• Title/Summary/Keyword: size-dependent

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Preparation of Polystyrene particles based on interfacial stability of suspension polymerization (현탁중합의 계면안정에 따른 폴리스티렌 입자 제조)

  • 이진호;이상남;박문수;김은경;문명준
    • Journal of the Korean Graphic Arts Communication Society
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    • v.20 no.1
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    • pp.65-78
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    • 2002
  • The suspension polymerization of styrene was carried out to obtain the narrow-size distribution of particle by using poly(vinyl alcohol) (PVA) as suspension stabilizer according to the degree of hydrolysis and the molecular weight. The stabilizing properties of suspension are also dependent on the interfacial tension of aqueous solution when PVA is added. When the polymerization process was carried out with low hydrolyzed PVA, it gave single, well-defined particles, while high hydrolyzed PVA gave clusters. The size of particle produced in this study ranged between 5${\mu}{\textrm}{m}$ and 10${\mu}{\textrm}{m}$. The suspending agent, PVA, influences on the drop size and drop stability, When the molecular weight of PVA is increased, the drop size decreases and the drops become more stable toward coalescence. An increase in the PVA concentration decreases the mean drop size and narrows the drop size distribution.

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Development of Control System of Twin-Fluid Nozzles for Controlling Spraying Rate and Droplet Size (이류체노즐을 이용한 분무량과 분무입경 제어시스템 개발)

  • 이중용;안형철;정창주
    • Journal of Biosystems Engineering
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    • v.25 no.1
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    • pp.11-18
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    • 2000
  • In precision chemical application increment of biological efficacy with less chemical is the virtue. spraying rate and droplet size is closely related to biological efficacy. this study was performed to develope a spray-control-system that could control spraying rate and droplet size independently. Twin-fluid nozzles were selected and tested to certify if the nozzles were suitable for the objective of this study. Characteritics of the nozzles i.e., spraying rte and droplet size change u8nder the changes of spraying pressure and air pressure were statistically modeled. The model had I to 1 matching property between dependent variables and independent variables. Using the property and the model, inverse relationship could be determined between variables. A feedback spray control system was developed and tested with predetermined error of 5 % in pressure. The system showed 4 % error in spraying rate and 9 % error in droplets size. Performance of the system could be upgraded by fine tuning but, in practical sense keeping air pressure in the field sprayer was the bottle neck of commercialization of the spray system.

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Model Gabion's Pollutant Accumulation Efficiency (모형 Gabion의 오염물질 포착률)

  • Jeong, Jae-Hoon;Jeong, Hae-Won;Yoon, Jung-Hwan;Park, Seung-Ki
    • Proceedings of the Korean Society of Agricultural Engineers Conference
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    • 2005.10a
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    • pp.91-96
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    • 2005
  • This study was performed for the research on the method for reducing non-point pollutant with the gabion which was made of gravel-packed plastic frame, and for the characterization of gabion adsorbing pollutant. The result showed that the concentrations of suspended solid in turbid water were reduced to $77.7{\sim}84.7%$ when the water was flowing through the gabion. The uniformity coefficients on the grain size accumulation curves of the adsorbed pollutant were larger on the large grain size gabion than those on the small grain size gabion, and the coefficients of curvature were smaller on the large grain size gabion than those of the small grain size gabion. The adsorption rates were dependent on the grain size of packed gravel. The rates were smaller on inlet and outlet than those on middle place on the series of gabion.

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The Organization of Nanoporous Structure Using Controlled Micelle Size from MPEG-b-PDLLA Block Copolymers

  • Chang, Jeong-Ho;Kim, Kyung-Ja;Shin, Young-Kook
    • Bulletin of the Korean Chemical Society
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    • v.25 no.3
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    • pp.351-356
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    • 2004
  • Selected MPEG-b-PDLLA block copolymers have been synthesized by ring-opening polymerization with systematic variation of the chain lengths of the resident hydrophilic and hydrophobic blocks. The size and shape of the micelles that spontaneously form in solution are then controlled by the characteristics of the block copolymer template. All the materials prepared in this study showed the tunable pore size of 20-80 ${\AA}$ with the increase of hydrophobic chain lengths and up to 660 $m^2$/g of specific surface area. The formation mechanism of these nanoporous structures obtained by controlling the micelle size has been confirmed using both liquid and solid state $^{13}C\;and\;^{29}Si$ NMR techniques. This work verifies the formation mechanism of nanoporous structures in which the pore size and wall thickness are closely dependent on the size of hydrophobic cores and hydrophilic shells of the block copolymer templates.

Fracture energy and tension softening relation for nano-modified concrete

  • Murthy, A. Ramachandra;Ganesh, P.;Kumar, S. Sundar;Iyer, Nagesh R.
    • Structural Engineering and Mechanics
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    • v.54 no.6
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    • pp.1201-1216
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    • 2015
  • This paper presents the details of size independent fracture energy and bi-linear tension softening relation for nano modified high strength concrete. Nano silica in powder form has been used as partial replacement of cement by 2 wt%. Two popular methods, namely, simplified boundary effect method of Karihaloo et al. (2003) and RILEM (1985) fracture energy with P-${\delta}$ tail correction have been employed for estimation of size independent fracture energy for nano modified high strength concrete (compressive strength ranges from 55 MPa to 72 MPa). It is found that both the methods gave nearly same values, which is an additional evidence that either of them can be employed for determination of size independent fracture energy. Bi-linear tension softening relation corresponding to their size independent fracture energy has been constructed in an inverse manner based on the concept of non-linear hinge from the load-crack mouth opening plots of notched three-point bend beams.

Size Dependent Absorption Spectrum of ZnO Nanocrystals

  • Chang Ho Jung;Wang Yongsheng;Suh Kwang-Jong;Son Chang-Sik
    • Korean Journal of Materials Research
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    • v.15 no.7
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    • pp.431-434
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    • 2005
  • To investigate the dependences of the absorption spectrum and electronic structure properties on the ZnO nano-particle size, ZnO nanocrystals were synthesized by a sol-gel method. The absorption onset peak exhibits a systematic blue-shift with decreasing particle size due to the quantum confinement effect, as well as, with decreasing $Zn^{2+}$ concentration. The increase of particle size is mainly controlled by coarsening and aggregation step during the nucleation and growth of ZnO nano-particles. The onset absorption spectrum of ZnO colloids changes from 310 to 355 nm as $Zn^{2+}$ concentration increases from 0.01 to 0.1 mole. The average particle size as a function of aging- time can be determined from the absorption spectra. The freshly prepared nanocrystal size was about 2.8nm.

Coercivity of Nd-Fe-B-type Fine Particles Prepared from Different Precursor Materials

  • Kim, K.M.;Kwon, H.W.;Lee, J.G.;Yu, J.H.
    • Journal of Magnetics
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    • v.20 no.1
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    • pp.21-25
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    • 2015
  • Fine Nd-Fe-B-type particles were prepared by ball milling of different types of Nd-Fe-B precursor materials, such as die-upset magnet, HDDR-treated material, and sintered magnets. Coercivity dependence on the grain and particle size of the powder was investigated. Coercivity of the milled particles was reduced as the particle size decreased, and the extent of coercivity loss was dependent upon the precursor material. Coercivity loss in the finely milled particles was attributed to the surface oxidation. The extent of coercivity loss in the fine particles was closely linked to grain size of the precursor materials. Coercivity loss was more profound for the fine particles with larger grain size. Contrary to the fine particles from the sintered magnets with larger grain size the fine particles (~10 um) from the die-upset magnet and HDDR-treated material with much finer grain size still retained high coercivity (> 10 kOe for die-upset magnet, > 4 kOe for HDDR-treated material).

Size-dependent Optical and Electrical Properties of PbS Quantum Dots

  • Choi, Hye-Kyoung;Kim, Jun-Kwan;Song, Jung-Hoon;Jeong, So-Hee
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.186-186
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    • 2012
  • This report investigates a new synthetic route and the size-dependent optical and electrical properties of PbS nanocrystal quantum dots (NQDs) in diameters ranging between 1.5 and 6 nm. Particularly we synthesize ultra-small sized PbS NQDs having extreme quantum confinement with 1.5~2.9 nm in diameter (2.58~1.5 eV in first exciton energy) for the first time by adjusting growth temperature and growth time. In this region, the Stokes shift increases as decreasing size, which is testimony to the highly quantum confinement effect of ultra-small sized PbS NQDs. To find out the electrical properties, we fabricate self-assembled films of PbS NQDs using layer by layer (LBL) spin-coating method and replacing the original ligands with oleic acid to short ligands with 1, 2-ethandithiol (EDT) in the course. The use of capping ligands (EDT) allows us to achieve effective electrical transport in the arrays of solution processed PbS NQDs. These high-quality films apply to Schottky solar cell made in an glass/ITO/PbS/LiF/Al structure and thin-film transistor varying the PbS NQDs diameter 1.5~6 nm. We achieve the highest open-circuit voltage (<0.6 V) in Schottky solar cell ever using PbS NQDs with first exciton energy 2.58 eV.

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Finite element vibration analysis of nanoshell based on new cylindrical shell element

  • Soleimani, Iman;Beni, Yaghoub T.;Dehkordi, Mohsen B.
    • Structural Engineering and Mechanics
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    • v.65 no.1
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    • pp.33-41
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    • 2018
  • In this paper, using modified couple stress theory in place of classical continuum theory, and using shell model in place of beam model, vibrational behavior of nanotubes is investigated via the finite element method. Accordingly classical continuum theory is unable to correctly compute stiffness and account for size effects in micro/nanostructures, higher order continuum theories such as modified couple stress theory have taken on great appeal. In the present work the mass-stiffness matrix for cylindrical shell element is developed, and by means of size-dependent finite element formulation is extended to more precisely account for nanotube vibration. In addition to modified couple stress cylindrical shell element, the classical cylindrical shell element can also be defined by setting length scale parameter to zero in the equations. The boundary condition were assumed simply supported at both ends and it is shown that the natural frequency of nano-scale shell using the modified coupled stress theory is larger than that using the classical shell theory and the results of Ansys. The results have indicated using the modified couple stress cylindrical shell element, the rigidity of the nano-shell is greater than that in the classical continuum theory, which results in increase in natural frequencies. Besides, in addition to reducing the number of elements required, the use of this type of element also increases convergence speed and accuracy.

Corporate Social Responsibility Regulation in the Indonesian Mining Companies

  • NUSWANTARA, Dian Anita;PRAMESTI, Dhea Ayu
    • The Journal of Asian Finance, Economics and Business
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    • v.7 no.10
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    • pp.161-169
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    • 2020
  • The condition of mining companies that exploit natural resources in their business processes underline this research to emphasize on social and environmental issues. After twelve years of government regulation on CSR practices, this study investigates the factors that influence mining companies in disclosing information about corporate social responsibility based on legitimacy, stakeholders, and agency theory. Thus, independent variables are foreign ownership, company size, leverage, and the board of commissioners. The dependent variable is the corporate social reporting disclosure that is measured using GRI indexing. For sampling, we have used thirty-four Indonesian mining companies listed in IDX during the 2014-2018. out of which only fifty-two companies meet the sample criteria. All data should pass the classical assumption test to get the best estimator. Multiple linear regression is used to test the hypothesis, and the results show that the model is good, and can explain 60% of the dependent variable. Based on F-test, all four variables affect CSR practices simultaneously. The findings of this study suggest that foreign ownership and firm size influences CSR disclosure in a positive direction. However, this study did not support the hypothesis that leverage negatively affects CSR disclosure and board size measures positively affect CSR disclosure.