• 제목/요약/키워드: soda process

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De-soda Process Using Silica for Fabrication of Low Soda Alumina Powder

  • Park, Sang-Chun;Kim, Dae-Woong;Heo, In-Woong;Lee, Sang-Jin
    • Journal of the Korean Ceramic Society
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    • v.52 no.3
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    • pp.192-196
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    • 2015
  • Low soda alumina powder was fabricated using silica (${\alpha}$-quartz) as an agent for removing soda components in the alumina. Quartz powder 2 mm in size was added to aluminum hydroxide obtained through the Bayer process, and then the mixture was heated at various temperatures. Finally, the heat-treated powders were sieved for classification. In this study, the effects of the quartz amount and heating temperature on the mechanism of removing soda were examined. A minimum soda content of 0.005 wt% was observed at the conditions of 15 wt% quartz (based on $Al(OH)_3$ amount) heat-treated at $1600^{\circ}C$ for 8 h. The soda components, such as $Na_2O$, NaOH, and $Na_2CO_3$, in alumina were ionized and activated at high temperature, and this facilitated the reaction with quartz silica and alumina producing nepheline. The advantages of using quartz include low iron content and low cost in comparison with the conventional de-soda process using chamotte, another silicate mineral.

Ion Exchange Behavior of Soda-Lime-Silicate Glass by Advanced Ion Exchange Process (새로운 이온교환 프로세스에 의한 Soda-Lime-Silicate 유리의 이온교환 거동)

  • 이회관;황성건;이용수;강원호
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.5 no.2
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    • pp.98-102
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    • 2004
  • Ion exchange behavior and property change of soda-lime-silicate glass by advanced ion exchange process were investigated. Refractive index, specific gravity and optical transmittance were changed similarly to $K^+$ ion penetration depth, and amount of ion exchange increased with the increase of the time and temperature. Especially, thermal expansion decreased greatly because of the structural compaction and residual stress by ion exchange process.

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Chemical Strengthening Involving Outward Diffusion Process of Na+ Ion in Iron-containing Soda-lime Silicate Glass

  • Choi, Hyun-Bin;Kang, Eun-Tae
    • Journal of the Korean Ceramic Society
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    • v.52 no.2
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    • pp.133-136
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    • 2015
  • The outward diffusion of $Na^+$ ions in iron-bearing soda lime silicate glass via oxidation heat treatment before the ion exchange process is artificially induced in order to increase the amount of ions exchanged during the ion exchange process. The effect of the addition process is analyzed through measuring the bending strength, the weight change, and the inter-diffusion coefficient after the ion exchange process. The glass strength is increased when the outward diffusion of $Na^+$ ions via oxidation heat treatment before the ion exchange process is added. For the glass subjected to the additional process, the weight change and diffusion depth increase compared with the glass not subjected to the process. The interdiffusion coefficient is also slightly increased as a result of the additional process.

Chemical Treatment of Low-level Radioactive Liquid Waste (I)

  • Lee, Sang-Hoon;Choe, Jong-In;Kim, Yong-Eak
    • Nuclear Engineering and Technology
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    • v.8 no.2
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    • pp.69-76
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    • 1976
  • This experiment has been carried out for the removal of long-lived radioactive-nuclides (Sr-90, Ru-106, Cs-137 and Ce-144) contained in the low-level radioactive effluents from the spent fuel reprocessing plant and nuclear power plant, in order to determine the decontaminability of various chemical coagulants and domestic clay mineral (montmorillonite). Phosphate process showed prominent efficiency for the removal of Ce-144, and lime-soda process did good removal efficiency for Sr-90. About Cs-137 copper-ferrocyanide process is much desirable. In phosphate or lime-soda process, most favorable removal efficiency was obtained at more than pH 11. The montmorillonite treated with sodium chloride showed a considerable improvement in the removal of the radioactive-nuclides. By a combined chemicals-montmorillionite process, the radioactive-nuclides could be more effectively removed than by the only chemicals process.

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Elucidating soda and soda-anthraquinone pulping characteristics of Korean bamboo species (국내산 주요 죽종의 소다 및 소다-안트라퀴논 펄핑 특성 비교)

  • Lee, Kyu-Seong;Song, Woo-Yong;Shin, Soo-Jeong
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.48 no.3
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    • pp.44-50
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    • 2016
  • As a raw material for pulp and paper industry, Moso bamboo, Timber bamboo and Henon bamboo pulps were prepared by soda or soda-anthraquinone(Soda-AQ) pulping process. Soda-AQ pulp yields was higher in Henon bamboo (43.2%) than in Moso bamboo or Timber bamboo (32.7-39.2%), but quite lower than hardwood species. In Kappa number comparison, Henon bamboo pulp showed lower (16.6) with 50 min cooking to $170^{\circ}C$ than that of Moso bamboo (22.8) and Timber bamboo (18.9) with 90 min cooking to $170^{\circ}C$. Fiber length of Timber bamboo soda pulp had higher (1.46 mm) than that of Moso bamboo or Henon bamboo (1.18-1.36 mm). All three bamboo pulps showed longer average fiber length than commercial hardwood pulp. With higher pulp yield and lower Kappa number, Henon bamboo is better raw material for pulp than Moso bamboo and Timber bamboo.

Optimization of Process Variables for the Soda Pulping of Carpolobia Lutea (Polygalaceae) G. Don

  • Ogunsile, B.O.;Uba, F.I.
    • Journal of the Korean Chemical Society
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    • v.56 no.2
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    • pp.257-263
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    • 2012
  • The selection of suitable delignification conditions and optimization of process variables is crucial to the successful operation of chemical pulping processes. Soda pulping of Carpolobia lutea was investigated, as an alternative raw material for pulp and paper production. The process was optimized under the influence of three operational variables, namely, temperature, time and concentration of cooking liquor. Equations derived using a second - order polynomial design predicted the pulp yield and lignin dissolution with errors less than 8% and 11% respectively. The maximum variations in the pulp yield using a second order factorial design was caused by changes in both time and alkali concentration. Optimum pulp yield of 43.87% was obtained at low values of the process variables. The selectivity of lignin dissolution was independent of the working conditions, allowing quantitative estimations to be established between the pulp yield and residual lignin content within the range studied.

Evaluation of Deodorization Capabilities, Morphologies, and Thermal Stabilities of Baking Soda, Charcoal, Coffee, and Green Tea for Kimchi Packaging Application

  • Jeong, Suyeon;Yoo, Seung Ran
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.26 no.1
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    • pp.1-9
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    • 2020
  • We evaluated the applicability of baking soda, charco'al, coffee, and green tea as a natural deodorant in Kimchi packaging. Moreover, to evaluate the potential usage of these deodorants in packaging materials and confirm their applicability in high-temperature melt-extrusion processing, the thermal stabilities of the deodorants were investigated, and heat-treated deodorants were evaluated in terms of the deodorizing function compared with non-treated deodorants. Aroma patterns were decreased after deodorizing treatment with all-natural deodorants. Dimethyl disulfide, methyl trisulfide, and diallyl disulfide, the most significant odorous Volatile organic compounds (VOCs) of Kimchi, decreased after treatment with the deodorants. In particular, baking soda and charcoal showed the highest efficiency in removing odorous compounds and VOCs from Kimchi, even after high-temperature processing. The acetic acid removal rates for both baking soda and charcoal were 99.9±0.0%. The heating process increases the deodorizing effects of baking soda. Sensory evaluation results showed that there is a significant increase (p < 0.05) in the overall preference for Kimchi samples packaged with charcoal and baking soda. This study provides useful information for the deodorization effects of natural deodorants for Kimchi smell and their applicability for packaging materials.

Leaching of Vanadium and Tungsten from Spent SCR Catalysts for De-NOx by Soda Roasting and Water Leaching Method (소다배소(焙燒) 및 수침출법(水浸出法)에 의한 탈질용(脫窒用) 폐(廢) SCR 촉매(觸媒)로부터 바나듐과 텅스텐 침출(浸出))

  • Kim, Hye-Rim;Lee, Jin-Young;Kim, Joon-Soo
    • Resources Recycling
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    • v.21 no.6
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    • pp.65-73
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    • 2012
  • Selective catalytic reduction(SCR) catalysts are obtained from de-NOx system of thermoelectric power plant. A process was developed for valuable metals such as vanadium and tungsten recovery from spent SCR catalyst by using soda roasting followed by water leaching. Spent SCR catalyst having $V_2O_5$(1.23 mass %) and $WO_3$(7.73 mass %). For getting soluble metal forms of the targeted metals like vanadium and tungsten soda roasting process was implemented. In soda roasting process, sodium carbonate added 5 equivalent ratio at roasted temperature $850^{\circ}C$ with 120 min roasted time for $544{\mu}m$ particle size of spent SCR catalyst. After soda roasting process moved to water leaching for roasted spent catalyst. Before leaching process the roasted spent catalyst was grinded up to $-45{\mu}m$ size. The leaching time is 30 min at $40^{\circ}C$ temperature, 10 % pulp density. The final leaching efficiency obtained 46 % of vanadium and 92 % of tungsten from present process.

Soda Pulp Properties from Corn Stalk as Raw Material (옥수수 줄기를 원료로 제조한 소다 펄프의 특성)

  • Song, Woo-Yong;Lee, Kyu-seong;Lee, Jai-Sung;Shin, Soo-Jeong
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.47 no.6
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    • pp.73-80
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    • 2015
  • Corn stalk is the lignocellulosic biomass, which remain as leftover after harvesting. To use the corn stalk as raw material for paper industry, soda pulping was applied. In chemical compositional analysis, extractive contents of corn stalk (45.1%) was higher than hardwood. With corn stalk pith, soda pulp yield was 25.3% at 10.6 Kappa number, but 39.5% yield with 14.8 Kappa number for corn stalk rind. Higher extractives content in pith is one of the reason for lower pulp yield than rind. Pith pulp fibers had higher fines content than rind pulp. Pith parenchyma cell was removed as fines during pulping or washing process, which caused the lower yield. To use the corn stalks as a raw material for paper making, de-pith process is essential for higher pulp yield and longer pulp length.

DC Sputtering Process of 2-Dimensional Tungsten Disulfide Thin Films on Soda-Lime Glass Substrates (DC 스퍼터링을 이용한 소다라임 유리 기판상에 2차원 황화텅스텐 박막 형성 공정)

  • Ma, Sang Min;Kwon, Sang Jik;Cho, Eou Sik
    • Journal of the Semiconductor & Display Technology
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    • v.17 no.3
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    • pp.31-35
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    • 2018
  • Tungsten disulfide($WS_2$) thin films were directly deposited by direct-current(DC) sputtering and annealed by rapid thermal processing(RTP) to materialize two-dimensional p-type transition metal dichalcogenide (TMDC) thin films on soda-lime glass substrates without any complicated exfoliation/transfer process. $WS_2$ thin films deposited at various DC sputtering powers from 80 W to 160W were annealed at different temperatures from $400^{\circ}C$ to $550^{\circ}C$ considering the melting temperature of soda-lime glass. The optical microscope results showed the stable surface morphologies of the $WS_2$ thin films without any defects. The X-ray photoelectron spectroscopy (XPS) results and the Hall measurement results showed stable binding energies of W and S and high carrier mobilities of $WS_2$ thin films.