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A STUDY ON THE SOFT MAGNETIC PROPERRTIES OF Fe-Ta-(N,C) NANOCRYSTALLINE THIN FILMS

  • Shin, Dong-Hoon;Ahn, Dong-Hoon;Kim, Hyoung-June;Nam, Seung-Eui
    • Journal of the Korean Magnetics Society
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    • v.5 no.5
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    • pp.601-605
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    • 1995
  • Magnetic properties of FeTaN and FeTaC films deposited by DC magnetron reactive sputter were investigated, and correlated with their microstructures. The optimum magnetic properties of Hc : 0.25 Oe, Bs : 14.5 kG, and ${\mu}'$ : 4000 (5MHz) are observed in the $Fe_{78.8}Ta_{8.5}N_{12.7}$ film, and Hc : 0.25 Oe, Bs : 14.5 kG, and ${\mu}'$ : 2700 (5MHz) in the $Fe_{75.6}Ta_{8.1}C_{16.3}$ film. In both FeTaN and FeTaC films with minimum grain size show the best soft magnetic properties. Thermal stability of the soft magnetic properties of FeTaN is found to be higher than FeTaC for similar compositons. TaN and TaC particles form to retard the growth of $\alpha$-Fe grains. TaN particles in FeTaN show higher efficiency in retarding the grain growth during heat treatments resulting the higher thermal stability, compared to TaC particles in FeTaC films.

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Development of Metal Composite Powder Non-corrosive Flux for Low Temperature Forming of the Aluminum Brazing Filler Material (비부식성 플럭스를 이용한 알루미늄 브레이징용 필러 소재의 저온 성형용 금속 복합 분말 개발)

  • Kim, Dae-Young;Jang, Ha-Neul;Yoon, Dae-Ho;Shin, Yun-Ho;Kim, Seong-Ho;Choi, Hyun-Joo
    • Journal of Powder Materials
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    • v.26 no.1
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    • pp.16-21
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    • 2019
  • In aluminum brazing processes, corrosive flux, which is used in preventing oxidation, is currently raising environmental concerns because it generates many pollutants such as dioxin. The brazing process involving non-corrosive flux is known to encounter difficulties because the melting temperature of the flux is similar to that of the base material. In this study, a new brazing filler material is developed based on aluminum and non-corrosive flux composite powder. To minimize the interference of consolidation aluminum alloy powder by the flux, the flux is intentionally embedded in the aluminum alloy powder using a mechanical milling process. This study demonstrates that the morphology of the composite powder can be varied according to the mixing process, and this significantly affects the relative density and mechanical properties of the final filler samples.

Study on the Distillation of Magnesium Alloy Scrap (마그네슘 합금 스크랩의 진공증류에 관한 연구)

  • Wi, Chang-Hyun;Yoo, Jung-Min;Jang, Byoung-Lok;You, Byoung-Don
    • Korean Journal of Metals and Materials
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    • v.46 no.1
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    • pp.13-19
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    • 2008
  • To develop a recycling process of magnesium alloy scrap, a fundamental study on the distillation of magnesium alloy melt was carried out. Melt temperature, vacuum degree and reaction time were considered as experimental variables. The amount of vaporized magnesium melt per unit surface area of melt increases with the increase of melt temperature, reaction time and vacuum degree. The vapor condensed at the tip of water cooling Cu-condenser as a form of pine cone. Magnesium and zinc were vaporized easily from the melt. However, It's difficult to separate magnesium and zinc by vacuum distillation because vapor pressure of zinc is similar to one of magnesium. The contents of aluminum, manganese and iron, etc. in residual melt increase due to the decrease of magnesium and zinc content after the distillation of magnesium alloy.

Synthesis and Characterization of Triptycene-Based Triphenylamine Electron Donor Molecules (트립티센 기반의 트리페닐아민 전자-주게 분자 합성 및 특성 분석)

  • Ryu, Youngjun;An, Byeong-Kwan
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.35 no.4
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    • pp.359-365
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    • 2022
  • The development of efficient electron donor (or hole-transporting) molecules that can be used in various optoelectronic device fields is highly demanded. In this work, a novel class of triptycene-based three-dimensional (3D) triphenylamine (TI-TPA) derivatives with different end substituents was designed and prepared for transparent electron donor materials. Owing to the rigid 3D triptycene framework, the obtained TI-TPA derivatives had an amorphous morphology with high thermal decomposition temperature. The oxidation potential of these TI-TPA derivatives decreased as the electron donating strength of the end substituent increased. Among TI-TPA derivatives, TI-TPA-OMe exhibited the highest HOMO level (-5.31 eV) which is similar to that of Spiro-OMeTAD (-5.22 eV). In addition, TI-TPA-OMe was found to form a strong charge transfer complex with the triptycene-based acceptor TI-BQ, leading to a new absorption band at around 640 nm. These results can be applied for developing efficient electron donor materials that can mimic the advantages of the spiro-linked structure and TPA units of Spiro-OMeTAD.

A parametric study on the free vibration of a functionally graded material circular plate with non-uniform thickness resting on a variable Pasternak foundation by differential quadrature method

  • Abdelbaki, Bassem M.;Ahmed, Mohamed E. Sayed;Al Kaisy, Ahmed M.
    • Coupled systems mechanics
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    • v.11 no.4
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    • pp.357-371
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    • 2022
  • This paper presents a parametric study on the free vibration analysis of a functionally graded material (FGM) circular plate with non-uniform thickness resting on a variable Pasternak elastic foundation. The mechanical properties of the material vary in the transverse direction through the thickness of the plate according to the power-law distribution to represent the constituent components. The equation of motion of the circular plate has been carried out based on the classical plate theory (CPT), and the differential quadrature method (DQM) is employed to solve the governing equations as a semi-analytical method. The grid points are chosen based on Chebyshev-Gauss-Lobatto distribution to achieve acceptable convergence and better accuracy. The influence of geometric parameters, variable elastic foundation, and functionally graded variation for clamped and simply supported boundary conditions on the first three natural frequencies are investigated. Comparisons of results with similar studies in the literature have been presented and two-dimensional mode shapes for particular plates have been plotted to illustrate the effect of variable thickness profile.

Manufacturing Technique of the Avalokitesvara Bodhisattva Mural Painting in Geungnakjeon Hall, Daewonsa Temple, Boseong

  • Yu, Yeong Gyeong;Jee, Bong Goo;Oh, Ran Young;Lee, Hwa Soo
    • Journal of Conservation Science
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    • v.38 no.4
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    • pp.334-346
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    • 2022
  • The manufacturing technique was studied through the structure and material characteristics of the walls and the painting layers of the Avalokitesvara Bodhisattva mural of Geungnakjeon Hall, Daewonsa Temple. The mural is painted and connected to the earthen wall and the Junggit, and the wall is composed of wooden laths as a frame, the first and middle layers, the finishing layer, and the painting layer. The first layer, middle layer, and finishing layer constituting the wall were made by mixing weathered soil and sand. It was confirmed that the first layer had a high content of loess below silt, and the finishing layer had a high content of fine-sand and very fine sand. For the painting layer, a ground layer was prepared using soil-based mineral pigments, and lead white, white clay, atacamite, minium, and cinnabar (or vermilion) pigments were used on top of it. The Avalokitesvara Bodhisattva mural was confirmed to belong to a category similar to the soil-made buddhist mural paintings of Joseon Dynasty. However, it shows characteristics such as a high content of fine sand in the finishing layer and overlapping over other colors. Such material and structural characteristics can constitute important information for future mural conservation status diagnoses and conservation treatment plans.

Suppression of Shrinkage Mismatch in Hetero-Laminates Between Different Functional LTCC Materials

  • Seung Kyu Jeon;Zeehoon Park;Hyo-Soon Shin;Dong-Hun Yeo;Sahn Nahm
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.36 no.2
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    • pp.151-157
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    • 2023
  • Integrating dielectric materials into LTCC is a convenient method to increase the integration density in electronic circuits. To enable co-firing of the high-k and low-k dielectric LTCC materials in a multi-material hetero-laminate, the shrinkage characteristics of both materials should be similar. Moreover, thermal expansion mismatch between materials during co-firing should be minimized. The alternating stacking of an LTCC with silica filler and that with calcium-zirconate filler was observed to examine the use of the same glass in different LTCCs to minimize the difference in shrinkage and thermal expansion coefficient. For the LTCC of silica filler with a low dielectric constant and that of calcium zirconate filler with a high dielectric constant, the amount of shrinkage was examined through a thermomechanical analysis, and the predicted appropriate fraction of each filler was applied to green sheets by tape casting. The green sheets of different fillers were alternatingly laminated to the thickness of 500 ㎛. As a result of examining the junction, it was observed through SEM that a complete bonding was achieved by constrained sintering in the structure of 'calcium zirconate 50 vol%-silica 30 vol%-calcium zirconate 50 vol%'.

Evaluation of the Friction Welding Properties on SUS304 Alloy (SUS304합금의 마찰접합특성 평가)

  • Y. -K. Kim;K. -H. Song;J. -K. Chung;T. -K. Ha
    • Transactions of Materials Processing
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    • v.33 no.3
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    • pp.193-199
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    • 2024
  • The friction welding characteristics of stainless steels, mainly used in energy and chemical plant industries due to its excellent corrosion resistance and high strength, was evaluated in this study. Friction welding was introduced and conducted at a rotation speed of 2,000 RPM, friction pressure of 30 MPa, burn-off length of 5 mm and upset pressure of 110 ~ 200 MPa on rod typed specimens. The grain boundary characteristics distributions such a grain size, shape, misorientation angle and kernel average misorientation of the welds were clarified by electron backscattering diffraction method. The application of friction welding on SUS304 alloy resulted in a significant refinement of the grain size in the weld zone (5.11 mm) compared to that of the base material (48.09 mm). The mechanical properties of the welds, on the other hand, appeared to be relatively low or similar to those of the base material, which were mainly caused by dislocation density in the initial material and grain refinement in the welds.

Evaluation of MUF uncertainty based on GUM method for benchmark bulk handling facility

  • Hyun Cheol Lee;Jung Youn Choi;Hana Seo;Hyun Ju Kim;Yewon Kim;Haneol Lee
    • Nuclear Engineering and Technology
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    • v.56 no.8
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    • pp.2937-2947
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    • 2024
  • The Republic of Korea is performing independent national inspections under the IAEA's State System of Accounting for and Control (SSAC), and developing an evaluation methodology for the material unaccounted for (MUF) to reinforce capabilities with the purpose of assessment for the accounting system of the facility handling bulk nuclear materials. In relation to this, a new approach for MUF evaluation was proposed in this study based on the guide to the expression of uncertainty in measurement (GUM). Both the conventional MUF evaluation method and the GUM method were applied to a hypothetical list of inventory items including material balance. Considering the ease of uncertainty propagation according to the GUM, it was assumed that independent uncertainty factors correspond to random factors, while correlated uncertainty factors correspond to systematic factors. The total MUF uncertainties were similar for both methods; however, it was verified that some uncertainties were affected by the measurement procedure in the GUM method. Furthermore, the GUM method was found to be more conducive to conducting a factor analysis for the MUF uncertainty. It was therefore concluded that application of the GUM approach could be beneficial in cases of national safeguard inspections where factor analysis is required for MUF assessment.

A Study on the Skin Disease of Sanghanron 《傷寒論》 and Geumgweyoryak 《金匱要略》 (《상한론(傷寒論)》, 《김궤요략(金匱要略)》의 피부증상(皮膚症狀) 및 질환(疾患)에 대한 연구(硏究))

  • Kang, Na-Ru;Han, Jung-Min;Ko, Woo-Shin;Yoon, Hwa-Jung
    • The Journal of Korean Medicine Ophthalmology and Otolaryngology and Dermatology
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    • v.25 no.1
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    • pp.55-74
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    • 2012
  • Objective : The purpose of this study is to investigate the skin disease in Sanghanron"傷寒論" and Geumgweyoryak"金匱要略". Methods : We conducted a study on the original text paragraphs of Sanghanron and Geumgweyoryak containing the skin disease and analysis of Woo, Oh, Sung, Zhang, etc. We drew a parallel between skin disease from Sanghanron and Geumgweyoryak and matching diagnoses from western medicine. Results : The results were as follows. 1. In Sanghanron and Geumgweyoryak pruritus was related to psychogenic pruritus and similar to skin disease caused by decrease of sweating, dry skin in cholinergic urticaria, atopic dermatitis and eczema, etc. in western medicine. 2. In Geumgweyoryak ichthyosis was caused by woman's disease, after menopause, chronic disease and malnutrition and related to winter itch and xerotic eczema in western medicine. 3. In Sanghanron Goose bumps, keratosis follicularis, acute and chronic urticaria and cold urticaria were occurred because of poorly managed fever care and side effect of antibiotic. 4. In Geumgweyoryak red face was similar to face flushing and side effects, which is after drug and laser treatment on face, in western medicine. 5. In Geumgweyoryak urticaria was, in a broad sense, skin disease with pruritus and secondary infection resulted from scratch. Skin diseases with pruritus are similar to urticaria, dermatitis herpetiformis, lichen planus, atopic dermatitis, contact dermatitis, psoriasis, nummular eczema, lichen simplex chronicus, prurigo nodularis, neurodermatitis and internal disease with pruritus in western medicine. 6. In Geumgweyoryak spots in the skin were caused by fever and similar to allergic purpura and SLE symptom in western medicine. 7. In Geumgweyoryak bullous disease with yellowish discharge was similar to eczema, pustule, atopic eczema, etc. in western medicine. 8. In Geumgweyoryak repeated inflammation of oral cavity, genitals, eyes and skin was similar to Behcet's disease in western medicine. 9. In Sanghanron and Geumgweyoryak boil was similar to abscess and acute lymphadenitis in western medicine caused by oily foods and infections. 10. In Geumgweyoryak swelling and boil were occurred in a poor health. Damage from metalic material could cause a convulsion and was similar to tetanus in western medicine. Conclusion : We analyzed the original text paragraphs of Sanghanron and Geumgweyoryak and explanations about skin disease. As a results, we found out etiology, pathogenesis, treatments of the skin disease in Sanghanron and Geumgweyoryak. Further we compared with western medicine to develop better understanding of the skin disease.