• Title/Summary/Keyword: similar material

Search Result 3,185, Processing Time 0.032 seconds

Synthesis and Characterization of Theophylline Molecularly Imprinted Polymers (테오필린 분자 날인 고분자의 합성 및 특성)

  • Ryu, Ho-Sik;Kim, Beom-Soo;Kim, Dae-Su
    • Polymer(Korea)
    • /
    • v.32 no.2
    • /
    • pp.138-142
    • /
    • 2008
  • Molecularly imprinting technology is an effective method to prepare a synthetic material with a high selectivity to a target molecule. In this study, a molecularly imprinted polymer (MIP) was synthesized via UV-polymerization using theophylline and UV-curable polyester-acrylate resin as a template molecule and a crosslinker, respectively. To elucidate the effects of functional monomer type on the performance of the MIP, each MIP was synthesized using mathacrylic acid, acrylic acid, and acryl amide as functional monomers. Each MIP showed higher rebinding capacity to theophylline than its corresponding non-imprinted polymer (NIP). The MIP synthesized using mathacrylic acid as a functional monomer showed the highest rebinding capacity to theophylline. The selectivity of the MIP was investigated using a solution with caffeine having a very similar structure to theophylline. The binding performance of the MIP to theophylline decreased when distilled water was used as a solvent, which has more polarity than chloroform.

Effect of Sintering Temperature on the Thermoelectric Properties of Bismuth Antimony Telluride Prepared by Spark Plasma Sintering (방전플라즈마 소결법으로 제조된 Bismuth Antimony Telluride의 소결온도에 따른 열전특성)

  • Lee, Kyoung-Seok;Seo, Sung-Ho;Jin, Sang-Hyun;Yoo, Bong-Young;Jeong, Young-Keun
    • Korean Journal of Materials Research
    • /
    • v.22 no.6
    • /
    • pp.280-284
    • /
    • 2012
  • Bismuth antimony telluride (BiSbTe) thermoelectric materials were successfully prepared by a spark plasma sintering process. Crystalline BiSbTe ingots were crushed into small pieces and then attrition milled into fine powders of about 300 nm ~ 2${\mu}m$ size under argon gas. Spark plasma sintering was applied on the BiSbTe powders at 240, 320, and $380^{\circ}C$, respectively, under a pressure of 40 MPa in vacuum. The heating rate was $50^{\circ}C$/min and the holding time at the sintering temperature was 10 min. At all sintering temperatures, high density bulk BiSbTe was successfully obtained. The XRD patterns verify that all samples were well matched with the $Bi_{0.5}Sb_{1.5}Te_{3}$. Seebeck coefficient (S), electric conductivity (${\sigma}$) and thermal conductivity (k) were evaluated in a temperature range of $25{\sim}300^{\circ}C$. The thermoelectric properties of BiSbTe were evaluated by the thermoelectric figure of merit, ZT (ZT = $S^2{\sigma}T$/k). The grain size and electric conductivity of sintered BiSbTe increased as the sintering temperature increased but the thermal conductivity was similar at all sintering temperatures. Grain growth reduced the carrier concentration, because grain growth reduced the grain boundaries, which serve as acceptors. Meanwhile, the carrier mobility was greatly increased and the electric conductivity was also improved. Consequentially, the grains grew with increasing sintering temperature and the figure of merit was improved.

Strength Evaluation on Sectional Members of Prefabricated Precast Concrete Arch with Reinforced Joint (보강된 이음부가 적용된 조립식 프리캐스트 콘크리트 아치의 단면 강도 평가)

  • Joo, Sanghoon;Chung, Chulhun;Bae, Jaehyun
    • KSCE Journal of Civil and Environmental Engineering Research
    • /
    • v.34 no.5
    • /
    • pp.1363-1372
    • /
    • 2014
  • In the previous study, the structural performance of proposed precast concrete arch with reinforced joint was evaluated by structural experiment. In this paper, finite element analysis considering both material and contact nonlinearity was carried out on the specimens of the previous study. Based on the result of analysis and experiment, friction coefficient between concrete blocks was determined. To evaluate the strength of sectional member, elastic analysis was carried out on the arch using linear elastic analysis program. The section force was compared with the nominal strength of arch section. It was concluded that the maximum load of all the specimens exceed the nominal strength of arch section. Those results of the strength evaluation were similar to the results of structural experiments. Therefore, it is concluded that the elastic analysis and ultimate strength model can effectively evaluate the strength for the proposed precast concrete arch composed of concrete blocks and reinforced joint in design.

Genesis of the REE Ore Deposits, Chungju District, Korea: Occurrence Features and Geochemical Characteristics (충주지역 희토류 광상의 성인: 산출상태와 지화학적 특성)

  • Park, Maeng-Eon;Kim, Gun-Soo
    • Economic and Environmental Geology
    • /
    • v.28 no.6
    • /
    • pp.599-612
    • /
    • 1995
  • Some REE ore deposits are located in the middle part the of Korean peninsula. Geotectonically, the REE ore deposits situated on the Kyemyeongsan Formation of northern margin of the Okcheon geosynclinal belt and in the transitional zone between Kyeonggi massif and the Okcheon belt, with a deep-seated fracture separating the two tectonic units. The Kyemyeongsan Formation are different in lithology and metamorphic grade from the Gyeonggi massif and the Okcheon super group. The sequence of Kyemyeongsan Formation is dominantly composed of acidic metavolcanic and volcaniclastic rocks associated with alkaline igneous rocks which are related to volcano-plutonism. The REE ore deposits contain mainly Ce-La, Ta-Nb, Y, Y-Nd and Nd-Th group minerals. More than 15 RE and REE minerals have been found in the deposits, such as allanite, fergusonite, thorite bestnaesite, euxenite, polyclase, monazite, columbite, (Nb)-rutile, okanoganite, sphene, zircon, illmenite and some other unknown minerals. According to the characteristics of the mineral association, the REE ore deposits may be divided into 4 ore types; Zircon-REE, allanite-REE, feldspar-REE and fluorite-REE type. The Sm-Nd isochron age of the REE ore is 330 Ma, and the Sm-Nd model age is 1.11 Ga with ${\varepsilon}_{Nd(t)}$ being - 2.9. This data suggest that the REE ore deposit was formed in the early Carboniferous, and the ore-forming material came from the mantle. The REE ores show distinct light REE enrichment with strong negative Eu anomaly. The REE patterns of schistose rocks from Kyemyeongsan Formation are similar to felsic volcanics from rifts or back arc basins in or near continental crust. The genesis of the REE ore deposit is quite complicated. Different geologic processes are displayed in the studied area; sedimentation, volcanic activity, metamorphism and hydrothermal replacement. Alkali granite has suffered extensive post-magmatic metasomatism of a high temperature to produce alkali metasomatites. Geochemical charateristics show that metasomatism of alkaline fluid was probably the dominant ore-forming process in Chungju district.

  • PDF

An Experimental Study on Estimate of the Optimal Grout Injection Ratio for Stabilization of Mudstone fill (이암 성토지반의 안정화를 위한 최적주입률 산정에 관한 실험적 연구)

  • Lee, Jungsang;Lee, Seungjun;Kim, Yunjoong;Kim, Taesoo;Do, Jongnam;Chun, Byungsik
    • Journal of the Korean GEO-environmental Society
    • /
    • v.13 no.7
    • /
    • pp.31-38
    • /
    • 2012
  • Water glass chemical grouts are primarily used in ground injection projects. Natural and Durable Stabilizer (NDS), Space Grout Rocket (SGR), and other similar materials composing of inorganic accelerating agents with ultra fine cement have been gaining popularity as ground improvement material in South Korea. However, there are questions as to grouting results and environmental issues caused by NDS grout. This study uses the injection method in mudstone embarkment to evaluate the differences in strength, permeability, and optimum injection volume through the use of uniaxial and triaxial compression tests and fish poison tests for NDS and SGR materials. After 28 days, results showed SGR and NDS to have a 50% increase in strength and 50% decrease in permeability with the proper injection rate at 50%.

Poverty and Relief during the Reign of Jungjong in Joseon Dynasty - focused on Jungjongsilok and the Perspective of Hermeneutics - (조선 중종대 빈곤과 구제 - "중종실록"과 해석학 관점 중심으로 -)

  • Choi, Ok-Chai
    • Korean Journal of Social Welfare
    • /
    • v.63 no.3
    • /
    • pp.261-283
    • /
    • 2011
  • This study aimed to understand the developmental process of poverty and relief during the reign of Jungjong in Joseon Dynasty. The reason why this study focus on the reign of Jungjong in Joseon Dynasty is that the poverty and relief had been happened most frequently, and that the meaning of social welfare could be profound during the periods of Joseon Dynasty. The data is collected based on Jungjongsilok, and the collected data is analyzed by the perspective of Hermeneutics. Five important meanings are resulted as follows: 1) concreted similar methods of social security had been partly carried out, 2) relief policies had been drawn up by the King's absolute authority, 3) given political and social economical conditions for relief had not been sufficient, 4) relief policies had been temporarily enforced, and 5) the king and the retainers had been charged to responsibility for poverty as well as they had been adapted to nature. In addition, three particulars are proposed for following studies such as comparative studies on poverty and relief before or after the reign of Jungjong, studies based on other historical material except Jungjongsilok, and studies on diseases and crimes except poverty.

  • PDF

Simulation Analysis on the Compression Property of Sandwich Composite (샌드위치 복합재료의 압축 특성에 관한 시뮬레이션 해석)

  • Bang, Seung-Ok;Kook, Jeong-Han;Kim, Sei-Hwan;Cho, Jae-Ung
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.13 no.2
    • /
    • pp.478-484
    • /
    • 2012
  • In this study, compression analyses of sandwich composites with porous core were carried out. Finite element models of aluminum foam and honeycomb core sandwich composite material were applied solid element. In the case of aluminum foam core, valid equivalence damage model was applied. In the in-plane compression analysis, the maximum load of aluminum foam core sandwich was similar with that of aluminum honeycomb core sandwich. But in case of aluminum honeycomb core sandwich, the load support region becomes longer in comparison with aluminum foam core sandwich. In the out-plane compression analysis, compression maximum load of aluminum honeycomb core sandwich was higher than that of aluminum foam core sandwich. Through these Simulation analysis, obtains the behavior of sandwich composites.

Post-buckling finite strip analysis of thick functionally graded plates

  • Hajikazemi, M.;Ovesy, H.R.;Assaee, H.;Sadr, M.H.
    • Structural Engineering and Mechanics
    • /
    • v.49 no.5
    • /
    • pp.569-595
    • /
    • 2014
  • In this paper, a novel semi-energy finite strip method (FSM) is developed based on the concept of first order shear deformation theory (FSDT) in order to attempt the post-buckling solution for thin and relatively thick functionally graded (FG) plates under uniform end-shortening. In order to study the effects of through-the-thickness shear stresses on the post-buckling behavior of FG plates, two previously developed finite strip methods, i.e., semi-energy FSM based on the concept of classical laminated plate theory (CLPT) and a CLPT full-energy FSM, are also implemented. Moreover, the effects of aspect ratio on initial post-buckling stiffness of FG rectangular plates are studied. It has been shown that the variation of the ratio of initial post-buckling stiffness to pre-buckling stiffness ($S^*/S$) with respect to aspects ratios is quite independent of volume fractions of constituents in thin FG plates. It has also been seen that the universal curve representing the variation of ($S^*/S$) with aspect ratio of a FG plate demonstrate a saw shape curve. Moreover, it is revealed that for the thin FG plates in contrast to relatively thick plates, the variations of non-dimensional load versus end-shortening is independent of ceramic-metal volume fraction index. This means that the post-buckling behavior of thin FG plates and the thin pure isotropic plates is similar. The results are discussed in detail and compared with those obtained from finite element method (FEM) of analysis. The study of the results may have a great influence in design of FG plates encountering post-buckling behavior.

Comparison of detergency effectiveness by the type of household washer, detergent and soil - Focused on detergency, rinsing, fabric damage and tanglement - (가정용 세탁기, 세제 및 오염의 종류별 세탁 성능 비교 - 세탁성, 헹굼성, 섬유손상도, 엉킴도를 중심으로 -)

  • Piao, Shujing;Park, Myung-Ja
    • The Research Journal of the Costume Culture
    • /
    • v.21 no.6
    • /
    • pp.950-960
    • /
    • 2013
  • The purpose of this research is to provide accurate information of household washers and detergents for consumers, so that help the producers who make washing machine and detergent to get basic material and also help consumers to choose washing machine. Experiment was proceed with two type of washers to compare energy consumption, washing performance, rinsing effectiveness further, damage caused by entanglement of laundry and fabric was assessed. Detergent P and T were used to compare the performance related to differences of ingredients of detergent. Soiled fabrics of EMPA 108 set were used to evaluate performance of washing by different types of contamination. A summary of experimental results are : First, for the consumption of water, drum-type washer consumed 53% less than pulsator-type washer. On the other hand, the washing time was almost similar for both these machines, but pulsator-type washer showed shorter progress, implying that power saving was more efficient in this case. Second, the drum-type washer showed better performance for contamination with all types of detergent, but the pulsator-type washer showed better rinsing performance. Third, the drum-type washer performed less data of tangle level and fabric damage. Fourth, detergent "P" exhibited better washing performance than did detergent "T", regardless of the type of soil. And with no limit of detergent variety, water-soluble protein soil showed high removal rate, liposoluble soil especially pigment was hardly removed.

Electrical Switching Characteristics of Ge-Se Thin Films for ReRAM Cell Applications

  • Kim, Jang-Han;Nam, Ki-Hyun;Chung, Hong-Bay
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2012.08a
    • /
    • pp.343-344
    • /
    • 2012
  • It has been known since the mid 1960s that Ag can be photodissolved in chalcogenide glasses to form materials with interesting technological properties. In the 40 years since, this effect has been used in diverse applications such as the fabrication of relief images in optical elements, micro photolithographic schemes, and for direct imaging by photoinduced Ag surface deposition. ReRAM, also known as conductive bridging RAM (CBRAM), is a resistive switching memory based on non-volatile formation and dissolution of a conductive filament in a solid electrolyte. Especially, Ag-doped chalcogenide glasses and thin films have become attractive materials for fundamental research of their structure, properties, and preparation. Ag-doped chalcogenide glasses have been used in the formation of solid electrolyte which is the active medium in ReRAM devices. In this paper, we investigated the nature of thin films formed by the photo-dissolution of Ag into Ge-Se glasses for use in ReRAM devices. These devices rely on ion transport in the film so produced to create electrically programmable resistance states. [1-3] We have demonstrated functionalities of Ag doped chalcogenide glasses based on their capabilities as solid electrolytes. Formation of such amorphous systems by the introduction of Ag+ ions photo-induced diffusion in thin chalcogenide films is considered. The influence of Ag+ ions is regarded in terms of diffusion kinetics and Ag saturation is related to the composition of the hosting material. Saturated Ag+ ions have been used in the formation of conductive filaments at the solid electrolyte which is the active medium in ReRAM devices. Following fabrication, the cell displays a metal-insulator-metal structure. We measured the I-V characteristics of a cell, similar results were obtained with different via sizes, due to the filamentary nature of resistance switching in ReRAM cell. As the voltage is swept from 0 V to a positive top electrode voltage, the device switches from a high resistive to a low resistive, or set. The low conducting, or reset, state can be restored by means of a negative voltage sweep where the switch-off of the device usually occurs.

  • PDF