• Title/Summary/Keyword: silicone-epoxy

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The Estimation of the Dielectric Strength Decrease of the Solid-solid Interfaces by using the Applied Voltage to Breakdown Time Characteristics

  • Shin, Cheol-Gi;Bae, Duck-Kweon
    • Transactions on Electrical and Electronic Materials
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    • v.8 no.6
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    • pp.278-282
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    • 2007
  • In the complex insulation system that is used in extra high voltage(EHV) devices, according to the trend for electric power equipment of high capacity and reduction of its size, macro interfaces between two different bulk materials which affect the stability of insulation system exist inevitably. In this paper, the dielectric strength decrease of the macro interfaces between epoxy and ethylene propylene diene terpolymer(EPDM) was estimated by using the applied voltage to breakdown time characteristics. Firstly, the AC short time dielectric strength of specimens was measured at room temperature. Then, the breakdown time was measured under the applied constant voltage which is 70% of short time breakdown voltage. With these processes, the life exponent n was determined by inverse power law, and the long time breakdown voltage can be evaluated. The best condition of the interface was LOS(low viscosity(350 cSt) silicone oil spread specimen). When 30 years last on the specimens, the breakdown voltage was estimated 44% of the short time breakdown voltage.

The Emulsification of Silane as Water REpellent for Concrete (콘크리트 발수제용 Silane의 유화)

  • 황인동;염희남;정윤중
    • Journal of the Korean Ceramic Society
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    • v.37 no.8
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    • pp.760-767
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    • 2000
  • Recently, the protection of construction is demanded with environmental pollution. These protect modes are use of concrete admixture, coat of protective polymer and impregnate of surface with chemicals etc. The most widely used impregnation is economical and effective. The define of Impregnation for construction protect is reacted in and consolidated substrate after absorbed. The impregnation agents are Polyesters, Acrylic monomers, Epoxy and Silicone derivatives. Commonly, because the Silane has good water repellency and environmental advantages that it widely used to water proofing agents, dampproofing agents and absorption reducer for concrete of bridges. When application of Silane, it occurs pollution and harmfulness as included organic solvent. The manufactures have tired to emulsification of Silane for the reducing of the defects. The Silane emulsion is vary unstable and does not stored long periods, and it is diminished in good properties with internal reaction. In this study we tried to emulsification of Silane for effectiveness improvement and reduce pollution and hazard and discussed properties variation of emulsion. The Silane emulsions are achieved emulsifying with W/O and O/W type surfactants. It used 0.24% PVA as protective colloid and stable phase is creamy. The creamy Silane emulsion performance as the penetration depth and water absorption rate are above 4 mm and below 0.1. It stable about 6 month at room temperature.

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Effects of Fume silica on synthesis of New Austria Tunnel Method Resin for new material in space aviation (우주항공의 신소재를 위한 New Austria Tunnel Method 수지합성에 대한 Fume silica의 영향)

  • Kim, Kijun;Lee, Jooho;Park, Taesul;Lee, Joo-Youb
    • Journal of the Korean Applied Science and Technology
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    • v.31 no.4
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    • pp.595-601
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    • 2014
  • The microstructures of NATM were examined by SEM, FT-IR spectra, tensile properties, mole % of [NCO/OH], and particle size analyzer. Growing concerns in the environment-friendly industries have led to the development of solvent-free formulations that can be cured. We had synthesized NATM(New Austria Tunnel Method) resin having the ability to protect stainless steel against corrosion. Comparing with general NATM resin and coatings, this resin that synthesized with polyurethane and epoxy was highly stronger in intensity and longer durability. Hybrid resin was composed of polyols, MDI, epoxy, silicone surfactant, catalyst and crosslink agent, and fillers. Moreover, fillers such as fume silica not only accelerated the curing rate but also improved the physical property as thermal barriers. The rigid segments of synthetic resin in mechanical properties were due to fume silica and the increase the mole% of [NCO/OH] for corrosion protection. In conclusion, the hybrid resin microstructure with crosslink agent and fume silica are good material for thermosetting coating of metal substrates such as stainless steel.

Study on the Synthsis of Tetramethyldisiloxane Derivatives Containing Silicone Hydride and Epoxy Functionalities at Each End (실리콘 하이드라이드 및 에폭시 관능기를 양 말단에 포함하는 테트라메틸디실록산 치환체의 합성에 관한 연구)

  • Chung, Dae-Won;Kang, Min Ha
    • Applied Chemistry for Engineering
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    • v.18 no.2
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    • pp.116-120
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    • 2007
  • The synthesis of 1-[2-(3-{7-oxabicyclo[4.1.0]heptyl} 1,1,3,3-tetramethyl-disiloxane (Mono), which is a key intermediate for the synthesis of monomers applied for photopolymer systems based on the cationic ring opening polymerization, was studied. Mono was successfully synthesized by the hydrosilylation reaction of 4-vinyl-1-cyclohexene 1,2-epoxide (VCHO) with an excess amount of 1,1,3,3-tetramethyldisiloxane (TMDS) in the presence of a Speier catalyst. The structure and the purity of Mono were characterized by FT-IR, $^1H-NMR$, and $^{29}Si-NMR$. The optimum conditions for the hydrosilyation reaction were found to be 1:4 molar ratio of VCHO to TMDS and 5 ppm of the catalyst at the temperature of $55^{\circ}C$.

Development of Retinal Prosthesis Module for Fully Implantable Retinal Prosthesis (완전삽입형 인공망막 구현을 위한 인공망막모듈 개발)

  • Lee, Kang-Wook;Kaiho, Yoshiyuki;Fukushima, Takafumi;Tanaka, Tetsu;Koyanagi, Mitsumasa
    • Journal of Biomedical Engineering Research
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    • v.31 no.4
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    • pp.292-301
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    • 2010
  • To restore visual sensation of blind patients, we have proposed a fully implantable retinal prosthesis comprising an three dimensionally (3D) stacked retinal chip for transforming optical signal to electrical signal, a flexible cable with stimulus electrode array for stimulating retina cells, and coupling coils for power transmission. The 3D stacked retinal chip is consisted of several LSI chips such as photodetector, signal processing circuit, and stimulus current generator. They are vertically stacked and electrically connected using 3D integration technology. Our retinal prosthesis has a small size and lightweight with high resolution, therefore it could increase the patients` quality of life (QOL). For realizing the fully implantable retinal prosthesis, we developed a retinal prosthesis module comprising a retinal prosthesis chip and a flexible cable with stimulus electrode array for generating optimal stimulus current. In this study, we used a 2D retinal chip as a prototype retinal prosthesis chip. We fabricated the polymide-based flexible cable of $20{\mu}m$ thickness where 16 channels Pt stimulus electrode array was formed in the cable. Pt electrode has an impedance of $9.9k{\Omega}$ at 400Hz frequency. The retinal prosthesis chip was mounted on the flexible cable by an epoxy and electrically connected by Au wire. The retinal prosthesis chip was cappted by a silicone to pretect from corrosive environments in an eyeball. Then, the fabricated retinal prosthesis module was implanted into an eyeball of a rabbit. We successfully recorded electrically evoked potential (EEP) elicited from the rabbit brain by the current stimulation supplied from the implanted retinal prosthesis module. EEP amplitude was increased linearly with illumination intensity and irradiation time of incident light. The retinal prosthesis chip was well functioned after implanting into the eyeball of the rabbit.

Comparison of relative fitness between zirconia single coping and 3-unit fixed partial dentures (FPDs) manufactured by dental CAD/CAM system (치과 캐드/캠 시스템으로 제작된 지르코니아 single 코핑과 3-unit 구조물의 상대적 적합도 비교)

  • Lee, Wan-Sun;Park, Jong-Kyoung;Kim, Wook-Tae
    • Journal of Dental Rehabilitation and Applied Science
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    • v.30 no.1
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    • pp.16-22
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    • 2014
  • Purpose: The purpose of this study was to assess the marginal and mesial fitness of zirconia single copings and 3-unit fixed partial dentures (FPDs) manufactured with an identical model. Materials and Methods: An epoxy model in which the maxillary right 2nd premolar is lost and maxillary 1st premolar and 2nd molar are formed as abutments was manufactured and scanned by using a laser scanner. A ten units of zirconia single copings were manufactured for maxillary 1st premolar and 2nd molar, respectively and the same number of 3-unit FPDs were manufactured. For the measurements of fitness, the manufactured silicone replicas were divided into four parts and the fitness were measured by digital microscope at measurement points (P1, P2, P3, P4 and P5) of each plane. The measured gaps were classified into three categories: marginal gap (MG, P1), axial gap (AG, average of P2 and P3), occlusal gap (OG, average of P4 and P5). Results: The ranges of MG, AG and OG for single copings were 18.47 - 40.54 ${\mu}m$, 39.73 - 73.61 ${\mu}m$ and 116.90 - 134.69 ${\mu}m$, respectively. The ranges of MG, AG and OG for 3-unit FPDs were 45.95 - 87.44 ${\mu}m$, 23.78 - 57.00 ${\mu}m$ and 99.89 - 131.06 ${\mu}m$, respectively. Conclusion: The result of the study shows that the MGs for 3-unit FPDs were higher than those of single copings, though they are within the range of clinical acceptance, indicating that the use of more homogeneous zirconia block and modification of sintering processes are needed to ensure the prevention of increase of gap in 3-unit FPDs.