• Title/Summary/Keyword: single ion exchange

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Properties of Substrate Glass by Single ion Exchange Process (단일이온교환 공정에 따른 기판유리의 특성)

  • 이회관;이용수;강원호
    • Journal of the Microelectronics and Packaging Society
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    • v.9 no.3
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    • pp.25-29
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    • 2002
  • Single ion exchange process was used, and the ion exchange behavior and mechanical properties were investigated in substrate glass for flat panel display. In order to study the effects of ion exchange, ion exchange behavior with ion penetration depth, amount of ion exchange, density and thermal expansion was measured according to the time and temperature. The mechanical properties were evaluated by the three point bending test and curvature change, and then the fracture patterns were investigated by optical microscope.

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Characteristics of Ammonium ion-exchange of Zeolit 4A synthesized from Coal Fly Ash (유연탄 Fly ash로부터 합성한 제올라이트 4A의 암모늄 이온교환 특성)

  • 연익준;박상찬;김광렬
    • Journal of environmental and Sanitary engineering
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    • v.14 no.1
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    • pp.42-53
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    • 1999
  • A study on the synthesis of zeolite from coal fly ash from power plant was carried out to reduce environmental problems and reuse industrial waste. The synthesized zeolite was proved to be Zeolite 4A type by means of the XRD and SEM analysis, and then the synthesized zeolite was used as an absorbent to remove the $NH_4^+$ ions in the wastewater and water. In the ion exchange of single $NH_4^+$ ions by the natural zeolite and the synthesized zeolite, the ion exchange reached equilibrium within 10 min. and 1hr, respectively. The amount of ion exchanged $NH_4^+$ to the unit weight of natural zeolite and zeolite 4A were 1.09 and 3.54 meq/g respectively, and the amount of $NH_4$ ion exchanged by the synthesized zeolite was higher than by the natural zeolite. The ion exchange kinetics fitted very well to the Feundlich and Langmuir isotherm. The effects of coexisting cations on the ion-exchange properties of zeolites were studied in order to apply them to water treatment. In the bisolute-system of the $NH_4^+-K^+$ and $NH_4^+-Na^+$ systems, the ion exchange capacity was smaller than the single $NH_4^+$ ion system. The effects of coexisting cations on the ion exchange system by the natural zeolite and the synthesized zeolite were found to be $K^+>Na^+$ and $Na^+>K^+>>Mg^{2+}>Ca^{2+}$, respectively.

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Equilibrium Property of Ion Exchange Resin for Silica Removal at Ultralow Concentration (초저이온농도에서 이온교환수지에 의한 실리카제거 평형특성)

  • Yoon, Tae-Kyung;Lee, Gang-Choon;Noh, Byeong-Il
    • Journal of Environmental Science International
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    • v.16 no.8
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    • pp.907-912
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    • 2007
  • Ion exchange resin was used to remove silica ion at ultralow concentration. The effects of temperature, type of ion exchange resin and single/mixed-resin systems on removal efficiency were estimated. As temperature increased, the slope of concentration profile became stiff, and the equilibrium concentration was higher. In the single resin system, the removal of silica was continued up to 400 min, but the silica concentration was recovered to initial concentration after 400 min due to the effect of dissolved $CO_2$. In the mixed-resin system it took about 600 min to reach equilibrium. Because of faster cation exchange reaction than anion exchange reaction, the effect of $CO_2$ could be removed. Based on the experimental results carried out in the mixed-resin system, the selectivity coefficients of silica ion for each ion exchange resin were calculated at some specific temperatures. The temperature dependency of the selectivity coefficient was expressed by the equation of Kraus-Raridon type.

Strengthening of Substrate Glass for LCD by Single ton Exchange Process (Single Ion Exchange Process에 의한 LCD용 기판유리의 강화)

  • 이회관;오영석;이용수;강원호
    • Journal of the Korean Ceramic Society
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    • v.39 no.7
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    • pp.675-679
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    • 2002
  • To produce a strengthened glass, single ion exchange properties such as three-point bend strength and residual stress were investigated in soda-lime-silicate substrate glass for display use. The present work showed that the maximum value of strength was 62.5${\times}$10$\sub$6/ kg/㎡ after, the two-step single ion exchange process at 470$^{\circ}C$ for 1 h and 450$^{\circ}C$ for 24 h. As the result of the fracture analysis after bending test, the residual stress on the fractured surface of the strengthened glass increased the flexibility by means of absorbing the elastic deformation energy in the glass. Also, the effects of absorbing the elastic deformation energy were analysed by curvature change, number of multiple crack branches and brittleness.

Ion Exchange Behavior of Soda-Lime-Silicate Glass by Advanced Ion Exchange Process (새로운 이온교환 프로세스에 의한 Soda-Lime-Silicate 유리의 이온교환 거동)

  • 이회관;황성건;이용수;강원호
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.5 no.2
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    • pp.98-102
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    • 2004
  • Ion exchange behavior and property change of soda-lime-silicate glass by advanced ion exchange process were investigated. Refractive index, specific gravity and optical transmittance were changed similarly to $K^+$ ion penetration depth, and amount of ion exchange increased with the increase of the time and temperature. Especially, thermal expansion decreased greatly because of the structural compaction and residual stress by ion exchange process.

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Analysis and Measurement of Effective Refractive Indices with Ion-exchanged Slab Waveguide (이온교환 평판도파로의 실효굴절율 측정 및 해석)

  • 천석표;박정일;박태성;정홍배
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1995.05a
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    • pp.73-76
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    • 1995
  • In this study, the slab waveguide was fabricated using potassium-nitride(KNO$_3$) or silver-nitride (AgNO$_3$) molten sources by ion-exchange process. The effective refractive indices of waveguide were measured by Prism-Coupling method. and The characteristics of waveguide(mode dispersion, effective diffusion depth. surface refractive index, diffusion coefficient, and refractive index profile etc,) were investigated by WKB method, In the case of potassium ion-exchange, the computer calculation showed that the refractive index profile of waveguide followed Gaussian function, the surface refractive index increased with ion-exchange time and the effective diffusion depth increased a little as ion-exchange time increased, while the surface refractive index of silver ion-exchanged waveguide decreased with ion-exchange time because of the ion depletion on the surface of waveguide, and the effective diffusion depth seriously with ion-exchange tim. Double ion-exchanged waveguide was fabricated by performing silver ion-exchange after potassium ion-exchange. Double ion-exchanged waveguide had a tight mode binding force since the surface refractive index was larger than single step ion-exchanged waveguide.

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Determination of Stress Profiles by Fractography in Single Ion-exchanged Glass (파괴분석을 이용한 단일이온교환된 유리의 응력 형성 관찰)

  • 이회관;강원호
    • Journal of the Microelectronics and Packaging Society
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    • v.10 no.4
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    • pp.61-64
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    • 2003
  • The fractography was used to observe the stress profile on a single ion-exchanged glass. In the processing, the temperature was varied during the ion exchange, and then the stress profile on the single ion-exchanged glass was shifted from glass surface to slightly below the glass surface. The hackle mark and mirror surface were varied according to process conditions, and the glass strength was increased with increasing the number of hackle markers. In case of breaking the stress profile by using indenter, the breaking property was similar to the annealed glass.

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Improvement of Mechanical Property by Single Ion Exchange Process in Substrate Glass

  • Lee, Hoi-Kwan;Kang, Won-Ho;Green, David J.
    • Journal of Information Display
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    • v.4 no.3
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    • pp.12-16
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    • 2003
  • In connection with the ion exchange strengthening on soda-lime-silicate, substrate glass for display use was investigated. In the processing, the temperature was varied during the ion exchange in order to make stress profile and to determine optimum condition. In the present work, we found that the maximum value of strength was 617.8 MPa after an ion exchange process at 470 $^{\circ}C$ for 1h, and then, at 450 $^{\circ}C$ for 24h. Also, the effect of residual stress placed on the near surface was measured by analyzing the number of crack branches and brittleness. This approach allowed us the residual stress profile to be engineered to improve mechanical reliability.

Characterization of Commercial Membranes for Non-aqueous Vanadium Redox Flow Battery (비수계 바나듐 레독스 흐름 전지를 위한 상용 멤브레인의 특성분석)

  • Sung, Ki-Won;Shin, Sung-Hee;Moon, Seung-Hyeon
    • Korean Chemical Engineering Research
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    • v.51 no.5
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    • pp.615-621
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    • 2013
  • Membrane characterization methods for aqueous redox flow batteries aqueous RFBs were modified for non-aqueous RFBs. The modified characterization methods, such as ion exchange capacity, transport number, permeability and single cell test, were carried out to evaluate commercial membranes in non-aqueous electrolyte. It was found that columbic efficiency and energy efficiency in a single cell test were dependent on the ion selectivity of commercial anion exchange membranes. Neosepta AHA anion exchange membrane showed the anion transport number of 0.81, which is a relatively low ion selectivity in non-aqueous electrolyte, however, exhibited 92% of coulombic efficiency and 86% of energy efficiency in a single cell test. It was also found that a porous membrane without ion selectivity is suitable for a non-aqueous redox flow battery at a high current density.