• Title/Summary/Keyword: size-dependent

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Grain Size Effect on Mechanical Properties of Polycrystalline Graphene

  • Park, Youngho;Hyun, Sangil;Chun, Myoungpyo
    • Composites Research
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    • 제29권6호
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    • pp.375-378
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    • 2016
  • Characteristics of nanocrystalline materials are known substantially dependent on the microstructure such as grain size, crystal orientation, and grain boundary. Thus it is desired to have systematic characterization methods on the various nanomaterials with complex geometries, especially in low dimensional nature. One of the interested nanomaterials would be a pure two-dimensional material, graphene, with superior mechanical, thermal, and electrical properties. In this study, mechanical properties of "polycrystalline" graphene were numerically investigated by molecular dynamics simulations. Subdomains with various sizes would be generated in the polycrystalline graphene during the fabrication such as chemical vapor deposition process. The atomic models of polycrystalline graphene were generated using Voronoi tessellation method. Stress strain curves for tensile deformation were obtained for various grain sizes (5~40 nm) and their mechanical properties were determined. It was found that, as the grain size increases, Young's modulus increases showing the reverse Hall-Petch effect. However, the fracture strain decreases in the same region, while the ultimate tensile strength (UTS) rather shows slight increasing behavior. We found that the polycrystalline graphene shows the reverse Hall-Petch effect over the simulated domain of grain size (< 40 nm).

품사 부착 말뭉치를 이용한 임베디드용 연속음성인식의 어휘 적용률 개선 (Vocabulary Coverage Improvement for Embedded Continuous Speech Recognition Using Part-of-Speech Tagged Corpus)

  • 임민규;김광호;김지환
    • 대한음성학회지:말소리
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    • 제67호
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    • pp.181-193
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    • 2008
  • In this paper, we propose a vocabulary coverage improvement method for embedded continuous speech recognition (CSR) using a part-of-speech (POS) tagged corpus. We investigate 152 POS tags defined in Lancaster-Oslo-Bergen (LOB) corpus and word-POS tag pairs. We derive a new vocabulary through word addition. Words paired with some POS tags have to be included in vocabularies with any size, but the vocabulary inclusion of words paired with other POS tags varies based on the target size of vocabulary. The 152 POS tags are categorized according to whether the word addition is dependent of the size of the vocabulary. Using expert knowledge, we classify POS tags first, and then apply different ways of word addition based on the POS tags paired with the words. The performance of the proposed method is measured in terms of coverage and is compared with those of vocabularies with the same size (5,000 words) derived from frequency lists. The coverage of the proposed method is measured as 95.18% for the test short message service (SMS) text corpus, while those of the conventional vocabularies cover only 93.19% and 91.82% of words appeared in the same SMS text corpus.

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Luminance에 의한 Pupil의 변화에 대한 모델 (A Model of Pupil's Change with Luminance)

  • 김용근
    • 한국안광학회지
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    • 제1권2호
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    • pp.7-11
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    • 1996
  • 동공반사에 의한 동공크기 변화는 luminance 량에 의해 결정되며, 동공크기에 따른 외부 광량의 투과량인 망막조도비 분포함수와 luminance 량에 따른 추체, 간체의 수용체 분포함수에 의존한다. Luminance 에 대한 동공크기 변화는 다음과 같은 수식적 모델로 표현 할 수 있다. $$y(x)={\alpha}+{\beta}\frac{1}{1+{e}{x}{p}(x-x_0)/{\theta}}$$ 여기서 ${\alpha}$는 luminance의 최대값에서 동공직경 크기이고, ${\beta}$는 동공직경 최대, 최소 편차, ${\theta}$는 개인차의 민감도를 나타내는 parameter이다. P.Moon등의 실험값과 비교해 보면 이모델식이 잘 일시함을 알 수 있다.

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의복관여 효과에 대한 메타분석 (Synthesis of Primary Studies Related to Clothing Involvement by Meta-analysis)

  • 이종남;유혜경
    • 한국의류학회지
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    • 제37권3호
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    • pp.386-398
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    • 2013
  • This study analyzes the effect of clothing involvement using meta-analysis. Metal-analysis (the analysis of analyses) is widely used in various academic areas to integrate individual empirical studies and generalize the knowledge of a specific research field. Previous studies regarding clothing involvement published since 1990 were researched from the KISS database using clothing involvement and fashion involvement as a keyword; subsequently, 127 articles were identified. Studies that had insufficient statistics or included clothing involvement as a moderating (or intervening variable) were eliminated; subsequently, 36 articles provided a total of 75 data sets that were used for the final analysis. Dependent variables were grouped into 10 categories to compare the differences between high and low involvement groups. The effect size of clothing involvement was large in non-personal information source; however, it was small in utility, brand royalty and quality. In the 7 categories of relational studies that showed homogeneity, the relation size regarding conformity was smaller than the personal information source.

SPF ICR 마우스에 있어서 1:1 상시동거 교배에 의한 번식성숙 (Reproductive Performance of SPF ICR Mice under Single Paired Mating)

  • 송창우;이상준;김정란;한상섭
    • 한국가축번식학회지
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    • 제16권3호
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    • pp.261-267
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    • 1992
  • The reproductive performance of SPF ICR mice under single paired mating were examined to get reproductive background data and to establish single paired rotational mating system. The results obtained were as follows : average litter size was 15.4$\pm$2.0 heads ; average weaning rate was 95.7$\pm$4.9% ; sex ratio(male/female) was 1.09$\pm$0.26 ; aveage delivery interval was 23.0$\pm$2.4 days. It was given the largest litter size at the age of 121~150 days and in 2nd~4th parities, but at the age of under 90 days and in 1st parity weaning rate and delivery interval were higher and shorter than those of the other ages and parities, respectively. In sex ratio, the number of male litters was slightly increased from that of female litters. The weaning rate of litters from dams which nuresed 12 litters was the highest among those of different litter sizes, and it was decreased dependent upon increment of litter size. There were no difference among 4 groups for reproductive performance, therefore the present study could have important sources for animal breeders who produce mice using the single paired rotational mating system.

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Ni-Grain Size Dependent Growth of Vertically Aligned Carbon Nanotubes by Microwave Plasma-Enhanced Chemical Vapor Deposition and Field Emission Properties

  • Choi, Young-Chul;Jeon, Seong-Ran;Park, Young-Soo;Bae, Dong-Jae;Lee, Young-Hee;Lee, Byung-Soo;Park, Gyeong-Su;Choi, Won-Bong;Lee, Nae-Sung;Kim, Jong-Min
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2000년도 제1회 학술대회 논문집
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    • pp.231-234
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    • 2000
  • Vertically aligned carbon nanotubes were synthesized on Ni-coated Si substrates using microwave plasma-enhanced chemical vapor deposition. The grain size of Ni thin films was varied with the RF power density during the RF magnetron sputtering process. It was found that the diameter, growth rate, and density of carbon nanotubes could be controlled systematically by the grain size of Ni thin films. With decreasing the grain size of Ni thin films, the diameter of the nanotubes decreased, whereas the growth rate and density increased. High-resolution transmission electron microscope images clearly demonstrated synthesized nanotubes to be multiwalled. The number of graphitized wall decreased with decreasing the diameter. Field emission properties will be further presented.

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The External Knowledge Utilization and Radical Innovation in Korea Electronic Industry

  • Lee, Youngwoo;Kim, Jae-Jin;Chang, Sul-Ki
    • 동아시아경상학회지
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    • 제6권4호
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    • pp.13-24
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    • 2018
  • Purpose - This study investigates the moderation effect of internal factor, a firms size, on the external knowledge sourcing strategy and its effectiveness in generating radical innovation. We incorporate concepts of breadth and depth as two measures to gauge the degree of openness in firms external search Research design and methodology - The dependent variable in the regression model is the percentage of innovative sales and therefore, Tobit regression is employed for estimating significant factors affecting on the ratio of first-to-market by breadth and depth in external knowledge, internationalization, and size. Results - The results show that the external knowledge, in terms of both breadth and depth, has a positive relationship with radical innovation. However internationalization as external knowledge resources is not statistically accepted. Firm size has moderating effect on innovation negatively only in case of using external knowledge resources to a high degree. Conclusions - Firms obtain external information mostly from customers, competitors, and suppliers etc. empirical knowledge in terms of scope and intensity is an important contributor to innovation. And intensity use of external knowledge and information resources can work in favor of smaller firms rather than larger ones. Internationalization seems to have little effect on innovation but it requires further researches with clear criteria and more data.

Size and Density of Graphene Domains Grown with Different Annealing Times

  • Jung, Da Hee;Kang, Cheong;Nam, Ji Eun;Kim, Jin-Seok;Lee, Jin Seok
    • Bulletin of the Korean Chemical Society
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    • 제34권11호
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    • pp.3312-3316
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    • 2013
  • Single crystals of hexagonal graphenes were successfully grown on Cu foils using the atmospheric pressure chemical vapor deposition (CVD) method. We investigated the effects of reaction parameters, such as the growth temperature and annealing time, on the size, coverage, and density of graphene domains grown over Cu foil. The mean size of the graphene domains increased significantly with increases in both the growth temperature and annealing time, and similar phenomena were observed in graphene domains grown by low pressure CVD over Cu foil. From the comparison of micro Raman spectroscopy in the graphene films grown with different annealing times, we found that the nucleation and growth of the domains were strongly dependent on the annealing time and growth temperature. Therefore, we confirmed that when reaction time was same, the number of layers and the degree of defects in the synthesized graphene films both decreased as the annealing time increased.

Formation of Poly(ethylene glycol)-Poly($\varepsilon$-caprolactone) Nanoparticles via Nanoprecipitation

  • Lee, Jae-Sung;Hwang, Su-Jong;Lee, Doo-Sung;Kim, Sung-Chul;Kim, Duk-Joon
    • Macromolecular Research
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    • 제17권2호
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    • pp.72-78
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    • 2009
  • Size control of therapeutic carriers in drug delivery systems has become important due to its relevance to biodistribution in the human body and therapeutic efficacy. To understand the dependence of particle size on the formation condition during nanoprecipitation method, we prepared nanoparticles from biodegradable, amphiphilic block copolymers and investigated the particle size and structure of the resultant nanoparticles according to various process parameters. We synthesized monomethoxy poly(ethylene glycol)-poly($\varepsilon$-caprolactone) block copolymer, MPEG-PCL, with different MPEG/PCL ratios via ring opening polymerization initiated from the hydroxyl end group of MPEG. Using various formulations with systematic change of the block ratio of MPEG and PCL, solvent choice, and concentration of organic phase, MPEG-PCL nanoparticles were prepared through nanoprecipitation technique. The results indicated that (i) the nanoparticles have a dual structure with an MPEG shell and a PCL core, originating from self-assembly of MPEG-PCL copolymer in aqueous condition, and (ii) the size of nanoparticles is dependent upon two sequential processes: diffusion between the organic and aqueous phases and solidification of the polymer.

Preparation and Characterization of Polypropylene/Waste Ground Rubber Tire Powder Microcellular Composites by Supercritical Carbon Dioxide

  • Zhang, Zhen Xiu;Lee, Sung-Hyo;Kim, Jin-Kuk;Zhang, Shu Ling;Xin, Zhen Xiang
    • Macromolecular Research
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    • 제16권5호
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    • pp.404-410
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    • 2008
  • In order to obtain 'value added products' from polypropylene (PP)/waste ground rubber tire powder (WGRT) composites, PP/WGRT microcellular foams were prepared via supercritical carbon dioxide. The effects of blend composition and processing condition on the cell size, cell density and relative density of PP/WGRT micro-cellular composites were studied. The results indicated that the microcellular structure was dependent on blend composition and processing condition. An increased content of waste ground rubber tire powder (WGRT) and maleic anhydride-grafted styrene-ethylene-butylene-styrene (SEBS-g-MA) reduced the cell size, and raised the cell density and relative density, whereas a higher saturation pressure increased the cell size, and reduced the cell density and relative density. With increasing saturation temperature, the cell size increased and the relative density decreased, whereas the cell density initially increased and then decreased.