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Effects of Conductive Material on $LiCoO_2$ Cathode for the Lithium ion Battery (리튬이온전지용 $LiCoO_2$ 정극의 도전재료에 따른 특성)

  • Coh Chil Hoon;Moon Seong In;Hyung Yoo Eup;Yun Mun Soo;Park Chun Jun;Yun Duk Hyun;Yun Suong Kyu
    • Journal of the Korean Electrochemical Society
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    • v.2 no.2
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    • pp.88-92
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    • 1999
  • The apparent density. self-separation of the electrode composite from current collector in the electrolyte solution and specific resistance of electronic conduction of the electrode composite were examined by the variation of content of conductive material such as graphitic and black carbons in $LiCoO_2$ composite electrode for lithium ion battery. Increasing the content of conductive material, the apparent density of Lico02 composite electrode was decreased and that of $LiCoO_2$ in composite electrode was only rapidly decreased compared to that of composite. $LiCoO_2$ composite electrodes containing more than 4.1 weight percent of super s black as a conductive material were seU-separated by the immersion into 1 mol/I $LiPF_6$ in propylene carbonate and diethyl carbonate (1:1 volume ratio). Specific resistances related to the electronic conduction of composite electrode were decreased by the increasing the content i)f conductive material. Specific resistance of the composite electrode including $2\~3\%w/w$ of super s black as conductive material was similar to that of $12\%w/w$ of Lonza KS6. In the range of this study, super s black as conductive material is better than Lonza KS6 on battery capacity because of apparent density of $LiCoO_2$ in electrode composite including super s black is higher than that of Lonza KS6.

Study on the Development and Property of Epoxy Putty with Excellent Low Shrinkage and Cutting Force Using Mercaptan Type and Diamine Type (Mercaptan계와 Diamine계를 이용한 저수축·절삭력이 우수한 Epoxy Putty의 개발 및 물성에 관한 연구)

  • Oh, Seung-Jun;Wi, Koang-Chul
    • Journal of Adhesion and Interface
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    • v.16 no.4
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    • pp.137-145
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    • 2015
  • This study aimed to develop epoxy putty as a multi-purpose connection and restoration material that can be used for material-specific restoration work such as metal, wood, ceramics, earthenware and stone artifacts by replacing synthetic resins currently being used for preservation treatment of cultural assets. Existing synthetic resins have the issue of cutting force resulting from high strength, deflection resulting from long hardening time, contaminating the surface of artifacts through staining on tools or gloves and need for re-treatment resulting from material discoloration. Accordingly, paste type restoration material most widely being used in the field of cultural assets preservation treatment was selected and examined the property to select it as an object of comparison. Based on such process, epoxy putty was developed according to the kind of agent, hardener and filler. For the purpose of solving the issues of existing material and allowing the epoxy putty developed to have similar property, property experiments were conducted by selecting agents and hardeners with different characteristics and conditions. The study findings showed that both kinds are paste type that improved work convenience and deflection issue as a result of their work time of within 5~10 minutes that are about 3~10 times shorter than that of existing material. In regards to wear rate for increasing cutting force, it improved by about 3 times, thereby allowing easy molding. For the purpose of improving the issue of surface contamination that occurs during work process, talc and micro-ballon were added as filler to reduce the issue of stickiness and staining on hand. Furthermore, a multi-purpose restoration material with low shrinkage, low discoloration and high cutting force was developed with excellent coloring, lightweight and cutting force features.

Burst Test and Finite Element Analysis for Failure Pressure Evaluation of Nuclear Power Plant Pipes (원전 배관 손상압력 평가를 위한 파열시험 및 유한요소해석)

  • Yoon, Min Soo;Kim, Sung Hwan;Kim, Taesoon
    • Journal of the Korean Society of Safety
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    • v.30 no.1
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    • pp.144-149
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    • 2015
  • This study aims to quantitatively evaluate failure pressure of wall-thinned elbow under combined load along with internal pressure, by conducting real-scale burst test and finite element analysis together. For quantitative evaluation, failure pressure data was extracted from the real-scale burst test first, and then finite element analysis was carried out to compare with the test result. For the test, the wall-thinning defect of the extrados or intrados inside the center of 90-degree elbow was considered and the loading modes to open or close the specimen maintaining a certain load or displacement were applied. Internal pressure was applied until failure occurred. As a result, when the bending load was applied under the load control condition, the intrados of the defect was more affected by failure pressure than the extrados, and the opening mode was more vulnerable to failure pressure than the closing mode. When the bending load was applied under the displacement control, it was hardly affected by failure pressure though it was slightly different from the defect position. The result of the finite element analysis showed a similar aspect with the test. Moreover, when major factors such as material properties and pipeline thickness were calibrated to accurate values, the analytical results was more similar to the test results.

A Study on a Morphological Identification of Adenophora triphylla var. japonica, Codonopsis lanceolata, Adenophora remotiflora and Codonopsis pilosula (사삼(沙參), 양유근(羊乳根), 제니 및 당삼(黨參)의 형태(形態) 감별에 관한 연구)

  • Kim, Joo-Young;Lee, Young-Jong
    • The Korea Journal of Herbology
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    • v.22 no.2
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    • pp.121-126
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    • 2007
  • Objectives : A morphological classification among Adenophora triphylla var. japonica, Codonopsis lanceolata, Adenophora remotiflora and Codonopsis pilosula was made through microscopic observation. Method : The slice of the tested material made by paraffin section technique was colored with Safranine Malachite Green contrast methods, and then observed and photographed by olymphus-BHT. Result : 1. Codonopsis pilosula is like a long cone, with amole-like projected parts at the beginning of the roots. 2. Adenophora triphylla var. japonica, Codonopsis lanceolata, Adenophora remotiflora, and Codonopsis pilosula are all similar as following: 1) Cork layers are composed of a few to over 10 subsidiary cells, with individual or a group of stone cells among them. 2) Phloem is wide and has a milk tube. Conclusion : Adenophora triphylla var. japonica, Codonopsis lanceolata, Adenophora remotiflora, and Codonopsis pilosula are all similar and difficult to be distinguished through microscopic observation, so that chemical experiments should be conducted for their identification.

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Comparative Analysis on the Types of Representation to Communicate in Elementary Science and Mathematics Textbooks - In Case of the Sixth Grade 1st Semester - (초등 과학·수학 교과서의 의사소통 표현 방식에 따른 유형 비교 분석 - 6학년 1학기를 중심으로 -)

  • Jang, Mikyung;Shin, Youngjoon
    • Journal of Korean Elementary Science Education
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    • v.36 no.3
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    • pp.256-272
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    • 2017
  • The purpose of this research is to study and learn more features how this type of distribution for communication in $6^{th}$ grade first semester elementary science and mathematics according to communicative expression by 2009 revised curriculum. For this study, based on an analysis standard presented in previous research on the types of communication. The results of this research are as follows. First, because the mathematics presents the number of ways to communicate twice more than science, mathematics go through with much more problems to solve than science. Second, in mathematics, spoken method and written method have similar proportion, less in physical activity method. Third, Science showed balanced proportion among four areas; earth, life, energy, and material. On the other hand, mathematics only showed small numbers in the area of geometry but similar numbers in number and operations, regularity, measurement. Fourth, there is no common feature or relevance about communicative approach for convergence thinking in 2009 revised curriculum, it seems that it doesn't consider it as a revised.

Textures and Sensible Images on Structural Properties of Washable Wool and Normal Wool Knit Fabrics (Part II) -Focus on Preferences- (워셔블 울과 노멀 울편성물의 구성특성에 따른 질감 및 감성이미지 (제2보) -구성특성에 따른 선호도를 중심으로-)

  • Kim, Hyun-Ah;Ryu, Hyo-Seon
    • Journal of the Korean Society of Clothing and Textiles
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    • v.36 no.5
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    • pp.501-511
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    • 2012
  • This study examines the effect of structural properties of F/W wool knit fabrics for woman's knitwear on the preferences for textile designing through analyzing the relationship among the structural properties, mechanical properties, objective hand measurements, and preferences. The 'knit structure' was determined to be the most important parameter in rating preferences, apart from the 'preference for cardigans'. Consumers preferred washable wool to normal wool when comparing a normal wool knit with a washable wool knit on a 'knit structure' factor. Preferred structural properties showed a similar tendency 'preference for fabric' and the 'preference for cardigans', 'preference for sweaters' and 'preference for vests'. The 'sophisticated/feminine' factor showed a correlation with 'fabric preference' and the texture and sensible images had a similar effect on fabric preferences. In the relationship between objective hand measurements and fabric preferences, the KOSHI value had a negative coefficient and the THV value had a positive correlation with fabric preferences. In conclusion, we found a consumer preference for more flexible fabrics.

Non-Constructive analysis for the cover and inner paper in the Taebaeksan volume of Joseon Dynasty annals (조선왕조실록 태백산사고본 표지 및 내지의 비파괴적 특성 연구)

  • Cho, Jung-Hye;Kim, Kang-Jae;Eom, Tae-Jin
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.42 no.3
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    • pp.28-36
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    • 2010
  • Today We have three full series of the annals of Joseon Dynasty. Taebaeksan volume which is one of them shows comparatively good maintenance but Taebaeksan volume also decomposed in patches. The size of cover and inner paper were increased in late Joseon Dynasty, but the weight, thickness and basis weight bears no relation to each other. The oxidation index of paper in annals of pre-periods of King Sunjo shows very high value. After the annals of King Sunjo, the oxidation index of paper is very similar to today's Hanji. L.a.b values of inner paper in the Taebaeksan volume are similar generally. The average length of fiber using image analysis soft ware is 8.08~9.92 mm, that like immediate value of measurement. The air fraction of fiber's range is 1.20~2.12%. It lower than today's Hanji. After considering the factors of the length of fiber, air fraction and FE-SEM, we reached that no difference between raw material of inner paper in the Taebaeksan volume.

Development of simple HPLC-UV method for discrimination of Adenophorae Radix

  • Vu, Thi Phuong Duyen;Kim, Kyung Tae;Pham, Yen;Bao, Haiying;Kang, Jong Seong
    • Analytical Science and Technology
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    • v.30 no.2
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    • pp.82-88
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    • 2017
  • Adenophorae Radix (AR) is a frequently used medicinal herb; because of its popularity, products containing similar herbal products are often sold as substitutes, especially if their morphology is similar. However, any analytical method to identify AR based on quantitative analysis is not registered in Korea, Japan and China Pharmacopoeias. This study developed a simple HPLC method to discriminate between authentic AR and substitutes. Linoleic acid was used as a marker compound of AR. Our optimized HPLC-UV conditions included a mobile phase of 90 % acetonitrile under isocratic condition, and a flow rate of 1.0 mL/min at room temperature. Detection wavelength was set at 205 nm. Linoleic acid was detected at 13.5 minutes for a total analysis time of 20 minutes. The standard herb of AR contained 0.025 % of linoleic acid, while four authentic AR samples and eight substitutes contained 0.040~0.071 % and 0.004~0.014 %, respectively. Comparison of the linoleic acid concentrations of the sample types to reference AR showed that among 12 samples, only the four samples were authentic. Thus, our HPLC-UV method, along with our suggested content criterion for linoleic acid concentration, can be used for the quick and accurate determination whether the herbal products are authentic AR or substitute.

Mortar Characteristics for Reinforcement of Ancient Tomb Murals Using Oyster Shells

  • Lee, Hwa Soo;Yu, Yeong Gyeong;Han, Kyeong Soon
    • Journal of Conservation Science
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    • v.34 no.4
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    • pp.295-303
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    • 2018
  • The application of reinforcing agents with hydraulic property and strength development characteristics was studied under conditions similar to those of mural-painting mortar made with oyster shell powder. Reinforcement mortar made with oyster shell powder showed hydraulic properties and strength to supplement the weaknesses of natural hydraulic lime(NHL); this confirmed its possibility as a wall-reinforcing material with enough strength for preserving mural paintings. Reinforcement mortar 1 showed hydraulic property and general characteristics of lime mortar, such as consistency and viscosity, as well as lower strength and higher whiteness compared to an NHL product. For Reinforcement mortar 2, the original wall sample characteristics were reflected by mixing more shell produced through calcination; and it showed similar strength to that of Reinforcement mortar 1 as well as high whiteness. In measuring the contraction ratio of reinforcement mortar samples, Reinforcement mortar 1 and 2 showed more stability in property change compared to the NHL Group.

Flexural strength of circular concrete-filled tubes

  • Lee, Minsun;Kang, Thomas H.-K.
    • Advances in Computational Design
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    • v.1 no.4
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    • pp.297-313
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    • 2016
  • The flexural strength of circular concrete-filled tubes (CCFT) can be estimated by several codes such as ACI, AISC, and Eurocode 4. In AISC and Eurocode, two methods are recommended, which are the strain compatibility method (SCM) and the plastic stress distribution method (PSDM). The SCM of AISC is almost the same as the SCM of the ACI method, while the SCM of Eurocode is similar to the ACI method. Only the assumption of the compressive stress of concrete is different. The PSDM of Eurocode approach is also similar to the PSDM of AISC, but they have different definitions of material strength. The PSDM of AISC is relatively easier to use, because AISC provides closed-form equations for calculating the flexural strength. However, due to the complexity of calculation of circular shapes, it is quite difficult to determine the flexural strength of CCFT following other methods. Furthermore, all these methods give different estimations. In this study, an effort is made to review and compare the codes to identify their differences. The study also develops a computing program for the flexural strength of circular concrete filled tubes under pure bending that is in accordance with the codes. Finally, the developed computing algorithm, which is programmed in MATLAB, is used to generate design aid graphs for various steel grades and a variety of strengths of steel and concrete. These design aid graphs for CCFT beams can be used as a preliminary design tool.