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Toxicity Evaluation of Complex Metal Mixtures Using Reduced Metal Concentrations: Application to Iron Oxidation by Acidithiobacillus ferrooxidans

  • Cho, Kyung-Suk;Ryu, Hee-Wook;Choi, Hyung-Min
    • Journal of Microbiology and Biotechnology
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    • v.18 no.7
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    • pp.1298-1307
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    • 2008
  • In this study, we investigated the inhibition effects of single and mixed heavy metal ions ($Zn^{2+},\;Ni^{2+},\;Cu^{2+},\;and\;Cd^{2+}$) on iron oxidation by Acidithiobacillus ferrooxidans. Effects of metals on the iron oxidation activity of A. ferrooxidans are categorized into four types of patterns according to its oxidation behavior. The results indicated that the inhibition effects of the metals on the iron oxidation activity were noncompetitive inhibitions. We proposed a reduced inhibition model, along with the reduced inhibition constant ($\alpha_i$), which was derived from the inhibition constant ($K_I$) of individual metals and represented the tolerance of a given inhibitor relative to that of a reference inhibitor. This model was used to evaluate the toxicity effect (inhibition effect) of metals on the iron oxidation activity of A. ferrooxidans. The model revealed that the iron oxidation behavior of the metals, regardless of metal systems (single, binary, ternary, or quaternary), is closely matched to that of any reference inhibitor at the same reduced inhibition concentration, $[I]_{reduced}$, which defines the ratio of the inhibitor concentration to the reduced inhibition constant. The model demonstrated that single metal systems and mixed metal systems with the same reduced inhibitor concentrations have similar toxic effects on microbial activity.

A Petrological and Geochemical Study of Granites in the Cheju Island (제주도에서 산출되는 화강암에 관한 연구)

  • Ahn, Kun Sang;Lee, Hyun Koo;Lim, Hyun Cheol
    • Economic and Environmental Geology
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    • v.28 no.5
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    • pp.513-518
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    • 1995
  • A granite drilling core (-1200 m) obtained near the Majang cave in east part of the Cheju island. The rock is pinksh in color and has miarolitic cavities. It is coarse-grained rock and consists of quartz, plagioclase, alkali feldspar, biotite and magnetite. The rock shows characteristically micrographic texture. The alkali feldspar is subhedral to anhedral and generally interstitial grains and fonns micrographic texture. K/Ar age of alkali feldspar in the core specimen is $58.14{\pm}1.4Ma $ (early Tertiary). The age, rock features and whole rock chemistry of the rock has strong resemblance to micrographic granites, so called "masanite", in southeastern part of the Korean peninsular. The granitic fragments from drilling core (- 920 m) obtained in Jungmun area in south part of the Cheju island consist of quartz, plagioclase, alkali feldspar and biotite. The fragments in the Jungmun area are similar to granitic xenolith near the Cheju city for the absence of micrographic texture and different alkali feldspar.

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Seeded Crystal Growth onto Enamel Mineral and Synthetic Hydroxyapatite in Dilute Supersaturated Solutions Containing Low Concentrations of Fluoride (불소농도가 Seeded Enamel Mineral과 합성 Hyproxyapatite에 Crystal 성장에 미치는 영향)

  • Lee, Chan-Young;Aoba, Takaaki
    • Restorative Dentistry and Endodontics
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    • v.20 no.2
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    • pp.818-826
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    • 1995
  • The present study was undertaken to investigate the crystal growth onto enamel mineral and synthetic hydroxyapatite seeds in media resembling the enamel fluid composition. Effects of fluoride at low concentrations on the precipitation were also examined in a benchtop crystal growth model adopting a miniaturized reaction column. X-ray diffraction and Fourier transform infrared spectroscopy(FTIR), as well as chemical analyses, were employed for characterization of both seed materials before and after experimentation. Remarkable findings were that (1) both biological and synthetic seeds at the same total surface areas yielded rather similar precipitation rates at all levels of fluoride concentration in solution and (2) the precipitation rate was accelerated in a manner depending on fluoride concentrations in media. FTIR differential analysis disclosed that the precipitating phase was characterized as poorly crystallized apatite, which incorporated subtle carbonate. Most of the fluoride ions in soution were readily incorporated into crystals. The overall results support the view that the seeded crystal growth model is of value to gain insight into the mechanism of enamel crystal growth under fluoride regimens.

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Partial Discharge Simulation and Analysis Based on Experiment in Underground Distribution Power Cables

  • Jung, Chae-Kyun;Kim, Jeong-Tae;Lee, Jong-Beom
    • Journal of Electrical Engineering and Technology
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    • v.8 no.4
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    • pp.832-839
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    • 2013
  • This paper describes the simulation and experiment for partial discharge (PD) pulse propagation in 22.9kV CNCV power cables. To investigate the propagation characteristics of PD, experiments are carried out by injecting the PD pulse in 100m-long 60 $mm^2$ CNCV cable in the laboratory. The characteristics of PD are also simulated using EMTP to investigate and analyze PD in the same cable. By comparing the simulation and test results, parameter permittivity is recalculated by considering semiconducting screen in the process of simulation and analysis of PD. After it is proved that simulation results and test results are almost similar in the laboratory, extensive simulations are performed to analyse various PD characteristics such as propagation velocity, attenuation, etc. in 60 $mm^2$ and 325 $mm^2$ CNCV cables. Authors are confident that results obtained in this paper will be used as important technical materials to detect and investigate PD generated in transmission and distribution power cables.

AC Electrical and Mechanical Properties of Epoxy-Nano-Microsilica Mixed Composites for Eco-Friendly GIS Spacer (친환경 GIS Spacer용, 에폭시-나노-마이크로실리카 혼합 콤포지트의 교류 전기적, 기계적 특성)

  • Park, Jae-Jun
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.67 no.9
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    • pp.1181-1188
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    • 2018
  • In order to develop new insulating materials for GIS Spacer using environmentally friendly insulating gas, three kinds of dispersed liquid nano composites of solid epoxy /nano layered silicate filled material were prepared. And the epoxy/nano/micro silica composite was prepared by mixing epoxy/nano 3 phr dispersion/4 kinds of filler contents(40,50,60, 70wt%). The electrical insulation breakdown strengths of the nano and nano/micro mixed composites were evaluated by using 8 kinds of samples including the original epoxy. The mechanical tensile strength of the epoxy / nano / micro silica composite were evaluated, also. The TEM was measured to evaluate the internal structure of nano/micro composites. As a result, it was confirmed that the layered silicate nano particles was exfoliated through the process of inserting epoxy resin between silicate layers and the layers. In addition, dispersion of nano / micro silica resulted in improvement of electrical insulation breakdown strength with increase of filling amount of dense tissue with nanoparticles inserted between microparticles. In addition, the tensile strength showed a similar tendency, and as the content of microsilica filler increased, the mechanical improvement was further increased.

Finite Element Analysis for Bending Behavior of Composite Beam with Perfobond FRP Used as a Permanent Formwork (퍼포본드 FRP를 영구거푸집으로 활용한 합성보의 휨거동에 관한 유한요소해석 연구)

  • Kook, Moo-Sung;Yoo, Seung-Woon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.12 no.7
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    • pp.3280-3286
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    • 2011
  • In recent years, many efforts have steadily been allocated to develop a new deck system in terms of its materials and structures in order to make up for the shortcomings of reinforced concrete deck. This study implemented and analyzed the verification for concrete composite beam with perfobond FRP as a permanent formwork and the tensile reinforcement, using non-linear finite element analysis program. Approximately 8-15% difference of ultimate failure load between numerical and experimental results were found and showed a similar figure of strain distribution in failure state.

A STUDY ON THE OPTIMAL RADIOPACITY OF POSTERIOR COMPOSITE RESINS (구치부 복합레진의 적정 RADIOPACITY에 관한 연구)

  • Kim, Byung-Hyun;Lee, Chung-Sik;Um, Chung-Moon
    • Restorative Dentistry and Endodontics
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    • v.17 no.1
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    • pp.206-213
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    • 1992
  • The aim of this study was to compare the accuracy of radiographic diagnosis of secondary carious lesions adjacent to composite filling materials with different radiopacity. The level of radiopacity that is most compatible with the radiographic diagnosis of secondary caries was studied in a two part experiment. In the first part, the radiopacity of 6 posterior composites CBP, CF, HM, LF, PQ, P50), enamel and dentin were measured by desitometer and 6 posterior composites divided into 3 groups based on their level of radiopacity compared with enamel and dentin. In the seocnd part, class II composite fillings with or without secondary caries were made in extracted premolar and radiographs of the teeth were examined by 10 dentists to diagnose simulated carious lesion. The following results were obtained: 1. The radiopacity of 6 posterior composites varied between 1.76(PQ) and 6.78(P50)mm Al equivalent. 2. For 4 composites the radiopacity exeeded that of an equal thickness of enamel, and for two the radiopacity was lower than that of dentin. 3. The detection of secondary caries was facillitated when the radiopacity of a composite resin was similar to or slightly greater than that of enamel.

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Effect of three different irrigation solutions applied by passive ultrasonic irrigation

  • Llena, Carmen;Forner, Leopoldo;Cambralla, Raquel;Lozano, Adrian
    • Restorative Dentistry and Endodontics
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    • v.40 no.2
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    • pp.143-148
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    • 2015
  • Objectives: This study evaluated the maximum depth and percentage of irrigant penetration into dentinal tubules by passive ultrasonic irrigation (PUI). Materials and Methods: Thirty extracted human teeth were instrumented and divided into three groups. According to final irrigation regimen, 5.25% sodium hypochlorite (Group A, NaOCl), 2% chlorhexidine (Group B, CHX) and saline solution (Group C, control group) were applied with Irrisafe 20 tips (Acteon) and PUI. Irrigant was mixed with 0.1% rhodamine B. Sections at 2 mm, 5 mm, and 8 mm from the apex were examined with confocal laser scanning microscopy (CLSM). The percentage and maximum depth of irrigant penetration were measured. Kruskal-Wallis test and Mann-Whitney test were performed for overall comparison between groups at each level and for pairwise comparison, respectively. Within a group, Wilcoxon test was performed among different levels. p values less than 0.05 were considered significant. Results: In all groups, highest penetration depth and percentage of penetration were observed at the 8 mm level. At 2 mm level, Groups A and B had significantly greater depths and percentages in penetration than Group C (p < 0.05), but there were no significant differences between Groups A and B. At 5 mm level, penetration depths and percentage of penetration was not significantly different among the groups. Conclusions: NaOCl and CHX applied by PUI showed similar depth and percentage of penetration at all evaluated levels.

Investigation of phenol phormaldehyde-based photoresist at an initial stage of destruction in $O_2$ and $N_2O$ radiofrequency discharges

  • Shutov, D.A.;Kang, Seung-Youl;Baek, Kyu-Ha;Suh, Kyung-Soo;Min, Nam-Ki;Kwon, Kwang-Ho
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.214-215
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    • 2007
  • Etch rates and surface chemistry of phenol formaldehyde-based photoresist after short time $O_2\;and\;N_2O$ radio frequency (RF) plasma treatment depending on exposure time were investigated. It was found that the etch rate of photoresist sharply increased after discharge turn on and reached a limit with increase in plasma exposure time in both gases. X-ray photoelectron spectroscopy (XPS) analysis showed that the surface chemical structure become nearly constant after the treatment of 15 sec. Concentration of surface oxygen-containing groups after processing both in oxygen and in $N_2O$ plasmas is similar.

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CMOS Integrated Multiple-Stage Frequency Divider with Ring Oscillator for Low Power PLL

  • Ann, Sehyuk;Park, Jusang;Hwang, Inwoo;Kim, Namsoo
    • Transactions on Electrical and Electronic Materials
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    • v.18 no.4
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    • pp.185-189
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    • 2017
  • This paper proposes a low power frequency divider for an integrated CMOS phase-locked loop (PLL). An injection-locked frequency divider (ILFD) was designed, along with a current-mode logic (CML) frequency divider in order to obtain a broadband and high-frequency operation. A ring oscillator was designed to operate at 1.2 GHz, and the ILFD was used to divide the frequency of its input signal by two. The structure of the ILFD is similar to that of the ring oscillator in order to ensure the frequency alignment between the oscillator and the ILFD. The CML frequency divider was used as the second stage of the divider. The proposed frequency divider was applied in a conventional PLL design, using a 0.18 ${\mu}m$ CMOS process. Simulation shows that the proposed divide-by-two ILFD and the divide-by-eight CML frequency dividers operated as expected for an input frequency of 1.2 GHz, with a power consumption of 30 mW.