• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2004.04a
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• pp.186-191
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• 2004

Sorption kinetics of 2-chlorophenol(2-ChP), 2,4-dichlorophenol(2,4-DChP) and 2,4,5-trichlorophenol (2,4,5-TChP), onto montmorillonite modified with hexadecyltrimethyl ammonium cations(HDTMA-mont) were investigated. One-site mass transfer model(OSMTM) and two compartment first-order kinetic model(TCFOKM) were used to analyze kinetics. As expected from the number of model parameters involved, the three-parameter TCFOKM was better than the two-parameter OSMTM in describing sorption and desorption kinetics of chlorophenols in HDTMA-mont. For all chlorophenols, the results of OSMTM analysis indicate that the predominant deprotonated speciation(at pH 9.15) exhibited higher mass transfer coefficient( $k_{s}$ ) than the protonated speciation(at pH 4.85). This is because the deprotonated speciation has stronger hydrophobic interaction than protonated speciation. Most sorption completes in three hours. The fraction of the fast sorption and the first-order sorption rate constants for the fast and slow compartments in TCFOKM were determined by fitting experimental data to the TCFOKM. The results of kinetics reveal that the fraction of the fast sorption( $f_1$) and the sorption rate constants in the fast compartments( $k_1$) were in the order 2,4,5-TChP > 2,4-DChP > 2-ChP, which agrees with the magnitude of the $K_{ow}$ . The first-order sorption rate constants in the fast compartment(10$^{0.8}$ - 10$^{1.22}$ h $r^{-1}$ ) were much larger than those in the slow compartment(10$^{-1}$.74/ - 10$^{-2}$.622/ h $r^{-1}$ ).> ).).

• Proceedings of the Korea Water Resources Association Conference
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• 2009.05a
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• pp.752-757
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• 2009

In the last decade, many methods such as greet chamber, reservoir, or debris barrier, have been utilized to manage and prevent muddy water problem. The Vegetative Filter Strip (VFS) has been thought to be one of the most effective methods to trap sediment effectively. The VFS are usually installed at the edge of agricultural areas adjacent to stream or drainage ditches, and it has been shown that the VFS effectively removes pollutants transported with upland runoff. But, if the VFS is installed without any scientific analysis of rainfall-runoff characteristics, soil erosion, and sediment analysis, it may not reduce the sediment as much as expected. Although Soil and Water Assessment Tool (SWAT) model has been used worldwide for many hydrologic and Non-Point Source Pollution (NPSP) analysis at a watershed scale. but it has many limitations in simulating the VFS. Because it considers only 'filter strip width' when the model estimates sediment trapping efficiency, and does not consider the routing of sediment with overland flow option which is expected to maximize the sediment trapping efficiency from upper agricultural subbasin to lower spatially-explicit filter strip. Therefore, the SWAT overland flow option between landuse-subbasins with sediment routing capability was enhanced with modifications in SWAT watershed configuration and SWAT engine. The enhanced SWAT can simulate the sediment trapping efficiency of the VFS in the similar way as the desktop VFSMOD-w system does. Also it now can simulate the effects of overland flow from upper subbasin to reflect the increased runoff volume at the receiving subbasin, which is what is occurring at the field if no diversion channel is installed. In this study, the enhanced SWAT model was applied to small watershed located at Jaun-ri in South Korea to simulate diversion channel and spatially-explicit VFS. It was found that approximately sediment can be reduced by 31%, 65%, 68%, with diversion channel, the VFS, and the VFS with diversion channel, respectively.

• Journal of Soil and Groundwater Environment
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• v.8 no.4
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• pp.12-20
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• 2003

This study presents a mathematical model for simulating the fate and transport of a reactive organic contaminant, TCE, degraded by cometabolism in dual-porosity soils during the installation of in situ biobarrier. To investigate the effect of dual-porosity on transport and biodegradation of organic hydrocarbons, a bimodal approach was incorporated into the model. Modified Monod kinetics and a microcolony concept were employed to represent the effects of biodegrading microbes on the transport and biodegradation of an organic contaminant. The effect of permeability reduction in biobarrier due to biomass accumulation on the flow field were examined in the simulation of a hypothetical field-scale in situ bioaugmentation. Simulation results indicate that the presence of the immobile region can decrease the bioavailability of biodegradable contaminants and that the placement of microbes and nutrients injection wells should be considered for an effective installation of biobarrier during in situ bioaugmentation scheme.

• Korean Journal of Soil Science and Fertilizer
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• v.50 no.4
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• pp.306-317
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• 2017

Unmanned aerial vehicles (UAVs) became popular platforms for the collection of remotely sensed data in the last years. This study deals with the monitoring of multi-temporal onion growth with very high resolution by means of low-cost equipment. The concept of the monitoring was estimation of multi-temporal onion growth using normalized difference vegetation index (NDVI) and meteorological factors. For this study, UAV imagery was taken on the Changnyeong, Hapcheon and Muan regions eight times from early February to late June during the onion growing season. In precision agriculture frequent remote sensing on such scales during the vegetation period provided important spatial information on the crop status. Meanwhile, four plant growth parameters, plant height (P.H.), leaf number (L.N.), plant diameter (P.D.) and fresh weight (F.W.) were measured for about three hundred plants (twenty plants per plot) for each field campaign. Three meteorological factors included average temperature, rainfall and irradiation over an entire onion growth period. The multiple linear regression models were suggested by using stepwise regression in the extraction of independent variables. As a result, $NDVI_{UAV}$ and rainfall in the model explain 88% and 68% of the P.H. and F.W. with a root mean square error (RMSE) of 7.29 cm and 59.47 g, respectively. And $NDVI_{UAV}$ in the model explain 43% of the L.N. with a RMSE of 0.96. These lead to the result that the characteristics of variations in onion growth according to $NDVI_{UAV}$ and other meteorological factors were well reflected in the model.

• Proceedings of the Korea Society of Environmental Toocicology Conference
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• 2003.05a
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• pp.150-151
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• 2003

Benzoyl peroxide is a high production volume chemical, which was produced about 1,375 tons/year in Korea as of 2001 survey. Most of them are used as initiators in polymerization, catalysts in the plastics industry, bleaching agents for flour and medication for acne vulgaris. The substance is one of the sever chemicals of which human and environmental risks are being assessed by National Institute of Environmental Research under the frame of OECD SIDS Program. It has a melting point of 104-106 $^{\circ}C$ and has solubility of 9.1 mg/1 in water at 25 $^{\circ}C$. The substance was readily biodegradable (83 % after 21days) and had toxic effects to aquatic organisms. The range of 72 hr-EbC50 (biomass) for algae was 0.07-0.44 mg/1 and 48 hr-EC50 for daphnia was 0.07-2.91 mg/1. The LC50 of acute toxicity to fish was 0.24-2.0 mg/1. Although the toxic effects of benzoyl peroxide to aquatic organisms were investigated, environmental monitoring data were not studied. In this study, distribution of the chemical among multimedia environment was estimated using EQC model based on the physical-chemical properties to evaluate the risk of benzoyl peroxide in environment. In level I, II calculation the chemical was distributed to soil (68.3 %) and water (28.7 %). In level III calculation it was primarily distributed to soil (99.9 %) and overall residence time of 3.4 years was estimated. Benzoyl peroxide could be persistent in environment.

• Journal of Biosystems Engineering
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• v.26 no.6
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• pp.553-562
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• 2001

The greenhouse heating system with heat pump and latent heat storage was built for development of simulation model and validation. The computer simulation model for the system to predict temperature of air, soil surface and cover film in the greenhouse were developed and its validity was justified by actual data. From the analysis of experimentally measured and the simulation output, following results were obtained. 1. The expected values of inside air temperature for the greenhouse with a heat pump and a latent heat storage system were very much close to the experimental values at the error range of 1.0$\^{C}$. 2. The expected values of soil surface temperature fur the geenhouse with a heat pump and a latent heat storage system were very much close to the experimental values at the error range of 1.0$\^{C}$. 3. The expected values of thermal energy flow fur the greenhouse with a heat pump and a latent heat storage system were very much close to the experimental values at the error range of 167.2kJ/m$^2$h. 4. Heat lass value of day time was found to be larger than that of night time as much as 1.11 time. 5. At day time. the inside air temperature was shown to be higher than the set point of 7.0$\^{C}$. At night time, the inside air temperature was controlled in order to maintain higher temperatures than the set point.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.16 no.3
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• pp.2234-2241
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• 2015

This study has been undertaken to develop a relationship between the shear strength coefficients and the cone index. The theoretic mathematical equations for the relationship were rigorously investigated, and then a Artificial Neural Network(ANN) analysis was adapted to enhance the reliability of the investigation. The theoretical investigation involved various assumptions resulting in the significant error involvement of geotechnical behaviors of ground. Therefore, a model using the ANN has been learned to enhance the prediction of the cone index form the shear strength parameters. Site investigation reports from various construction fields were used for ANN model learning. The results of the study show that the model predicts the cone index from the shear strength parameters of soils very well. The further study that is undertaking has a potential promise of the generalized prediction technique for the cone index from the soil parameters.

• Journal of the Korean Society for Railway
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• v.11 no.1
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• pp.54-60
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• 2008

In the trackbed design using elastic multilayer model, the stress-dependent resilient modulus $(E_R)$ is an important input parameter, that is, reflects substructure performance under repeated traffic loading. However, the evaluation method for resilient modulus using repeated loading triaxial test is not fully developed for practical purpose, because of costly equipment and the significantly fluctuated values depending on the testing equipment and laboratory personnel. The this study, the paper will present an indirect method to estimate the resilient modulus using dynamic properties. The resilient modulus of crushed stone, which is the typical material of sub-ballast, was calculated with the measured dynamic properties and the range of stress level of the sub-ballast, and approximated with the power model combined with bulk and deviatoric stresses. The resilient modulus of coarse grained material decreases with increasing deviatoric stress at a confining pressure, and increases with increasing bulk stress. Sandy soil (SM classified from Unified Soil Classification System) of subgrade was also evaluated and best fitted with the power model of deviatoric stress only.

• Proceedings of the Korean Geotechical Society Conference
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• 2008.03a
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• pp.1144-1154
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• 2008

In this paper, the behaviour of shell foundation was studied. In order to perform this study, three studies such as theoretical, numerical and experimental programs were performed. In the theoretical program, the general shallow foundation theories and failure mechanism developed by Terzaghi, Mayerhof and others were reviewed and compared. Based on the previous shallow foundation behaviour, the shell foundation theory was developed using the upper boundary theorem. In the numerical study, the 2 and 3 dimensional FEM simulations were carried out using an uncoupled-analysis approach. From the analysis results, the adequate depth of shell foundation was evaluated. It was also evaluated the bearing capacity according to the shell angle ($120^{\circ}$, $90^{\circ}$, $60^{\circ}$). In the experimental study, the laboratory model tests were carried out for five cases of different foundation shapes including the rectangular and circular foundation in order to verify the theoretical and nemerical study. According to the results of this study, the bearing capacity of shell foundation was theoretically about 15% larger than that of general foundation. However, in the model test, the bearing capacity of shell foundation was about 25 to 30% larger than that of general foundation. In the case of shell angle, the maximum bearing capacity of shell foundation shows when the shell angle of foundation was $60^{\circ}$. In addition, Even if the shell foundation has the various advantages compared with the general foundations as described above, the practical verifications in full scale size will be necessary to use in the field and will be helpful in the technical development of other special foundations.

• Proceedings of the Korean Geotechical Society Conference
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• 2000.11a
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• pp.705-712
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• 2000

The fluid generally flows through fractures in crystalline rocks where most of underground storage facilities are constructed because of their low hydraulic conductivities. The fractured rock is better to be conceptualized with a discrete fracture concept, rather continuum approach. In the aspect of fluid flow in underground, the simultaneous flow of groundwater and gas should be considered in the cases of generation and leakage of gas in nuclear waste disposal facilities, air sparging process and soil vapor extraction for eliminating contaminants in soil or rock pore, and pneumatic fracturing for the improvement of permeability of rock mass. For the purpose of appropriate analysis of groundwater-gas flow, this study presents an unsteady-state multi-phase FEM fracture network simulator. Numerical simulation has been also conducted to investigate the hydraulic head distribution and air tightness around Ulsan LPG storage cavern. The recorded hydraulic head at the observation well Y was -5 to -10 m. From the results obtained by the developed model, it shows that the discrete fracture model yielded hydraulic head of -10 m, whereas great discrepancy with the field data was observed in the case of equivalent continuum modeling. The air tightness of individual fractures around cavern was examined according to two different operating pressures and as a result, only several numbers of fractures neighboring the cavern did not satisfy the criteria of air tightness at 882 kPa of cavern pressure. In the meantime, when operating pressure is 710.5 kPa, the most areas did not satisfy air tightness criteria. Finally, in the case of gas leaking from cavern to the surrounding rocks, the resulted hydraulic head and flowing pattern was changed and, therefore, gas was leaked out from the cavern ceiling and groundwater was flowed into the cavern through the walls.