• Korean Journal of Materials Research
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• v.28 no.9
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• pp.506-510
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• 2018

Nitrogen is a serious contaminant in natural gas because it decreases the energy density. The natural gas specification in South Korea requires a $N_2$ content of less than 1 mol%. Thus, cost-effective $N_2$ removal technology from natural gas is necessary, but until now the only option has been energy-intensive processes, e.g., cryogenic distillation. Using porous materials for the removal process would be beneficial for an efficient separation of $CH_4/N_2$ mixtures, but this still remains one of the challenges in modern separation technology due to the very similar size of the components. Among various porous materials, metal-organic frameworks (MOFs) present a promising candidate for the potential $CH_4/N_2$ separation material due to their unique structural flexibility. A MIL-53(Al), the most well-known flexible metal-organic framework, creates dynamic changes with closed pore (cp) transitions to open pores (ops), also called the 'breathing' phenomenon. We demonstrate the separation performance of $CH_4/N_2$ mixtures of MIL-53(Al) and its derivative $MIL-53-NH_2$. The $CH_4/N_2$ selectivity of $MIL-53-NH_2$ is higher than pristine MIL-53(Al), suggesting a stronger $CH_4$ interaction with $NH_2$.

• Journal of Welding and Joining
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• v.32 no.1
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• pp.6-14
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• 2014

This paper has an aim to evaluate microstructure and fracture toughness of TMCP steel weldment applied for off-shore wind tower with the focus on the effect of heat input on the weldment with various welding processes; FCAW(13kJ/cm and 30kJ/cm), SAW(62kJ/cm), and EGW(177kJ/cm). Based on experimental results developed from this study, it was found that the impact toughness of top side for TMCP steel weldments with heat input up to 62 kJ/cm satisfied the required minimum value except the EGW(177kJ/cm). The heat input and microstructure are the main factors of impact toughness. The heat input of 13kJ/cm on back side with low heat input increased the amount of grain boundary ferrite which has low impact toughness, and heat input of 177kJ/cm on top side is significant enough to produce the austenite grain growth. The compositions and sizes of inclusions which are the dominant factors for the formation of acicular ferrite were analyzed by OM and EDS. As the heat input increased, the inclusions also grew and a nucleation site decreased. The size of nonmetallic inclusions and the crack width was nearly similar, therefore the inclusions were related with the crack propagation.

• Journal of Powder Materials
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• v.17 no.3
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• pp.216-222
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• 2010

Self-standing $TiO_2$ nanotube arrays were fabricated by potentiostatic anodic oxidation method using pure Ti foil as a working electrode and ethylene glycol solution as electrolytes with small addition of $NH_4F$ and $H_2O$. The influences of anodization temperature and time on the morphology and formation of $TiO_2$ nanotube arrays were investigated. The fabricated $TiO_2$ nanotube arrays were applied as a photoelectrode to dye-sensitized solar cells. Regardless of anodizing temperature and time, the average diameter and wall thickness of $TiO_2$ nanotube show a similar value, whereas the thickness show a different trend with reaction temperature. The thickness of $TiO_2$ nanotube arrays anodized at $20^{\circ}C$ and $30^{\circ}C$ was time-dependent, but on the other hand its at $10^{\circ}C$ are independent of anodization time. The conversion efficiency is low, which is due to a morphology breaking of the $TiO_2$ nanotube arrays in manufacturing process of photoelectrode.

• Journal of Conservation Science
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• v.26 no.4
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• pp.361-370
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• 2010

The open pore of stone cultural heritage is not expected to have an effect only by consolidation, and it has a drawback that only the internal wall adheres and gets consolidated due to the incrase of liquidity caused by the low viscosity and difference of materials in the case of filling with high molecules synthetic resins. Therefore, this research selected the effective filler for Three-storied Stone Pagoda at the West of Gameunsaji Site through the verification of filling effects of materials using the information about various fillers based on minerals. As the result of filler experiment, got filled with the combination of KSE 500 STE + KSE Filler A${\cdot}$KSE Filler B that is the same as the Member or has very similar properties. The total surface area of the west stone is $252.6m^2$ and the area where the internal opening has been developed is $17.77m^2$(7.03%) requiring a task that fills the internal($24,885m{\ell}$).

• Journal of Korea Technology Innovation Society
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• v.10 no.4
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• pp.789-807
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• 2007

Technology Readiness Levels were initially proposed by NASA in 1995. TRL's definition and range were modified within adopted feilds such as hardware and software products. Many national R&D programs have similar evaluation conditions. However, they are influenced by the experts' ability. Relatively, they have shown the little reliance and the low performance of the developed prototype and technology. The purpose of this study is to apply the TRL to the materials and components development program. We defined TRLs for the program and devided them in three technology fields. Proposals, which were submitted for the program in 2007, were assessed with our TRL definitions for the study on the applicability. As a result, we could understand the characteristic TRLs of the technical proposals to the materials and components development program. This shows that the objective tools such as TRLs are required as the R&D program management factors. For the sake, it is the important factor that the detail directives to assess TRL should be developed according to the branches of industrial technology fields.

• Journal of Surface Science and Engineering
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• v.48 no.6
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• pp.260-268
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• 2015

The thermal barrier coating (TBC) for inner wall of liquid-fuel rocket combustor consists of NiCrAlY as bonding layer and $ZrO_2$ as a top layer. In most case, the plasma spray coating is used for TBC process and this process has inherent possibility of cracking due to large difference in thermal expansion coefficients among bonding layer, top layer and metal substrate. In this paper, we suggest crack-free TBC process by using a precise electrodeposition technique. Electrodeposited Ni-P/Cr double layer has similar thermal expansion coefficient to the Cu alloy substrate resulting in superior thermal barrier performance and high temperature oxidation resistance. We studied the effects of phosphorous concentrations (2.12 wt%, 6.97 wt%, and 10.53 wt%) on the annealing behavior ($750^{\circ}C$) of Ni-P samples and Cr double layered electrodeposits. Annealing temperature was simulated by combustion test condition. Also, we conducted SEM/EDS and XRD analysis for Ni-P/Cr samples. The results showed that the band layers between Ni-P and Cr are Ni and Cr, and has no formed with heat treatment. These band layers were solid solution of Cr and Ni which is formed by interdiffusion of both alloy elements. In addition, the P was not found in it. The thickness of band layer was increased with increasing annealing time. We expected that the band layer can improve the adhesion between Cr and Ni-P.

• Resources Recycling
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• v.26 no.6
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• pp.50-57
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• 2017

In this study, characteristics of Mongolian fly ash and the possibility of its use as a cement additive through grinding process were examined. Mongolian fly ash was larger than domestic fly ash and less spherical. The CaO content of Mongolian fly ash was higher than domestic fly ash and the other components were similar. After vibratory milling, the mean particle size of fly ash decreased to $7.9{\mu}m$ and the blaine increased. When milled fly ash was mixed with cement, it showed the best compressive strength value at 60 min. These strength values were higher than OPC at all curing times.

• Steel and Composite Structures
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• v.27 no.6
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• pp.717-725
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• 2018

One of the most important design criteria in military tunnels and armoured doors is to resist the blast loads with minimum structural weight. This can be achieved by using steel sandwich panels. In this paper, the nonlinear behaviour of steel sandwich panels, with different core materials: (1) Hollow (no core material); (2) Rigid Polyurethane Foam (RPF); and (3) Vulcanized Rubber (VR) under free air blast loads, was investigated using detailed 3D nonlinear finite element models in Ansys Autodyn. The accuracy of the finite element model proposed was verified using available experimental test data of a similar steel sandwich panel tested. The results show the developed finite element model can be reliably used to simulate the nonlinear behaviour of the steel sandwich panels under free air blast loads. The verified finite element model was used to examine the different parameters of the steel sandwich panel with different core materials. The result shows that the sandwich panel with RPF core material is more efficient than the VR sandwich panel followed by the Hollow sandwich panels. The average maximum displacement of RPF sandwich panel under different ranges of TNT charge (1 kg to 10 kg at a standoff distance of 1 m) is 49% and 53% less than the VR and Hollow sandwich panels, respectively. Detailed empirical design equations were provided to quantify the maximum deformation of the steel sandwich panels with different core materials and core thickness under a different range of blast loads. The developed equations can be used as a guide for engineer to design steel sandwich panels with RPF and VR core material under a different range of free air blast loads.

• International Journal of Knowledge Content Development & Technology
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• v.1 no.1
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• pp.61-79
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• 2011

This study purposed to discover whether or not academic libraries reflect these changing roles. We selected K University as the research target and surveyed user satisfaction of materials, staff services, facilities, electronic devices, media, and so on. The research findings are as follows: 1) the frequency of library visits of University K was on the high side, 2) the primary purpose of using the academic library was associated with learning or reading, therefore, the most used library spaces were related to that, 3) the most used library materials were 'general books', the most unused were 'reference books', 4) the most preferred way to obtain needed materials when failing to find wanted materials was 'Contact librarian'. A similar phenomenon occurred in terms of facility use, 5) university K's users were usually satisfied with the loan policy, 6) the rate of users who don't know whether there is user education was very high, the rate of users who have no experience with user education was extremely low. These research findings can be referenced by library management to improve libraries' service quality and take advantage of complex spatial configurations.

• Journal of architectural history
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• v.23 no.1
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• pp.7-19
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• 2014

This study considers the proper repair techniques by examining the most representative repair cases of the Korean arch bridges and proposes the constructional manual which can apply similar occasions. The cases are Seonamsa Seungseongyo and Songgwangsa Geukrockgyo where this researcher had taken part in the repair works. This Study proposes the maintenance construction manual about the performance degradation drew by performance degradation of the both Korean arch bridges in the maintenance process. First, arch bridge maintenance should be carried out in the dry season, when water is impermeable in the bottom surface of the bridge. Moreover, risk factors of the maintenance should be excluded to secure the water vally flow, the bypass and the temporary bridge. Second, prior to repair, it has to precede (1)3D shooting (2)formal examination (3)structure safety test (4)geological and lithic surveys (5)arch curvature establishment and makeshift frame settlement before transformation (6)relationship expert comments. Third, if the baduk and the foundation stones are inevitable to replace due to performance degradation on the foundation, it should use the high quality stones and secure greater stress by extending the standard range. The foundation on irregular rock needs to be flattened and underside on the replaced materials require Grengyijil to deliver the equal loads. Fourth, In the process of dismantling the stones of the arched bridge, it could make heavy weathering degree and not reuse the materials. Charge should converge the expert advices to choose the reuseable, the conservate and the alternative materials, and increase the reutilization of the raw materials by preservation and reinforcement treatments. Fifth, the side wall should be repaired by the rubble work technique which is not able to pile compost satiety, so it must use long depth of masonary stones for reinforcement. It is considered to reinforce the stone wall in shore as much as possible and protect the abutment and the side wall on the upstream for the arch bridge maintenance works.