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Screening of Dietary Fiber Degradation Enzyme for Making Sweet Potato Soju by Vacuum Distillation (감압증류법의 고구마소주 제조를 위한 식이섬유 분해효소의 선별)

  • Takamine, Kazunori;Jeon, Byung-Hun;Kim, Won-Sin
    • Journal of Physiology & Pathology in Korean Medicine
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    • v.26 no.1
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    • pp.35-39
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    • 2012
  • Sweet potato soju(SPS) has been made by vacuum distillation because sweet potato contains much fibrous materials which give high density to sweet potato mash. Generally, the SPS made by vacuum distillation has soft flavors and tastes. If the viscosity of sweet potato mash could be decreased by degradation enzyme, the process and production of SPS making by the method of vacuum distillation may be simplified and easier to distil the fermented sweet potato. Because the fibrous materials of sweet potato contains pectin with methoxyl group, methanol can be produced by fibrous degradation enzyme. For appling the fiber degradation enzymes to sweet potato mash for making SPS, the enzyme should be needed to degrade fibrous material without producing methanol. Special two fibrolytic enzymes are selected from 26 kind of commercial enzymes for the simplified and easier production of sweet potato soju by vacuum distillation, The selected enzyme A and X can degrade the fibrous material pectin of sweet potato without producing methanol. Although the different companies have produced the enzymes, same cellulase has been prepared from Trichoderma. reesei. The viscosity of sweet potato mash treated by the enzymes is decreased by 3 times with comparison to the viscosity of sweet potato mash of control group. The methanol concentration in the vacuum distilled SPS treated with the enzymes is 0.16%. The concentration is similar to that of commercially distilled SPS(0.15%). The result may suggest that the selected cellulases, A and X, can be used to make SPS by vacuum distillation.

Nanocrystalline Diamond Coated SiC Balls in Tribometer (나노결정질 다이아몬드가 코팅된 SiC 마모시험기 볼)

  • Im, Jong Hwan;Kang, Chan Hyoung
    • Journal of Surface Science and Engineering
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    • v.47 no.5
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    • pp.263-268
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    • 2014
  • Nanocrystalline diamond(NCD) coated SiC balls were applied in a ball-on-disk tribometer. After seeding in an ultrasonic bath containing nanometer diamond powders, $2.2{\mu}m$ thick NCD films were deposited on sintered 3 mm diameter SiC balls at $600^{\circ}C$ in a 2.45 GHz microwave plasma CVD system. Bare $ZrO_2$ and SiC balls were prepared for comparison as test balls. Tribology tests were performed in air with pairs of three different balls and mirror polished steel(SKH51) disk. The wear tracks on balls and disks were examined by optical microscope and alpha step profiler. Under the load of 3 N, the friction coefficients of steel against $ZrO_2$, SiC and NCD-coated balls were between 0.4 and 0.8. After a few thousands sliding laps, the friction coefficient of NCD-coated balls dropped from 0.45 to below 0.1 and maintained thereafter. Under a higher load of 10 N or 20 N with a long sliding distance of 2 km, $ZrO_2$ and SiC balls exhibited the similar friction coefficients as above. The friction coefficient of NCD-coated balls was less than 0.1 from the beginning and increased to above 0.1 steadily or with some fluctuations as sliding distance increased. NCD coating layers were found worn out after long duration and/or high load sliding test, which resulted in the friction coefficient higher than 0.1.

Measurement of Adhesion Strength and Nanoindentation of Metal Interconnections of Al/Ni and TiW/Ni Layers Formed on Glass Substrate (유리기판 위에 형성된 Al/Ni 및 TiW/Ni 다층 금속배선막의 계면 접합력 및 나노압입특성 평가)

  • Joe, Chul Min;Kim, Jae Ho;Hwang, So Ri;Yun, Yeo Hyeon;Oh, Yong Jun
    • Korean Journal of Metals and Materials
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    • v.48 no.12
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    • pp.1116-1122
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    • 2010
  • Metal interconnections of multilayer Al/Ni and TiW/seed-Ni/Ni were formed on glass, and the adhesion strength and nanoindentation response of the composite layers were evaluated. The Al/Ni multilayer was formed by an anodic bonding of glass to Al and subsequent electroless plating of Ni, while the TiW/Ni multilayer was fabricated by sputter deposition of TiW and seed-Ni onto glass and electroless plating of Ni. Because of the diffusion of aluminum into glass during the anodic bonding, anodically bonded glass/Al joint exhibited greater interfacial strength than the sputtered glass/TiW one. The Al/Ni on glass also showed excellent resistance against delamination by bending deformation compared to the TiW/seed-Ni/Ni on glass. From the nanoindentation experiment of each metal layer on glass, it was found that the aluminum layer had extremely low hardness and elastic modulus similar to the glass substrate and played a beneficial role in the delamination resistance by lessening stress intensification at the joint. The indentation data of the multilayers also supported superior joint reliability of the Al/Ni to glass compared to that of the TiW/seed-Ni/Ni to glass.

Evaluations of Microstructure and Electrochemical Anodic Polarization of AISI 304L and AISI 316L Stainless Steel Weld Metals with Creq/Nieq Ratio (Creq/Nieq비에 따른 AISI 304L 및 AISI 316L 스테인리스강 용접부의 미세조직 및 전기화학적 양극분극 평가)

  • Kim, Yeon Hee;Jang, Ah Young;Kang, Dong Hoon;Ko, Dae Eun;Shin, Yong Taek;Lee, Hae Woo
    • Korean Journal of Metals and Materials
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    • v.48 no.12
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    • pp.1090-1096
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    • 2010
  • This pitting corrosion study of welded joints of austenitic stainless steels (AISI 304L and 316L) has addressed the differentiating solidification mode using three newly introduced filler wires with a flux-cored arc welding process (FCAW). The delta ferrite (${\delta}$-ferrite) content in the welded metals increased with an increasing equivalent weight ratio of chromium/nickel ($Cr_{eq}/Ni_{eq}$). Ductility dip cracking (DDC) was observed in the welded metal containing ferrite with none of AISI 304L and 0.1% of AISI 316L. The potentiodynamic anodic polarization results revealed that the $Cr_{eq}/Ni_{eq}$ ratio in a 3.5% NaCl solution didn't much affect the pitting potential ($E_{pit}$). The AISI 316L welded metals with ${\ddot{a}}$-ferrite content of over 10% had a superior $E_{pit}$ value. Though the AISI 316L welded metal with 0.1% ferrite had larger molybdenum contents than AISI 304L specimens, it showed a similar $E_{pit}$ value because the concentration of chloride ions and the corrosion product induced severe damage near the DDC.

Nanocomposite Coating with TiAlN and Amorphous Carbon Phases Synthesized by Reactive Magnetron Sputtering

  • Kim, Bom Sok;Kim, Dong Jun;La, Joung Hyun;Lee, Sang Yong;Lee, Sang Yul
    • Korean Journal of Metals and Materials
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    • v.50 no.11
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    • pp.801-808
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    • 2012
  • TiAlCN coatings with various C contents were synthesized by unbalanced magnetron sputtering. The characteristics, the crystalline structure, surface morphology, hardness, and friction coefficient of the coatings as a function of the C content were investigated by X-ray diffraction (XRD), atomic force microscopy (AFM), a microhardness tester, and a wear test. In addition, their corrosion behaviors in a deaerated 3.5 wt% NaCl solution at $40^{\circ}C$ were investigated by potentiodynamic polarization tests. The results indicated that the $Ti_{14.9}Al_{15.5}C_{30.7}N_{38.9}$ coating had the highest hardness, elastic modulus, and a plastic deformation resistance of 39 GPa, 359 GPa, and 0.55, respectively, and it also had the lowest friction coefficient of approximately 0.26. Comparative evaluation of the TiAlCN coatings indicated that a wide range of coating properties, especially coating hardness, could be obtained by the synthesis methods and processing variables. The microhardness of the coatings was much higher than that from previously reported coating using similar magnetron sputtering processes. It was almost as high as the microhardness measured from the TiAlCN coatings (~41 GPa) synthesized using an arc ion plating process. The potentiodynamic test showed that the corrosion resistance of the TiAlCN coatings was significantly better than the TiAlN coatings, and their corrosion current density ($i_{corr}$), corrosion potentials ($E_{corr}$) and corrosion rate decreased with an increasing C content in the coatings. The much denser microstructure of the coatings due to the increased amount of amorphous phase with increasing C contents in the coatings could result in the the improved corrosion resistance of the coatings.

Reducing Soil Loss of Sloped Land using Lime-Organic Compost mixtures under Rainfall Simulation (인공강우 모사를 통한 석회/유기퇴비 혼합물의 경사지 토양유실 억제효과)

  • Koh, Il-Ha;Roh, Hoon;Hwang, Wonjae;Seo, Hyunggi;Ji, Won Hyun
    • Journal of Soil and Groundwater Environment
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    • v.23 no.3
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    • pp.43-50
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    • 2018
  • In a previous study, the feasibility of four materials (bentonite, steelmaking slag, lime and organic compost) to induce soil aggregate formation was assessed and the mixtures of organic compost and lime were chosen as most effective amendments in terms of cost benefit. This work is a subsequent study to evaluate the effectiveness of those amendments in reducing soil loss in $15^{\circ}$ sloped agricultural area by using rainfall simulation test. Three different soils were treated with two conditions of organic compost/lime mixtures (2% + 2%, 3% + 1%, w/w). In the amended soils, soil fertility was increased due to the increase of CEC, T-N, and T-P. During the rainfall simulation, suspended solid in run-off water from amended soil were reduced by 43% ~ 78%. When the content of organic compost was higher than that of lime, reduction of soil loss was also increased by 67% ~ 78%. Sediment discharge was also decreased by 72% ~ 96% in the amended soil. Similar to the suspended solid analysis, higher organic compost content led to more reduction of soil discharging, which implies organic compost is more effective than lime in reducing soil loss. The overall result suggests that the mixtures of organic compost and lime could be used as amendment materials to reduce soil loss in sloped farmland.

NiOx-based hole injection layer for organic light-emitting diodes (유기발광소자에 적용 가능한 NiOx 기반의 정공주입층 연구)

  • Kim, Junmo;Gim, Yejin;Lee, Wonho;Lee, Donggu
    • Journal of Sensor Science and Technology
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    • v.30 no.5
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    • pp.309-313
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    • 2021
  • Organic semiconductors have received tremendous attention for their research because of their tunable electrical and optical properties that can be achieved by changing their molecular structure. However, organic materials are inherently unstable in the presence of oxygen and moisture. Therefore, it is necessary to develop moisture and air stable semiconducting materials that can replace conventional organic semiconductors. In this study, we developed a NiOx thin film through a solution process. The electrical characteristics of the NiOx thin film, depending on the thermal annealing temperature and UV-ozone treatment, were determined by applying them to the hole injection layer of an organic light-emitting diode. A high annealing temperature of 500 ℃ and UV-ozone treatment enhanced the conductivity of the NiOx thin films. The optimized NiOx exhibited beneficial hole injection properties comparable those of 1,4,5,8,9,11-hexaazatriphenylene hexacarbonitrile (HAT-CN), a conventional organic hole injection layer. As a result, both devices exhibited similar power efficiencies and the comparable electroluminescent spectra. We believe that NiOx could be a potential solution which can provide robustness to conventional organic semiconductors.

A Study on the Development of Gear Transmission Error Measurement System and Verification (기어 전달오차 계측 시스템 개발 및 검증에 관한 연구)

  • Moon, Seok-Pyo;Lee, Ju-Yeon;Moon, Sang-Gon;Kim, Su-Chul
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.20 no.12
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    • pp.136-144
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    • 2021
  • The purpose of this study was to develop and verify a precision transmission error measurement system for a gear pair. The transmission error measurement system of the gear pair was developed as a measurement unit, signal processing unit, and signal analysis unit. The angular displacement for calculating the transmission error of the gear pair was measured using an encoder. The signal amplification, interpolation, and transmission error calculation of the measured angular displacement were conducted using a field-programmable gate array (FPGA) and a real-time processor. A high-pass filter (HPF) was applied to the calculated transmission error from the real-time processor. The transmission error measurement test was conducted using a gearbox, including the master gear pair. The same test was repeated three times in the clockwise and counterclockwise directions, respectively, according to the load conditions (0 - 200 N·m). The results of the gear transmission error tests showed similar tendencies, thereby confirming the stability of the system. The measured transmission error was verified by comparing it with the transmission error analyzed using commercial software. The verification showed a slight difference in the transmission error between the methods. In a future study, the measurement and analysis method of the developed precision transmission error measurement system in this study may possibly be used for gear design.

Static and Fatigue Flexural Tests of Ductile High-performance Fiber Reinforced Cementitious Composites (고인성 섬유보강 콘크리트의 정적 및 피로 휨시험)

  • Shin, Kyung-Joon;Lee, Do-Keun;Lee, Kyoung-Chan;Kim, Sung-Il
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.4
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    • pp.602-608
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    • 2021
  • Recently, research and development has been conducted to impart high performance and functionality to concrete materials by mixing various reinforcing materials into the matrix. Ductile fiber reinforced concrete using a large amount of fibers shows a distributed multiple cracking behavior, and various studies are being conducted on this material. However, research is focused on static behavioral analysis but studies on cyclic behaviors are not sufficient. In this study, beams were made of ductile fiber reinforced concrete with various fiber contents, and static and fatigue flexural tests were performed. As a result, the effect of fiber content on the flexural behavior was analyzed. Also, the applied load level and fatigue life relationship of ductile fiber reinforced concrete was proposed. Concrete with high ductile property could be achieved with a fiber content of 2%. When 0.5% fiber was more added, the maximum flexural strength was similar, but the flexural toughness is nearly doubled. On the other hand, there was no significant difference in the fatigue life of these two mixtures.

Effect of Alloying Element Addition on the Microstructure and Wear Properties of Die-casting ADC12 Alloy (ADC12 다이캐스팅 합금의 미세조직 및 기계적 특성에 미치는 개량 원소 첨가의 영향)

  • Kang, Y.J.;Yoon, S.I.;Kim, D.H.;Lee, K.A.
    • Transactions of Materials Processing
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    • v.28 no.1
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    • pp.34-42
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    • 2019
  • In this study, various alloying elements (Cr, Sr, Ca, Cd) were added to improve the mechanical properties of ADC12 fabricated by a die casting process. The effect of alloying elements on the microstructure and mechanical properties were investigated. The phase analysis results of the modified ADC12 alloy with conventional ADC12 alloy, showed the similar characteristics of Al matrix, Si phase, $CuAl_2$ phase and the Fe intermetallic phase. As a result of the microstructure observation, the secondary dendrite arm spacing (SDAS) was shown to have decreased after the addition of the alloying elements. The eutectic Si phase, which existed as flake form in the conventional ADC12 alloy, was modified finely as a fiber form in the modified ADC12 alloy. It was observed that the $CuAl_2$ phase as the strengthening phase was relatively finely distributed in the modified ADC12 alloy. The Fe intermetallic appeared as a Chinese script shaped $Al_6$ (Mn,Fe) which is detrimental to mechanical properties in conventional ADC12 alloy. On the other hand, in the modified ADC12 alloy, polyhedral ${\alpha}-Al_{15}Si_2$ $(Fe,Mn,Cr)_3$ was observed. The tensile properties were improved in the modified ADC12 alloy. The yield strength and tensile strength increased by 12.4% and 10.0%, respectively, in the modified ADC12 alloy, and the elongation was also seen to have been increased. As a result of the pin on disk wear test, the wear resistance properties were also improved by up to about 7% in the modified ADC12 alloy. It is noted that the wear deformation microstructures were also observed, and it was found that the fine eutectic Si and strengthening phases greatly improved abrasion resistance.