• Computers and Concrete
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• v.26 no.1
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• pp.31-52
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• 2020

This paper investigates the size dependent effect on the vibration analysis of a porous nanocomposite viscoelastic plate reinforced by functionally graded-single walled carbon nanotubes (FG-SWCNTs) by considering nonlocal strain gradient theory. Therefore, using energy method and Hamilton's principle, the equations of motion are derived. In this article, the effects of nonlocal parameter, aspect ratio, strain gradient parameter, volume fraction of carbon nanotubes (CNTs), damping coefficient, porosity coefficient, and temperature change on the natural frequency are perused. The innovation of this paper is to compare the effectiveness of each mentioned parameters individually on the free vibrations of this plate and to represent the appropriate value for each parameter to achieve an ideal nanocomposite plate that minimizes vibration. The results are verified with those referenced in the paper. The results illustrate that the effect of damping coefficient on the increase of natural frequency is significantly higher than the other parameters effect, and the effects of the strain gradient parameter and nonlocal parameter on the natural frequency increase are less than damping coefficient effect, respectively. Furthermore, the results indicate that the natural frequency decreases with a rise in the nonlocal parameter, aspect ratio and temperature change. Also, the natural frequency increases with a rise in the strain gradient parameter and CNTs volume fraction. This study can be used for optimizing the industrial and medical designs, such as automotive industry, aerospace engineering and water purification system, by considering ideal properties for the nanocomposite plate.

• Proceedings of the Korean Vacuum Society Conference
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• 2010.02a
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• pp.393-393
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• 2010

The biocompatibility of materials used for biomedical applications depends on chemical composition, mechanical stiffness, surface energy, and roughness. The plasma treatment and etching process is a very important technology in the biomedical fields due to possibility of controlling the surface chemistry and properties of materials. In this work, $N_2/H_2$ plasma were treated on single-walled carbon nanotubes (SWCNTs) paper and characterization of treated SWCNTs paper was carried out. Also we investigated neurite outgrowth from SH-SY5Y on treated SWCNTs paper. The results indicated that $N_2/H_2$ plasma-modified SWCNTs paper enhanced neuronal cell adhesion, viability, neurite outgrowth and branching in vitro and exerted a positive role on the health of neural cells.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2010.06a
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• pp.264-264
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• 2010

Single-walled carbon nanotubes (SWCNTs) were grown on a Si wafer by using thermal chemical vapor deposition (t-CVD). We investigated the effect of the catalyst deposition rate on the types of CNTs grown on the substrate. In general, smaller islands of catalyst occur by agglomeration of a catalyst layer upon annealing as the catalyst layer becomes thinner, which results in the growth of CNTs with smaller diameters. For the same thickness of catalyst, a slower deposition rate will cause a more uniformly thin catalyst layer, which will be agglomerated during annealing, producing smaller catalyst islands. Thus, we can expect that the smaller-diameter CNTs will grow on the catalyst deposited with a lower rate even for the same thickness of catalyst. The 0.5-nm-thick Fe served as a catalyst, underneath which Al was coated as a catalyst support as well as a diffusion barrier on the Si substrate. The catalyst layers were. coated by using thermal evaporation. The deposition rates of the Al and Fe layers varied to be 90, 180 sec/nm and 70, 140 sec/nm, respectively. We prepared the four different combinations of the deposition rates of the AI and Fe layers. CNTs were synthesized for 10 min by flowing 60 sccm of Ar and 60 sccm of $H_2$ as a carrier gas and 20 sccm of $C_2H_2$ as a feedstock at 95 torr and $810^{\circ}C$. The substrates were subject to annealing for 20 sec for every case to form small catalyst islands prior to CNT growth. As-grown CNTs were characterized by using field emission scanning electron microscopy, high resolution transmission electron microscopy, Raman spectroscopy, UV-Vis NIR spectroscopy, and atomic force microscopy. The fast deposition of both the Al and Fe layers gave rise to the growth of thin multiwalled CNTs with the height of ${\sim}680\;{\mu}m$ for 10 min while the slow deposition caused the growth of ${\sim}800\;{\mu}m$ high SWCNTs. Several radial breathing mode (RBM) peaks in the Raman spectra were observed at the Raman shifts of $113.3{\sim}281.3\;cm^{-1}$, implying the presence of SWCNTs (or double-walled CNTs) with the tube diameters 2.07~0.83 nm. The Raman spectra of the as-grown SWCNTs showed very low G/D peak intensity ratios, indicating their low defect concentrations.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.10 no.5
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• pp.131-136
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• 2011

Many researchers are recently studying about Electroactive polymer(EAP). But it has a physical limitation, because of property of material. Carbon nanotube(CNT) is known as the promising material which has excellent electro-mechanical characteristics and is mostly defect-free. It is expected that a successful synthesis of CNT and Nafion known as a primary material for IPMC would make a great improvement on its electro-mechanic feature. This study focuses on the method of synthesis of CNT with Nafion which improves electro-mechanical characteristic. To come up with mechanical dispersion with Nafion and Isopropyl Alcohol(IPA), we dispersed Single-walled carbon nanotubes(SWCNTs). For a uniformly layer of CNT, we used a spray gun on a hot plate by a simplified method. We fabricated a disperse SWCNT/Nafion composite uniformly. Through the use of the E-beam evaporator to form an uniform electrode layer, we consummated the IPMC actuator. This result shows improving 1.5 times mechanical properties about driving force in IPMC.

• Polymer(Korea)
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• v.35 no.6
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• pp.615-618
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• 2011

Carbon nanotubes (CNTs) draw attention as promising materials due to their excellent electrical and mechanical properties. However, the intrinsic strong interaction between CNTs presents a challenge to their use in various applications. Here, we present a facile method to disperse single-walled carbon nanotubes (SWCNTs) in a polar solution using a graft copolymer, poly(vinyl chloride)-graft-poly(oxyethylene methacrylate), PVC-g-POEM. The graft copolymer was synthesized via atom transfer radical polymerization (ATRP), as confirmed by gel permeation chromatography (GPC) and $^1H$ NMR spectroscopy. The SWCNTs were uniformly dispersed in a polar solvent such as dimethylsiloxane (DMSO) using PVC-g-POEM as a dispersant, due to interaction between CNT and the graft copolymer, as revealed by transmission electron microscopy (TEM) analysis. Upon removal of the solvent, free standing nanocomposite films with good homogeneity were obtained.

• Geomechanics and Engineering
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• v.12 no.2
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• pp.327-346
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• 2017

Laminated plates have many applications in different industrials. Buckling analysis of these structures with the nano-scale reinforcement has not investigated yet. However, buckling analysis of embedded laminated plates with nanocomposite layers is studied in this paper. Considering the single-walled carbon nanotubes (SWCNTs) as reinforcement of layers, SWCNTs agglomeration effects and nonlinear analysis using numerical method are the main contributions of this paper. Mori-Tanaka model is applied for obtaining the equivalent material properties of structure and considering agglomeration effects. The elastic medium is simulated by spring and shear constants. Based on first order shear deformation theory (FSDT), the governing equations are derived based on energy method and Hamilton's principle. Differential quadrature method (DQM) is used for calculating the buckling load of system. The effects of different parameters such as the volume percent of SWCNTs, SWCNTs agglomeration, number of layers, orientation angle of layers, elastic medium, boundary conditions and axial mode number of plate on the buckling of the structure are shown. Results indicate that increasing volume percent of SWCNTs increases the buckling load of the plate. Furthermore, considering agglomeration effects decreases the buckling load of system. In addition, it is found that the present results have good agreement with other works.

• Advances in concrete construction
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• v.13 no.6
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• pp.451-459
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• 2022

In present study, the nonlocal Flügge shell model based is utilized to investigate the vibration characteristics of armchair and chiral single-walled carbon nanotubes with impact of small-scale effect subjected to two boundary supports. The wave propagation approach is employed to determine eigen frequencies for armchair and chiral tubes. The fundamental frequencies scrutinized with assorted aspect ratios by varying the bending rigidity. The raised in value of nonlocal parameter reduces the corresponding fundamental frequency. It is investigated with higher aspect ratio, the boundary conditions have a momentous influence on vibration of CNT. It is concluded that frequencies would increase by increasing of the bending rigidity. Solutions of the frequency equation have determined by writing in MATLAB coding.

• Korean Chemical Engineering Research
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• v.61 no.3
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• pp.456-462
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• 2023

An electrically conductive and transparent electrode was created by applying a dispersion of pristine single-walled carbon nanotubes (SWCNTs) and silver nanowires to a polyethylene terephthalate (PET) film using a bar coating method. The SWCNTs were added to increase the electrical conductivity and transmittance of the silver nanowires while also preventing the haze from increasing due to the stacking of multiple layers containing SWCNTs and silver nanowires on the PET substrate. The silver nanowires in the electrode were also found to be stable against oxidation. The transparent electrode displayed excellent electrical and optical properties, with a sheet resistance of 47 Ω/□, transmittance of 96.72%, and haze of 1.93%. Additionally, the sheet resistance of the electrode remained stable over time, with a change of only 6.4% after a constant temperature and humidity test, making it suitable for long-term use. A hybrid transparent electrode that is economically feasible and environmentally sustainable has been developed through the utilization of pristine SWCNT and silver nanowire.

• Steel and Composite Structures
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• v.25 no.3
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• pp.315-326
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• 2017

In this work, thermoelastic dynamic behavior of functionally graded carbon nanotube reinforced composite (FG-CNTRC) cylinders subjected to mechanical pressure loads, uniform temperature environment or thermal gradient loads is investigated by a mesh-free method. The material properties and thermal stress wave propagation of the nanocomposite cylinders are derived after solving of the transient thermal equation and obtaining of the time history of temperature field of the cylinders. The nanocomposite cylinders are made of a polymer matrix and wavy single-walled carbon nanotubes (SWCNTs). The volume fraction of carbon nanotubes (CNTs) are assumed variable along the radial direction of the axisymmetric cylinder. Also, material properties of the polymer and CNT are assumed temperature-dependent and mechanical properties of the nanocomposite are estimated by a micro mechanical model in volume fraction form. In the mesh-free analysis, moving least squares shape functions are used to approximate temperature and displacement fields in the weak form of motion equation and transient thermal equation, respectively. Also, transformation method is used to impose their essential boundary conditions. Effects of waviness, volume fraction and distribution pattern of CNT, temperature of environment and direction of thermal gradient loads are investigated on the thermoelastic dynamic behavior of FG-CNTRC cylinders.

• Structural Engineering and Mechanics
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• v.53 no.3
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• pp.497-517
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• 2015

In this study, nonlocal nonlinear buckling analysis of embedded polymeric temperature-dependent microplates resting on an elastic matrix as orthotropic temperature-dependent elastomeric medium is investigated. The microplate is reinforced by single-walled carbon nanotubes (SWCNTs) in which the equivalent material properties nanocomposite are estimated based on the rule of mixture. For the carbon-nanotube reinforced composite (CNTRC) plate, both cases of uniform distribution (UD) and functionally graded (FG) distribution patterns of SWCNT reinforcements are considered. The small size effects of microplate are considered based on Eringen's nonlocal theory. Based on orthotropic Mindlin plate theory along with von K$\acute{a}$rm$\acute{a}$n geometric nonlinearity and Hamilton's principle, the governing equations are derived. Generalized differential quadrature method (GDQM) is applied for obtaining the buckling load of system. The effects of different parameters such as nonlocal parameters, volume fractions of SWCNTs, distribution type of SWCNTs in polymer, elastomeric medium, aspect ratio, boundary condition, orientation of foundation orthtotropy direction and temperature are considered on the nonlinear buckling of the microplate. Results indicate that CNT distribution close to top and bottom are more efficient than those distributed nearby the mid-plane for increasing the buckling load.