• Title/Summary/Keyword: size dependent effect

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Study on effect of chemical impregnation on the surface and porous characteristics of activated carbon fabric prepared from viscose rayon

  • Bhati, Surendra;Mahur, J.S.;Dixit, Savita;Chobey, O.N.
    • Carbon letters
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    • v.15 no.1
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    • pp.45-49
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    • 2014
  • In this study, synthetic viscose rayon fabric has been used for preparing activated carbon fabric (ACF), impregnated with different concentrations of $H_3PO_4$. The effect of $H_3PO_4$ impregnation on the weight yield, surface area, pore volume, chemical composition and morphology of ACF were studied. Experimental results revealed that both Brunauer-Emmett-Teller surface area and micropore volume increased with increasing $H_3PO_4$ concentration; however, the weight yield and microporosity (%) decreased. It was observed that samples impregnated at $70^{\circ}C$ (AC-70) give higher yield and higher microporosity as compared to $30^{\circ}C$ (AC-30). The average pore size of the ACF also gradually increases from 18.2 to 19 and 16.7 to $20.4{\AA}$ for $30^{\circ}C$ and $70^{\circ}C$, respectively. The pore size distribution of ACF was also studied. It is also concluded that the final ACF strength is dependent on the concentration of impregnant.

Modified DEBA for determining size dependent shear fracture energy of laminates

  • Goodarzi, M. Saeed;Hosseini-Toudeshky, Hossein
    • Steel and Composite Structures
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    • v.28 no.1
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    • pp.111-121
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    • 2018
  • It has been argued that fracture energy of composite laminates depends on their thickness and number of layers. In this paper a modified direct energy balance approach (DEBA) has been developed to evaluate the mode-II shear fracture energy for E-glass/Epoxy laminates from finite element model at an arbitrary thickness. This approach considers friction and damage/plasticity deformations using cohesive zone modeling (CZM) and nonlinear finite element modeling. The presence of compressive stress and resulting friction was argued to be a possible cause for the thickness dependency of fracture energy. In the finite element modeling, CZM formulation has been developed with bilinear cohesive constitutive law combined with friction consideration. Also ply element have been developed with shear plastic damage model. Modified direct energy balance approach has been proposed for estimation of mode-II shear fracture energy. Experiments were performed on laminates of glass epoxy specimens for characterization of material parameters and determination of mode-II fracture energies for different thicknesses. Effect of laminate thickness on fracture energy of transverse crack tension (TCT) and end notched flexure (ENF) specimens has been numerically studied and comparison with experimental results has been made. It is shown that the developed numerical approach is capable of estimating increase in fracture energy due to size effect.

Enhanced Crystallization of Bisphenol-A Polycarbonate by Organoclay in the Presence of Sulfonated Polystyrene Ionomers

  • Govindaiah, Patakamuri;Lee, Jung-Min;Lee, Seung-Mo;Kim, Jung-Hyun;Subramani, Sankaraiah
    • Macromolecular Research
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    • v.17 no.11
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    • pp.842-849
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    • 2009
  • Polycarbonate (PC)/sulfonated polystyrene (SPS) ionomer/organoclay nanocomposites were prepared by a solution intercalation process using the SPS ionomer as a compatibilizer. The effect of an organoclay on the melt crystallization behavior of the ionomer compatibilized PC were examined by differential scanning calorimetry (DSC). The melt crystallization behavior of PC was dependent on the extent of organoclay dispersion. The effect of the ionomer loading and cation size on intercalation/exfoliation efficiency of the organoclay in PC/SPS ionomer matrix was also studied using wide angle X-ray diffraction (WAXD) and transmission electron microscopy (TEM). Dispersion of the organically modified clay in the polymer matrix improved with increasing ionomer compatibilizer loadings and cation size. The SPS ionomer compatibilized PC/organoclay nanocomposite showed enhanced melt crystallization compared to the SPS ionomer/PC blend. Well dispersed organoclay nanocomposites showed better crystallization than the poorly dispersed clay nanocomposites. These nanocomposites also showed better thermal stability than the SPS ionomer/PC blend.

Junction Area Dependence of Tunneling Magnetoresistance in Spin-dependent Tunneling Junction with Natural $Al_2O_3$Barrier (자연산화 $Al_2O_3$장벽층을 갖는 스핀의존 터널링 접합에서 자기저항특성의 접합면적 의존성)

  • 이긍원;이상석
    • Journal of the Korean Magnetics Society
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    • v.11 no.5
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    • pp.202-210
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    • 2001
  • Spin dependent tunneling (SDT) junction devices of Ta/NiFe/Ta/NiFe/FeMn/NiFe/AlOx/CoFe/NiFe/Al with in-situ naturally oxidized Al barrier were fabricated using ion beam deposition and dc sputtering in UHV chamber of 10$^{-9}$ Torr. The maximum tunneling magnetoresistance (TMR) and the product resistance by junction (R$_{j}$ A) are 16-17% and 50-60 $\Omega$${\mu}{\textrm}{m}$$^2$, respectively. The values of TMR and (R$_{j}$ A) with field annealing were slightly increased. The TMR and (R$_{j}$ A) dependence versus the junction area size was observed. These results were explained by using sheet resistance effect of bottom electrode and spin channel effects.

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Limit Span/Depth Ratio for Indirect Deflection Control in Reinforced Concrete Flexural Members (철근콘크리트 휨부재의 처짐 간접제어를 위한 한계 지간/깊이-비 연구)

  • Choi, Seung-Won;Kim, Woo
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.31 no.1A
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    • pp.35-41
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    • 2011
  • In concrete structural design provisons, two methods are normally provided to control deflection; direct method and indirect method. It is more efficient to use the indirect deflection control by which the span/depth ratio is limited not to exceed an allowable deflection limit. Because actual deflections are affected by many causes, it is complicated to evaluate actual deflections. In this study, limit span/depth ratios are derived from the deflection calculated directly at the serviceability limit state in RC members. The deflection is obtained from using average curvature, which depends on materials model used. The main variables examined are tension stiffening effect, concrete strength, cross section size and compressive steel ratio. It could be appeared that more analytical consistency is secured to use the 2nd order form of tension stiffening effect. And the limit span/depth ratio is dependent on material strength, tensile and compressive steel ratio but it is independent on cross-section size.

A Meta-Analytic Review of Effects of Brain-Based Education (뇌기반 교육의 효과에 대한 메타분석)

  • Jang, Hwan Young;Jang, Bong Seok
    • Journal of Practical Engineering Education
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    • v.12 no.1
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    • pp.41-47
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    • 2020
  • This study aims to investigate effects of brain-based learning. 27 primary studies were selected through rigorous search process and analyzed through meta-analytic methods. Research findings are as follows. First, the total effect size was .67. Second, the effect of dependent variables was academic achievement, cognitive domain, and affective domain in order. Third, with respect to types of cognitive domain, the effect was self-regulation, creativity, competence, communication, and research ability in order. Fourth, the effect of affective domains was sociality, learning interest, and subject attitude in order. Fifth, regarding development of cognitive ability, the effect size was combined, brain training, learning environments, and right brain activities in order. Sixth, the effect of learning activities was memory improvement and attention enhancement in order.

A Meta-Analysis of Librarians' Job Satisfaction Studies (사서의 직무만족도에 관한 메타분석 연구)

  • Ro, Jung-Soon
    • Journal of the Korean Society for information Management
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    • v.25 no.3
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    • pp.273-296
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    • 2008
  • This study conducted meta-analysis of librarians' job satisfaction using the Hedges & Olkin's Effect Size Model. Sex and Marrage as group variables, and Total Satisfaction and 7 sub-variables(Work Itself, Salary, Promotion, Supervision, Working Conditions, Social Recognition, Self-actualization) as dependent variables were selected from 27 studies. The effect sizes between men and women were significantly different on Supervision, Working conditions, Promotion, and Social Recognition, of which first two were homogeneous. But the difference of Social Recognition was not significant in Random Effect Model. The effect sizes difference between married and unmarried were significant on Self Recognition, Salary, and Work Itself. However the difference of Work Itself was not significant in Random Effect Model. Study Year could not be a moderator.

Meta-analysis of the Effects of Obesity Management Program for Children (국내 비만아동의 비만관리프로그램의 효과에 대한 메타분석)

  • Sung, Kyung-Suk;Yoon, Young-Mi;Kim, Eun-Joo
    • Child Health Nursing Research
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    • v.19 no.4
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    • pp.262-269
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    • 2013
  • Purpose: The aims of this study is to analysis the effects of obesity management programs for children and to measure the differences in the effects by type and dependent variables in order to analyze the structures of the programs. Methods: Sixty-one peer-reviewed journals including child obesity and intervention studies published between 2000 and 2010 were included for meta-analysis. Effect size and statistics of homogeneity were by STAT 10.0. Results: A total of 61 studies were used in the analysis, and the effect size of the independent studies was determined to be -0.23 (95% CI, -0.32 ~ -0.15). Serum Leptin and Insulin were the big effect size among the studies that used dependent variables. The theses used in the research did not display publishing bias. Conclusion: Obesity management programs that have been confirmed to be effective need to be developed into regional protocols. A continuous control of obese children and research for effective intervention program are in need.

Effect of Joint Geometry on Anisotropic Deformability of Jointed Rock Masses (절리의 기하학적 속성이 절리성 암반의 이방적 변형 특성에 미치는 영향)

  • Ryu, Seongjin;Um, Jeong-Gi
    • Economic and Environmental Geology
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    • v.53 no.3
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    • pp.271-285
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    • 2020
  • In this study, a numerical experiment related to the stress-strain analysis was performed on 3-D discrete fracture network(DFN) systems based on the distinct element method to evaluate the effect of joint geometry on deformability of jointed rock masses. Using one or two joint sets with deterministic orientation, a total of 12 3-D DFN blocks having 10m cube domain were generated with different joint density and size distribution. Directional deformation modulus of the DFN cube blocks were estimated along the axis directions of 3-D cartesian coordinate. In addition, deviatoric stress directions were chosen at every 30° of trend and plunge in 3-D for some DFN blocks to examine the variability of directional deformation modulus with respect to joint geometry. The directional deformation modulus of the DFN block were found to reduce with the increase of joint size distribution. The increase in joint density was less likely to have a significant effect on directional deformation modulus of the DFN block in case of the effect of rock bridges was relatively large because of short joint size distribution. It, however, was evaluated that the longer the joint size, the increase in the joint density had a more significant effect on the anisotropic deformation modulus of the DFN block. The variation of the anisotropic deformation modulus according to the variations in joint density and size distribution was highly dependent on the number of joint sets and their orientation in the DFN block. Finally, this study addressed a numerical procedure for stress-strain analysis of jointed rock masses considering joint geometry and discussed a methodology for practical application at the field scale.

A Study on Electrode Preparation for Alkaline Fuel Cell (알칼리 연료전지 전극제조에 관한 연구)

  • Hong, Jin Ki;Lee, Kyung Ju;Lee, Wha Young
    • Journal of Hydrogen and New Energy
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    • v.2 no.1
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    • pp.57-67
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    • 1990
  • This study is proposed to investigate the effect of electrode preparation method for Alkaline Fuel Cell using NaOH as an electrolyte on the Fuel Cell performance. The materials used for the preparation of electrode are Pt and Ag on Vulcan XC-72. Surface area of Vulcan XC-72 have different values according to the pretreatment conditions and the dispersion of Pt is dependent on the impregnation Particle size of Pt impregnated on unpretreated carbon was observed to be $20{\sim}40{\AA}$ and that on pretreated carbon in $N_2$ stream at $950^{\circ}C$ was found to be finely dispersed less then $15{\AA}$. The electrode performance was affected by the particle size of metals and operating temperature. It was revealed from this study that the optimum particle size about $30{\AA}$ and optimum temperature range is between $90{\sim}100^{\circ}C$.

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