cd in metal contaminated soils depending on physicochemical properties of soil in a target site was assessed using biotic ligand model. Heavy metal activity in soil solution defined as exposure activity (EA) was assumed to be toxic to Vibrio fischeri and soil organisms. Predicted effective activity (PEA) determined by biotic ligand model was compared to EA value to calculate risk quotient. Field contaminated soils (n = 10) were collected from a formes area and their risk based pollution levels were assessed in the present study using the calculated risk quotient. Concentrations of Pb determined by aqua regia were 295, 258, and 268 mg/kg in B, H and J points and concentrations of Cd were 4.73 and 6.36 mg/kg in G and I points, respectively. These points exceeded the current soil conservation standards. However, risk based pollution levels of the ten points were not able to be calculated because concentrations of Pb and Cd in soil solution were smaller than detection limits or one (i.e., non toxic). It was because heavy metal activity in soil solution was dominant toxicological form to organisms, not a total heavy metal concentration in soil. In addition, heavy metal toxicity was decreased by competition effect of major cations and formation of complex with dissolved organic carbon in soil solution. Therefore, it is essential to consider site-specific factors affecting bioavailability and toxicity for estimating reliable risk of Pb and Cd.

Comparison to Soil Environment of Tricholoma matsutake and Sarcodon aspratus at Uljin Sokwang-ri Pinus densiflora for. erecta Uyeki Forest (울진 소광리 금강소나무림의 송이발생지와 능이발생지의 토양환경 비교)

  • Hur, Tae-Chul;Joo, Sung-Hyun
    • Current Research on Agriculture and Life Sciences
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    • v.20
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    • pp.77-82
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    • 2002
  • This study was carried out in order to produce useful material for the forest multiple use and forest protection by physico-chemical soil analysis of studied area in Sokwang-ri Forest Genetic Resource Protection Forest which was divided into in standard plots include Tricholoma matsutake and Sarcodon aspratus production forest. The result of physico-chemical soil analysis represented as following. The soil type of T. matsutake production forest was Dry brown forest soil(B1), while on the other hand the soil type of S. aspratus production forest was Moderately moist brown forest soil(B3). Between T. matsutake and S. aspratus production forest did not result in significant changes in soil pH(5.22-5.60) and soil depth(47cm), but available phosphorus, carbon, and nitrogen contents were different results. CN ratio of the fairy ring of T. matsutake was quite lower than that in S. aspratus production forests, which indicated that T. matsutake production forest was built up in the relatively immature soils which contain little organic matter. Generally, it was predicted that Pinus densiflora for. erecta forest succeeded to deciduous tree forest in stable soil environments. To conserve these T. matsutake and S. aspratus production forest, the contents of available phosphorous and exchangeable cation should be increased by continuous soil environment management and it should be established the secondary growth forests of old aged Pinus densiflora for. erecta trees as soon as possible.

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Effects of Aging and Soil Texture on Composting of Diesel-Contaminated Soil (디젤오염기간 및 토성이 오염토양 콤포스팅 처리에 미치는 영향)

  • Choi, Jung-Young;Namkoong, Wan;Park, Joon-Seok;Hwang, Eui-Young
    • Journal of the Korea Organic Resources Recycling Association
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    • v.10 no.2
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    • pp.132-139
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    • 2002
  • This study was carried out to investigate the effects of aging and soil texture on composting of diesel-contaminated soil. The soils used for this study were silt loam and sand. Target contaminant, diesel oil, was spiked at 10,000mgTPH/kg of dry soil. Aging times of diesel-contaminated soils were 15days and 60days, respectively. Fresh diesel-contaminated soil was also investigated. Moisture content was controlled to 70% of soil field capacity. Mix ratio of soil to sludge was 1:0.3 as wet weight basis. Temperature was maintained at $20^{\circ}C$ Volatilization loss of TPH was below 2% of initial concentration. n-Alkanes lost by volatilization were mainly by the compounds of C10 to C17. Diesel in contaminated soil was mainly removed by biodegradation mechanism. First order degradation rate constant of TPH in sandy soil was ranged from 0.081 to 0.094/day, which is higher than that in silt loam(0.056-0.061/day). From fresh to 60day-aged soils, there was little difference of TPH biodegradation rate between the soils. Carbon recovery ranged from 0.61 to 0.89. TPH degradation rate was highly correlated with $CO_2$ production rate.

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Study on the characterization of dissolved organic matters in Nakdong River (낙동강의 용존 유기물질 특성에 관한 연구)

  • Heo, Seong-Nam;Park, Jeong-Min;Im, Tae-Hyo;Shin, Chan-Ki
    • Journal of environmental and Sanitary engineering
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    • v.22 no.3
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    • pp.13-26
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    • 2007
  • Changes in the characteristics of dissolved organic matter was studied at selected stations in the Nakdong river basin using physical and chemical methods. Characteristics of dissolved organic matters were analysed and assessed. Production of disinfection byproducts were also investigated. 1. Result of relatedness study among each items of analyses showed that relatedness on BOD values were highest with cattle excrement treatment facilities where there is no synthetic organic materials and relatedness on $COD_{Mn}$ were highest at the mainstream Nakdong river. In case of $COD_{Cr}$ (which has more oxidative power than $COD_{Mn}$), the values were higher in the sidestreams indicating the higher content of recalcitrant compounds. The relatedness values for the $UV_{254}$ also showed higher values in the sidestreams and treatment facilities than mainstream indicating the presence of organic aromatic compounds. 2. Ratio of DOC on total organic carbon were higher in the mainstream which is attributable to the influent particulate organic materials produced by agricultural activities. The values were 10-15% higher in the mainstream compared with sidestreams. 3. Result of biodegradability test indicate that concentrations of recalcitrant DOC were higher in the sidestreams than in the mainstream. The values of recalcitrant DOC were higher with the forest stream indicating the effect of soil oriented humic substances. 4. Result of THM production test carried out at 10 stations in the Nakdong river show that $CHCl_3$ was detected with the highest value and the value was highest at Waekwan station.

Effect of Organic Fertilizer and Mulch Sources on Growth and CO2 Assimilation in MM.106 Apple Trees (유기질 비료와 멀칭자재가 MM.106 사과 대목의 생장과 광합성에 미치는 영향*)

  • Choi, Hyun-Sug;Rom, Curt;Kim, Wol-Soo;Choi, Kyeong-Ju;Lee, Youn
    • Korean Journal of Organic Agriculture
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    • v.18 no.2
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    • pp.245-255
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    • 2010
  • The study was conducted to investigate the effects of organic fertilizers and mulches on the growth and $CO_2$ assimilation in MM.106 apple trees. Growth and $CO_2$ assimilation of MM.106 apple trees grown in a greenhouse were affected by the nutrient concentrations and carbon (C) and nitrogen (N) ratio in the raw materials of organic fertilizers and mulches. The optimum C:N ratios, which makes microorganism convert the organic N into the inorganic N, were obtained in the organic fertilizer, poultry litter, green compost, and grass clippings, resulting in increasing single shoot height, SPAD, and $CO_2$ assimilation. The SPAD and $CO_2$ assimilation were affected by the treatments 5 weeks after the treatments, and then the tree growth was affected by the treatments 6 weeks later. The most efficient tree growth and development were observed in the 10 to $15\;mg{\cdot}kg^{-1}$ of the inorganic N in a soil, and the N was strongly related to the tree growth and development.

The Effect of Aircraft Traffic Emissions on the Soil Surface Contamination Analysis around the International Airport in Delhi, India

  • Ray, Sharmila;Khillare, P.S.;Kim, Ki-Hyun
    • Asian Journal of Atmospheric Environment
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    • v.6 no.2
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    • pp.118-126
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    • 2012
  • To investigate the effect of aircraft traffic emissions on soil pollution, metal levels were analyzed for 8 metals (Fe, Cr, Pb, Zn, Cu, Ni, Mn and Cd) from the vicinity of the Indira Gandhi International (IGI) airport in Delhi, India. The texture of the airport soil was observed to be sandy. Among the metals, Cd showed minimum concentration ($2.07{\mu}g\;g^{-1}$), while Fe showed maximum concentration ($4379{\mu}g\;g^{-1}$). The highest metal accumulation was observed at the landing site. Significant correlations were observed between metals and different textures (sand, silt, and clay) as well as with organic carbon (OC). The results indicate that grain size play a major role in OC retention in soil and subsequently helps in adsorption of metals in soil. M$\ddot{u}$ller's geoaccumulation index (I-geo) showed that airport soil was contaminated due to Cd and Pb with the pollution class 2 and 1, respectively. Pollution load index of the airport site was 1.34-3 times higher than the background site. The results of factor analysis suggested that source of the soil metal is mainly from natural weathering of soil, aircraft exhaust, and automobile exhaust from near by area. With respect to Dutch target values, the airport soils showed ~3 times higher Cd concentration. The study highlighted the future risk of enhanced metal pollution with respect to Cd and Pb due to aircraft trafficking.

Introduction of Soil Network(Gold Network) as one of the Ecological Network (생태네트워크로서의 토양네트워크(Gold Network) 제안)

  • Lee, Dong-Kun;Lee, Hochul;Kim, Eunyoung;Song, Wonkyong;Kim, Young Ja;Hwang, Sangyeon
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.16 no.1
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    • pp.245-257
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    • 2013
  • Lately, besides promoting the biodiversity of the natural ecosystems, there is a demand for climate change mitigation features that will reduce greenhouse gases and prevent disasters that will bring damages such as torrential rains. However, there was not a lot of discussion on the soils that are key in these features. Therefore, this paper proposes a network (Gold Network) as an alternative that will solve the problem that was filed earlier by figuring out how to compose the soil environment. First, in order to maximize the ecological status and value of the soil, a soil network can be proposed through the vertical and horizontal connections of the fragmented soil. Second, there is a need to understand and research the organic system of the ecosystems as well as the complex perspective of the ecosystem services, not only the fragmentary perspectives of the soil remediation, planting improvements or the other existing elements. Third, there is a need to apply the integrated perspective of the Landscape Ecology, Ecological Engineering and Restoration Ecology for the connectivity of the soil (network) due to it being in the execution of the soil network. If a soil network was to be built, a fundamental ecological network would be realized to not only promote biodiversity but also to prepare effective adaptation to climate change.

Sorption of PAHs by Soil Humins and Effect of Soil Inorganic Matrixs (PAHs의 토양휴민과의 흡착특성 및 토양 무기물의 영향 해석)

  • Lim, Dong-Min;Lee, Seung-Sik;Shin, Hyun-Sang
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.12
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    • pp.1337-1346
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    • 2006
  • Soil humin is the insoluble fraction of humic materials and play an important roles in the irreversible sorption of hydrophobic organic contaminants onto soil particles. However, there have been limited knowledge about the sorption and chemical properties of humin due to the difficulties in its separation from the inorganic matrix(mainly clays and oxides). In this study, de-ashed soil humins($Hu_1-Hu_6$) were isolated from a soil residues(Crude Hu) after removing alkali-soluble organic fractions followed by consecutive dissolution of the mineral matrix with 2%-HF for 2 hr. The humin samples were characterized by elemental analysis and $^{13}C$ NMR spectroscopic method and their sorption-desorption behavior for 1-naphthol were investigated from aqueous solution. The results were compared one another and that with peat humin. $^{13}C$ NMR spectra features indicate that the soil humin molecules are mainly made up of aliphatic carbons(>80% in total carbon) including carbohydrate, methylene chain. Freundlich sorption parameter, n was increased from 0.538 to 0.697 and organic carbon-normalized sorption coefficient(log $K_{OC}$) values also increased from 2.43 to 2.74 as inorganic matrix of the soil humin removed by HF de-ashing. The results suggest that inorganic phase in humin plays an important, indirect role in 1-naphthol sorption and the effects on the sorption non-linearity and intensity are analyzed by comparison between the results of soil humin and peat humin. Sorption-desorption hysteresis were also observed in all the humin samples and hysteresis index(HI) at low solute concentration($C_e$=0.1 mg/L) are in order of Peat humin(2.67)>De-ashed humin(0.74)>Crude Hu(0.59).

Effect of micro-environment in ridge and southern slope on soil respiration in Quercus mongolica forest

  • Lee, Jae-Seok
    • Journal of Ecology and Environment
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    • v.42 no.4
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    • pp.210-218
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    • 2018
  • Background: Soil respiration (Rs) is a major factor of the absorption and accumulation of carbon through photosynthesis in the ecosystem carbon cycle. This directly affects the amount of net ecosystem productivity, which affects the stability and sustainability of the ecosystem. Understanding the characteristics of Rs is indispensable to scientifically understand the carbon cycle of ecosystems. It is very important to study Rs characteristics through analysis of environmental factors closely related to Rs. Rs is affected by various environmental factors, such as temperature, precipitation, soil moisture, litter supply, organic matter content, dominant plant species, and soil disturbance. This study was conducted to analyze the effects of micro-topographical differences on Rs in forest vegetation by measuring the Rs on the ridge and southern slope sites of the broadly established Quercus mongolica forest in the central Korean area. Method: Rs, Ts, and soil moisture data were collected at the southern slope and ridge of the Q. mongolica forest in the Mt. Jeombong area in order to investigate the effects of topographical differences on Rs. Rs was collected by the closed chamber method, and data collection was performed from May 2011 to October 2013, except Winter seasons from November to April or May. For collecting the raw data of Rs in the field, acrylic collars were placed at the ridge and southern slope of the forest. The accumulated surface litter and the soil organic matter content (SOMC) were measured to a 5 cm depth. Based on these data, the Rs characteristics of the slope and ridge were analyzed. Results: Rs showed a distinct seasonal variation pattern in both the ridge and southern slope sites. In addition, Rs showed a distinct seasonal variation with high and low Ts changes. The average Rs measurements for the two sites, except for the Winter periods that were not measured, were $550.1\;mg\;CO_2m^{-2}h^{-1}$ at the ridge site and $289.4\;mg\;CO_2m^{-2}h^{-1}$ at the southern slope, a difference of 52.6%. There was no significant difference in the Rs difference between slopes except for the first half of 2013, and both sites showed a tendency to increase exponentially as Ts increased. In addition, although the correlation is low, the difference in Rs between sites tended to increase as Ts increased. SMC showed a large fluctuation at the southern slope site relative to the ridge site, as while it was very low in 2013, it was high in 2011 and 2012. The accumulated litter of the soil surface and the SOMC at the depth range of 0~5 cm were $874g\;m^{-2}$ and 23.3% at the ridge site, and $396g\;m^{-2}$ and 19.9% at the southern slope site. Conclusions: In this study, Rs was measured for the ridge and southern slope sites, which have two different results where the surface litter layer is disturbed by strong winds. The southern slope site shows that the litter layer formed in autumn due to strong winds almost disappeared, and while in the ridge site, it became thick due to the transfer of litter from the southern slope site. The mean Rs was about two times higher in the ridge site compared to that in the southern slope site. The Rs difference seems to be due to the difference in the amount of litter accumulated on the soil surface. As a result, the litter layer supplied to the soil surface is disturbed due to the micro-topographical difference, as the slope and the change of the community structure due to the plant season cause heterogeneity of the litter layer development, which in turn affects SMC and Rs. Therefore, it is necessary to introduce and understand these micro-topographical features and mechanisms when quantifying and analyzing the Rs of an ecosystem.

Woody Plant Species Composition, Population Structure and Carbon Sequestration Potential of the A. senegal (L.) Willd Woodland Along a Distance Gradient in North-Western Tigray, Ethiopia

  • Birhane, Emiru;Gebreslassie, Hafte;Giday, Kidane;Teweldebirhan, Sarah;Hadgu, Kiros Meles
    • Journal of Forest and Environmental Science
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    • v.36 no.2
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    • pp.91-112
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    • 2020
  • In Ethiopia, dry land vegetation including the fairly intact lowland and western escarpment woodlands occupy the largest vegetation resource of the country. These forests play a central role in environmental regulation and socio-economic assets, yet they received less scientific attention than the moist forests. This study evaluated the woody plant species composition, population structure and carbon sequestration potential of the A. senegal woodland across three distance gradients from the settlements. A total of 45 sample quadrants were laid along a systematically established nine parallel transect lines to collect vegetation and soil data across distance gradients from settlement. Mature tree dry biomass with DBH>2.5 cm was estimated using allometric equations. A total of 41 woody plant species that belong to 20 families were recorded and A. senegal was the dominant species with 56.4 IVI value. Woody plant species diversity, density and richness were significantly higher in the distant plots compared to the nearest plots to settlement (p<0.05). The cumulative DBH class distribution of all individuals had showed an interrupted inverted J-shape population pattern. There were 19 species without seedlings, 15 species without saplings and 14 species without both seedlings and saplings. A significant above ground carbon (5.3 to 12.7 ton ha-1), root carbon (1.6 to 3.6 ton ha-1), soil organic carbon (35.6 to 44.5 ton ha-1), total carbon stock (42.5 to 60.7 ton ha-1) and total carbon dioxide equivalent (157.7 to 222.8 ton ha-1) was observed consistently with an increasing of distance from settlement (p<0.05). Distance from settlement had significant and positive correlation with species diversity and carbon stock at 0.64⁎⁎ and 0.78⁎⁎. Disturbance intensity may directly influence the variation of species composition, richness and density along the A. senegal woodland. The sustainability of the A. senegal woodland needs urgent protection, conservation and restoration.