• Title/Summary/Keyword: silver solution

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Study on PVC Mixed Silver Iodide Membrane Electrode (PVC 를 섞은 요오드화은 막전극에 관한 연구)

  • Kwon Young-Soon;Kim Jung-Hee;Park Kee-Chae
    • Journal of the Korean Chemical Society
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    • v.20 no.6
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    • pp.486-493
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    • 1976
  • The PVC mixed silver iodide pellet was prepared by means of the Infrared Pellet presser and the pellet was used as an indicating membrane electrode, to measure the potentials for various silver ion activities, ranging from $10^{-1}$ to $10^{-6}$ M. The potential responses to silver ion activities were linear and the slope was much close to Nernstian relation as compared with that of the pure silver iodide pellet membrane electrode and the PVC coated silver iodide pellet membrane electrode. The mechanical property and chemical durability of this electrode were found much better than the others. This electrode did not show significant response to the other except silver ion, but had good response to halide ions, i.e., iodide, chloride, bromide and cyanide ions, in the concentration range $10^{-1}$ to $10^{-6}$ M. This electrode could be used as an indicating electrode in potentiometric titrations of single halide ion and also halide mixture with standard solution of silver nitrate.

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Antifungal Effects of Silver Nanoparticles (AgNPs) against Various Plant Pathogenic Fungi

  • Kim, Sang-Woo;Jung, Jin-Hee;Lamsal, Kabir;Kim, Yun-Seok;Min, Ji-Seon;Lee, Youn-Su
    • Mycobiology
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    • v.40 no.1
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    • pp.53-58
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    • 2012
  • This research is concerned with the fungicidal properties of nano-size silver colloidal solution used as an agent for antifungal treatment of various plant pathogens. We used WA-CV-WA13B, WA-AT-WB13R, and WA-PR-WB13R silver nanoparticles (AgNPs) at concentrations of 10, 25, 50, and 100 ppm. Eighteen different plant pathogenic fungi were treated with these AgNPs on potato dextrose agar (PDA), malt extract agar, and corn meal agar plates. We calculated fungal inhibition in order to evaluate the antifungal efficacy of silver nanoparticles against pathogens. The results indicated that AgNPs possess antifungal properties against these plant pathogens at various levels. Treatment with WA-CV-WB13R AgNPs resulted in maximum inhibition of most fungi. Results also showed that the most significant inhibition of plant pathogenic fungi was observed on PDA and 100 ppm of AgNPs.

Synthesis, characterization and dose dependent antimicrobial and anticancerous efficacy of phycogenic (Sargassum muticum) silver nanoparticles against Breast Cancer Cells (MCF 7) cell line

  • Supraja, Nookala;Dhivya, J.;Prasad, T.N.V.K.V.;David, Ernest
    • Advances in nano research
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    • v.6 no.2
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    • pp.183-200
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    • 2018
  • In the present study silver nanoparticles (AgNPs) were successfully synthesized using aqueous extract of Sargassum muticum. The aqueous extract (10%) treated with 1 mM silver nitrate solution resulted in the formation of AgNPs and the surface plasmon resonance (SPR) of the formed AgNPs was recorded at 360 nm using UV-Visible spectrophotometer. The molecules involved in the formation of AgNPs were identified by Fourier transform infrared spectroscopy (FT-IR), surface morphology was studied by using scanning electron microscopy (SEM), SEM micrograph clearly revealed the size of the AgNPs was in the range of 40-65 nm with spherical, hexagonal in shape and poly-dispersed nature, and X-ray diffraction spectroscopy (XRD) was used to determine the crystalline structure. High positive Zeta potential (36.5 mV) of formed AgNPs indicates the stability and XRD pattern revealed the crystal structure of the AgNPs by showing the Bragg's peaks corresponding to (111), (200), (311) and (222) planes of face-centered cubic crystal phase of silver. The synthesized AgNPs exhibited effective anticancerous activity (at doses 25 and $50{\mu}g/ml$ of AgNPs) against Breast cancer cell line (MCF7).

Selective Trace Analysis of Mercury (II) Ions in Aqueous Media Using SERS-Based Aptamer Sensor

  • Lee, Chank-Il;Choo, Jae-Bum
    • Bulletin of the Korean Chemical Society
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    • v.32 no.6
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    • pp.2003-2007
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    • 2011
  • We report a highly sensitive surface-enhanced Raman scattering (SERS) platform for the selective trace analysis of mercury (II) ions in drinkable water using aptamer-conjugated silver nanoparticles. Here, an aptamer designed to specifically bind to $Hg^{2+}$ ions in aqueous solution was labelled with a TAMRA moiety at the 5' end and used as a Raman reporter. Polyamine spermine tetrahydrochloride (spermine) was used to promote surface adsorption of the aptamer probes onto the silver nanoparticles. When $Hg^{2+}$ ions are added to the system, binding of $Hg^{2+}$ with T-T pairs results in a conformational rearrangement of the aptamer to form a hairpin structure. As a result of the reduced of electrostatic repulsion between silver nanoparticles, aggregation of silver nanoparticles occurs, and the SERS signal is significantly increased upon the addition of $Hg^{2+}$ ions. Under optimized assay conditions, the concentration limit of detection was estimated to be 5 nM, and this satisfies a limit of detection below the EPA defined limit of 10 nM in drinkable water.

An Experimental Study on Nozzle Spray Characteristics for the Design of Heat Exchangers of a Nano-Silver HVAC System (은나노 공조시스템의 열교환기 설계를 위한 노즐의 분무특성 실험)

  • Heo, Ju-Yeong;Kang, Byung-Ha
    • 한국전산유체공학회:학술대회논문집
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    • 2008.03b
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    • pp.534-537
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    • 2008
  • Growing attention has been given to sterilizing and antibacterial effects of nano-silver, recently. Nano-silver solution can be applied to the heat exchanger in an air conditioner to prevent bad smell or bacteria. The present study is directed at the nozzle spray characteristics over a heat exchanger. This problem is of particular interest in the design of a nano-silver HVAC system. The effects of nozzle position and flow rate on the spray area over a horizontal surface have been investigated for various nozzles. The results obtained indicate that spray area is increased as the height of spray position is increased or mass flow rate is increased. The wetted area over a practical heat exchanger is also studied at a given nozzle height. It is found that the wetted area is gradually increased with an increase in the flow rate. However, the effect of flow rate on the wetted area is a little affected by flow rate in the range of too much flow rate. It is also found that the wetted area is decreased as the inclination angle of a heat exchanger is increased.

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Nelumbo nucifera extracts mediated synthesis of silver nanoparticles for the potential applications in medicine and environmental remediation

  • Supraja, N.;Avinash, B.;Prasad, T.N.V.K.V.
    • Advances in nano research
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    • v.5 no.4
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    • pp.373-392
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    • 2017
  • Silver nanoparticles (AgNPs) were successfully synthesized through a simple green route using the Nelumbo nucifera leaf, stem and flower extracts. These nanoparticles showed characteristic UV-Vis absorption peaks between 410-450 nm which arises due to the plasmon resonance of silver nanoparticles. The Fourier transform infrared spectroscopy (FT-IR) confirmed the presence of amides and which acted as the stabilizing agent. X-ray diffraction spectrum of the nanoparticles confirmed the Face centered cubic (FCC) structure of the formed AgNPs. Dynamic light scattering technique was used to measure hydrodynamic diameter (68.6 nm to 88.1 nm) and zeta potential (-55.4 mV, -57.9 mV and 98.9 mV) of prepared AgNPs. The scanning electron micrographs of dislodged nanoparticles in aqueous solution showed the production of reasonably monodispersed silver nanoparticles (1-100 nm). The antimicrobial activity of prepared AgNPs was evaluated against fungi, Gram-positive and Gram-negative bacteria using disc diffusion method. Anti-corrosion studies were carried out using coupon method (mild steel and iron) and dye degradation studies were carried out by assessing photo-catalytic activity of Nelumbo nucifera extracts mediated AgNPs.

In vitro protoscolicidal effects of hypertonic glucose on protoscolices of hydatid cyst

  • Hosseini Seyed Vahid;Ghanbarzadeh Kurosh;Barzin Zahra;Sadjjadi Seyed Mahmoud;Tanideh Nader;Mehrabani Davood
    • Parasites, Hosts and Diseases
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    • v.44 no.3
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    • pp.239-242
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    • 2006
  • To evaluate the protoscolicidal effects of various concentrations of hypertonic glucose, live protoscolices of sheep were exposed to 10%, 15%, 25% and 50% glucose solutions. Cetrimide (0.5%), silver nitrate (0.5%) and hypertonic saline (20%) were used as positive controls, while physiological saline was used as a negative control. After 1, 2 and 5 min, the protoscolicidal effects were determined by 1 % eosin. A 25% glucose solution had no significant protoscolicidal effect. However, a 50% glucose solution revealed higher protoscolicidal effect than 0.5% silver nitrate but weaker effect than 0.5% cetrimide; the effect was comparable with that of 20% hypertonic saline. The results showed that hypertonic glucose solution is highly effective in killing protoscolices of Echinococcus granulosus in vitro.

SPECTRAL SENSITIZATION OF BENZOXAZOLO CARBOCYANINE DYE IN PHOTOGRAPHIC EMULSION

  • Kim, Yeoung-Chan
    • Journal of Photoscience
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    • v.5 no.1
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    • pp.45-46
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    • 1998
  • The green-sensitive silver halide emulsion layer has been studied UV-Vis absorption band of 9-methvl-5,5'-diphenyl-3,3'-bis(3-sulfopropyl)benzoxazolo carbocyanine triethyl ammonium salt in methanol solution and 10% methanol containing 10$^{-2}$ M KCl. the products were observed at 502nm and 540nm(J-band), respectively. The maximum spectral sensitivity of sensntizing silver halide emulsion showed at 546nm. In conclusion, benzoxazolo carbocyanine dye can be used as a green-sensitizing dye for the photographic emulsion.

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Recovery of Silver from Nitrate Leaching Solution of Silicon Solar Cells (실리콘 태양전지 질산침출액에서 LIX63를 이용한 은(Ag) 회수)

  • Cho, Sung-Yong;Kim, Tae-Young;Sun, Pan-Pan
    • Resources Recycling
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    • v.30 no.2
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    • pp.39-45
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    • 2021
  • Spent photovoltaic module is one of the important resource of silver, while related research concerning silver recovery remains limited. In our previous research, HNO3 was utilized to dissolve Ag(I) and Al(III) from the spent silicon solar cells. In order to recover Ag(I) from the leachate of a silicon solar cell, the present study made use of a nitrate solution containing Ag(I) and Al(III), which was subjected to a solvent extraction process with 5,8-diethyl-7-hydroxydodecan-6-oxime (LIX63). Ag(I) was selectively extracted with LIX63 over Al(III) from the nitrate leach solution. Subsequently, quantitative stripping of Ag(I) from the loaded LIX63 was performed by using 20% ammonia water. The McCabe-Thiele plots for the extraction and stripping isotherms of Ag(I) were also constructed. Extraction and stripping simulation tests confirmed an Ag(I) extraction and stripping efficiency of >99.99% and 98.9%, respectively with high purity Ag (99.998%) and Al (99.99%) solution. A process flow sheet for Ag(I) recovery from the nitrate leach solution was proposed.

Design of Fast Acting Fuse Characteristics Using a Precision Multi-layer Thin Film Plating (정밀 다층 박막 도금을 이용한 빠른 동작 퓨즈 특성 설계)

  • Kim, Eun-Min;Kang, Chang-Yong
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.65 no.3
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    • pp.445-451
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    • 2016
  • General fuse elements of solution for fast acting operation characteristics made using silver or silver alloy, those are not able to dominate cost competition to the advanced global leaders that have not only high technology but competitive price. In this study, the method that compose the fuse elements manufactured solution of fast acting operation characteristics by using precision multi-layer thin film plating and helical cutting process from low-priced copper metal. Furthermore, in order to move rated current line of fuse due to the heat loses, the manufacture construction method of fixed resistor is introduced, and then Ni-P plating layer and Sn plating layer are introduced multiply for controling fine opening time characteristics. So this study can establish the high productive and low-priced production method.