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Comparative evaluation of the subtractive and additive manufacturing on the color stability of fixed provisional prosthesis materials (고정성 임시 보철물 재료의 색 안정성에 대한 절삭 및 적층가공법의 비교평가)

  • Lee, Young-Ji;Oh, Sang-Chun
    • Journal of Dental Rehabilitation and Applied Science
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    • v.37 no.2
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    • pp.73-80
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    • 2021
  • Purpose: The purpose of this study is to compare the color stability of provisional restorative materials fabricated by subtractive and additive manufacturing. Materials and Methods: PMMA specimens by subtractive manufacturing and conventional method and bis-acryl specimens by additive manufacturing were fabricated each 20. After immersing specimens in the coffee solution and the wine solution, the color was measured as CIE Lab with a colorimeter weekly for 4 weeks. Color change was calculated and data were analyzed with one-way ANOVA and the Tukey multiple comparisons test (α = 0.05). Results: PMMA provisional prosthetic materials by subtractive manufacturing showed superior color stability compared to bis-acryl provisional prosthetic materials by additive manufacturing (P < 0.05), and showed similar color stability to the PMMA provisional prosthetic materials by conventional method (P > 0.05). Conclusion: It is recommended to fabricate provisional restorations by subtractive manufacturing in areas where esthetics is important, such as anterior teeth, and consideration of the color stability will be required when making provisional prosthetic using additive manufacturing.

Synthesis and Optical Property of (GaN)1-x(ZnO)x Nanoparticles Using an Ultrasonic Spray Pyrolysis Process and Subsequent Chemical Transformation (초음파 분무 열분해와 화학적 변환 공정을 이용한 (GaN)1-x(ZnO)x 나노입자의 합성과 광학적 성질)

  • Kim, Jeong Hyun;Ryu, Cheol-Hui;Ji, Myungjun;Choi, Yomin;Lee, Young-In
    • Journal of Powder Materials
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    • v.28 no.2
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    • pp.143-149
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    • 2021
  • In this study, (GaN)1-x(ZnO)x solid solution nanoparticles with a high zinc content are prepared by ultrasonic spray pyrolysis and subsequent nitridation. The structure and morphology of the samples are investigated by X-ray diffraction (XRD), field-emission scanning electron microscopy, and energy-dispersive X-ray spectroscopy. The characterization results show a phase transition from the Zn and Ga-based oxides (ZnO or ZnGa2O4) to a (GaN)1-x(ZnO)x solid solution under an NH3 atmosphere. The effect of the precursor solution concentration and nitridation temperature on the final products are systematically investigated to obtain (GaN)1-x(ZnO)x nanoparticles with a high Zn concentration. It is confirmed that the powder synthesized from the solution in which the ratio of Zn and Ga was set to 0.8:0.2, as the initial precursor composition was composed of about 0.8-mole fraction of Zn, similar to the initially set one, through nitriding treatment at 700℃. Besides, the synthesized nanoparticles exhibited the typical XRD pattern of (GaN)1-x(ZnO)x, and a strong absorption of visible light with a bandgap energy of approximately 2.78 eV, confirming their potential use as a hydrogen production photocatalyst.

Verification of Shielding Materials for Customized Block on Metal 3D Printing (금속 3D 프린팅을 통한 맞춤형 차폐블록 제작에 사용되는 차폐 재료 검증)

  • Kyung-Hwan, Jung;Dong-Hee, Han;Jang-Oh, Kim;Hyun-Joon, Choi;Cheol-Ha, Baek
    • Journal of the Korean Society of Radiology
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    • v.17 no.1
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    • pp.25-30
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    • 2023
  • As 3D printing technology is used in the medical field, interest in metal materials is increasing. The Department of Radiation Oncology uses a shielding block to shield the patient's normal tissue from unnecessary exposure during electron beam therapy. However, problems such as handling of heavy metal materials such as lead and cadmium, reproducibility according to skill level and uncertainty of arrangement have been reported. In this study, candidate materials that can be used for metal 3D printing are selected, and the physical properties and radiation dose of each material are analyzed to develop a customized shielding block that can be used in electron beam therapy. As candidate materials, aluminum alloy (d = 2.68 g/cm3), titanium alloy (d = 4.42 g/cm3), and cobalt chromium alloy (d = 8.3 g/cm3) were selected. The thickness of the 95% shielding rate point was derived using the Monte Carlo Simulation with the irradiation surface and 6, 9, 12, and 16 energies. As a result of the simulation, among the metal 3D printing materials, cobalt chromium alloy (d = 8.3 g/cm3) was similar to the existing shielding block (d = 9.4 g/cm3) in shielding thickness for each energy. In a follow-on study, it is necessary to evaluate the usefulness in clinical practice using customized shielding blocks made by metal 3D printing and to verify experiments through various radiation treatment plan conditions.

Comparative Analysis of the Physical and Biochemical Properties of Light-cure Resin-modified Pulp Capping Materials

  • Tae Gyeom Kim;Jongsoo Kim;Joonhaeng Lee;Jisun Shin;Mi Ran Han;Jongbin Kim;Yujin Kim;Jae Hee Park
    • Journal of the korean academy of Pediatric Dentistry
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    • v.51 no.2
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    • pp.149-164
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    • 2024
  • This study compared the solubility, water absorption, dimensional stability, release of various ions (hydroxyl, calcium, sulfur, strontium, and silicon), and cytotoxicity of light-cured resin-modified pulp-capping materials. Resin-modified calcium hydroxide (Ultra-blendTM plus, UBP), light-cured resin-modified calcium silicate (TheraCal LCTM, TLC), and dual-cure resin-modified calcium silicate (TheraCal PTTM, TPT) were used. Each material was polymerized; solubility, 24-hour water absorption, and 30- day dimensional stability experiments were conducted to test its physical properties. Solubility was assessed according to the ISO 6876 standard, and 24 hours of water absorption, 30 days of dimensional stability were assessed by referring to the previous protocol respectively. Eluates at 3 and 24 hours and on 7, 14, and 28 days were analyzed according to the ISO 10993-12 standard. And the pH, Ion-releasing ability, cell proliferation rate, and cell viability were assessed using the eluates to evaluate biochemical characteristics. pH was measured with a pH meter and Ion-releasing ability was assessed using inductively coupled plasma atomic emission spectrometry (ICP-AES). Cell proliferation rate and cell viability were assessed using human dental pulp cells (hDPCs). The former was assessed by an absorbance assay using the CCK-8 solution, and the latter was assessed by Live and Dead staining. TPT exhibited lower solubility and water absorption than TLC. UBP and TPT demonstrated higher stability than TLC. The release of sulfur, strontium, calcium, and hydroxyl ions was higher for TLC and TPT than for UBP. The 28-day release of hydroxyl and silicon ions was similar for TLC and TPT. TLC alone exhibited a lower cell proliferation rate compared to the control group at a dilution ratio of 1 : 2 in cell proliferation and dead cells from Live and Dead assay evaluation. Thus, when using light-cure resin-modified pulp-capping materials, calcium silicate-based materials can be considered alternatives to calcium hydroxide-based materials. Moreover, when comparing physical and biochemical properties, TPT could be prioritized over TLC as the first choice.

Comparison of CNG and LPG Combustion Characteristics in a Large-sized Gas Engine (대형 가스엔진에서 CNG와 LPG 연료의 연소 특성 비교)

  • Yongrae Kim;Cheolwoong Park;Hyungjun Jang;Sangho Lee;Young Choi;Sunyoep Lee
    • Journal of the Korean Institute of Gas
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    • v.28 no.2
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    • pp.1-6
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    • 2024
  • An easy approach to replacing older diesel engines is to replace them with gas engines using fuels such as CNG or LPG. However, fuels such as LPG have not been applied to large gas engines in many cases, so it is not easy to predict the performance of gas engines based on CNG fuel. Accordingly, in this study, we applied LPG fuel to a CNG-based large gas engine and examined the performance and emission characteristics. In particular, the results were confirmed through tests to see how effective EGR, which is widely used for NOx reduction, is applied. As a result, in the case of LPG, even though the operating conditions were secured to a level that excludes serious knocking, mild knocking at high loads was still found to be more frequent than CNG. However, it was possible to secure an output level similar to CNG in the high-speed range. Efficiency was higher due to a faster combustion speed than CNG, and it was confirmed that it was possible to simultaneously reduce NOx and the frequency of mild knocking through the application of EGR.

Deformation Behavior Investigation of Materials by Debonding Failure in Adhesion and Repairing-strengthening Methods of RC Construction (RC구조물 접착 보수·보강 공법의 박리와 연관한 재료의 변형 거동 분석)

  • Han, Cheon-Goo;Byun, Hang-Yong;Park, Yong-Kyu
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.11 no.5
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    • pp.89-98
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    • 2007
  • This study investigates the deformation behavior, related to debonding failure, of adhesion and repairing-strengthening materials of RC construction. A strain-stress curve shows that when the stress of specimens reached the highest and then fails, the strain value of cement mortar is $2.0{\times}10^{-3}$, while concrete was indicated at around $1.3{\times}10^{-3}$, epoxy resins are $0.8{\times}10^{-3}$, polymer mortar is $2.5{\times}10^{-3}$, steel plate is $2.5{\times}10^{-3}$, and carbon bar was $9.1{\times}10^{-3}$, respectively. For a thermal expansion coefficient with temperature variation, those basis materials, cement mortar and concrete, exhibited around $10{\mu}{\varepsilon}/{^{\circ}C}$, but adhesive materials, such as epoxy resins and polymer mortar, were $41{\sim}54{\mu}{\varepsilon}/{^{\circ}C}$ and $-0.5{\sim}0.7{\mu}{\varepsilon}/{^{\circ}C}$, respectively. In the case of steel plate is similar to basic materials but carbon fiber is indicates at $-1.7{\mu}{\varepsilon}/{^{\circ}C}$, which is the lowest value. Especially, between basic and adhesive materials, the thermal expansion coefficient was highly different. Although the coefficient depends on the type of epoxy resins, it is clear that the epoxy resins are susceptible to be debonded in nature, when the difference of environmental temperature varies more than $20{\sim}35{^{\circ}C}$.

Evaluation of Lac Cultivation in Two South-Western Districts of Bangladesh

  • Bahar, Habibullah;Islam, Tarikul;Islam, Monirul;Mannan, Abdul
    • International Journal of Industrial Entomology and Biomaterials
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    • v.15 no.1
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    • pp.79-82
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    • 2007
  • Lac is the dermal secretion of lac insect, Kerria lacca Kerr., which is used to make expensive natural dye, burnish, coating materials, in cosmetics and jewelry industry. Though it is very perspective industry and available of host plants over the country especially in southern districts of Bangladesh, lac cultivation is confined within some northern districts of Bangladesh. Experiment was conducted to find out the possibility of lac cultivation in two southwestern districts of Bangladesh: Khulna and Satkhira compared to Chapainowabgonj, the key lac producing district in Bangladesh, during February-October, 2006. The bark thickness, bark weight of ber plant, ratio of harvested and inoculated lac sticks, harvested raw lac, and harvested processed lac were measured and compared. Statistically, similar performance of lac cultivation was found regarding all parameters in three districts. These results recommended that lac cultivation is possible at the south-western coastal part of Bangladesh.

Mechanical Properties of FRP for Electrical Insulators (전기절연용 FRP의 강도특성)

  • Park, Hoy-Yul;Kang, Dong-Pil;Han, Dong-Hee;Pyo, Hyun-Dong
    • Proceedings of the KIEE Conference
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    • 1999.07d
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    • pp.1572-1574
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    • 1999
  • FRP has been used very much as high strength core materials for insulators because of its high strength and good insulation properties. The fiber orientation of FRP has a great effect on FRP strength because the strength of FRP mainly depends on the strength of fiber. In this study, compression and bending stress were simulated along to the orientation of glass fiber. In addition, FRP was made by pultrusion and filament winding method. The compression and flexural strength were measured. The tendency of compression and flexural strength according to the fiber orientation of practical measured value of FRP was similar to simulated results.

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Hydrogen and Alkali Ion Sensing Properties of Ion Implanted Silicon Nitride Thin Film

  • Park, Gu-Bum
    • Transactions on Electrical and Electronic Materials
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    • v.9 no.6
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    • pp.231-236
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    • 2008
  • B, P, and Cs ions were implanted with various parameters into silicon nitride layers prepared by LPCVD. In order to get the maximum impurity concentration at the silicon nitride surface, a high temperature oxide (HTO) buffer layers was deposited prior to the implantation. Alkali ion and pH sensing properties of the layers were investigated with an electrolyte-insulator-silicon (EIS) structure using high frequency capacitance-voltage (HF-CV) measurements. The ion sensing properties of implanted silicon nitrides were compared to those of as-deposited silicon nitride. Band Cs co-implanted silicon nitrides showed a pronounced difference in pH and alkali ion sensing properties compared to those of as-deposited silicon nitride. B or P implanted silicon nitrides in contrast showed similar ion sensitivities like those of as-deposited silicon nitride.

Type I Ventricular Septal Defect in Korean Pateints (한국인의 심실중격결손증 제 1형)

  • Lee, Yung-Kyoon;Yang, Gi-Min
    • Journal of Chest Surgery
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    • v.13 no.4
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    • pp.418-421
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    • 1980
  • During the period from August 1959 to end of July 1980, 69 cases of Type I VSD were noted among 235 cases of ventricular septal defect who were operated utilizing cardiopulmonary bypass in the Department of Cardio-thoracic Surgery, College of Medicine, Seoul National University(29.4%). During the same period 1162 open heart surgery cases were experienced among whom 778 cases were congenital anomalies. There were no significent differences between Type I '||'&'||' other tvpo:s of VSD in sex and age distribution. In Type I VSD frequency of aortic regurgitation association was much higher than rest of the types. (8.7% to 2.6%). Necessity of patch closure in Type I was not different from other types. The high incidence of Type I VSD is quite similar to Japanese references which show quite higher ratio compared with from Euroamerican caucasian patients materials. All cases were operated on with bubble type oxygenator mainly Shiley**" oxygenator utilizing hypothermic hemodilution perfusion technique.echnique.

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