• Title/Summary/Keyword: silver solution

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Electrochemistry and Leaching Kinetics of Gold-Silver Alloys in Cyanide Solutions

  • Guan, Y.Charles;Sun, Xiaowei;Han, Kenneth N.
    • Resources Recycling
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    • v.10 no.1
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    • pp.42-48
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    • 2001
  • The dissolution behavior of gold and silver from gold-silver alloys in aerated cyanide solutions has been investigated by an electrochemical means as well as a direct measurement of gold and silver ions reported in the bulk solution as a function of time using rotating disc electrodes. The variables studied included oxygen partial pressure, rotating speed of the disc, concentration of cyanide, temperature and composition of the allyos. The dissolution potential and the rate of dissolution were obtained in view of the anodic and cathodic current-potential relationships. The results were discussed in terms of the mixed potential theory. The results showed that the dissolution rate of gold and silver from the alloys was controlled partially by chemical reaction. but largely by transport of either oxygen or cyanide, depending on their relative concentration under the experimental conditions employed in this study.

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Synthesis of aerosol nanoparticles by spark discharge and applications

  • Park, Jaehong;Byeon, Jeong Hoon;Yoon, Ki Young;Park, Jae Hong;Hwang, Jungho
    • Particle and aerosol research
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    • v.5 no.3
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    • pp.111-122
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    • 2009
  • This paper reviews about synthesis of nanoparticles by spark discharge and applications. A method of catalytic activation with Pd and Pt aerosol nanoparticles produced by spark discharge was introduced. After annealing, the catalytically activated substrate placed into a solution for electroless silver deposition. The silver was then formed only on the activated regions of the substrate. Silver line patterns having a width of $18{\mu}m$ and a height of $1{\mu}m$ were created with the ability to be effectively reproduced. Antimicrobial nanoparticles such as silver were used for removal of bioaerosols. Silver nanoparticles deposited air filters such as ACF filters were evaluated by antimicrobial test.

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Homogeneously Dispersed Silver Nanoparticles on the Honeycomb-Patterned Poly(N-vinylcarbazole)-cellulose triacetate Composite Thin Films by the Photoreduction of Silver Nitrate

  • Kim, Kwang Il;Basavaraja, C.;Huh, Do Sung
    • Bulletin of the Korean Chemical Society
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    • v.34 no.5
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    • pp.1391-1396
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    • 2013
  • The photocontrolled reduction of silver nitrate to silver (Ag) nanoparticles on honeycomb-patterned poly(N-vinylcarbazole) (PVK)-cellulose triacetate (CTA) composite thin films was studied. The composites were prepared via the oxidative polymerization of N-vinylcarbazole with ferric chloride using different CTA concentrations. A honeycomb-patterned film was fabricated by casting the composite solution under humid conditions. Ag particles with a homogeneous distribution were produced by the composite film in a moderate CTA concentration, whereas aggregated Ag was obtained from the pure PVK film.

Antimicrobial Properties and Characteristic Changes of Nylon Treated with Glycidyltrimethylammonium chloride(GTAC) and Silver nanoparticles(AgNPs) (Glycidyltrimethylammonium chloride(GTAC)와 Ag 나노입자 가 코팅된 나일론의 항균성 및 특성변화)

  • Kang, Dakyung;Lee, Jaewoong;Lee, Sang Oh
    • Textile Coloration and Finishing
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    • v.28 no.4
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    • pp.271-279
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    • 2016
  • This study deals with antibacterial properties of nylon fiber treated with glycidyltrimethylammonium chloride(GTAC) and silver nanoparticles(AgNPs). Nylon fibers were soaked into GTAC(2-30%, v:v) solution for 20 min. After sample was pre-drying at $80^{\circ}C$ for 10min and cured at $180^{\circ}C$ for 5min. The AgNPs coating was accomplished by soaking in silver colloid solution at $45^{\circ}C$ for 90min. The coated nylon fibers were characterized by scanning electron microscopy-energy dispersive spectroscopy(SEM-EDS). EDS analysis indicated that AgNPs and GTAC was attached on nylon fibers. The treated nylon fibers showed antimicrobial properties against Escherichia coli(ATCC 43895), Pseudomonas aeruginosa(ATCC 13388) and Staphylococcus aureus(ATCCBAA-1707).

Leaching of the Mixture of Metallic Gold and Silver (금과 은 금속혼합물의 침출)

  • Xing, Weidong;Lee, Manseung
    • Resources Recycling
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    • v.26 no.2
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    • pp.39-45
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    • 2017
  • In order to exclude the effect of uneven distribution of gold in anode slime, the dissolution of gold and silver from the metal mixture was investigated in different systems, such as the mixture of hydrochloric acid and oxidizing reagents ($H_2O_2$, NaClO and $HNO_3$), thiosulfate and thiourea. In the mixture of HCl and either $HNO_3$ or $H_2O_2$, Au was completely dissolved but the leaching percentage of Ag was around 1%. In both thiosulfate and thiourea solution, gold was not dissolved at all. The presence of ferric ion in acidic thiourea solution showed a favorable effect on the leaching of silver but further study is necessary to elucidate the combined effect of ferric ion and sulfuric acid.

Memory Effect of Silver and Aqua Regia by their Permeation into Microwave Digestion Vessels (마이크로파 분해 용기 내로 침투에 의한 은과 왕수의 기억효과)

  • Cho, Sung-Ill;Kim, Young-Sang;Lee, Sueg-Geun
    • Analytical Science and Technology
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    • v.16 no.3
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    • pp.212-217
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    • 2003
  • The memory effect of silver and aqua regia in the vessel by their permeation was studied during the microwave digestion of samples under the operating conditions of high temperature and pressure. The extent of permeation in vessels with the solution containing silver 5 mg has been shown to be $0.97{\mu}g/mL$ for the digestion of $HNO_3$ solution and $0.47{\mu}g/mL$ for the digestion of oil sample under condition of MDS 180T program ($180^{\circ}C$, 220 psi).

Transport of PVP-coated Silver Nanoparticles in Saturated Porous Media (포화된 다공성매체에서 PVP-코팅된 은나노입자의 이동성 연구)

  • Bae, Sujin;Jang, Min-Hee;Lee, Woo Chun;Park, Jae-Woo;Hwang, Yu Sik
    • Journal of Soil and Groundwater Environment
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    • v.21 no.1
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    • pp.104-110
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    • 2016
  • The transport of silver nanoparticles (AgNPs) was investigated through a column packed with sand. A series of column experiments were carried out to evaluate the effect of ionic strength (IS), pH, electrolyte type and clay mineral on mobility of polyvinylpyrrolidone-coated silver nanoparticles (PVP-AgNPs). The deposition of PVP-AgNPs was increased with increasing solution ionic strength and decreasing pH. Furthermore, the depositon of PVP-AgNPs was affected by the electrolyte type (NaCl vs. NaNO3) and was shown to be greater at NaNO3 solution. Also, the transport of PVP-AgNPs was greatly increased after the pre-deposition of clay particles on sand. Our results suggest that various environmental factors can influence the mobility of PVP-AgNPs in soil-groundwater systems and should be carefully considered in assessing their environmental risks.

A Research for the Property of the Concrete Using Functional Materials (기능성 재료를 사용한 콘크리트의 특성에 관한 연구)

  • Lee, Jong-Chan
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.2 no.2
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    • pp.93-100
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    • 2006
  • Building materials are trending toward environmental materials nowadays and the market share of those is growing. So those researches and developments for environmental property are proceeding now. The main properties of environmental products are far infrared emission, negative ion emission, electro magnetic wave shielding, and anti fungus, these products are used with shape of mortar, and spray on the finish material. But There are not much researches for the concrete, main material in construction field, with those functional properties. So in this research we evaluated slump, compressive strength and air content as basic properties for concrete using functional materials of sericite, wood pattern sand stone, carbon black and nanometric silver solution and functional properties like far infrared emission, negative ion emission, electro magnetic wave shielding, and anti fungus. The results were as follows. The most useful material in the functional materials was carbon black. Sericite and nanometric silver solution had a little effect on functional property, so it was difficult to apply to concrete, and wood pattern sand stone had a high functional property but low compressive strength, can be applied to a factory product. Anti fungus of the concrete using nanometric silver solution was not clear but if those specimens were aged in $CO_2$ gas for a long time it might apparent.

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Fundamental Investigation of Functional Property of Concrete Mixed with Functional Materials

  • Lee, Jong-Chan;Lee, Moon-Hwan;Lee, Sae-Hyun;Park, Young-Sin;Park, Jae-Myung
    • International Journal of Concrete Structures and Materials
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    • v.18 no.3E
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    • pp.165-171
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    • 2006
  • Environment-friendly materials are increasingly used as building construction materials nowadays, and the market share of those is growing. Accordingly, the research and developments in terms of environmental value are progressing steadily now. The main characteristics of environmental products are far-infrared radiation, negative-ion emission, electromagnetic wave shielding, and antimicrobial property. These products are often used in mortar and as spray on the finishing material. Nevertheless, there are hardly any research on the functional properties of concrete, the main material in construction field. Thus, we evaluated such basic properties of concrete as slump, compressive strength and air content while using such functional materials as sericite, wood-pattern sandstone, carbon black and nano-metric silver solution to focus on their functional properties like far-infrared radiation, negative ion emission, electro magnetic wave shielding, and antimicrobial activity in this research. The results indicated that the most useful material in the functional materials was carbon black. Sericite and nano-metric silver solution had a little effect on the functional property. Moreover, although wood-pattern sandstone had very high functional property, it exhibited too low compressive strength to be applied, to concrete as a factory product. Antimicrobial property of nano-metric silver solution in the concrete was not clear demonstrated, but if these specimens were to be aged in $CO_2$ gas for a long time, it might be apparent.

Effect of Reductants and their Properties of Electric Resistivity on the Preparation of Ag coated Cu Powders by Chemical Reduction Method (화학환원법을 이용한 은 코팅 구리 분말 제조 시 환원제의 영향 및 전기비저항 특성)

  • Ahn, Jong-Gwan;Yoon, Chi-Ho;Kim, Dong-Jin;Cho, Sung-Wook;Park, Je-Shin
    • Korean Journal of Metals and Materials
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    • v.48 no.12
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    • pp.1097-1102
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    • 2010
  • Silver coated copper powders were prepared by a chemical reduction method with controlling the deposition process variables such as the feeding rate of the silver ionic solution and concentration of the reductants at room temperature. The characteristics of the products were evaluated by scanning electron microscope (SEM), X-ray diffractometer (XRD), atomic absorption spectrophotometer (AA) and a 4 probe resistivity measurement system. The optimum condition of the preparation of Ag coated Cu powders was at 0.05 M of potassium sodium tartrate and 2 ml/min of the feeding rate of the silver ionic solution. Our method successfully produced dense, uniform, and well-dispersed Ag coated Cu powder of $2{\sim}2.5{\mu}m$ witha silver layer of 100~200 nm. Additionally, we found that thespecific resistivity of the 30 wt.% Ag coated Cu powder was similar to that of pure silver, so that the composite powder could be used as an alternative electromagnetic shielding material for silver.