• 제목/요약/키워드: size-dependent

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Characterization of gold nanoparticles on optical fiber for localized surface plasmon resonance sensor (광섬유 국소화 표면 플라즈몬 공명 센서를 위한 광섬유 표면상의 금 나노 입자 특성 분석)

  • Lee, Hoon;Lee, Seung-Ki
    • Journal of Sensor Science and Technology
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    • v.18 no.3
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    • pp.226-233
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    • 2009
  • In this study, the optical properties of localized surface plasmon resonance sensor using optical fiber was analyzed as the variation of a size and surface density of gold nano particles on the etched optical fiber surface. It is shown that a size and surface density of gold nano particles on optical fiber surface are controlled by $Na_3$ citrate quantity and pH of gold colloid solution. To measure the sensitivity, peak wavelength of absorbance spectrum was detected as the reflective index of the solution. The sensor sensitivity is linearly dependent on the size and surface densities of gold nano particles from the results of optical experiments.

Effect of Reaction Conditions on the Preparation of Nano-sized Ni Powders inside a Nonionic Polymer

  • Kim, Tea-Wan;Kim, Dong-Hyun;Park, Hong-Chae;Yoon, Seog-Young
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.462-463
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    • 2006
  • Monodispersed and nano-sized Ni powders were synthesized from aqueous nickel sulfate hexahydrate $(NiSO_4{\cdot}6H_2O)$ inside nonionic polymer network by using wet chemical reduction process. The sucrose was used as a nonionic polymer network source. The effect of reaction conditions such as the amount of sucrose and a various reaction temperature, nickel sulfate hexahydrate molarity. The influence of a nonionic polymer network on the particle size of the prepared Ni powders was characterized by means of X-ray diffraction (XRD), scanning electron microscopy (SEM), and particle size analysis (PSA). The results showed that the obtained Ni powders were strong by dependent of the reaction conditions. In particular, the Ni powders prepared inside a nonionic polymer network had smooth spherical shape and narrow particle size distribution.

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Synthesis of Size Controlled Gold Nanoparticles and Surface Enhanced Raman Spectroscopy (SERS) Effect (크기가 조절된 골드 나노 입자의 합성과 표면 라만 증강의 효과)

  • Lee, Young Wook;Shin, Tae Ho
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.32 no.6
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    • pp.462-465
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    • 2019
  • Nanoscale gold particles have been intensively researched due to their potential applications in catalysis, electronics, plasmonics, and biological assays. In our study, we fabricated gold nanoparticles (NPs) that were synthesized in an aqueous environment via the reduction of $HAuCl_4$ by ascorbic acid (AC) with a sodium citrate (SC) surfactant. Highly monodispersed gold particles with sizes ranging from 123 to 184 nm were prepared in high-yield by a surfactant concentration. The structural and optical properties of the synthesized gold nanoparticles were characterized by transmission electron microscopy (TEM) and UV-vis spectroscopy. The prepared nanoparticles exhibited efficient surface-enhanced Raman scattering (SERS) properties that were dependent on their on size.

The Impact of Macroeconomic Variables on the Profitability of Korean Ocean-Going Shipping Companies

  • Kim, Myoung-Hee;Lee, Ki-Hwan
    • Journal of Navigation and Port Research
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    • v.43 no.2
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    • pp.134-141
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    • 2019
  • The objective of this study was to establish whether global macroeconomic indicators affect the profitability of Korean shipping companies by using panel regression analysis. OROA (operating return on assets) and ROA (ratio of net profit to assets) were selected as proxy variables for profitability. OROA and ROA were used as dependent variables. The world GDP growth rate, interest rate, exchange rate, stock index, bunker price, freight, demand and supply of the world shipping market were set as independent variables. The size of the firm was added to the control variable. For small-sized firms, OROA was not affect by macroeconomic indicators. However, ROA was affected by variables such as interest rates, bunker prices, and size of firms. For medium-sized firms, OROA was affected by demand, supply, GDP, freight, and asset variables. However, macroeconomic indicators did not affect ROA. For large-sized firms, freight, GDP, and stock index (SCI; Shanghai Composite Index) have an effect on OROA. ROA was analyzed to be influenced by bunker price and SCI.

Mechanistic representation of the grading-dependent aggregates resiliency using stress transmission column

  • Sun, Yifei;Wang, Zhongtao;Gao, Yufeng
    • Geomechanics and Engineering
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    • v.17 no.4
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    • pp.405-411
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    • 2019
  • A significant influence of the particle size distribution on the resilient behaviour of granular aggregates was usually observed in laboratory tests. However, the mechanisms underlying this phenomenon were rarely reached. In this study, a mechanistic model considering particle breakage is proposed. It is found to be the combined effects of the coefficient of uniformity and the size range between maximum and minimum particle sizes that influences the resilient modulus of granular aggregates. The resilient modulus is found to undergo reduction with evolution of particle breakage by shifting the initial particle size distribution to a broader one.

Recycling of Aluminum Alloy from Al-Cu Metal Matrix Composite Reinforced with SiC Particulates

  • Sharma, Ashutosh;Ahn, Byungmin
    • Korean Journal of Materials Research
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    • v.28 no.12
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    • pp.691-695
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    • 2018
  • In this study, we investigate the recycling of aluminum-based metal matrix composites(AMCs) embedded with SiC particulates. The microstructure of the AMCs is characterized by X-ray diffraction and scanning electron microscopy. The possibility of recycling the composite scrap is attempted from the melted alloy and SiC particulates by re-melting, holding and solidification in crucibles. The recovery percentage of the matrix alloy is calculated after a number of holding times, 0, 5, 10, 15, 20, 25 and 30 minutes and for different particulate sizes and weight fractions in the Al matrix. The results show that the recovery percentage of the matrix alloy, as well as the time required for maximum recovery of the matrix, is dependent on the size and weight fraction of SiC particulates. In addition, the percentage recovery increases with particulate size but drops with the particulate fraction in the matrix. The time to reach maximum recovery falls rapidly with an increase in particulate size and fraction.

Knowledge Exchange Activities and Performances in Software Industry Clusters: Focus on Firm Size Effect

  • CHO, Sung Eui
    • The Journal of Economics, Marketing and Management
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    • v.10 no.6
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    • pp.9-16
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    • 2022
  • Purpose: This research investigates the differences in knowledge exchange activities and performances between startups and large companies in software industry clusters. Research design, data, and methodology: Six independent factors of human resource information, R&D and technology, marketing knowledge, government support information, strategic knowledge, and cooperation information were extracted to test the firm size effect in the relationships with two performance factors such as satisfaction with industry cluster location and satisfaction with financial performances. Data were collected through a survey of entrepreneurs, managers, and employees and tested by statistical analysis methodologies. Results: Three independent factors of human resource information, R&D and technology, and cooperation information were particularly significant in the relationship with both dependent factors. Strategic knowledge significantly affected financial performance. Knowledge exchange activities were more important in startups than in large companies for all eight factors. Conclusion: Policies for software industry clusters need a different approach for startups and large companies.

An Electron Microscopic Investigation of the Structure of Thin Film Tin Oxide Material

  • Jeon, Eok-Gui;Choy, Jin-Ho;Choi, Q.-won;Kim, Ha-Suck
    • Bulletin of the Korean Chemical Society
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    • v.6 no.5
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    • pp.304-308
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    • 1985
  • Morphological structure of tin oxide thin films was examined by transmission electron microscopy. TEM samples were prepared by chemical etching in hydrogen fluoride solution: firstly floating for 2-3 minutes in acid solution, then suspending on water found to be useful for the preparation of TEM samples. Electron micrographs showed the size of grains of the tin oxide crystal was dependent upon the temperature of the film preparation. Dopant concentration and heating time also influence the grain size. The resistivity of tin oxide material was explained by grain size and grain boundaries in a limited temperature and dopant concentration ranges.

Size Effects of MoS2 on Hydrogen and Oxygen Evolution Reaction

  • Ghanashyam, Gyawali;Jeong, Hae Kyung
    • Journal of Electrochemical Science and Technology
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    • v.13 no.1
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    • pp.120-127
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    • 2022
  • Molybdenum disulfide (MoS2) has been widely used as a catalyst for the bifunctional activities of hydrogen and oxygen evolution reactions (HER and OER). Here, we investigated size dependent HER and OER performance of MoS2. The smallest size (90 nm) of MoS2 exhibits the lowest overpotential of -0.28 V at -10 mAcm-2 and 1.52 V at 300 mAcm-2 with the smallest Tafel slopes of 151 and 176 mVdec-1 for HER and OER, respectively, compared to bigger sizes (2 ㎛ and 6 ㎛) of MoS2. The better HER and OER performance is attributed to high electrochemical active surface area (6 × 10-4 cm2) with edge sites and low charge transfer resistance (18.1 Ω), confirming that the smaller MoS2 nanosheets have the better catalytic behavior.

Evaluation of Human Factors on Text Content Displayed in Mixed Reality (혼합현실에서 텍스트 콘텐츠 표시에 대한 휴먼팩터 평가)

  • Kim, Dae-Yeon
    • Journal of Korea Multimedia Society
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    • v.25 no.9
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    • pp.1316-1327
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    • 2022
  • In this study, the effect of text content on users in mixed reality was investigated and subjective evaluation was performed using a statistical approach. The position and size of the text were defined as independent variables, and eye comfort and visibility were analyzed as dependent variables. Twenty participants viewed the content for 96 seconds and then performed a related survey rating task. As a result of two-way ANOVA, the interaction between text position and size and the main effect on text size were not statistically significant. The main effect on text position was found to be statistically significant, and as a result of the analysis, the bottom middle was preferred for both eye comfort and visibility.