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Synthesis of Nitrogen-Doped Porous Carbon Fibers Derived from Coffee Waste and Their Electrochemical Application (커피 폐기물 기반의 질소가 포함된 다공성 탄소 섬유의 제조 및 전기화학적 응용)

  • Dong Hyun Kim;Min Sang Kim;Suk Jekal;Jiwon Kim;Ha-Yeong Kim;Yeon-Ryong Chu;Chan-Gyo Kim;Hyung Sub Sim;Chang-Min Yoon
    • Journal of the Korea Organic Resources Recycling Association
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    • v.31 no.1
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    • pp.57-68
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    • 2023
  • In this study, coffee waste was recycled into nitrogen-doped porous carbon fibers as an active material for high-energy EDLC (Electric Double Layer Capacitors). The coffee waste was mixed with polyvinylpyrrolidone and dissolved into dimethylformamide. The mixture was then electrospun to fabricate coffee waste-derived nanofibers (Bare-CWNF), and carbonization process was followed under a nitrogen atmosphere at 900℃. Similar to Bare-CWNF, the as-synthesized carbonized coffee waste-derived nanofibers (Carbonized-CWNF) maintained its fibrous form while preserving the composition of nitrogen. The electrochemical performance was analyzed for carbonized coffee waste (Carbonized-CW)-, carbonized PAN-derived nanofibers (Carbonized-PNF)-, and Carbonized-CWNF-based electrodes in the operating voltage window of -1.0-0.0V, Among the electrodes, Carbonized-CWNF-based electrodes exhibited the highest specific capacitance of 123.8F g-1 at 1A g-1 owing to presence of nitrogen and porous structure. As a result, nitrogen-contained porous carbon fibers synthesized from coffee waste showed excellent electrochemical performance as electrodes for high-energy EDLC. The experimental designed in this study successfully demonstrated the recycling of the coffee waste, one of the plant-based biomass that causes the environmental pollution into high-energy materials, also, attaining the ecofriendliness.

An Analysis of the PCK Components in Elementary Science Government-Authorized Teacher's Guides Developed under 2015 Revised National Curriculum: Focused on Material Units in 3rd~4th Grade (2015 개정 교육과정에 따른 초등학교 과학과 검정 교사용 지도서에 나타난 교과교육학 지식(PCK) 요소 분석 - 3~4학년 물질 영역을 중심으로 -)

  • Song, Nayoon;Cho, Yoonyoung;Noh, Taehee
    • Journal of Korean Elementary Science Education
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    • v.42 no.1
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    • pp.47-63
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    • 2023
  • In this study, we analyzed the PCK components in the materials units of the third and fourth grades of the Korean government-authorized teacher's guides for elementary school, developed in the 2015 revised national curriculum. The results showed that the PCK components were presented in a relatively balanced manner compared to the teacher's guides for middle school. Knowledge of the subject matter accounted for the highest proportion, and knowledge of instructional strategies in science accounted for a higher proportion than knowledge of the science curriculum. The knowledge of assessment in science showed the greatest deviation among publishers, and knowledge of students tended to show the lowest. By subcomponents, experiments and inquiries had a higher proportion than concepts and theories. The ratio of horizontal articulation was lower than that of vertical articulation or lesson objectives, and lesson objectives were presented in various ways, such as in core competencies and achievement standards for science. As questioning was emphasized, teaching strategies and questioning appeared at a similar rate. Motivation and interest, misconceptions were linked to teaching strategies and questioning. In some cases, assessment items and assessment criteria were presented at each level, and various PCK components were linked to these two components. Components with relatively large differences among publishers were supplementary or in-depth concepts, inquiry in textbooks, instruction sequence and method, subject-specific strategies, and assessment items. From the results, the implications for the development of teacher's guides were discussed.

Risk Assesment of Subsidence which utilized Fuzzy-FMEA (Fuzzy-FMEA를 활용한 지반함몰 위험도 평가)

  • Deacheon Kim;YoungMin Jung;Dongil Shin
    • Journal of the Society of Disaster Information
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    • v.19 no.2
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    • pp.313-325
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    • 2023
  • Purpose: According to the recent occurrence statistics of ground accidents, ground subsidence and subsidence have become social problems as the frequency has increased centering around the downtown areas. This study tried to clarify risk of detailed factors which have an effect on subsidence. Method: For the study, detailed risk factors of 28 foundations were mainly drawn through the materials, precedent studies, and research reports shown by analyzing JIS' accident cases from 2016 to September 6, 2022 and by taking advice from an excavation expert. And risk was assessed by conducting a survey on 12 subsidence experts from the universities, research institutes, and industries and applying Fuzzy-FMEA to it. Result: It has found that damage of sewer pipes is 24.99% of overall risk, followed by excavation work (17.34%), water pipes (14.84%), and poor compaction (refill) (13.93%). And it has found that risk of damaging utilities (water pipes, sewer pipes, and other utilities) is highest, followed by poor construction works (excavation work, damage of sewer and water pipes, and other utility work) and poor compaction (refill). Conclusion: This shows that risk of subsidence factors judged by experts is similar with JIS' cases of ground subsidence.

Effects of Fiber Orientations and Hybrid Ratios on Lubricant Tribological Characteristics of $Al_2O_{3f}/SiC_p$ Reinforced MMCs ($Al_2O_{3f}/SiC_p$ 금속복합재료의 섬유방향과 혼합비가 윤활마모특성에 미치는 영향)

  • Wang, Yi-Qi;Song, Jung-Il
    • Composites Research
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    • v.22 no.5
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    • pp.15-23
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    • 2009
  • The lubricant tribological characteristics of $Al_2O_3$ fiber and SiC particle hybrid metal matrix composites (MMCs) fabricated by squeeze casting method was investigated using a pin-on-disk wear tester. The wear tests of the MMCs were performed according to fiber/particle hybrid ratio in the planar-random (PR) and normal (N) orientations sliding against a counter steel disk at a fixed speed and $25\;kg_f$ loading under different sliding distances and temperatures. The test results showed that the wear behavior of MMCs varied with fiber orientation and hybrid ratio. At room temperature, the lubricant wear behavior of F20P0 unhybrid PR-MMCs was superior to that of N-MMCs while the hybrid composites exhibited the reverse lubricant wear behavior. It was also revealed that the wear resistance of PR-MMCs was superior to that of the N-MMCs due to the joint action of reinforcements and lubricant film between the friction surfaces at an elevated temperature of $100^{\circ}C$ for both fiber only and hybrid cases. In case of $150^{\circ}C$, although the trend of weight loss was similar to that of others, the wear resistance of PR-MMCs was better than that of N-MMCs for hybrid MMCs.

Fabrication and Electromechanical Behaviors of a SWNT/PANi Composite Film Actuator (탄소나노튜브/도전성폴리머 복합재 엑츄에이터의 제조 및 특성실험)

  • Zhang, Shuai;Kim, Cheol
    • Composites Research
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    • v.19 no.5
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    • pp.7-11
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    • 2006
  • The improved SWNTs/PANi composite actuator films applicable to an artificial muscle were fabricated successfully using a new process of manufacture that consists of 90% pure single-walled carbon nanotubes (SWNT) and chemical polymerization. PANi is electrically conducting polyaniline polymer. The conductivities of the composite SWNTs/PANi film-type actuators and the pure PANi films fabricated were measured as 56.15 S/cm and 17.38 S/cm, respectively, by the 4-prove method. The conductivity of the composite actuator is 3.2 times higher than the pure PANi film. The fabricated composite actuator showed higher conductivity than any other similar ones. The quality of samples was investigated by an electron scanning microscope (SEM). To measure the actuating strains, a specially designed beam balance apparatus was developed and strains of the composite actuators was measured by a laser displacement sensor subjected to electric currents. During the operation, the sample was soaked in the $NaNO_3$ solution and the sine-wave voltage in the range of $+1V{\sim}-1V$ was applied. The length of the composite actuator changed from $l_0=12.690$ mm to $l_1=12.733$ so that the change of length was l=0.043 mm and the strain was 0.34 %. This is a very high strain for this kind of a composite actuator. Other result reported by Tahhan showed 0.23 % strain, so that the present result is improved by 48%.

Experimental Assessment of Reduction in the Negative Skin Friction Using a Pile with a Member Responding to Ground Deformation (지반 변형 대응 부재를 적용한 말뚝의 부마찰력 저감 성능의 실험적 검증)

  • Shin, Sehee;Lee, Haklin;Woo, Sang Inn
    • Journal of the Korean Geotechnical Society
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    • v.38 no.3
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    • pp.5-16
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    • 2022
  • Ground in extremely cold and hot regions can sink by various environmental factors. Ground settlement can generate the negative skin friction to pile shaft, increase the base load of pile, and cut the stability of the pile. This study proposed a member responding ground deformation which can be inserted inside the pile. The member slightly compresses according to the ground settlement to reduce the negative skin friction. As the member materials, this study considered spring and spring-dashpot. To assess the ability of the member, the present research performed model tests for piles with or without the member within settled ground. In the model tests, the base load, total shaft resistance, and horizontal earth pressure were monitored and analyzed. Experimental results show that the pile with spring member can reduce the negative skin friction under small settlement conditions whereas it acts similar to the pile without the member under large settlement conditions as the spring was no longer compressed. However, the pile with the spring-dashpot member can reduce the negative skin friction continuously upon the ground settlement as the dashpot delays the load transfer to the spring and locates friction force on the unloading path.

Development of a real-time polymerase chain reaction assay for reliable detection of a novel porcine circovirus 4 with an endogenous internal positive control

  • Kim, Hye-Ryung;Park, Jonghyun;Park, Ji-Hoon;Kim, Jong-Min;Baek, Ji-Su;Kim, Da-Young;Lyoo, Young S.;Park, Choi-Kyu
    • Korean Journal of Veterinary Service
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    • v.45 no.1
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    • pp.1-11
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    • 2022
  • A novel porcine circovirus 4 (PCV4) was recently identified in Chinese and Korean pig herds. Although several conventional polymerase chain reaction (cPCR) and real-time PCR (qPCR) assays were used for PCV4 detection, more sensitive and reliable qPCR assay is needed that can simultaneously detect PCV4 and internal positive control (IPC) to avoid false-negative results. In the present study, a duplex qPCR (dqPCR) assay was developed using primers/probe sets targeting the PCV4 Cap gene and pig (glyceraldehyde-3-phosphate dehydrogenase) GAPDH gene as an IPC. The developed dqPCR assay was specifically detected PCV4 but not other PCVs and porcine pathogens, indicating that the newly designed primers/probe set is specific to the PCV4 Cap gene. Furthermore, GAPDH was stably amplified by the dqPCR in all tested viral and clinical samples containing pig cellular materials, indicating the high reliability of the dqPCR assay. The limit of detection of the assay 5 copies of the target PCV4 genes, but the sensitivity of the assay was higher than that of the previously described assays. The assay demonstrated high repeatability and reproducibility, with coefficients of intra-assay and inter-assay variation of less than 1.0%. Clinical evaluation using 102 diseased pig samples from 18 pig farms showed that PCV4 circulated in the Korean pig population. The detection rate of PCV4 obtained using the newly developed dqPCR was 26.5% (27/102), which was higher than that obtained using the previously described cPCR and TaqMan probe-based qPCR and similar to that obtained using the previously described SYBR Green-based qPCR. The dqPCR assay with IPC is highly specific, sensitive, and reliable for detecting PCV4 from clinical samples, and it will be useful for etiological diagnosis, epidemiological study, and control of the PCV4 infections.

Early Onset Subsequent Vertebral Compression Fracture after Percutaneous Verteroplasty (경피적 척추 성형술 후 조기에 발생한 새로운 척추 압박골절)

  • Kim, Jong-Kil;Choi, Byeong-Yeol;Park, Young-Chul;Kim, Dong-Hyun
    • Journal of the Korean Orthopaedic Association
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    • v.54 no.1
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    • pp.24-29
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    • 2019
  • Purpose: To evaluate the characteristics and the risk factors of early onset subsequent vertebral compression fractures after percutaneous vertebroplasty. Materials and Methods: A total of 44 patients, who had a new subsequent vertebral fracture after percutaneous vertebroplasty for an osteoporotic vertebral compression fracture between January 2013 and December 2015, were recruited. The patients were divided into two groups according to the onset period of subsequent fracture. The number of patients who had a fracture within 3 months following vertebroplasty were 22 cases (Group A); after 3 months were 22 cases (Group B). Variables, including age, sex, bone mineral density (BMD), body mass index (BMI), preexisting vertebral compression fracture, location of the initial fracture, intradiscal cement leakage, injected cement volume, restoration of vertebral body height, and correction of kyphosis, in the two groups were analyzed and compared retrospectively. Results: The age, sex, BMD, BMI, preexisting vertebral compression fracture, location of the initial fracture, intradiscal cement leakage, and correction of kyphosis were similar in the two groups. Both a greater volume of bone cement injected and a greater degree of vertebral height restoration contributed significantly to the risk of fracture within 3 months. Conclusion: The cement volume and degree of height restoration are risk factors for early onset fracture at the adjacent vertebrae after percutaneous vertebroplasty and close attention is needed during the follow-up period.

Analysis of the Risk Factors for Posterior Migration of Single Cage after Transforminal Lumbar Interbody Fusion (경추간공 요추 추체간 유합술 후 단일 케이지 후방이동의 위험인자에 대한 분석)

  • Ko, Young-Chul;Ha, Dong-Jun;Park, Man-Jun;Huh, Jung-Wook;Park, Joon-Hyung;Lee, Woo-Myung
    • Journal of the Korean Orthopaedic Association
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    • v.54 no.3
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    • pp.237-243
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    • 2019
  • Purpose: To analyze the risk factors for posterior migration of a single cage after transforminal lumbar interbody fusion (TLIF). Materials and Methods: This study was conducted retrospectively on 48 patients (60 discs) who were followed-up for 1 year after TLIF from January 2015 to January 2017. The patients were divided into two groups: group 1 containing 16 patients (17 discs) with cage migration and group 2 containing 32 patients (43 discs) without it. Information related to cage migration, such as the demographic factors, shape of disc, level and location of the cage inserted, and disc height change, was acquired from the medical records and radiologic images, and the possibility for generating posterior migration of cage was evaluated statistically. Results: The demographic factors and cage-inserted level were similar in the two groups (16 patients in group 1, 32 patients in group 2). In the migration group, number of patients with a pear-type disc, 9 patients, was significantly larger; the disc height change, 1.8 mm, was significantly smaller; and the cage was located frequently on non-center in the anteriorposterior view and center in the lateral view in 9 and 15 out of 16 patients, respectively. Conclusion: A pear-type disc shape, small disc height change, cage with non-center on the anteriorposterior view and non-anterior on the lateral view are the risk factors for posterior migration. These factors are important for preventing posterior migration of the cage.

Public Exposure to Natural Radiation and the Associated Increased Risk of Lung Cancer in the Betare-Oya Gold Mining Areas, Eastern Cameroon

  • Joseph Emmanuel Ndjana Nkoulou II;Louis Ngoa Engola;Guy Blanchard Dallou;Saidou;Daniel Bongue;Masahiro Hosoda;Moise Godefroy Kwato Njock;Shinji Tokonami
    • Journal of Radiation Protection and Research
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    • v.48 no.2
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    • pp.59-67
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    • 2023
  • Background: This study aims to reevaluate natural radiation exposure, following up on our previous study conducted in 2019, and to assess the associated risk of lung cancer to the public residing in the gold mining areas of Betare-Oya, east Cameroon, and its vicinity. Materials and Methods: Gamma-ray spectra collected using a 7.62 cm×7.62 cm in NaI(Tl) scintillation spectrometer during a car-borne survey, in situ measurements and laboratory measurements performed in previous studies were used to determine the outdoor absorbed dose rate in air to evaluate the annual external dose inhaled by the public. For determining internal exposure, radon gas concentrations were measured and used to estimate the inhalation dose while considering the inhalation of radon and its decay products. Results and Discussion: The mean value of the laboratory-measured outdoor gamma dose rate was 47 nGy/hr, which agrees with our previous results (44 nGy/hr) recorded through direct measurements (in situ and car-borne survey). The resulting annual external dose (0.29±0.09 mSv/yr) obtained is similar to that of the previous study (0.33±0.03 mSv/yr). The total inhalation dose resulting from radon isotopes and their decay products ranged between 1.96 and 9.63 mSv/yr with an arithmetic mean of 3.95±1.65 mSv/yr. The resulting excess lung cancer risk was estimated; it ranged from 62 to 216 excess deaths per million persons per year (MPY), 81 to 243 excess deaths per MPY, or 135 excess deaths per MPY, based on whether risk factors reported by the U.S. Environmental Protection Agency, United Nations Scientific Committee on the effects of Atomic Radiation, or International Commission on Radiological Protection were used, respectively. These values are more than double the world average values reported by the same agencies. Conclusion: There is an elevated level of risk of lung cancer from indoor radon in locations close to the Betare-Oya gold mining region in east Cameroon. Therefore, educating the public on the harmful effects of radon exposure and considering some remedial actions for protection against radon and its progenies is necessary.