• Title/Summary/Keyword: size dependence

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Gel Electrophoresis Analysis of the Hard Coronas of Human Serum Albumin on Silica Nanoparticles: Size Dependence of Corona Formation

  • Kim, Sung-Jong;Han, Sang Yun
    • Bulletin of the Korean Chemical Society
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    • v.35 no.9
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    • pp.2621-2624
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    • 2014
  • The rapid and spontaneous adsorption of proteins on nanoparticle (NP) surfaces in biological fluids such as blood is an important phenomenon as it possibly determines "what the cells see" and, thus, the fates of NPs in living organisms. In order to quantitatively understand protein coronas at the molecular level, we investigated human serum albumin (HSA) coronas that were produced on silica NPs of 20 nm and 50 nm diameters using conventional gel electrophoresis. Analysis of the concentration dependence of protein adsorption showed that HSA coronas preferentially formed a monolayer on silica NPs and revealed the presence of hard protein coronas. HSA adsorption was clearly dependent on NP size, and this might be due to the different surface curvatures of NPs of different sizes.

Temperature Dependence of Galvanomagnetic Properties in Thin Bi Film

  • Nam, S.W.
    • Journal of Magnetics
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    • v.4 no.4
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    • pp.111-114
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    • 1999
  • Numerical calculation for temperature dependence of galvanomagnetic properties of thin bismuth films is pursued. The quasi-two dimensional system is treated in the perturbation formalism of previous study, where realistic screened potential due to impurity is assumed to be the only scattering channel. The potential is separated into pure two dimensional part and the remaining presumed perturbation part. Relaxation time and mobilities for both electron and hole are evaluated, then temperature dependence of the Hall coefficient and magnetoresistance is obtained. The broad minimum of magnetoresistnace is manifested, and the interpretation under the kinetic theory is made. Thickness dependence of the quantities are also shown, which are in good agreement with the expected quantum size effect.

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Changes in the Orientation and Frequency Dependence of Target Strength due to Morphological Differences in the Fish Swim Bladder (어류 부레의 형태학적 차이에 따른 음향산란강도의 자세 및 주파수 의존성의 변화)

  • Lee, Dae-Jae
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.48 no.2
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    • pp.233-243
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    • 2015
  • Controlled broadband acoustic scattering laboratory experiments were conducted using a linear chirp signal (95-220 kHz), and x-ray images of live and model fish with an artificial swim bladder were analyzed to investigate the changes in orientation and frequency dependence of target strength (TS) due to morphological differences in fish swim bladders. The broadband echoes from live and model fish were measured over an orientation angle range of ${\pm}45^{\circ}$ in the dorsal plane and in approximately $1^{\circ}$ increments. The location of nulls in the simulated echo response of the SINC [sinc function] model was overlaid on the TS map, showing the orientation and frequency dependence of fish TS, and they matched very well. It was possible to infer the equivalent fish scattering size (or swim bladder) using the null spacing in the experimentally obtained broadband TS map. Good agreement was observed for inferring the equivalent scattering size between the SINC model and the broadband echoes measured for the three fish species (black scraper Thamnaconus modestus; goldeye rockfish Sebastes thompsoni; and whitesaddled reef fish Chromis notatus). Some results of this inference are discussed.

Efficient Dynamic Slicing of Object-Oriented Program

  • Park, Soon-Hyung
    • Proceedings of the Korea Society for Industrial Systems Conference
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    • 2008.10b
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    • pp.651-655
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    • 2008
  • Traditional slicing techniques make slices through dependence graphs. They also improve the accuracy of slices. However, traditional slicing techniques require many vertices and edges in order to express a data communication links. Therefore the graph becomes complicated, and size of the slices is larger. We propose the representation of a dynamic object-oriented program dependence graph so as to process the slicing of object-oriented programs that is composed of related programs in order to process certain jobs. The efficiency of the proposed efficient dynamic object-oriented program dependence graph technique is also compared with the dependence graph techniques discussed previously. As a result, this is certifying that an efficient dynamic object-oriented program dependence graph is more efficient in comparison with the traditional dynamic object-oriented program dependence graph.

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Optical properties of InAs quantum dots with different size (InAs 양자점의 크기에 따른 분광학적 특성)

  • 권영수;임재영;이철로;노삼규;유연희;최정우;김성만;이욱현;류동현
    • Journal of the Korean Vacuum Society
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    • v.8 no.4A
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    • pp.450-455
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    • 1999
  • We present Photoluminescence (PL) and Atomic Force Microscopy (AFM) image on InAs quantum dots (QDs) having different size which grown by Molecualr Beam Epitaxy (MBE). For different size QDs, analysis of the AFM profiles show that the density of QDs was the maximum value $(1.1\times10^{11}\textrm{/cm}^2)$ at 2.0 ML. In the spectra of QDs, it is found that the peak energy decreases with increasing dot size due to the effect of quantum confinement. Temperature dependence of PL intensities show that the PL is quenching and Red shift as the temperature increase. The FWHM range of 20K~180K is narrowing with increasing temperature. When temperature is over 180K, the line-width starts to in creases with increasing temperature. At last, temperature dependence of the integrated intensities were fit using the Arrehenius-type function for the activation energy. Fit value of the activation energy was increased with increasing QDs-size.

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The Relation of Crystallite Size and Ni2+ Content to Ferromagnetic Resonance Properties of Nano Nickel Ferrites

  • Lafta, Sadeq H.
    • Journal of Magnetics
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    • v.22 no.2
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    • pp.188-195
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    • 2017
  • The ferromagnetic resonance and other magnetic properties dependence on $Ni^{2+}/Fe^{3+}$ ratio and crystallite size were investigated for nano nickel ferrite ($NiFe_2O_4$). The crystallite size was controlled by controlling the nickel content in the starting material solution. The XRD and TEM were utilized to measure the crystallite size through Scherrer formula and particle size respectively. The most frequent particle sizes were lower than crystallite size, which ranged from 16.5 to 44.65 nm. The general behavior of M-H loop shapes and parameters showed superparamagnetic one. The saturation magnetization had a maximum value at $Ni^{2+}/Fe^{3+}$ molar ratio equal to 0.186. The FMR signals showed, generally, broad linewidths, where the maximum width and minimum resonance field were for the sample of the lowest crystalline size. Furthermore, FMR resonance field shows linear dependence on crystalline size. The fitting relation was estimated to express this linear dependency on the base of behavior coincidence between particle size and the inverse of saturation magnetization. The given interpretations to understand the intercept and the slope meanings of the fitted relation were based on Larmor equation, and inhomogeneous in the anisotropy constant.

Frequency Dependence of High-Frequency Bottom Reflection Loss Model (주파수 종속성을 갖는 고주파 해저면 반사손실 모델)

  • 박순식;윤관섭;나정열;석동우;주진용;조진석
    • The Journal of the Acoustical Society of Korea
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    • v.23 no.5
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    • pp.362-369
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    • 2004
  • The High-frequency (30 ∼ 120 ㎑) bottom reflection loss at rough water-sediment interface is affected by the gram size distribution of the sediments. The roughness of the bottom surface is represented by "acoustical roughness. g/sub R/" The grain size of sandy sediments is g/sub R/∼O(1) and the dependence as a function of frequency. We suggest the modified bottom reflection loss model (HYBRL model , HanYang university Bottom Reflection Loss model) that include in the deviation of the reflection loss as a function of the grain size distribution and frequency dependence. And bottom reflection loss model of frequency dependence and deviation of bottom properties is verified by water tank and field experiments.

Size dependence of Cation Distribution in Magnetic Nanoparticles (자성 나노입자에서 양이온 분포의 크기 의존성)

  • Cho, Jun-Hee;Ko, Sang-Kil;Lee, Hwan;Ahn, Yang-Kyu;Song, Ki-Chang;Choi, Eun-Jung
    • Journal of the Korean Magnetics Society
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    • v.16 no.1
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    • pp.60-65
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    • 2006
  • In order to investigate the dependence of the particle size on the cation distribution in the spinel structure, Mossbauer spectra were taken in the presence of an external magnetic field f3r the magnetic nanoparticles prepared by using a microemulsion method. The crystals are found to have a cubic structure. The results show that as the particle sizes decrease, $Fe^{3+}$ ions migrate from the octahedral site to tetrahedral site.

Size Distribution and Temperature Dependence of Magnetic Anisotropy Constant in Ferrite Nanoparticles

  • Yoon, Sunghyun
    • Proceedings of the Korean Magnestics Society Conference
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    • 2012.11a
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    • pp.104-105
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    • 2012
  • The temperature dependence of the effective magnetic anisotropy constant K(T) of ferrite nanoparticles is obtained based on the measurements of SQUID magnetometry. For this end, a very simple but intuitive and direct method for determining the temperature dependence of anisotropy constant K(T) in nanoparticles is introduced in this study. The anisotropy constant at a given temperature is determined by associating the particle size distribution f(r) with the anisotropy energy barrier distribution $f_A(T)$. In order to estimate the particle size distribution f(r), the first quadrant part of the hysteresis loop is fitted to the classical Langevin function weight-averaged with the log?normal distribution, slightly modified from the original Chantrell's distribution function. In order to get an anisotropy energy barrier distribution $f_A(T)$, the temperature dependence of magnetization decay $M_{TD}$ of the sample is measured. For this measurement, the sample is cooled from room temperature to 5 K in a magnetic field of 100 G. Then the applied field is turned off and the remanent magnetization is measured on stepwise increasing the temperature. And the energy barrier distribution $f_A(T)$ is obtained by differentiating the magnetization decay curve at any temperature. It decreases with increasing temperature and finally vanishes when all the particles in the sample are unblocked. As a next step, a relation between r and $T_B$ is determined from the particle size distribution f(r) and the anisotropy energy barrier distribution $f_A(T)$. Under the simple assumption that the superparamagnetic fraction of cumulative area in particle size distribution at a temperature is equal to the fraction of anisotropy energy barrier overcome at that temperature in the anisotropy energy barrier distribution, we can get a relation between r and $T_B$, from which the temperature dependence of the magnetic anisotropy constant was determined, as is represented in the inset of Fig. 1. Substituting the values of r and $T_B$ into the $N{\acute{e}}el$-Arrhenius equation with the attempt time fixed to $10^{-9}s$ and measuring time being 100 s which is suitable for conventional magnetic measurement, the anisotropy constant K(T) is estimated as a function of temperature (Fig. 1). As an example, the resultant effective magnetic anisotropy constant K(T) of manganese ferrite decreases with increasing temperature from $8.5{\times}10^4J/m^3$ at 5 K to $0.35{\times}10^4J/m^3$ at 125 K. The reported value for K in the literatures is $0.25{\times}10^4J/m^3$. The anisotropy constant at low temperature region is far more than one order of magnitude larger than that at 125 K, indicative of the effects of inter?particle interaction, which is more pronounced for smaller particles.

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Cloud Generation Using a Huge Vertical Mine

  • Ma, Chang-Jin
    • Journal of Korean Society for Atmospheric Environment
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    • v.22 no.E2
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    • pp.78-88
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    • 2006
  • In order to study the characteristics of cloud, a real-scale experiment for cloud generation was carried out using an extinct vertical mine (430 m height) located in the northeastern Honshu, Japan. The dry particles generated from the three-step concentrations of NaCl solutions were used for cloud generation. The number size distributions of initial dry particles and cloud droplets were monitored by Scanning Mobility Particle Sizer (SMPS) and Forward Scattering Spectrometer Probe (FSSP) at bottom and upper sites of pit, respectively. The polymeric water absorbent film (PWAF) method was employed to measure liquid water content ($W_L$) as a function of droplet size. Moreover the chemical properties of individual droplet replicas were determined by micro-PIXE. The CCN number concentration shows the lognormal form in dependence of the particle size, while the number size distributions of droplets are bimodal showing the peaks around $9{\mu}m$ and $20{\mu}m$ for every case. In comparison to background mineral particles, right shifting of size distribution line for NaCl particles was occurred. When NaCl solutions with three-step different concentrations were neulized, $W_L$ shows the strong droplet size dependence. It varied from $10.0mg\;m^{-3}$ up to $13.6mg\;m^{-3}$ with average $11.6mg\;m^{-3}$. A good relationship between $W_L$ and cloud droplet number concentration was obtained. Both chemical inhomogeneities (mixed components with mineral and C1) and homogeneities (only mineral components or C1) in individual droplet replicas were obviously observed from micro-PIXE elemental images.