• 제목/요약/키워드: size-dependent

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입자 크기 분포가 금 콜로이드의 광학성질에 미치는 영향에 대한 이론 연구 (Theoretical Study on the Effects of Particle Size Distribution on the Optical Properties of Colloidal Gold)

  • 김효정;;장준경
    • 대한화학회지
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    • 제51권5호
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    • pp.407-411
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    • 2007
  • 크기 분포를 가진 금 나노 입자 콜로이드의 소광 스펙트럼을 미 이론으로 계산하고 실험과 비교하였다. 입자 크기 분포를 고려한 계산이 크기 분포를 고려하지 않은 계산보다 실험과 더 가까움을 확인하였다. 최소 자승법을 이용하여 실험에서 얻은 소광 스펙트럼으로부터 입자 크기 분포를 이론적으로 도출하였다. 이렇게 얻은 입자 크기는 입자 지름이 10에서 28 나노미터인 경우 투과전자현미경 분석 결과와 잘 일치하였다.

Investigation on the Factors Determining the Size Distribution of Gold Nanoparticles in the Citrate Reduction Method

  • Kang, Ae-Yeon;Park, Dae-Keun;Lee, Cho-Yeon;Yun, Wan-Soo
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2012년도 제42회 동계 정기 학술대회 초록집
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    • pp.554-554
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    • 2012
  • Controlling the size distribution of gold nanoparticles (NPs) is of great importance due to the fact that their properties are strongly dependent upon the size distribution as well as the size itself. In the citrate reduction method for gold NP synthesis, the citrate works as (1) a reducing agent, (2) a surfactant, and also (3) a weak base: it raises the pH of the whole reaction mixture. Here, we have extensively studied the all three roles of the citrate, by adding other reagents separately (NaBH4, CTAB, and NaOH) for the independent control of the three roles of the citrate. Among the roles of the citrate, that as a weak base was found to be the most critical parameter affecting the size distribution of gold NPs and the size distribution became much more improved with the increase of the solution pH, while adding a supplementary surfactant or reducing agent resulted in the formation of less homogeneous NPs.

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Particle Size, Morphology and Color Characteristics of C.I. Pigment Red 57:1 : 1. Effect of Synthesis Conditions

  • Seo, Hee Sung;Lee, Hyun Kyung;Yoo, Eui Sang
    • 한국염색가공학회지
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    • 제27권4호
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    • pp.229-244
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    • 2015
  • The effects of synthesis conditions on characteristics of the calcium-azo complex pigment, C.I. Pigment Red 57:1, were studied. It was mainly considered that the industrially required synthesis conditions for lowering electrical conductivity of the pigment solution keeping pigment quality such as particle size and color characteristics. Three parameters were chosen as control factors during the synthesis. The first was the amount of hydrochloric acid added to transform sodium nitrite into nitrous acid. The second was the amount of calcium chloride added to insolubilize the synthesized azo dye. The final factor was pH control during the coupling reaction. The electrical conductivity and pigment aggregate particle size were dependent on the amount of hydrochloric acid and calcium chloride. Higher HCl concentration gave brighter yellowish-red color because of smaller particle aggregate size and narrower size distribution. Amount of charged ions in the synthesis process might affect the "lake" formation resulting different particle aggregate size and color shade.

Wide LCD 모니터의 프레임 형태에 따른 감성 선호도 연구 (Affective Design for the Frame Size and Shape of Wide LCD Monitors)

  • 이한나;정의승;최재호
    • 대한인간공학회지
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    • 제28권4호
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    • pp.61-69
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    • 2009
  • With increasing needs for affective design, it became an essential part in a product development process to look up quantitative ergonomic data that reflects customers' preferences on design factors in various products. This study looked at wide LCD monitors and analyzed customers' affective preferences regarding monitor's bezel frame size and shape. The monitor's bezel frame depth, size and ratio were selected as independent variables among many design parameters. As dependent variables, customer's subjective preferences were measured. A statistical analysis revealed that monitor's bezel frame depth, size and ratio had significant effects on customer's preferences. Also, it was possible to find a different tendency on affective variables and their levels for 19" and 24" wide LCD monitors. In general, experiments revealed that customers reacted more sensitively in 24" wide LCD monitors to all variables. In 19" wide LCD monitors, only the lower frame bezel size had a significant effect, otherwise, lower, upper and side frame bezels appeared to be effective variables in 24" monitors. In order to reflect customer's affective preferences to new design of wide LCD monitors, this study is expected to provide quantitative ergonomic data and guidelines for the design of wide LCD monitor's bezel frame depth and size.

Variation in Reproductive Efficiency of Indonesian Native Cows

  • Paputungan, Umar
    • Asian-Australasian Journal of Animal Sciences
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    • 제10권2호
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    • pp.240-244
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    • 1997
  • This study was conducted in North Sulawesi, Indonesia to identify the factors affecting reproductive efficiency and to determine the contribution of each factor in reproductive efficiency of Indonesian native cows. Records of reproductive efficiency, body size (hip height, body weight, body length, heart girth) as well as age on one hundred and sixty seven Indonesian native cows (seventy six cows of the Bali breed and ninety one cows of the synthetic breed from unknown proportion of th Madura, the Sumba and the Ongole breeds) of 58 farmers were available in this research. The data were analyzed by covariance analysis using SAS package including reproductive efficiency as a dependent variable and breed, body size (hip height, body weight, body length, heart girth) and age of cows as independent variables. The contribution of each independent factor to dependent variable was estimated as the percentage of the sum of square in the corrected total sum of squares. The results showed that body weight and body size of cows would be considered as th most important factors affecting reproductive efficiency of Indonesian native cows. Therefore, the reproductive efficiency could be increased by 1) using cows that reached a target weight of at least 250 kg, 2) using cows with relatively well developed height at hip of at least 117 cm, heart girth of at least 150 cm, and body length of at least 125 cm, 3) keeping breeding cows that reach a target age of 24 months old with the maximum interval between postpartum and next breeding season of 90 days for each year, and 4) using good nutritional feeding to reach the optimum weight and body condition.

Nonlinear magneto-electro-mechanical vibration analysis of double-bonded sandwich Timoshenko microbeams based on MSGT using GDQM

  • Mohammadimehr, M.;Shahedi, S.
    • Steel and Composite Structures
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    • 제21권1호
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    • pp.1-36
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    • 2016
  • In the present study, the nonlinear magneto-electro-mechanical free vibration behavior of rectangular double-bonded sandwich microbeams based on the modified strain gradient theory (MSGT) is investigated. It is noted that the top and bottom sandwich microbeams are considered with boron nitride nanotube reinforced composite face sheets (BNNTRC-SB) with electrical properties and carbon nanotube reinforced composite face sheets (CNTRC-SB) with magnetic fields, respectively, and also the homogenous core is used for both sandwich beams. The connections of every sandwich beam with its surrounding medium and also between them have been carried out by considering Pasternak foundations. To take size effect into account, the MSGT is introduced into the classical Timoshenko beam theory (CT) to develop a size-dependent beam model containing three additional material length scale parameters. For the CNTRC and BNNTRC face sheets of sandwich microbeams, uniform distribution (UD) and functionally graded (FG) distribution patterns of CNTs or BNNTs in four cases FG-X, FG-O, FG-A, and FG-V are employed. It is assumed that the material properties of face sheets for both sandwich beams are varied in the thickness direction and estimated through the extended rule of mixture. On the basis of the Hamilton's principle, the size-dependent nonlinear governing differential equations of motion and associated boundary conditions are derived and then discretized by using generalized differential quadrature method (GDQM). A detailed parametric study is presented to indicate the influences of electric and magnetic fields, slenderness ratio, thickness ratio of both sandwich microbeams, thickness ratio of every sandwich microbeam, dimensionless three material length scale parameters, Winkler spring modulus and various distribution types of face sheets on the first two natural frequencies of double-bonded sandwich microbeams. Furthermore, a comparison between the various beam models on the basis of the CT, modified couple stress theory (MCST), and MSGT is performed. It is illustrated that the thickness ratio of sandwich microbeams plays an important role in the vibrational behavior of the double-bonded sandwich microstructures. Meanwhile, it is concluded that by increasing H/lm, the values of first two natural frequencies tend to decrease for all amounts of the Winkler spring modulus.

태평양 연어류(Oncorhynchus spp.)의 장기 풍도 변화 및 개체 크기 변화 (Long-term Variation in the Relative Abundance and Body Size of Pacific Salmon Oncorhynchus species)

  • 서현주;강수경
    • 한국수산과학회지
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    • 제44권6호
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    • pp.717-731
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    • 2011
  • To clarify relationships between the abundance and biological characteristics of Pacific salmon Oncorhynchus spp., we analyzed spatiotemporal changes in fork length, body weight, and an index of relative abundance (catch per unit effort, CPUE) for pink salmon (O. gorbuscha), chum salmon (O. keta), and sockeye salmon (O. nerka) collected by research gill-nets from the T/V Oshoro-maru and the T/V Hokusei-maru of Hokkaido University in the North Pacific during 1953-2007. Populations of each species were distributed throughout the western Bering Sea, eastern Bering Sea (EB), western North Pacific (WNP), central North Pacific (CNP), eastern North Pacific (ENP), and Okhotsk Sea. Since 1970, the average body size of chum salmon at ocean ages 0.3-0.4 has generally declined in the WNP and CNP. However, the average body sizes of sockeye and pink salmon have not shown temporal changes. Chum salmon showed significant negative (positive) correlations between CPUE and body size for populations in CNP (ENP) at ocean ages 0.2-0.3 (age 0.1) for both sexes. In general, sockeye salmon also showed significant negative (positive) correlations between CPUE and body size for populations in the EB at ocean ages X.2-X.3 (age X.1) for both sexes, except in CNP at age 2. Our results suggest that better growth by chum and sockeye salmon in the early periods of their ocean life histories might produce higher abundance. This higher abundance, which might also be affected by overlapping distributions among Pacific salmon species and populations in certain seas, in turn appears to cause density-dependent declines in growth in the following ocean life history period due to the limited carrying capacity of the seas. To understand complex dynamics in Pacific salmon species in the North Pacific Ocean, research on interactions among species and populations is needed.

의복의 사이즈 체계 설정을 위한 신체 발달 경향에 대한 연구 (A Study on the Developmental Trend of the Human body for the establishment of the Apparel Sizing System -on the high school boys and girls between age 16 and 18-)

  • 김구자;이순원
    • 한국의류학회지
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    • 제15권1호
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    • pp.48-60
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    • 1991
  • The purpose of this study is to analyze the pattern of human developmental growth with empirical anthropometric data for clothing construction. The sample was drawn randomly out of senior high school boys and girls in seoul urban area. The sample size was 424 boys and 301 girls between age 16 and 18. Dependent variables of this study were modified after extraction of common variables from raw data. 42 dependent variables were analyzed by the method of Duncan Test as Multiple Range Test among three age groups and T-Test between male and female of same age groups. The analysis of these data was carried with spss-x package by the computer installed in INHA University. The major findings can be summarized as follows. 1. In Duncan Test, female students between age 16 and 18 were not significantly different in the majority of dependent variables, but girth measurements and weight of 17 and 18 age groups were significantly different from that of 16 age groups. 2. In Duncan Test, male students were significantly different in the majority of the dependent variables, especially 33 variabls from 42 variables, among three age groups. 3. In T-Test, hip girth was only not significantly different between male and female and neck girth of the female students was only significantly larger than that of the male students.

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Dynamic modeling of nonlocal compositionally graded temperature-dependent beams

  • Ebrahimi, Farzad;Fardshad, Ramin Ebrahimi
    • Advances in aircraft and spacecraft science
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    • 제5권1호
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    • pp.141-164
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    • 2018
  • In this paper, the thermal effect on buckling and free vibration characteristics of functionally graded (FG) size-dependent Timoshenko nanobeams subjected to an in-plane thermal loading are investigated by presenting a Navier type solution for the first time. Material properties of FG nanobeam are supposed to vary continuously along the thickness according to the power-law form and the material properties are assumed to be temperature-dependent. The small scale effect is taken into consideration based on nonlocal elasticity theory of Eringen. The nonlocal equations of motion are derived based on Timoshenko beam theory through Hamilton's principle and they are solved applying analytical solution. According to the numerical results, it is revealed that the proposed modeling can provide accurate frequency results of the FG nanobeams as compared to some cases in the literature. The detailed mathematical derivations are presented and numerical investigations are performed while the emphasis is placed on investigating the effect of the several parameters such as thermal effect, material distribution profile, small scale effects, aspect ratio and mode number on the critical buckling temperature and normalized natural frequencies of the temperature-dependent FG nanobeams in detail. It is explicitly shown that the thermal buckling and vibration behaviour of a FG nanobeams is significantly influenced by these effects. Numerical results are presented to serve as benchmarks for future analyses of FG nanobeams.

반응표면법을 이용한 DTF의 석탄 연소 안전성 평가 (Assessment of Coal Combustion Safety of DTF using Response Surface Method)

  • 이의주
    • 한국안전학회지
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    • 제30권1호
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    • pp.8-13
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    • 2015
  • The experimental design methodology was applied in the drop tube furnace (DTF) to predict the various combustion properties according to the operating conditions and to assess the coal plant safety. Response surface method (RSM) was introduced as a design of experiment, and the database for RSM was set with the numerical simulation of DTF. The dependent variables such as burnout ratios (BOR) of coal and $CO/CO_2$ ratios were mathematically described as a function of three independent variables (coal particle size, carrier gas flow rate, wall temperature) being modeled by the use of the central composite design (CCD), and evaluated using a second-order polynomial multiple regression model. The prediction of BOR showed a high coefficient of determination (R2) value, thus ensuring a satisfactory adjustment of the second-order polynomial multiple regression model with the simulation data. However, $CO/CO_2$ ratio had a big difference between calculated values and predicted values using conventional RSM, which might be mainly due to the dependent variable increses or decrease very steeply, and hence the second order polynomial cannot follow the rates. To relax the increasing rate of dependent variable, $CO/CO_2$ ratio was taken as common logarithms and worked again with RSM. The application of logarithms in the transformation of dependent variables showed that the accuracy was highly enhanced and predicted the simulation data well.