• Title/Summary/Keyword: simultaneous removal

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Simultaneous Removal of Cd & Cr(VI) by Fe-loaded Zeolite in Column System (Fe-loaded zeolite를 이용한 칼럼 실험에서의 Cd & Cr(VI) 동시제거 반응성 평가)

  • Lee Ah-Ra;Lee Seung-Hak;Park Jun-Boum
    • Journal of Soil and Groundwater Environment
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    • v.11 no.1
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    • pp.14-22
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    • 2006
  • Laboratory column experiment for simultaneous removal of Cd and Cr(VI) were conducted using newly developed material of Fe-loaded zeolite having both reduction ability and sorption capacity. The solution containing Cd and Cr(VI) was injected into the column and the breakthrough curves (BTCs) for the contaminants were observed at the effluent port. Cd breakthrough was not initialized until Cr(VI) breakthrough was completed. Therefore it could be concluded that overall efficiency of Fe-loaded zeolite should be determined by the reactivity for Cr(VI). The relative concentration of Cr(VI) BTC increased to the unit value while initial breakthrough was delayed and the propagation of breakthrough was slowed. In order to quantitatively describe the shape of Cr(VI) BTC, new parameters of ${\alpha}\;and\;{\beta}$ designated to be shape parameters, were defined and applied in contaminant transport concentration. These parameters were employed to represent the degree of initial breakthrough delay and the degree of breakthrough propagation, respectively. As initial contaminant concentration increased, ${\alpha}$ decreased, which indicated the delay of BTC's initiation. And as initial contaminant flow rate increased, ${\beta}$ decreased, which represented the faster propagation of the BTC. From these results, Fe-loaded zeolite was found to be an effective reactive material for PRBs against heavy metals having different ionic forms in groundwater. And it could be expected that as groundwater flows faster, the propagation of breakthrough would be faster and as contaminant concentration is higher, the initial point of breakthrough would appear earlier.

Influence of COD/Nitrate-N Ratio on Denitrification and Methanogenesis in Anaerobic Sludge (COD/Nitrate-N비가 혐기성 슬러지에서 탈질과 메탄화에 미치는 영향)

  • Park, Sang-Min;Jun, Hang-Bae;Choi, Chang-Ok;Lee, Joon-Sang
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.7
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    • pp.739-745
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    • 2005
  • Simultaneous denitrification and methanogenesis at various influent COD/Nitrate-N(below C/N) ratio was investigated with two different anaerobic sludges of which one was inoculated with glucose only and the other was inoculated with glucose and nitrate. Three different C/N ratios of 30, 20, and 10 were applied with each anaerobic sludge in serum bottles agitated in a rotary shaker to monitor the time related changes of amount of gas production and gas composition. Glucose was used as a single carbon source, which was adjusted to 1,000 mg/L as COD and potassium nitrate was used as a nitrogen source to adjust the each C/N ratio. COD removal by methanogenesis was dominant at higher C/N ratios, while COD removal by denitrification was dominant at lower C/N ratios. With the sludges cultured at C/N ratios below 10, SMA and SDNR rising different carbon substrates were investigated. The most efficient carbon substrate was acetate and the highest SMA and SDNR were 0.76 g COD/g VSS day with pure anaerobic sludge and 1.38 g ${NO_3}^--N/g$ VSS day with sludge cultured at C/N ratio of 5, respectively.

Simultaneous Removal of Cd and Cr(VI) in the Subsurface Using Permeable Reactive Barrier Filled with Fe-loaded Zeolite: Soil Box Experiment (Fe-loaded zeolite로 충진된 투수성 반응벽체를 이용한 지반 내 Cd과 Cr(VI)의 동시제거: 모형 토조 실험)

  • Rhee, Sung-Su;Lee, Seung-Hak;Park, Jun-Boum
    • Journal of the Korean Geotechnical Society
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    • v.26 no.10
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    • pp.61-68
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    • 2010
  • A pilot-scale model test was performed to estimate the availability of new material, Fe-loaded zeolite, as the filling material in permeable reactive barrier (PRB) against the contaminated groundwater with both Cd and Cr(VI). Aquifer was simulated by filling up a large scale soil tank with sands, and mobilizing the water flow by the head difference of water level in both ends of the tank. Then, the mixture of concentrated Cd and Cr(VI) solution was injected into the aquifer to form a contaminant plume, and its behavior through Fe-loaded zeolite barrier was monitored. The test results showed that Fe-loaded zeolite barrier successfully treated the contaminant plume containing both Cd and Cr(VI) and that the immobilized contaminants in the barrier were not desorbed or released. The results indicated that the Fe-loaded zeolite could be a promising material in PRBs against the multiple contaminants with different ionic forms like Cr(VI) and Cd.

Simultaneous Unwrapping Phase and Error Recovery from Inhomogeneity (SUPER) for Quantitative Susceptibility Mapping of the Human Brain

  • Yang, Young-Joong;Yoon, Jong-Hyun;Baek, Hyun-Man;Ahn, Chang-Beom
    • Investigative Magnetic Resonance Imaging
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    • v.22 no.1
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    • pp.37-49
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    • 2018
  • Purpose: The effect of global inhomogeneity on quantitative susceptibility mapping (QSM) was investigated. A technique referred to as Simultaneous Unwrapping Phase with Error Recovery from inhomogeneity (SUPER) is suggested as a preprocessing to QSM to remove global field inhomogeneity-induced phase by polynomial fitting. Materials and Methods: The effect of global inhomogeneity on QSM was investigated by numerical simulations. Three types of global inhomogeneity were added to the tissue susceptibility phase, and the root mean square error (RMSE) in the susceptibility map was evaluated. In-vivo QSM imaging with volunteers was carried out for 3.0T and 7.0T MRI systems to demonstrate the efficacy of the proposed method. Results: The SUPER technique removed harmonic and non-harmonic global phases. Previously only the harmonic phase was removed by the background phase removal method. The global phase contained a non-harmonic phase due to various experimental and physiological causes, which degraded a susceptibility map. The RMSE in the susceptibility map increased under the influence of global inhomogeneity; while the error was consistent, irrespective of the global inhomogeneity, if the inhomogeneity was corrected by the SUPER technique. In-vivo QSM imaging with volunteers at 3.0T and 7.0T MRI systems showed better definition in small vascular structures and reduced fluctuation and non-uniformity in the frontal lobes, where field inhomogeneity was more severe. Conclusion: Correcting global inhomogeneity using the SUPER technique is an effective way to obtain an accurate susceptibility map on QSM method. Since the susceptibility variations are small quantities in the brain tissue, correction of the inhomogeneity is an essential element for obtaining an accurate QSM.

Combined Aqueous Ammonia-Dilute Sulfuric Acid Pretreatment of Miscanthus for Bioethanol Production (바이오에탄올 제조를 위한 억새의 암모니아-희황산 복합 전처리)

  • Bark, Surn-Teh;Koo, Bon-Cheol;Choi, Yong-Hwan;Moon, Youn-Ho;Ahn, Seung-Hyun;Cha, Young-Lok;Kim, Jung Kon;An, Gi Hong;Suh, Sae-Jung;Park, Don-Hee
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.179.1-179.1
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    • 2011
  • Pretreatment of cellulosic biomass is necessary before enzymatic saccharification and fermentation. The objective of this study was to evaluate the effect of combined aqueous ammonia-dilute sulfuric acid treatment on cellulosic biomass. Miscanthus was pretreated using aqueous ammonia and dilute sulfuric acid solution under high temperature and pressure conditions to be converted into bioethanol. Aqueous ammonia treatment was performed with 15 %(w/w) ammonia solution at $150^{\circ}C$ of reaction temperature and 20 minutes of reaction time. And then, dilute sulfuric acid treatment was performed with 1.0 %(w/w) sulfuric acid solution at $150^{\circ}C$ of reaction temperature and 10 minutes of reaction time. The compositional variations of this combined aqueous ammonia-dilute sulfuric acid treatment resulted in 68.0 % of cellulose recovery and 95.7 % of hemicellulose, 81.3 % of lignin, 89.1 % of ash removal respectively. The enzymatic digestibility of 90.5 % was recorded in the combined pretreated Miscanthus sample and it was 14.7 times higher than the untreated sample. The ethanol yield in the Simultaneous Saccharification and Fermentation was 90.4 % of maximum theoretical yield based on cellulose content of the combined pretreated sample and it was about 98 % compared to the ${\alpha}$-cellulose ethanol yield.

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Highly Accelerated SSFP Imaging with Controlled Aliasing in Parallel Imaging and integrated-SSFP (CAIPI-iSSFP)

  • Martin, Thomas;Wang, Yi;Rashid, Shams;Shao, Xingfeng;Moeller, Steen;Hu, Peng;Sung, Kyunghyun;Wang, Danny JJ
    • Investigative Magnetic Resonance Imaging
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    • v.21 no.4
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    • pp.210-222
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    • 2017
  • Purpose: To develop a novel combination of controlled aliasing in parallel imaging results in higher acceleration (CAIPIRINHA) with integrated SSFP (CAIPI-iSSFP) for accelerated SSFP imaging without banding artifacts at 3T. Materials and Methods: CAIPI-iSSFP was developed by adding a dephasing gradient to the balanced SSFP (bSSFP) pulse sequence with a gradient area that results in $2{\pi}$ dephasing across a single pixel. Extended phase graph (EPG) simulations were performed to show the signal behaviors of iSSFP, bSSFP, and RF-spoiled gradient echo (SPGR) sequences. In vivo experiments were performed for brain and abdominal imaging at 3T with simultaneous multi-slice (SMS) acceleration factors of 2, 3 and 4 with CAIPI-iSSFP and CAIPI-bSSFP. The image quality was evaluated by measuring the relative contrast-to-noise ratio (CNR) and by qualitatively assessing banding artifact removal in the brain. Results: Banding artifacts were removed using CAIPI-iSSFP compared to CAIPI-bSSFP up to an SMS factor of 4 and 3 on brain and liver imaging, respectively. The relative CNRs between gray and white matter were on average 18% lower in CAIPI-iSSFP compared to that of CAIPI-bSSFP. Conclusion: This study demonstrated that CAIPI-iSSFP provides up to a factor of four acceleration, while minimizing the banding artifacts with up to a 20% decrease in the relative CNR.

Determining the Proportions of Bone and Cartilage Growth in the Crucian Carp (carassius auratus) Using the Modified Simultaneous Differential Staining Technique

  • Lee, Jin-Heon
    • Journal of Environmental Health Sciences
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    • v.36 no.4
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    • pp.337-341
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    • 2010
  • The modified simultaneous differential staining technique, which enables double staining of cartilage and bones, needs to be improved to prevent soft tissues from being damaged during the staining process. Key factors influencing the extent to which soft tissues are damaged include the fixative used, macerating time, potassium hydroxide concentration, incubation temperature and the removal of skin from specimens. Here we describe a protocol that enables the hardening of tissues during bleaching and maceration. We also describe a method for objectively measuring rates of cartilage and bone growth. The use of formalin as a fixative rendered soft tissues more rigid due to the resulting chemical bonds formed between proteins. Blotted specimens were immersed in 1% potassium hydroxide (KOH) and incubated at $37^{\circ}C$ for 1 day (smaller specimens) or 2-3 days (larger specimens). The 1% KOH solution was also used as the diluent solution for the subsequent immersion in a graded series of 30%, 50%, 70%, 90%, 100% glycerol solutions, a procedure that made soft tissues even more transparent and hardened. It was not necessary to remove the skin of specimens shorter than 2 cm, since the macerating solution could easily penetrate their thin skin layer and continuously remove those pigments hindering visibility. Since excessive osmosis is another factor that can damage soft tissues in the macerating process by causing the rupture of those cells not able to withstand the osmotic pressure, here it was minimized by balancing the salt concentration between the interior and exterior of cells with the addition of 0.9% sodium chloride (NaCl) in the macerating solution. Finally, to determine the proportions of cartilage and bone growth, photographs of the stained specimens were taken with a dissecting microscope and sections corresponding to the cartilage and bones were cut out from the printed pictures and weighed. Our results show that this method is suitable for the objective evaluation of bone and cartilage growth.

Simultaneous Simplification of Multiple Triangle Meshes for Blend Shape (블렌드쉐입을 위한 다수 삼각 메쉬의 동시 단순화 기법)

  • Park, Jung-Ho;Kim, Jongyong;Song, Jonghun;Park, Sanghun;Yoon, Seung-Hyun
    • Journal of the Korea Computer Graphics Society
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    • v.25 no.3
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    • pp.75-83
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    • 2019
  • In this paper we present a new technique for simultaneously simplifying N triangule meshes with the same number of vertices and the same connectivities. Applying the existing simplification technique to each of the N triangule mesh creates a simplified mesh with the same number of vertices but different connectivities. These limits make it difficult to construct a simplified blend-shape model in a high-resolution blend-shape model. The technique presented in this paper takes into account the N meshes simultaneously and performs simplification by selecting an edge with minimal removal cost. Thus, the N simplified meshes generated as a result of the simplification retain the same number of vertices and the same connectivities. The efficiency and effectiveness of the proposed technique is demonstrated by applying simultaneous simplification technique to multiple triangle meshes.

Effects of Slow Release Fertilizer and Dispersant on Biodegradation of Oil Contaminated in Sand Seashore Mesocosms (지속성 영양염제와 유분산제가 해변모래에 오염된 유류의 생분해에 미치는 영향)

  • 손재학;권개경;김상진
    • Korean Journal of Microbiology
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    • v.39 no.1
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    • pp.8-15
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    • 2003
  • To evaluate the effects of slow release fertilizer and chemical dispersant on oil biodegradation, mesocosm studies were conducted on sand seashore. The rapid removal rates (85%) of aliphatic hydrocarbons and the simultaneous decreases of n-$C_{17}$/pristane (69%) and $n-C_{18}/phytane$ (61%) ratios by the addition of slow-release fertilizer (SRF) within 37 days of experiment indicated that SRF could enhance the oil degrading activity of indigenous microorganisms in sand mesocosm. Although the growth of heterotrophic bacteria and petroleumdegrading bacteria in the mesocosm treated with $Corexit 9527^{R}$ was stimulated, the biological oil removal based on the ratios of $Corexit 9527^{R}$ and $n-C_{18}/phytane$ was inhibited. Removal rates of aliphatic hydrocarbons (56%), and n-$C_{17}$/pristane (27%) and $n-C_{18}/phytane$ (17%) ratios by the addition of chemical dispersant $Corexit 9527^{R}$ were similar or lower than those values of control (50, 60, 46%), respectively. The biodegradation activity, however, when simultaneously treated with SRF and $Corexit 9527^{R}$, was not highly inhibited and even recovered after the elimination of chemical dispersant. From these results it could be concluded that the addition of SRF enhanced the oil removal rate in oligotrophic sand seashore and chemical dispersant possibly inhibit the oil biodegradation. Hence, in order to prevent the unrestrained usage of chemical dispersant in natural environments contaminated with oil, the National Contingency Plan of Oil Spill Response should be carefully revised in consideration of the application for bioremedaition techniques.

The effectiveness of step feeding strategies in sequencing batch reactor for a single-stage deammonification of high strength ammonia wastewater

  • Choi, Wonyoung;Yu, Jaecheul;Kim, Jeongmi;Jeong, Soyeon;Direstiyani, Lucky Caesar;Lee, Taeho
    • Membrane and Water Treatment
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    • v.11 no.1
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    • pp.79-85
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    • 2020
  • A single-stage deammonification with a sequencing batch reactor (SBR) that simultaneous nitritation, anaerobic ammonia oxidation (anammox), and denitrification (SNAD) occur in one reactor has been widely applied for sidestream of wastewater treatment plant. For the stable and well-balanced SNAD, a feeding strategy of influent wastewater is one of the most important operating factors in the single-stage deammonification SBR. In this study, single-stage deammonification SBR (working volume 30L) was operated to treat a high-strength ammonium wastewater (1200 mg NH4+-N/L) with different feeding strategies (single feeding and nine-step feeding) under the condition without COD. Each cycle of the step feeding involved 6 sub-cycles consisted of aerobic and anoxic periods for partial nitritation (PN) and anammox, respectively. Contrary to unstable performance in the single feeding, the step feeding showed better deammonification performance (0.565 kg-N/m3/day). Under the condition with COD, however, the nitrogen removal rate (NRR) decreased to 0.403 kg-N/m3/day when the Nine-step feeding strategies had an additional denitrification period before sub-cycles for PN and anammox. The NRR was recovered to 0.518 kg-N/m3/day by introducing an enhanced multiple-step feeding strategy. The strategy had 50 cycles consisted of feed, denitrification, PN, and anammox, instead of repeated sub-cycles for PN and anammox. The multiple-step feeding strategy without sub-cycle showed the most stable and excellent deammonification performance: high nitrogen removal efficiency (98.6%), COD removal rate (0.131 kg-COD/m3/day), and COD removal efficiency (78.8%). This seemed to be caused by that the elimination of the sub-cycles might reduce COD oxidation during aerobic condition but increase the COD utilization for denitrification period. In addition, among various sensor values, the ORP pattern appeared to be applicable to monitor and control each reaction step for deammonification in the multiple-step feeding strategy without sub-cycle. Further study to optimize the number of multiple-step feeding is still needed but these results show that the multiple-step feeding strategy can contribute to a well-balanced SNAD for deammonification when treating high-strength ammonium wastewater with COD in the single-stage deammonification SBR.