• Title/Summary/Keyword: single grain

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Sintering of Surface-Modified PMN-PT-BT Powder with MgO Sol and Its Dielectric Properties (MgO 졸로 표면개질된 PMN-PT-BT 분말의 소결 및 유전특성)

  • Han, Kyoung-Ran;Kim, Chang-Sam
    • Journal of the Korean Ceramic Society
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    • v.41 no.12 s.271
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    • pp.929-932
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    • 2004
  • It is known that small amount of MgO in excess is often added to develop pure perovskite single phase of PMN-based composite, however, extra MgO precipitates in grains and inhibits densification of PMN. In this study PMN-PT-BT (PBT) powder was prepared by a conventional mixed oxide method using $(MgCO_3)_4{\cdot}Mg(OH)_2{\cdot}5H_{2}O$ instead of MgO. The precursor was heated at $500^{\circ}C/1h$ and its surface was modified with MgO sol. This effect was investigated in the aspects of sintering and dielectric properties. Small amount of added MgO sol ($0.5{\sim}1.0wt\%$) enhanced sintering substantially below $1000^{\circ}C$. The PBT with $0.5wt\%$ MgO sol sintered at $900^{\circ}C/2h$ had density of $7.62\;g/cm^3$, room temperature dielectric constant of 14800, loss of dielectric constant of $1.1\%$, which were comparable to those of the PBT sintered at $1000^{\circ}C/2h$. It was noticeable that the extra MgO precipitated mostly on triple points and grain boundaries and resulted in inhibition of grain growth.

Development of molybdenum silicides for hydrogen fueled combustion turbine by mechanical alloying (기계적 합금화에 의한 수소연소 터어빈용 Mo-Si계 금속간화합물의 개발에 관한 연구)

  • 이충효
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.7 no.4
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    • pp.665-672
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    • 1997
  • We applied mechanical alloying process by ball milling to produce molybdenum silicides $MoSi_2$ and $Mo_5Si_3$ using a mixture of elemental molybdenum and silicon powders at room temperature. The intermetallic compound MoSi$_3$ have been obtained by ball milling of $Mo_{33}Si_{67}$ mixture powders for 100 h, which is transformed to single $MoSi_2$ phase by subsequent heat treatment up to $725^{\circ}C$. The grain size of the $MoSi_2$ powders thus obtained was 19 nm, being approximately four times smaller than that of the commercial alloy. The intermetallic compound $MoSi_2$ with grain size of 30 nm have been also obtained by ball milling of $Mo_{62}Si_{38}$ mixture powders for 500 h, which is transformed to single $MoSi_2$ phase by heating up to $1000^{\circ}C$. We believe that the retarded ball milling time for the formation of $MoSi_2$ phase is attributed to its complicated crystal structure and large unit cell. The finer grain size in the ball-milled molybdenum silicides powders is expected to improve room-temperature mechanical properties for high-temperature structural materials.

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Age comparisons of coastal sand dune stratum in Chollipo, Korea by altering preheat and cut-heat, and grain size distributions by OSL dating (예열 및 cut-heat 온도와 입자의 크기에 따른 천리포 해안사구 퇴적층의 OSL 연대측정 비교)

  • Bang, Jun-Hwan;Kim, Ki-Dong;Eum, Chul-Hun
    • Analytical Science and Technology
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    • v.22 no.1
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    • pp.51-56
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    • 2009
  • The samples from coastal sand dune stratum in Chollipo were dated by Optically Stimulated Luminescence (OSL) with modified Single Aliquots Regeneration (SAR) method. It is possible to choose the OSL signals by thermal treatments such as preheat and cut-heat in SAR procedure. Preheat and cut-heat of $260^{\circ}C$ for 10 sec $-220^{\circ}C$ for 0 sec, and $270^{\circ}C$ for 10 sec $-270^{\circ}C$ for 10 sec were applied for estimation of equivalent dose of the samples. The OSL signals from different thermal treatment were used for OSL dating. Equivalent dose were estimated with 4 fractionated grain distributions with $75{\mu}m$, $150{\mu}m$ and $200{\mu}m$ sieves with above heating treatments. Consequently, the estimated dose were differently valued in sample sizes and applied heating treatments, different stratum ages were calculated. The ages from radiocarbon dating were compared with the OSL ages. The ages varying with grain sizes produce that the site sampled were formed with mixed soil sources.

An Analysis of Design Elements in Chosun Dynasty Furniture (조선조 가구에 나타난 의장요소의 분석 -단층장, 이층장, 삼층장을 중심으로-)

  • 박영순
    • Journal of the Korean Home Economics Association
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    • v.29 no.2
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    • pp.87-120
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    • 1991
  • The purpose of this study was to identify the design characteristics of the multi-leveled chest(jang) which was the main furniture of the master bedrom(anbang) in the Chosun Dynasty. The major findings and conclusions were: 1. The front view of the multi-leveled chest were composed of a protruded top panel(kaepan), drawers, folded doors, sectional panels(chwibyok kan and morum kan) and base stand(madae) in general. Variety in the front view found more frequently in single level chests than bi- or tir-level chests. 2. The overall dimensions of each type of chest increased with increase in number of levels, but the height of the sectional parts decreased. That is, the overall proportion of the single level chests were 10 : 9, bi-level chests were 5 : 6, and tri-level chests were 2 : 3. The proportion of 1 : 1, 4 : 5, 1 : 3, 1 : 4, 1 : 5 were found often in the sectional parts such as drawers, doors, chwibyok kans and morum kans. 3. In general, the surface treatments were subtle. Carved or inlayed ornamentation were seldom seen, and most chess were finished with clear lacquer to show the natural wood grain. There were no distinctive characteristics of surface ornamentation characteristic of any one type of chest. 4. The general patterns of the metal ornaments were spade(yowidu), round, bow, rectangular(yakgua), bat and flower shapes. The multi-level chests were decorated with more metal ornament types compared with the single-level chests. 5. In conclusion, there was more variety in all the design elements in the single level chests compared with the other types of chests. The bi-and tri-level chests were quite stylized in composition, size, proportion, surface treatment, and metal ornamentation.

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Al2O3 High Dense Single Layer Gas Barrier by Neutral Beam Assisted Sputtering (NBAS) Process

  • Jang, Yun-Seong;Hong, Mun-Pyo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.157-157
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    • 2015
  • Recently, the growing interest in organic microelectronic devices including OLEDs has led to an increasing amount of research into their many potential applications in the area of flexible electronic devices based on plastic substrates. However, these organic devices require a gas barrier coating to prevent the permeation of water and oxygen because organic materials are highly susceptible to water and oxygen. In particular, high efficiency OLEDs require an extremely low water vapor transition rate (WVTR) of $1{\times}10^{-6}g/m^2day$. The Key factor in high quality inorganic gas barrier formation for achieving the very low WVTR required ($1{\times}10^{-6}g/m^2day$) is the suppression of defect sites and gas diffusion pathways between grain boundaries. In this study NBAS process was introduced to deposit enhanced film density single gas barrier layer with a low WVTR. Fig. 1. shows a schematic illustration of the NBAS apparatus. The NBAS process was used for the $Al_2O_3$ nano-crystal structure films deposition, as shown in Fig. 1. The NBAS system is based on the conventional RF magnetron sputtering and it has the electron cyclotron resonance (ECR) plasma source and metal reflector. $Ar^+$ ion in the ECR plasma can be accelerated into the plasma sheath between the plasma and metal reflector, which are then neutralized mainly by Auger neutralization. The neutral beam energy is controlled by the metal reflector bias. The controllable neutral beam energy can continuously change crystalline structures from an amorphous phase to nanocrystal phase of various grain sizes. The $Al_2O_3$ films can be high film density by controllable Auger neutral beam energy. we developed $Al_2O_3$ high dense barrier layer using NBAS process. We can verified that NBAS process effect can lead to formation of high density nano-crystal structure barrier layer. As a result, Fig. 2. shows that the NBAS processed $Al_2O_3$ high dense barrier layer shows excellent WVTR property as a under $2{\times}10^{-5}g/m^2day$ in the single barrier layer of 100nm thickness. Therefore, the NBAS processed $Al_2O_3$ high dense barrier layer is very suitable in the high efficiency OLED application.

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Magnetic Properties of RF Diode Sputtered FeN Multilayer Films (RF Diode 스퍼터 방법으로 증착된 FeN 다층 박막의 자기적 특성)

  • 최연봉;박세익;조순철
    • Journal of the Korean Magnetics Society
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    • v.5 no.1
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    • pp.42-47
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    • 1995
  • FeN thin films for inductive recording heads were sputter deposited using RF diode sputtering mehtod from a pure iron target onto 7059 glass substrates, and their magnetic properties were measured. The magnetic properties were greatly affected by film thickness, gas pressure, sputter power and flow ratio of $N_{2}$ to Ar. Single layer FeN films with their thickness varied from $1,000\;{\AA}$ to $6,000\;{\AA}$ were doposited. 800 W sputter power, 3 mT gas pressure, $N_{2}$ to Ar flow ratio of 6.6 : 100 were the sputtering conditions. Up to 7 layers of FeN films having total thickness of $6,000\;{\AA}$ were deposited using $SiO_{2}$ of $30\;{\AA}$ thickness as intermediate layers and their coercivity and saturation magnetization were measured. The sputtering conditions were the same as those in the single layer films. Easy axis coercivity of the single layer FeN films gradually decreased as their thickness was increased, but for the films with their thicknesses above $3,000\;{\AA}$, the coercivity changed very little. As the number of the FeN layers were increased, the coercivity decreased We estimated the grain size of FeN films from the FWHM (Full Width at Half Maximum) of X-ray diffraction peaks. The grain size steadily decreased from about $200\;{\AA}$ to $120\;{\AA}$ as the number of layers were increased. Minimum hard axis coercivity of 0.4 Oe was obtained when the number of layers was four. Maximum relative permeability was 2,900 when the number of layers was three. The cut off frequeocy of the multilayer films were above 100 MHz.

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Studies on the Controlled Release Fertilizer METAP Application on Paddy Rice (1972) (수도에 대한 완효성비료 METAP의 비효시험(1972))

  • Lee, E.W.;Ahn, S.B.;Lee, M.H.;Lee, Z.Y.;Song, N.H.;Kwon, S.M.;Kim, C.Y.;Choe, B.C.;Chung, H.S.;Cho, B.O.;Lee, I.J.;Park, C.S.;Ko, C.S.;Park, K.H.;Chung, S.C.;Chung, H.S.;Lee, H.D.;Park, S.T.;Lee, H.S.;Choe, S.R.
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.13
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    • pp.107-118
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    • 1973
  • Experiments were carried out to study the effectiveness of METAP as a slow released fertilizer on the growth, grain yield and its components of paddy rice, and to compare its effects with those of single fertilizers in the fields of 3 Crop Experiment Stations and 7 provincial Offices of Rural Development. The effectiveness of METAP seems to be different according to the physical and chemical characteristics of soil, the time of application, climatic conditions, variety and cultural methods. Therefore, the experimental results obtained from the above experiment are summurized as follows: 1. When METAP was applied into sandy soil, grain yield was increased due to increase of the number of panicles, and split application of METAP was more effective than basal only. However, in the reclaimed soil, not heavily percolated soil and fertile soil, no differences were observed between MET AP and single fertilizer applied plot. 2. When a rice variety, 'TONGIL' which is sensitive to the low temperature and produce higher yield in the early transplanting, was not transplanted early and air temperature is relatively lower during the ripening stage, the percentage of ripened grains and 1,000 grains weight were not higher in the METAP applied plots than in the single fertilizer applied plots.

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Preparation of SnS Thin Films by MOCVD Method Using Single Source Precursor, Bis(3-mercapto-1-propanethiolato) Sn(II)

  • Park, Jong-Pil;Song, Mi-Yeon;Jung, Won-Mok;Lee, Won-Young;Lee, Jin-Ho;Kim, Hang-Geun;Shim, Il-Wun
    • Bulletin of the Korean Chemical Society
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    • v.33 no.10
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    • pp.3383-3386
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    • 2012
  • SnS thin films were deposited on glasses through metal organic chemical vapor deposition (MOCVD) method at relatively mild conditions, using bis(3-mercapto-1-propanethiolato) tin(II) precursor without toxic $H_2S$ gas. The MOCVD process was carried out in the temperature range of $300-400^{\circ}C$ and the average grain size in fabricated SnS films was about 500 nm. The optical band gap of the SnS film was about 1.3 eV which is in optimal range for harvesting solar radiation energy. The precursor and SnS films were characterized through infrared spectroscopy, nuclear magnetic resonance spectroscopy, DIP-EI mass spectroscopy, elemental analyses, thermal analysis, X-ray diffraction, and field emission scanning electron microscopic analyses.

Planting foundations and Turfgrass Species Adapted to Grounds (스포츠 그라운드에 적합한 식재지반과 잔디 초종에 관한 연구)

  • 심상렬;정대영;김경남
    • Journal of the Korean Institute of Landscape Architecture
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    • v.28 no.2
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    • pp.61-70
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    • 2000
  • The purpose of this study is to identify the proper species of turf and the ground structure for the turf sports grounds. Analysis items are particle distribution of sand and gravel, saturated hydraulic conductivity, soil hardness, and turf growth. Results of this study are as follows. 1)The particle distribution of sand used in the multi-layer rootzone is within the upper limit of the standard level. The diameter of mid-size grain({TEX}$D_{50}${/TEX})was 0.62mm and the value of uniformity ({TEX}$D_{90}${/TEX}/{TEX}$D_{10}${/TEX}) was 3.93. The particle size distribution of sand used in the single-layer rootzone was beyond the standard level as {TEX}$D_{50}${/TEX})=0.86 and {TEX}$D_{90}${/TEX}/{TEX}$D_{10}${/TEX}=8.86. 2) Saturated hydraulic conductivity of the sand was higher in the multi-layer rootzone than in the single-layer rootzone while bulk density was vice versa. 3) Surface hardness was high on Kentucky bluegrass+perennial ryegrass compared to zoysiagrass probably caused by root density. 4) Visual covering and visual rating were highly evaluated on zoysiagrass within summer while better evaluated on Kentucky bluegrass+perennial ryegrass throughout fall to spring. 5) Visual color was better evaluated on Kentucky bluegrass+perennial ryegrass than on zoysiagrass throughout the year. These studies are demanded urgently according to increase in interest in the ground and turf species of the turf sports ground because of World Cup 2002.

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Fabrications and measurements of single layer YBCO dc-SQUID magnetometers designed with parallel-loop pickup coil (Parallel-loop 검출코일을 가지는 단일층 YBCO dc-SQUID 자력계의 제작 및 특성 연구)

  • 유권규;김인선;박용기
    • Progress in Superconductivity
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    • v.5 no.1
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    • pp.45-49
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    • 2003
  • We have designed and fabricated the single-layer high $T_{c}$ SQUID magnetometer consisting of a directly coupled grain boundary junction SQUID with an inductance of 100 pH and 16 nested parallel pickup coils with the outermost dimension of 8.8 mm ${\times}$ 8.8 mm. The magnetometer was formed from a YBCO thin film deposited on an STO(100) bicrystal substrate with a misorientation angle of $30^{\circ}$. The SQUID magnetometer was further improved by optimizing the multi-loop pickup coil design for use in unshielded environments. Typical characteristics of the dc SQUID magnetometer had a modulation voltage of 40 $\mu\textrm{V}$ and a white noise of $30fT/Hz^{1}$2/. The SQUID magnetometer exhibited a 1/f noise level at 10 Hz reduced by a factor of about 3 compared with that of the conventional solid type pickup coil magnetometers and a very stable flux locked loop operation in magnetically disturbed environments.s.

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