• Title/Summary/Keyword: softwood by-products

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Penetrating Performance of Wood-preservatives by Ultrasonic Steeping (초음파침지처리에 의한 목재방부제의 주입성)

  • Lee, Myung Jae;Lee, Dong-Heub;Lee, Hyun-Mi;Son, Dong-Won
    • Journal of the Korean Wood Science and Technology
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    • v.33 no.3 s.131
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    • pp.64-71
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    • 2005
  • In this study, we attempted to apply ultrasonic treatment for the preservative treatment of two softwood species, Korean pine and Japanese red pines to evaluate its effectiveness. Wood samples were submerged in oilborne preservative, copper naphthenate (NCU) and waterborne preservative, alkyl ammonium compound (AAC) and then treated with ultrasonic wave of 40 kHz, 400 W. After the treatment, the retention and penetration depth of these preservatives in the specimens were measured as a function of treatment time. Both the retention and penetration depth were continuously increased with increasing the treatment time up to 120 hours, where the retention reached about 95% by the application of AAC and the penetrating depth of 95% and 83% by the application of NCU, respectively for both species. The results of electronic microscopic observation showed that the improved retention capacity could be attributed to air deflation, wood extractive deflation working of ultrasonic wavelength, and destruction of wood pits which served as the pathway of preservatives. The results suggested that the use of ultrasonic treatment could be applied to thick wood veneers for the production of laminated wood products.

Biological Pretreatment of Softwood Pinus densiflora by Three White Rot Fungi

  • Lee, Jae-Won;Gwak, Ki-Seob;Park, Jun-Yeong;Park, Mi-Jin;Choi, Don-Ha;Kwon, Mi;Choi, In-Gyu
    • Journal of Microbiology
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    • v.45 no.6
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    • pp.485-491
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    • 2007
  • The effects of biological pretreatment on the Japanese red pine Pinus densiflora, was evaluated after exposure to three white rot fungi Ceriporia lacerata, Stereum hirsutum, and Polyporus brumalis. Change in chemical composition, structural modification, and their susceptibility to enzymatic saccharification in the degraded wood were analyzed. Of the three white rot fungi tested, S. hirsutum selectively degraded the lignin of this sortwood rather than the holocellulose component. After eight weeks of pretreatment with S. hirsutum, total weight loss was 10.7%, while lignin loss was the highest at 14.52% among the tested samples. However, holocellulose loss was lower at 7.81 % compared to those of C. lacerata and P. brumalis. Extracelluar enzymes from S. hirsutum showed higher activity of ligninase and lower activity of cellulase than those from other white rot fungi. Thus, total weight loss and changes in chemical composition of the Japanese red pine was well correlated with the enzyme activities related with lignin- and cellulose degradation in these fungi. Based on the data obtained from analysis of physical characterization of degraded wood by X-ray Diffractometry (XRD) and pore size distribution, S. hirsutum was considered as an effective potential fungus for biological pretreatment. In particular, the increase of available pore size of over 120 nm in pretreated wood powder with S. hirsutum made enzymes accessible for further enzymatic saccharification. When Japanese red pine chips treated with S. hirsutum were enzymatically saccharified using commercial enzymes (Cellulclast 1.5 L and Novozyme 188), sugar yield was greatly increased (21.01 %) compared to non-pre treated control samples, indicating that white rot fungus S. hirsutum provides an effective process in increasing sugar yield from woody biomass.

Analysis of Anatomical Characteristics for Wood Species Identification of Commercial Plywood in Korea (국내 유통 합판의 수종식별을 위한 해부학적 특성 분석)

  • LEE, Hyun Mi;JEON, Woo Seok;LEE, Jei Wan
    • Journal of the Korean Wood Science and Technology
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    • v.49 no.6
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    • pp.574-590
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    • 2021
  • International efforts to prevent illegally logged wood are expanding around the world. The "Legal Wood Trade Promotion System" was enacted in Korea in 2019 to strengthen the legal import and distribution of commercial wood in Korea. Since then, this system has promoted and ensured that the imported wood and wood products are legal with respect to the country of origin, wood species, and harvested area. As verification methods, DNA analysis technology and anatomical analysis using a microscope are mainly used in conjunction. Therefore, in this study, wood species of plywood were identified by analyzing the anatomical characteristics of various wood products for the first time. Douglas fir (Pseudotsuga menziesii (Mirb.) Franco.) and larch (Larix kaempferi (Lamb.) Carriere) plywoods (7, 9 ply) were obtained from four companies that supply plywood in Korea. After cutting each company's plywood to a size of about 1 cm3, the layers from top to bottom were separated into single layers, and three sections were observed using an optical microscope. The results revealed that the plywood was composed of a mixture of softwood and hardwood wood species, pine wood species, poplar wood species, or a mixture of larch and pine wood species. Identification of wood species using microscopy is important and can enable the scientific analysis and verification of various wood products, including plywood, imported from countries where the likelihood of indiscriminate distribution of illegal wood and illegal logging is high.

An Isotopic Study of the Effects of Refining on Fiber

  • FRANCES L WALSH; SUJIT BANERJEE
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2006.06a
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    • pp.31-36
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    • 2006
  • Tritium has been used to directly measure the exchangeable hydrogen in bleached softwood kraft pulp. The hydrogen atoms associated with hydroxyl groups in pulp or with water contained in the pulp can dissociate and exchange with the hydrogen atoms in bulk water. Tritium is a radioactive isotope of hydrogen and behaves almost identically to it. The distribution of tritium between pulp and water ($k_{pw}$) can be easily measured and becomes an index of the protons available fur hydrogen bonding. Bleached kraft pulp was refined in a PFI mill to a range of freenesses. Tritiated water was added and the amount exchanged measured. There was a slight steady increase in $k_{pw}$ until approximately 300 CSF; $k_{pw}$ then rose sharply between 300 CSF and 100 CSF. This rise appears to correlate with FSP. It is likely that the action of refining on the fiber reaches a threshold at about 300 CSF causing the fiber surface to break open creating exponentially more surface area. This theory is visually confirmed through light microscopy. The slow increase in fibrillation of the fibers above 300 CSF correlates with the increase in $k_{pw}$. Beyond the threshold of 300 CSF a dramatic difference in fibrillation is shown, also corresponding with the large increase in $k_{pw}$. The freeness difference around 300 CSF is small, but the change in fiber properties is extreme within this region. This change in properties could lead to sheet breaks and other disruptions when producing products around the threshold. This study leads to a better understanding of how fiber changes during refining, resulting in a practical benefit of target freeness determination. Presently, freeness is selected based on product quality and on some measure of runnability. Yet, there are other considerations, demonstrated by the extreme change in fiber properties around 300 CSF.

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Anatomical Comparison of Compression, Opposite, and Lateral Woods in New Zealand Rimu (Dacrydium cupressinum Lamb.)

  • Eom, Young-Geun;Butterfield, Brian G.
    • Journal of the Korean Wood Science and Technology
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    • v.29 no.3
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    • pp.1-13
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    • 2001
  • Compression, lateral, and opposite woods in the stem and branch of rimu (Dacrydium cupressinum Lamb.), a softwood species indigenous to New Zealand, were described and compared in the anatomical aspects. Qualitatively, growth rings were wide in the compression wood, intermediate in the lateral wood, and narrow in the opposite wood. Tracheid transition from early wood to late wood was very gradual in the compression wood but was more abrupt in both the lateral and opposite woods. When viewed transversely, compression wood tracheids showed a roundish outline except at the growth ring boundary but lateral and opposite wood tracheids were angular to rectangular in outline. Intercellular spaces were occasionally detected in the compression wood except in the late wood at the growth ring boundary but were absent from both the lateral and opposite woods. Slit-like extensions of the bordered pit openings caused by the location of pit apertures within short and narrow helical grooves were observed in the compression wood tracheids but not in the opposite or lateral wood tracheids. In the compression wood tracheids, fine striations in the form of fine checks or grooves were observed on the lumen surfaces and the innermost $S_3$ layer of secondary wall was absent. In the tracheids of lateral and opposite woods, the $S_3$ layer was sometimes absent but occasionally highly developed. Cross-field pits in the compression wood appeared to be piceoid due to slit-like pit apertures but those in the lateral and opposite wood tracheids showed cupressoid to taxodioid. Quantitatively, compression wood tracheids were somewhat shorter than those of opposite or lateral wood in stem but not different from the opposite or lateral wood tracheids in branch. The walls were thicker in the compression wood than in the lateral or opposite wood. Uniseriate rays in the compression wood were fewer than in the lateral or opposite wood.

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Study on the check by static driving nail in softwood (정적(靜的) 못 박기에 의(依)한 침엽수재(針葉樹材)의 할열(割裂))

  • Shim, Sang-Ro;Kim, Su-Chang
    • Journal of the Korean Wood Science and Technology
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    • v.4 no.1
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    • pp.15-20
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    • 1976
  • This is the abstract of the study on the check by static driving nail in Pinus koraiensis Sieb. et Zucc., Abies holophylla Maximowicz, and Larix leptolepis Gordon Pinet. which are commercial woods and main forestation species in Korea. The static driving resistance of nail is decresed straightly and the surface and back check's length and width were increased in proportion to increase of the moisture content, but the surface check length and width were over twice as large as the back check, also the check were happened in order of Pinus koraiensis Sieb. et Zucc., Abies holophylla Maximowicz., and Larix leptolepis Gordon Pinet. As the driving nail speed was increased, surface check length and width were increased and the back check was over twice as large as the surface check.

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Effects of Molecular Weight of Polyethylene Glycol on the Dimensional Stabilization of Wood (Polyethylene Glycol의 분자량(分子量)이 목재(木材)의 치수 안정화(安定化)에 미치는 영향(影響))

  • Cheon, Cheol;Oh, Joung Soo
    • Journal of Korean Society of Forest Science
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    • v.71 no.1
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    • pp.14-21
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    • 1985
  • This study was carried out in order to prevent the devaluation of wood itself and wood products causing by anisotropy, hygroscopicity, shrinkage and swelling - properties that wood itself only have, in order to improve utility of wood, by emphasizing the natural beautiful figures of wood, to develop the dimensional stabilization techniques of wood with PEG that it is a cheap, non-toxic and the impregnation treatment is not difficult, on the effects of PEG molecular weights (200, 400, 600, 1000, 1500, 2000, 4000, 6000) and species (Pinus densiflora S. et Z., Larix leptolepis Gordon., Cryptomeria japonica D. Don., Cornus controversa Hemsl., Quercus variabilis Blume., Prunus sargentii Rehder.). The results were as follows; 1) PEG loading showed the maximum value (137.22%, Pinus densiflora, in PEG 400), the others showed that relatively slow decrease. The lower specific gravity, the more polymer loading. 2) Bulking coefficient didn't particularly show the correlation with specific gravity, for the most part, indicated the maximum values in PEG 600, except that the bulking coefficient of Quercus variabilis distributed between the range of 12-18% in PEG 400-2000. In general, the bulking coefficient of hardwood was higher than that of softwood. 3) Although there was more or less an exception according to species, volumetric swelling reduction was the greatest in PEG 400. That is, its value of Cryptomeria japonica was the greatest value with 95.0%, the others indicated more than 80% except for Prunus sargentii, while volumetric swelling reduction was decreased less than 70% as the molecular weight increase more than 1000. 4) The relative effectiveness of hardwood with high specific gravity was outstandingly higher than softwood. In general, the relative effectiveness of low molecular weight PEG was superior to those of high molecular weight PEG except that Quercus variabilis showed more than 1.6 to the total molecular weight range, while it was no significant difference as the molecular weight increase more than 4000. 5) According to the analysis of the results mentioned above, the dimensional stabilization of hardwood was more effective than softwood. Although volumetric swelling reduction was the greatest at a molecular weight of 400. In the view of polymer loading, bulking coefficiency reduction of swelling and relative effectiveness, it is desirable to use the mixture of PEG of molecular weight in the range of 200-1500. To practical use, it is recommended to study about the effects on the mixed ratio on the bulking coefficient, reduction of swelling and relative effectiveness.

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Characterization of Bio-oils Produced by Fluidized Bed Type Fast Pyrolysis of Woody Biomass (목질바이오매스의 급속열분해에 의해 생성된 바이오오일의 특성 분석)

  • Choi, Joon-Weon;Choi, Don-Ha;Cho, Tae-Su;Meier, Dietrich
    • Journal of the Korean Wood Science and Technology
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    • v.34 no.6
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    • pp.36-43
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    • 2006
  • Using fluidized bed type fast pyrolysis system (capacity 400 g/h) bio-oils were produced from beech (Fagus sylvatica) and softwood mixture (spruce and larch, 50:50). The pyrolysis was performed for 1~2 s at the temperature of $470{\pm}5^{\circ}C$. Pyrolysis products consisted of liquid form of bio-oil, char and gases. In beech wood bio-oil was formed to ca. 60% based on dry biomass weight and the yield of bio-oil was 49% in soft wood mixture. The moisture contents in both bio-oils were ranged between 17% and 22% and the bio-oil's density was measured to $1.2kg/{\ell}$. Bio-oils were composed of 45% carbon, 47% oxygen, 7% hydrogen and lower than 1% nitrogen,which was very similar to those of original biomass. In comparison with oils from fossil resources, oxygen content was very high in bio-oils, while no sulfur was found. More than 90 low molecular weight components, classified to aromatic and non aromatic compounds, were identified in bio-oils by gas chromatographic analysis, which amounted to 31~33% based on the dry weight of bio-oils.

Analysis of Allowable Stresses of Machine Graded Lumber in Korea (국내 기계등급구조재의 허용응력 분석)

  • Hong, Jung-Pyo;Oh, Jung-Kwon;Park, Joo-Saeng;Han, Yeon Jung;Pang, Sung-Jun;Kim, Chul-Ki;Lee, Jun-Jae
    • Journal of the Korean Wood Science and Technology
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    • v.43 no.4
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    • pp.456-462
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    • 2015
  • 365 pieces of domestic $38{\times}140{\times}3600mm$ Red pine structural lumber were machine graded conforming to a softwood structural lumber standard (KS F 3020). The allowable bending stresses calculated for each grade were compared with the values currently tabulated in the standard. Four calculation methods for lower $5^{th}$ percentile bending stress were non-parametric estimation with 75% confidence level, 2-parameter and 3-parameter Weibull distribution fit, and bending modulus of rupture (MOR)-modulus of elasticity (MOE) regression based method. Only the data set of Grades E8, E9, and E10 were statistically eligible for the $5^{th}$ percentile calculation. The MOR-MOE regression based method only was able to estimate the lower $5^{th}$ percentile values theoretically for the full range of grades. The results showed that all allowable bending stresses calculated were lower than the design values tabulated in the standard. This implies that the current machine grading system has the pitfall of structural safety. Improvement in current machine grading system could be achieved by introducing the bending strength and stiffness combination grade system.

Development of Structural Glued Laminated Timber with Domestic Cedar (국산 삼나무를 이용한 구조용 집성재 이용기술)

  • Kim, Kwang-Mo;Shim, Sang-Ro;Shim, Kug-Bo;Park, Joo-Saeng;Kim, Wun-Sub;Kim, Byoung-Nam;Yeo, Hwanmyeong
    • Journal of the Korean Wood Science and Technology
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    • v.37 no.3
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    • pp.184-191
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    • 2009
  • In the southern part of the Korean Peninsula including Jeju-island, the production amount of domestic cedar has increased gradually. However, their low qualities, expected to be caused by the low density and frequent knots, have restricted their practical utilization as the high value-added products. In this study, it is aimed to look for the new uses of domestic cedar and to examine the applicability for lamination lumbers of structural glued laminated timber (glulam). Above all, machine stress ratings for individual sawn lumbers confirmed that modulus of elasticity (MOE) of cedar lumber was lower than that of other common softwood species in Korea. On the other hand, cedar lumbers have enough stiffness to manufacture the structural glulam in accordance with Korean Industrial Standard (KS). The bonding strength and durability also met the KS limitation. Nevertheless, from the result of bending tests for cedar glulam, it was shown that the modulus of elasticity (MOE) did not meet the KS limitation. Therefore, it was concluded that additional researches were needed for reinforcing the stiffness of cedar glulam.