• Journal of Korean Society for Atmospheric Environment
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• v.16 no.4
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• pp.299-308
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• 2000

This study analyzed solid wastes generated from a school. The emission potential of hazardous pollutants generated from incineration of the school solid wastes (SSWs) was analyzed. Components of the SSWs were identified and the SSWs were classified into combustible and non-combustible wasts. The combustible wastes consisted of papers of 56.5^ plastics of 30.2% woods of 7.1% and fibers of 6.1% based on weight of the wastes. The moisture content and the ash content of the combustible wastes were 18~20% and 11~13% respectively. The combustible wastes of the SSWs were incinerated by using a small-scale incinerator. Fly and bottom ashes and volatile organic compounds (VOCs) were collected from the incineration. Also the metal leaching experiments on the fly and bottom ashes were performed, In analysis of metals leached from the ashes the total amounts of metals leached in the acid solution (pH=3) were much greater than those in the neutral solution (pH=5.8~6.2) For the same amounts of the fly and bottom ashes the total amounts of metals leached from the fly ashes were much greater than those from the bottom ashes. The VOCs produced from incineration of the SSWs consisted of aromatics of 42.1% aliphatic alkenes of 26.3% oxidized forms of 17.3% and aliphatic alkanes of 14.3% In addition the considerable amounts of hazardous air pollutants (e.g benzene chloro-benzene and chloro-alkanes) and compounds (e. g, aliphatic alkenes) with high potential of ozone or photochemical smog formation were identified from the incineration experiment of the SSWs.

• Environmental Engineering Research
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• v.12 no.2
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• pp.46-54
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• 2007

Concentrations of the principal volatile organic compounds, such as benzene, toluene, ethylbenzene, m,p,o-xylene, styrene, and chlorobenzene were measured at the solid waste treatment plants classified into four categories; municipal waste incinerator, municipal waste landfill site, industrial waste incinerator and industrial waste landfill site. The average concentration of VOCs in industrial waste treatment facilities was 33.43 ppb and was significantly higher than that measured at municipal waste treatment facilities (4.71 ppb). The average toluene concentrations measured at incinerators (13.05 ppb) were a little higher than those measured at landfill sites (11.54 ppb). The contribution of the waste treatment facilities to the concentration of benzene (0.35 ppb) and o-xylene (0.15 ppb) in the industrial area was relatively small. However, toluene measured in the industrial waste treatment facilities was the most abundant VOCs with the average concentration of 21.37 ppb. As a result of analyses of fingerprint, in cases of IISH and ILUS, a variety of compounds other than major VOCs were detected in high level. On the Pearson correlation analysis, the correlation was generally positive and some pairs of these VOCs were very strongly correlated (correlation coefficient > 0.75).

• Journal of Electrical Engineering and Technology
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• v.9 no.1
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• pp.239-246
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• 2014

Incineration is conceptually sound as a waste treatment technology. There is, however, concern over its emissions when it is improperly designed and operated. An electrostatic precipitator is one of the most commonly used devices to control particulate emissions from boilers, incinerators and some other industrial processes. In this work, a modular electrostatic precipitator with sizing of $1m{\times}1m{\times}1m$ was developed for removal of particulate matter from the exhaust gases of a small waste incinerator. Its design was based on a simple wire-and-plate concept. The corona discharge wires were connected to a positive high-voltage pulse generator, while the collection plates were grounded. The high-voltage pulse generator was used to produce the corona discharge field between the individual discharge wire and the collection plate. The particulate-laden exhaust gas flow was directed across the corona discharge field. The charged particles were deflected outward and collected on the plate. The collection efficiency was evaluated as a mass loading ratio between the difference at the inlet and the outlet to the particulate loading at the inlet of the precipitator. The collection efficiency of this modular electrostatic precipitator design was approximately 80 %.

• Transactions of the Korean Society of Mechanical Engineers
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• v.18 no.8
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• pp.2184-2193
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• 1994

A flow visualization experiment using water-table models was performed. The water-table models simulated the two-dimensional cold flow fields inside the combustion chambers of incinerators. The flow were visualized by small but neutrally bouyant particles photographed by an overhead camera. The experimentally simulated flow fields apparently showed distinct features of two combustion chamber shapes; counter and parallel flow types. The significance of the secondary air injection on the mixing of combustion gases were clearly observed. The effects of the recirculation zones, which were present in the secondary chamber, were discussed by considering the importance of them for optimal combustion.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.19 no.1
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• pp.51-59
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• 2007

The waste bunker usually consists of waste entrance zone and waste pit. In this paper, the distributions of air flow, $NH_3$ concentration and $H_2S$ concentration in a waste bunker were investigated to prevent an odor generated in a waste pit from dispersing to the waste entrance zone by numerical method. Four cases were considered such that 1) the waste incinerators is operated, 2) the waste incinerators is stopped, 3) the waste incinerator is operated and the direction of a supply diffuser is $45^{\circ}$ upward, 4) the waste incinerator is stopped and the direction of a supply diffuser is $45^{\circ}$ upward. In case of 1), the fresh air from the waste entrance zone is exhausted smoothly to the main exhaust grill of the waste pit. It means that an odor dispersion to the waste entrance zone will not occur. However in case of 2), the induction of fresh air is so small and the supply air with an odor in waste pit can flow to the waste entrance zone. Therefore, an odor will be dispersed to the waste entrance zone. This paper shows the solution that the supply diffuser with the direction of $45^{\circ}$ upward is chosen. As a result in case of 3) and 4), an odor dispersion to the waste entrance zone does not occurred and on odor is exhausted smoothly to the auxiliary exhaust grill.

• Journal of Korean Society of Environmental Engineers
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• v.27 no.11
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• pp.1205-1214
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• 2005

This study was carried out to investigate the emission characteristics of volatile metals(Hg, As, Se) and semi volatile metals such as Pb from small and medium size municipal solid waste incinerators(MSWIs). The concentrations of Hg, Pb, As and Se in emission gas from small size waste incinerators were higher than those of medium size waste incinerators. This is probably due to less air pollutant control devices and high emission gas temperature of the small size waste incinerators relative to the medium size waste incinerators. Emission gas temperature from small and medium size waste incinerators were divided into 2 groups. The first group was about $100^{\circ}C$ and the second roup in the range of $400{\sim}700^{\circ}C$. The concentrations of emission gas at the second group were Hg $70.43\;{\mu}g/Sm^3$, Pb $0.94\;{\mu}g/Sm^3$, As $9.83\;{\mu}g/Sm^3$ and Se $5.05\;{\mu}g/Sm^3$. The concentrations of Hg, Pb, As and Se at the first group were lower than those found at the second group. Besides, the removal efficiencies of Hg in medium size waste incinerators were $55.2{\sim}95.9%$. Emission gas temperature reduction from waste heat boiler(WHB) contribute to control of Hg. Based on above results, we postulate that the temperature of flue gas should play a very important role in volatile metal control in small and medium size MSWIs. In order to improve the volatile metals removal efficiency, the temperature of cooling system must be controlled and the air pollution control device should be operated properly.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.21 no.2
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• pp.264-274
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• 1997

A numerical analysis on condensation and coagulation of the metallic species with fly ash particles pre-existing in an incinerator was performed. Waste was simplified as a mixture of methane, chlorine, and small amounts of Pb and Sn. Vapor-phase amounts of Pb- and Sn -compounds were first calculated assuming a thermodynamic equilibrium state. Then theories on vapor-to-particle conversion, vapor condensation onto the fly ash particles, and particle-particle interaction were examined and incorporated into equations of aerosol dynamics and vapor continuity. It was assumed that the particles followed a log-normal size distribution and thus a moment model was developed in order to predict the particle concentration and the particle size distribution simultaneously. Distributions of metallic vapor concentration (or vapor pressure) were also obtained. Temperature drop rate of combustion gas, fly ash concentration and its size were selected as parameters influencing the discharged amount of metallic species. In general, the coagulation between the newly formed metal particles and the fly ash particles was much greater than that between the metal particles themselves or between the fly ash particles themselves. It was also found that the amount of metallic species discharged into the atmosphere was increased due to coagulation. While most of PbO vapors produced from the combustion were eliminated due to combined effect of condensation and coagulation, the highly volatile species, PbCl$_{2}$ and SnCl$_{4}$ vapors tended to discharge into the atmosphere without experiencing either the condensation or the coagulation. For Sn vapors the tendency was between that of PbO vapors and that of PbCl$_{2}$ or SnCl$_{4}$. To restrain the discharged amount of hazardous metallic species, the coagulation should be restrained, the number concentration and the size of pre-existing fly ash particles should be increased, and the temperature drop rate of combustion gas should be kept low.

• Journal of Environmental Health Sciences
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• v.33 no.4
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• pp.317-324
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• 2007

The sewage treatment sludge disposal has become a serious environmental problem because of restricted direct land-filling and oceandumping in spite of their large amounts discharged. So the recycling of sewage treatment sludge is very useful alternative for waste management. Here, we studied the feasibility of zeolite synthesis in open system from the sewage treatment sludge incinerator fly ash by means of hydrothermal synthesis. We considered the concentration of NaOH, reaction time, reaction temperature and reaction step as synthesis variables. The phase of zeolite products was identified by X-ray diffractometer(XRD) and ammonium ion exchange test was performed for the raw fly ash and two zeolite products(Z-3 and Z-5). In leaching test of the raw fly ash, hazard metal is detected very low level compared with regulatory leaching test standard. But in total recoverable test, the total contents of the fly ash were very high in terms of the standard for waste-derived fertilizer. Through hydrothermal reaction, small amount of zeolite P was synthesied in 1 N of NaOH solution and relatively large amount of hydroxysodalite was synthesied in 3 N and 5 N of NaOH solution with similar peak intensity. Addition of an aging step in the synthesis didn't increase the amount of zeolite phase. Maximum $NE_4^+-N$ exchange capacity is 1.49 mg $NH_4^+-N/g$ in Z-3 and 1.38 mg $NH_4^+-N/g$ in Z-5. Most of the ammonium ion is exchanged in 30 minutes and disorption did not occur until 5 hours.

• Journal of the Korean Ceramic Society
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• v.53 no.6
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• pp.659-664
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• 2016

Ash deposition of heat exchange boiler, caused mainly by accumulation of particulate matter, reduces heat transfer of the boiler system. Heat and mass transfer through porous media such as ash deposits mainly depend on the microstructure of deposited ash. Therefore, in this study, we investigated microstructural and thermal properties of the ash deposited on the boiler tube. Samples for this research were obtained from the fuel economizer tube in an industrial waste incinerator. To characterize microstructures of the ash deposit samples, scanning electron microscope (SEM), energy-dispersive spectroscopy (EDS), inductively coupled plasma optical emission spectroscopy (ICP-OES), X-ray diffraction (XRD) and BET analysis were employed. The results revealed that it had a porous structure with small particles mostly of less than a few micrometers; the contents of Ca and S were 19.3, 22.6% and 18.5, 18.7%, respectively. Also, the results showed that it consisted mainly of anhydrite ($CaSO_4$) crystals. - The thermal conductivities of the ash deposit sample obtained from the economizer tube in industrial waste incinerator were measured to be 0.63 and 0.54 W/mK at $200^{\circ}C$, which were about 100 times less than the thermal conductivity (61.32 W/mK) of the boiler tube itself, indicating that ash deposition on the boiler tube was closely related to a decrease in boiler heat transfer.

• 한국신재생에너지학회:학술대회논문집
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• 2009.06a
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• pp.794-797
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• 2009

중소형 폐기물 소각설비의 폐열보일러에서 생산되는 10 $kg/cm^2$미만의 저압증기를 이용한 증기터빈발전에서 증기의 건도를 높이이 위한 증기 전처리가 필수적이며, 건도를 증가시킨 증기를 이용하여 발전실험을 하였다. 본 연구에 적용된 증기터빈발전기는 마이크로 축류식 증기터빈으로 배압식을 채택하였으며, 증기터빈에 공급되는 증기압력의 증가에 따라 증기공급량, 발전량이 증가하였으며, 이에 따른 발전 효율은 설비의 효율에 따라 변하였다. 또한, 배압식 증기터빈의 경우, 공급.배기측의 증기 압력의 차이가 증가함에 따라 발전을 위한 증기 소비율이 감소하고 발전 효율이 증가함을 볼 수 있었다.