• Title/Summary/Keyword: sodium tartrate

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Effects of Complex Agents and pH on the Deposition Behavior of Electroless Ni-Co-P Film (착화제와 pH가 무전해 Ni-Co-P 도금 피막의 석출거동에 미치는 영향)

  • Choi, Byuck-Keun;Yang, Seung-Gi;Shin, Ji-Wung;Hwang, Woon-Suk
    • Corrosion Science and Technology
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    • v.13 no.3
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    • pp.107-111
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    • 2014
  • Electroless plated Ni-Co-P films have been used to suppress the electromagnetic waves from magnetic recording media, and the suppression is known to be achieved with films made with optimized plating composition and plating condition. Effects of complexing agents on the deposition rate and bath stability of Ni-Co-P film were studied using sodium citrate, sodium tartrate and multi-complex agents containing both of them. Deposition of electroless Ni-Co-P platings was dependent upon the complexing agents. Deposition rate was twice when using sodium tartrate compared to that using sodium citrate. And it was slightly slower with multi-complex agents than with sodium tartrate, bath stability being declined in the former. Deposition rate increased with increasing pH until pH 11. Excellent bath stability and good deposition rate were obtained using multi-complex agent as sodium citrate 0.10 mol/L and sodium tartrate 0.15 mol/L in the electroless Ni-Co-P plating films.

Effect of Salts on the Formation of $\alpha$-Calcium Sulfate Hemihydrate from by-Product Gypsum of Phosphoric Acid Process under Water Vapor at Atmospheric Pressure (상압 수증기중에서 인산 석고로부터 $\alpha$형 반수석고의 생성에 미치는 염류의 영향)

  • 이구종;최상흘
    • Journal of the Korean Ceramic Society
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    • v.25 no.3
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    • pp.300-306
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    • 1988
  • The catalytic effect of salts on formation of ${\alpha}$-calcium sulfate hemihydrate under water vapor at atmospheric pressure was studied and the formation of q-calcium sulfate hemilydrate from by-product gypsum of phosphoric acid process was investigated. The order of catalytic effect of salts are as follow: Ammonium chloride>Sodium succinate>Calcium chloride>Sodium tartrate>Magnesium chloride The prismatic crystals was formed when ammonium chloride, calcium chloride and magnesium chloride was added, whereas the needle crystals was formed when sodium tartrate was added. Ammonium chlorideis most successful in catalytic effects in formation of ${\alpha}$-calcium sulfate hermihydrate for the by-product gypsum of phosphoric acid process.

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Transport Characteristics and Screening of Penetration Enhancer through Buccal Mucosa of Butorphanol Tartrate from [P(AA-co-PEGMM)] Copolymer Films ([P(AA-co-PEGMM)] 공중합체 필름으로부터 Butorphanol Tartrate의 구강점막 투과 특성 및 투과촉진제의 검색)

  • Kim, Joun-Sik;Park, Jeong-Sook;Jeong, Yeon-Bok;Han, Kun
    • Journal of Pharmaceutical Investigation
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    • v.33 no.3
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    • pp.157-162
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    • 2003
  • The feasibility of [P(AA-co-PEGMM)] film as a buccal mucoadhesive patch was previously reported by estimating mucoadhesiveness and release characteristics. To find a rational penetration enhancer of [P(AA-co-PEGMM)] film containing butorphanol tartrate (Bt), penetration of Bt from [P(AA-co-PEGMM)] film which contained various additives was estimated by measuring its flux, Papp and lag tme in in vitro buccal membrane of porcine. EDTA showed almost no increase of Bt permeability, wherease SGC, STDHF and SLS increased the permeability of Bt with the order of SGC > STDHF > SLS. The rational additive concentration of SGC was 4% and its Papp and lag time were $1.93{\times}10^{-4}{\pm}4.21{\times}10^{-6},\;126.60{\pm}21.88min\;(control\;:\;Papp\;0.45{\times}10^{-4};\;lag\;time\;211.01{\pm}16.77\;min)$, respectively.

Decolorization of Poly R-478 Dye by Coriolus versicolor IFO 30388 (구름버섯(Coriolus versicolor IFO 30388)에 의한 Poly R-478 염료의 탈색)

  • Yoon, Kyung-Ha
    • Korean Journal of Microbiology
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    • v.32 no.3
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    • pp.182-185
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    • 1994
  • Effects of nitrogen and carbon sources on the decolorization rate of poly R-478 dye by a white rot basidiomycete Coriorus versicolor IFO 30388 were examined. The fungus exhibited 87.2% of decolorization rate when it was cultured in the state of stationary in a nitrogen-limited medium (pH 4.5) which contained 2.0% glucose, 0.04% ammonium tartrate, 0.02% poly R-478 dye, 2% $KH_2PO_4$, 0.5% $MgSO_4{\cdot}7H_2O$, 0.1% $CaCl_2{\cdot}2H_2O$, 0.002% thiamine-HCl and 10 mM 2,2 dimethylsuccinate (sodium) at $28^{\circ}C$ for 10 days. Decolorization of the dye occurred in the presence of nitrogen source in the medium and decolorization rate increased rapidly after depletion of $NH_4^+$ from the medium.

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Effects of Salts on the Formation of $\alpha$-Calcium Sulfate Hemihydrated from by-Product Gypsum of Phosphoric Acid Process at Hydrothermal Condition (가압수열 수용액중에서 인산석고로부터 $\alpha$형 반수석고의 생성에 미치는 염류의 영향)

  • 이구종;최상흘
    • Journal of the Korean Ceramic Society
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    • v.24 no.4
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    • pp.343-348
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    • 1987
  • The effects of salts such as aluminum sulfate as inorganic salt(2-4%), and sodium salts of citrate, tartrate, succinate, potassium tartrate and gelatin as organic salts(0.1%) on the formation of ${\alpha}$-calcium sulfate hemihydrate from by-product gypsum of phosphoric acid process under hydrothermal condition at 123$^{\circ}C$ and 133$^{\circ}C$ were investigated. Aluminum sulfate solution exhibited the catalystic effected on the crystallization of ${\alpha}$-calcium sulfate hemihydrate of which was assumed in the prismatic form, and organic salts solution exhibited little effect on the catalystic action to the crystallization, than inorganic salts. In the acidic solution with sulfuric acid(pH=2), needle like crystal of calcium sulfate hemihydrate was obtained. Hydrothermal process with aluminum sulfate solution also showed certain amounts of impurity removal such as phosphorus penataoxide from calcium sulfate hemihydrate.

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Establishment of Dyeing Data for Silk Fabrics and Cells Using Diospyros kaki Thunb (감나무 열매를 이용한 실크 및 세포에 대한 염색 데이터 확립)

  • Suk-Yul Jung
    • Journal of Internet of Things and Convergence
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    • v.9 no.3
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    • pp.27-33
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    • 2023
  • In this study, it was analyzed with the dyeing pattern of Diospyros kaki Thunb (persimmon) and was tried to numerically evaluate how the dyeing pattern in silk fabrics and cells was changed by different mordants. When the dyed silk fabrics were sufficiently dried, the silk fabrics were found to have a pale yellow color. Interestingly, iron II sulfate mordant changed the color change the most, silk fabrics were dyed with a color close to brown or dark purple. For numerical analysis, 19% and 62.5% color changes could be induced by sodium tartrate plus citric acid and copper acetate, respectively. Iron II sulfate induced the greatest difference than that of untreated mordants at 88%. About 5% and 10% of Chinese hamster ovary (CHO) cells were stained by sodium tartrate plus citric acid and copper acetate, respectively. The staining effect induced by iron II sulfate was about 2.4 times higher than the staining effect by sodium tartrate plus citric acid. In previous studies, staining results have been visually confirmed. However, this results not only visually confirmed the dyeing, but also quantified the color change. In particular, if numerical results are continuously integrated into big data, any researcher will be able to easily obtain similar results even if the method, time, volume, etc. are changed. In addition, the numerical data of this study is considered to be an important basis for building a database for IoT construction and computer analysis.

Swelling and Shrinking Behavior of Lyocell Fibers

  • Donkai, Nobuo;Sasaki, Hiroari;Kasahara, Katsuji
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10a
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    • pp.17-18
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    • 2003
  • Swelling behaviors of Lyocell and Polynosic fibers are investigated by measuring fiber sizes in ferric sodium tartrate complex (FeTNa) and NaOH solution. They showed an anisotropic swelling behavior, i.e., a large expansion in a radius and small shrinking in a longitudinal direction. Birefringent structure was maintained in Lyocell fibers in the swollen state but not in Polynosic fibers for both solvent systems.

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The Study on the Separation of the Subsidiary Elements in Iron and Steel by Using Ion Exchangers (I). The Separation of Cations (이온교환수지에 의한 철 및 강의 분석에 관한 연구 (제1보) 양이온 성분의 분리)

  • Lee, Byoung-Cho;Park, Myon-Yong;Park, Kee-Chae
    • Journal of the Korean Chemical Society
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    • v.17 no.5
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    • pp.346-352
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    • 1973
  • The quantitative separations of a mixture containing equal amounts of each cation such as Mn(Ⅱ), Cr(Ⅲ), V(Ⅴ), Cu(Ⅱ), Ni(Ⅱ), Co(Ⅱ), and Fe(Ⅲ) are carried out by the elution through $35cm{\times}3.14cm^2$ column of cation exchange resin, $Dowex 50w{\times}12$. The eluents are a mixture of 0.6 M sodium chloride and 0.1 M sodium tartrate (pH = 2.00 and 4.50) for Fe(Ⅲ), V(Ⅴ), Cu(Ⅱ), Ni(Ⅱ) and Co(Ⅱ), and a mixture of 3 M sodium chloride and 0.1 M sodium tartrate (pH = 4.50) or a mixture of 0.7 M sodium chloride and 0.5 M sodium oxalate (pH = 4.50 and 5.00) for Mn(Ⅱ) and Cr(Ⅲ). The subsidiary cations in a standard iron mixture such as V(Ⅴ), Cu(Ⅱ), Ni(Ⅱ), Mn(Ⅱ) and Cr(Ⅲ) are separated together from the large amount of Fe(Ⅲ) through $15cm{\times}3.14cm^2$ column of the resin, $Dowex 1{\times}8$, by elution with the eluent of 4.0 M hydrochloric acid. A small amount of Fe(Ⅲ), however, is eluted together with Cu(Ⅱ). V(Ⅴ), Ni(Ⅱ), Mn(Ⅱ) and Cr(Ⅲ) eluted together are separated quantitatively through $10cm{\times}3.14cm^2$ column of the resin,$Dowex 50w{\times}12$. Cu (Ⅱ) and a small amount of Fe(Ⅲ) are separated quantitatively through $10cm{\times}3.14cm^2$ column of the resin, $Dowex 50w{\times}12$, by the elution with a mixture of 0.6 M sodium chloride and 0.1 M sodium tartrate (pH = 2.00 and 4.50) as an eluent. By the conditions obtained in the separations of the standard iron mixture, Fe(Ⅲ) and all of the subsidiary cations in steel are quantitatively separated.

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Effects of Salts on the Hydration of $\alpha$-Calcium Sulfate Hemihydrate ($\alpha$형 반수석고의 수화에 미치는 염류의 영향)

  • 최상흘;이구종;홍성윤;이석곤
    • Journal of the Korean Ceramic Society
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    • v.25 no.5
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    • pp.449-454
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    • 1988
  • The effects of salts which was used as a catalysis in formation of $\alpha$-calciumusulfate hemihydrate from dicalcium sulfate hydrate were investigated on the hydration of $\alpha$-calciumsulfate hemihydrate. The hydration of $\alpha$-calciumsulfate hemihydrate was studied by the measurements of crystalline water, heat evolution. Also the hydrates were analyzed by XRD, DSC and SEM. The promotive effect each salts on the hydration was as follows: NaCl>NH4Cl>NaNO3>NH4NO3, and the hydration rate was accelerated with concentration of salts. The effect of Al2(SO4)3 and potassium sodium tartrate on the hydration was slmilar to water, whereas sodium succinate and gelatin retarded the hydration in comparision with water. These salts affected the hydration time but total heat evoution was similar.

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Determination of Chromium(VI) by Differential-Pulse Polarography with a Sodium Borate Supporting Electrolyte

  • Hong, Tae-kee;Czae, Myung-Zoon
    • Bulletin of the Korean Chemical Society
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    • v.9 no.2
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    • pp.77-80
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    • 1988
  • A suituable choice of supporting electrolyte medium for trace level determinations of chromium(VI) by differential pulse polarography is described. A comparative study suggests that sodium borate buffer is superior to ammonium acetate, ammonium tartrate, and especially to NaF which was recently known to be one of the most proper medium for the purpose. With 0.01 M borate, the best combination of high sensitivity, well-defined base line, and freedom from common interferents was attained. With $5.0{\times}10^{-7}$M Cr(VI), tenfold excesses of Cu(II) and Fe(III), and a five hundred-fold excess of $Cl^-$ do not change the peak current by more than about 1%. And the detection limit was $5.0{\times}10^{-8}$M Cr(VI).