• Title/Summary/Keyword: soil organic carbon

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Carbon and Nitrogen Dynamics of Wood Stakes as Affected by Soil Amendment Treatments in a Post-Fire Restoration Area (산불 훼손 복원지 내 토양개량제 처리가 Wood stakes의 탄소 및 질소 동태에 미치는 영향)

  • Park, Seong-Wan;Baek, Gyeongwon;Byeon, Hee-Seop;Kim, Yong Suk;Kim, Choonsig
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.20 no.4
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    • pp.357-365
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    • 2018
  • This study was carried out to evaluate the weight loss rates, carbon and nitrogen dynamics of wood stakes following soil amendment treatments (CLB: compound fertilizer + lime + biochar; LB: lime + biochar) in a post-fire restoration area, Ulsan Metropolitan city, southern Korea. Soil amendments in the fire-disturbed area were applied to two-times (Mar. and Jun. 2015, 2016) during the study period. Wood stakes on Mar. 2015 were buried at a top 15cm of mineral soil in two soil amendment and control treatments of Liriodendron tulipifera, Prunus yedoensis, Quercus acutissima, Pinus thunbergii plantations and an unplanted area in the post-fire restoration area. Wood stakes were collected at Oct. 2015, Mar. 2016 and Oct. 2016 to measure weight loss rates, organic carbon and nitrogen concentrations. Weight loss rates of wood stakes were not significantly affected by soil amendment treatments. However, remaining carbon of wood stakes were lowest in the control treatment (43.7%), followed by the CLB (71.3%) and the LB (71.6%) treatments. Remaining nitrogen of wood stakes was less in the control treatment (29.7%) compared with the LB treatment (52.6%). The results indicate that carbon and nitrogen mineralization of wood stakes in post-fire restoration area were delayed by soil amendment treatments.

Analyses of intermediate products during degradation of pyrene in soil by hemoglobin-catalyzed reaction

  • Keum, Haein;Kang, Guyoung
    • Journal of Applied Biological Chemistry
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    • v.61 no.4
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    • pp.335-340
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    • 2018
  • Hemoglobin (Hb) is a member of heme-protein that can perform catalytic non-specific chain reaction in the presence of hydrogen peroxide ($H_2O_2$). Catalytic ability of Hb to degrade pyrene was demonstrated using soil contaminated with $^{14}C$ pyrene and 10 mg pyrene /kg soil. The composition of soil was similar to previously used soil except that it had lower organic carbon content. Bench scale laboratory tests were conducted in the presence of buffer only, $H_2O_2$ only, or Hb with $H_2O_2$ for 24 h. After 24 h reaction, 0.1 and 1.3% of $^{14}C$ pyrene in contaminated soil were mineralized with $H_2O_2$ only or Hb plus $H_2O_2$. No mineralization to $^{14}CO_2$ was detected with buffer only. Approximately 12.2% of pyrene was degraded in the presence of $H_2O_2$ only while 44.0% of pyrene was degraded in the presence of Hb plus $H_2O_2$ during 24 h of catalytic reaction. When degradation intermediate products were examined, two chemicals were observed in the presence of $H_2O_2$ only while 25 chemicals were found in the presence of Hb plus $H_2O_2$. While most degradation products were simple hydrocarbons, four of the 27 chemicals had aromatic rings. However, none of these four chemicals was structurally related to pyrene. These results suggest that Hb catalytic system could be used to treat pyrene-contaminated soil as an efficient and speedy remediation technology. In addition, intermediate products generated by this system are not greatly affected by composition change in soil organic matter content.

Changes in CO2 Absorption Efficiency of NaOH Solution Trap with Temperature

  • Park, Se-In;Park, Hyun-Jin;Yang, Hye In;Choi, Woo-Jung
    • Korean Journal of Soil Science and Fertilizer
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    • v.50 no.6
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    • pp.554-561
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    • 2017
  • Under the projected global warming, release of carbon as $CO_2$ through soil organic matter decomposition is expected to increase. Therefore, accurate measurement of $CO_2$ released from soil is crucial in understanding the soil carbon dynamics under increased temperature conditions. Sodium hydroxide (NaOH) traps are frequently used in laboratory soil incubation studies to measure soil respiration rate, but decreasing $CO_2$ gas solubility with increasing temperature may render the reliability of the method questionable. In this study, the influences of increasing temperature on the $CO_2$ capture capacity of NaOH traps were evaluated under $5{\sim}35^{\circ}C$ temperature range at $10^{\circ}C$ interval. Two closed-chamber experiments were performed where NaOH traps were used to capture $CO_2$ either released from acidified $Na_2CO_3$ solution or directly injected into the chamber. The sorption of ambient $CO_2$ within the incubators into NaOH traps was also measured. The amount $CO_2$ captured increased as temperature increased within 2 days of incubation, suggesting that increased diffusion rate of $CO_2$ at higher temperatures led to increases in $CO_2$ captured by the NaOH traps. However, after 2 days, over 95% of $CO_2$ emitted in the emission-absorption experiment was captured regardless of temperature, demonstrating high $CO_2$ absorption efficiency of the NaOH traps. Thus, we conclude that the influence of decreased $CO_2$ solubility by increased temperatures is negligible on the $CO_2$ capture capacity of NaOH traps, supporting that the use of NaOH traps in the study of temperature effect on soil respiration is a valid method.

Effect of Crop Yield and Soil Physical Properties to Application of Organic Resources in Upland (밭 토양에서 유기물 자원의 시용이 작물 수량 및 토양 물리성에 미치는 영향)

  • Han, Kyunghwa;Jung, Kangho;Cho, Heerae;Lee, Hyubsung;Ok, Junghun;Zhang, Yongseon;Kim, Gisun;Seo, Youngho
    • Journal of the Korea Organic Resources Recycling Association
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    • v.25 no.4
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    • pp.15-22
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    • 2017
  • Application of organic resources to agricultural land can increase crop yield by improving soil characteristics. The objective of this study was to evaluate effect of crop yield and soil physical properties including aggregate stability to application of organic resources in upland. The soybean was cultivated in a sandy loam field and a clay loam field located at Suwon and a sandy loam field located at Pyeongchang. The organic resources used in this study were rice straw compost (RSC), composted pig manure with sawdust (CPIG), composted poultry manure with sawdust (CPM), and cocopeat applied before sowing crop. Application rate of organic resources was determined based on carbon content and water content. The inorganic fertilizers were applied based on soil testing. In addition, the decomposition of RSC, CPIG, and cocopeat was characterized by isothermal incubation with sandy loam soil. The decomposition rate was highest for RSC followed by CPIG and cocopeat. Organic resource application increased yield of soybean, which effect was greater in clay loam than in sandy loam. In addition, increase in gas phase proportion by organic resource application was distinct in clay loam soil compared with sandy loam soil. In terms of aggregate stability, increasing effect was more obvious in sandy loam soils than in a clay loam soil. The highest yield was observed in RSC treatment plots for all the fields. Improvement of soybean yield and soil physical characteristics by cocopeat was not as much as that of the other organic resources. The results implied that RSC could be recommended for promoting aggregate stability and crop yield in upland cultivation.

Evaluation of Efficiency to Plant Growth in Horticultural Soil Applied Biochar Pellet for Soil Carbon Sequestration (토양 탄소 격리 적용을 위한 바이오차 팰렛 혼합 상토를 사용한 작물 재배 효율성 평가)

  • Shin, JoungDu;Choi, YoungSu;Choi, Eunjung;Kim, MyungSook;Heo, JeongWook
    • Journal of the Korea Organic Resources Recycling Association
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    • v.25 no.3
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    • pp.73-78
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    • 2017
  • Objective of this experiment was to evaluate efficiency of application of biochar pellet in case of application of soil carbon sequestration technology. The treatments were consisted of control as general agricultural practice method, pellet(100% pig compost), biochar pellets with mixture ratio of pig compost(9:1, 8:2, 6:4, 4:6, 2:8) for comparatives of pH, EC, $NH_4-N$ and $NO_3-N$ concentrations, and yields in the nursery bed applied biochar pellets after lettuce harvesting. The application rates of biochar pellet was 6.6g/pot regardless of their mixed rates based on recommended amount of application (330kg/10a) for lettuce cultivation. pH in the nursery bed applied different biochar pellets after lettuce harvesting was only increased in the treatment plot of pig compost pellet application, but decreased in 4:6 and 2:8 pellet application plots. However, EC was observed to be not significantly different among the treatments. $NH_4-N$ concentration was only increased in the treatment plot of pig compost pellet application, but $NO_3-N$ concentrations were decreased as compared to the control. Yields in the treatments of 9:1, 8:2 and 4:6 biochar pellet application plot were increased from 9.5% to 11.4%. Therefore, this biochar pellet application might be useful for soil carbon sequestration and greenhouse gas mitigation in the agricultural farming practices because it was appeared to be a positive effect on lettuce growth.

Effects of Dolomite and Oyster Shell on Nitrogen Processes in an Acidic Mine Soil Applied with Livestock Manure Compost

  • Yun, Seok-In;Seo, Dong-Hyuk;Kang, Ho Sang;Cheng, Hyocheng;Lee, Gunteak;Choi, Woo-Jung;Lee, Chang-Kyu;Jung, Mun Ho
    • Korean Journal of Soil Science and Fertilizer
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    • v.49 no.5
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    • pp.614-620
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    • 2016
  • Mine soils are usually unfavorable for plant growth due to their acidic condition and low contents of organic matter and nutrients. To investigate the effect of organic material and lime on nitrogen processes in an acidic metal mine soil, we conducted an incubation experiment with treating livestock manure compost, dolomite, and oyster shell and measured soil pH, dehydrogenase activity, and concentration of soil inorganic N ($NH_4{^+}$ and $NO_3{^-}$). Compost increased not only soil inorganic N concentration, but also soil pH from 4.4 to 4.8 and dehydrogenase activity from 2.4 to $3.9{\mu}g\;TPF\;g^{-1}day^{-1}$. Applying lime with compost significantly (P<0.05) increased soil pH (5.9-6.4) and dehydrogenase activity ($4.3-7.0{\mu}g\;TPF\;g^{-1}day^{-1}$) compared with applying only compost. Here, the variation in dehydrogenase activity was significantly (P<0.05) correlated with that in soil pH. Soil inorganic N decreased with time by 14 days after treatment (DAT) due to N immobilization, but increased with time after 14 DAT. At 28 DAT, soil inorganic N was significantly (P<0.05) higher in the lime treatments than the only compost treatment. Especially the enhanced dehydrogenase activity in the lime treatments would increase soil inorganic N due to the favored mineralization of organic matter. Although compost and lime increased soil microbial biomass and enzyme activity, ammonia oxidation still proceeded slowly. We concluded that compost and lime in acidic mine soils could increase soil microbial activity and inorganic N concentration, but considerable ammonium could remain for a relatively long time.

Effect of Surfactant Molecules on the Aqueous Solubility of two PAHs (새로운 계면활성제들에 의한 두 PAH의 수중 용해도 증가)

  • 이진희;박재우
    • Journal of Korea Soil Environment Society
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    • v.5 no.1
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    • pp.65-73
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    • 2000
  • Surfactants have been extensively considered for decontamination of the subsurface polluted with hydrophobic organic compounds. In order to investigate the effect of molecular structures on the solubilization of hydrophobic organic compounds, solubility enhancement of two PAHs in solutions of three different surfactants-conventional, dianionic, and gemini. The batch experimental results showed that the gemini was the most effective and the dianionic was the least, indicating that organic carbon content of the surfactants was the major factor which determines the sorption capacity of surfactant aggregates in water, unlike some of the previous reports.

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Comparison of Tyurin Method and Dry Combustion Method for Carbon Analysis in Soils of Low Iorganic Carbon content (무기탄소 함량이 낮은 토양의 탄소함량 분석을 위한 Tyurin법과 건식연소법의 비교)

  • Seo, Myung-Chul;So, Kyu-Ho;Ko, Byong-Gu;Son, Yeon-Kyu
    • Korean Journal of Soil Science and Fertilizer
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    • v.37 no.5
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    • pp.315-321
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    • 2004
  • To compare soil carbon contents by Tyurin method and dry combustion method, we carried out analysis for 212 samples of agricultural land in Korea. The average values of soil carbon contents analyzed by Tyurin method and dry combustion method were $17.47{\pm}10.80$ and $19.91{\pm}10.63g\;kg^{-1}$, respectively. Both methods were evaluated as acceptable methods for soil carbon contents as the results showed. The results showed that soil texture had little effect on analysis method of carbon contents. Highly significant linear regression equation, Y = 0.846X ($R^2=0.991$), was obtained between carbon contents analyzed by Tyurin method (Y) and dry combustion method (X). As a result of comparison with data of carbon contents of the two methods, about 69% of results at dry combustion method have exceeded to results at Tyurin method. Especially, differences between results at two methods became higher as carbon contents were increasing. Tyurin method has been advantages such as shorter analysis time for one sample, more recognition for carbon analysis, and no need for expensive analyzer, while dry combustion method has simpler procedure, no heavy metal wastes, and more samples for analysis at one time.

Development of Regression Models for Estimation of Unmeasured Dissolved Organic Carbon Concentrations in Mixed Land-use Watersheds (복합토지이용 유역의 수질 관리를 위한 미측정 용존유기탄소 농도 추정)

  • Min Kyeong Park;Jin a Beom;Minhyuk Jeung;Ji Yeon Jeong;Kwang Sik Yoon
    • Journal of Korean Society on Water Environment
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    • v.39 no.2
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    • pp.162-174
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    • 2023
  • In order to prevent water pollution caused by organic matter, Total Organic Carbon(TOC) has been adopted indicator and monitored. TOC can be divided into Dissolved Organic Carbon(DOC) and Particulate Organic Carbon(POC). POC is largely precipitated and removed during stream flow, which making DOC environmentally significant. However, there are lack of studies to define spatio-temporal distributions of DOC in stream affected by various land use. Therefore, it is necessary to estimate the past DOC concentration using other water quality indicators to evaluate status of watershed management. In this study, DOC was estimated by correlation and regression analysis using three different organic matter indicators monitored in mixed land-use watersheds. The results of correlation analysis showed that DOC has the highest correlation with TOC. Based on the results of the correlation analysis, the single- and multiple-regression models were developed using Biochemical Oxygen Demand(BOD), Chemical Oxygen Demand(COD), and TOC. The results of the prediction accuracy for three different regression models showed that the single-regression model with TOC was better than those of the other multiple-regression models. The trend analysis using extended average concentration DOC data shows that DOC tends to decrease reflecting watershed management. This study could contribute to assessment and management of organic water pollution in mixed land-use watershed by suggesting methods for assessment of unmeasured DOC concentration.

Nitrous Oxide Emission from Livestock Compost applied Arable Land in Gangwon-do

  • Seo, Young-Ho;Kim, Se-Won;Choi, Seung-Chul;Jeong, Byeong-Chan;Jung, Yeong-Sang
    • Korean Journal of Soil Science and Fertilizer
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    • v.45 no.1
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    • pp.25-29
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    • 2012
  • Agriculture activities account for 58% of total anthropogenic emissions of nitrous oxide ($N_2O$) with global warming potential of 298 times as compared to carbon dioxide ($CO_2$) on molecule to molecule basis. Quantifying $N_2O$ from managed soil is essential to develop national inventories of greenhouse gas (GHG) emissions. The objective of the study was to compare $N_2O$ emission from livestock compost applied arable land with that for fertilizer treatment. The study was conducted for two years by cultivating Chinese cabbage (Brassica campestris L.) in Chuncheon, Gangwon-do. Accumulated $N_2O$ emission during cultivation of Chinese cabbage after applying livestock compost was slightly greater than that for chemical fertilizer. Slightly greater $N_2O$ emission factor for livestock compost was observed than that for chemical fertilizer possibly due to lump application of livestock compost before crop cultivation compared with split application of chemical fertilizers and enhanced denitrification activity through increased carbon availability by organic matter in livestock compost.