• Title/Summary/Keyword: silicate solution

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Synthesis Conditions and Rheological Characteristics of Aluminum Magnesium Silicate (규산알루민산마그네슘의 합성조건과 유동학적 특성)

  • 신화우;정동훈
    • YAKHAK HOEJI
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    • v.39 no.1
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    • pp.68-77
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    • 1995
  • Aluminum magnesium silicate was synthesized by reacting the mixed solutions of sodium aluminate and magnesium chloride with sodium silicate solution in this study. The optimal synthesis conditions based on the yield of the product has been attained according to Box-Wilson experimental design. It was found that the optimal synthetic conditions of aluminum magnesium silicate were as follows: Reaction temperature=$69~81^{\circ}C$; concentration of two reactants, sodium aluminate and magnesium chloride= 13.95~14.44 w/w%; molar concentration ratio of the two reactants, [NaAlO$_{2}$]/MgCl$_{2}$]=3.63~4.00; reaction time= 12~15 min; drying temp. of the product=$70~76^{\circ}C$. Aluminum magnesium silicate synthesized under the optimal synthesis condition was dispersed in 0.75, 1.0 and 1.5w/w% aqueous solution or suspension of six dispersing agents, and the Theological properties of the dispersed systems prepared have been investigated at $15^{\circ}C$ and $25^{\circ}C$ using Brookfield LVT Type Viscometer. The acid-consuming capacity of the most excellent product was 272~278 ml of 0.1N-HCl per gram of the antacid. The flow types of 5.0 w/w% aluminum magnesium silicate suspension were dependent upon the kind and concentration of dispersing agents added. The apparent viscosity of the suspension was generally increased with concentration of dispersing agents and was not significantly changed or decreased as the temperature was raised. A dispersing agent, hydroxypropyl cellulose suspension, exhibited an unique flow behavior of antithixotropy. The flow behavior of the suspension dispersed in a given dispersing agent not always coincided with that of the dispersing agent solution or suspension itself.

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Effect of Potassium Silicate Amendments in Hydroponic Nutrient Solution on the Suppressing of Phytophthora Blight (Phytophthora capsici) in Pepper

  • Seo, Sang-Tae;Wang, T.C.;Jang, Han-Ik;Pae, Do-Ham;Engle, L.M.;Lee, Jung-Sup
    • The Plant Pathology Journal
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    • v.20 no.4
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    • pp.277-282
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    • 2004
  • Amendments of a recirculating nutrient solution with potassium silicate were evaluated as a means to control Phytophthora capsici infections on pepper plant(Capsicum annuum L.). Supplying the solutions with 100 or 200 ppm of silicate significantly reduced motility, root decay, and yield losses attributed to infection of P. capsici. Treating inoculated plants with potassium silicate increased root dry weights and number of fruit, especially high-grade fruit. Results were slightly superior to non-inoculated controls. The two varieties, PBC 137 and PBC 602, responded similarly to the treatments. No significant differences were observed between the 100- and 200 ppm silicate treatments. Results were better when greenhouse conditions favored the spread of P. capsici. Silicon alone did not increase pepper yield, suggesting that it acts as a disease suppression agent rather than as a fertilizer, The phenomena by which silicon confers protection against P. capsici infection and disease development are not fully understood, but our results indicate that mechanisms other than a mechanical barrier to fungal penetration are involved.

Adsorption of Hydrophobic Organic Compounds from Aqueous Solution with CTAB Coated Silicate (CTAB가 코팅된 Silicate을 이용한 소수성 유기물질의 흡착)

  • 김학성;정영도;한훈석
    • Journal of environmental and Sanitary engineering
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    • v.10 no.3
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    • pp.78-84
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    • 1995
  • Cationic surfactants can be used to modify surface of solids to promote adsorption of hydrophobic organic compounds. This behavior is due to the surfactant forming aggregate structure on the solid surface. Partition coefficients are commonly used to quantify the distribution of organic pollutants between the aqueous and particulate phases of aquatic system Partitioning of hydrophobic compounds to cetyltrimethylammonium bromide ( CTAB ) coated silicate has been investigated as a function of surfactant surface coverage at I=0 and 0.1 ionic strength. Toluene, Xylene, TCI sorption experiments demonstrated that the CTAB coated silicate was able to remove these hydrophobic organic compounds from solution The hydrophobic organic compound with the higher Kow had higher removals than lowest Kow hydrophobic organic compound.

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Organic Passivation Material-Polyvinyl Alcohol (PVA)/Layered Silicate Nanocomposite-for Organic Thin Film Transistor

  • Ahn, Taek;Suk, Hye-Jung;Yi, Mi-Hye
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08b
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    • pp.1539-1542
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    • 2007
  • We have synthesized novel organic passivation materials to protect organic thin film transistors (OTFTs) from $H_2O$ and $O_2$ using polyvinyl alcohol (PVA)/layered silicate (SWN) nano composite system. Up to 3 wt% of layered silicate to PVA, very homogeneous nanocomposite solution was prepared.

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Consolidation of Quartz Powder by the Geopolymer Technique

  • Ikeda, Ko;Nakamura, Yoshinori
    • The Korean Journal of Ceramics
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    • v.6 no.2
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    • pp.120-123
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    • 2000
  • The geopolymer technique may be a future-oriented technology for saving energies and resources. This technique requires 3 fundamental elements so-called filler, hardener and geopolymer liquor being generally an alkaline silicate solution. Quartz powder, water quenched granulated blast furnace slag and sodium silicate solution prepared from $Na_2O\cdot2SiO_2$were chosen for these three elements. After mixing these starting materials in appropriate proportions, monoliths were prepared by casting at room temperature. Strength tests showed the following results for 28d age speciment: 7.9-12.7 MPa in flexural strength and 20.2-32.8 MPa in compressive strength, depending on geopolymer liquor/solid ratio, P/S and fineness of the quartz powders used.

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Coating of ZnS phosphor by $SiO_2$ sol-gel

  • Lee, You-Hui;Han, Sang-Do;Han, Chi-Hwan;Yang, Hua;Singh, Ishwa
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.719-723
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    • 2004
  • Silica coating on ZnS particles with buffer solution has been investigated. Diluted sodium silicate in water was used as the precursor material and it was diluted in water. Sodium silicate was added drop-wise in the continuously stirred suspension of ZnS in the buffer solution at room temperature. Smooth and evenly distributed silica coated ZnS phosphors has been obtained when the pH of buffer solution was 10, the concentration of sodium silicate in water was 20 wt%, firing temperature was 500 $^{\circ}C$.

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Low Temperature Synthesis of Forsterite Powders by the Geopolymer Technique (지오폴리머 기술에 의한 포스테라이트 분말의 저온합성)

  • Son, Se-Gu;Lee, Ji-Hyeon;Lee, Sang-Hoon;Kim, Young-Do
    • Journal of the Korean Ceramic Society
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    • v.46 no.3
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    • pp.242-248
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    • 2009
  • Forsterite is a crystalline magnesium silicate with chemical formula $Mg_2SiO_4$, which has extremely low electrical conductivity that makes it an ideal substrate material for electronics. In this study, forsterite precursors were synthesized with magnesium silicate gels from the mixture of magnesium nitrate solution and various sodium silicate solution by the geopolymer technique. Precursors and heattreated powders were characterized by thermogravimetrical differential thermal analyzer(TG-DTA), X-ray diffractometer(XRD), scanning electron microscopy(SEM), Si magic angle spinning nuclear magnetic resonance(MAS-NMR), transmission electron microscopy(TEM). As the result of analysis about the crystallization behavior by DTA, the synthesized precursors were crystallized in the temperature range of $700^{\circ}C$ to $900^{\circ}C$. The XRD results showed that the gel composition began to crystallize at various temperature. Also, it was found that the sodium orthosilicate based precursors(named as 'FO') began to crystallize at above $550^{\circ}C$. The FO peaks were much stronger than sodium silicate solution based precursors(named as 'FW'), sodium metasilicate based precursors(named as 'FM') at $800^{\circ}C$. TEM investigation revealed that the 100nm particle sized sample was obtained from FO by heating up to $800^{\circ}C$.

Particle-size Effect of Silicate Fertilizer on Its Solubility and Mobility in Soil (토양(土壤)에 처리한 광재규산질비료의 입도별(粒度別) 용해도(溶解度) 및 이동성(移動性))

  • Yoo, Sun-Ho;Park, Lee-Dal
    • Korean Journal of Soil Science and Fertilizer
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    • v.13 no.2
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    • pp.57-63
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    • 1980
  • The effect of particle size of silicate fertilizer, crushed slag from the steel industry, on the behavior of silicate in soil was investigated through laboratory experiments. The silicate fertilizer was sieved to obtain three fractions of particles, coarser than 10 mesh 20-35 mesh, and finer than 100 mesh. Silicate concentration of the extract obtained by shaking 20 mg of particles, coarser than 10 mesh, 20-35 mesh, and finer than 100 mesh, in 50 ml of distilled water for 4 hours was 0.3, 1.0, and 3.2 ppm respectively. As shaking the mixture of the silicate fertilizer and soil proceeded, silicate concentration of the extract increased, and this increase after 4 hour shaking was attributed mainly to dissolution of soil silicate. When the mixture of soil and the silicate fertilizer was incubated under submerged condition, silicate concentration of the solution decreased for the first 2-4 weeks, thereafter increased with incubation time. During this incubation period, silicate concentration of the solution changed inversely with pH of the solution. After 6-10 weeks, however, both silicate concentration and pH of the solution increased with incubation time. Silicate concentration of the effluent from the 14.5 cm soil column of which top 4.5 cm was packed with the mixture of 30 g of soil and 30 mg of the silicate fertilizer reached maximum at 0.94 pore volumes for the particles of 20-35 mesh and 1.03 pore volumes for the particles finer than 100 mesh, whereas the effluent concentration reached maximum at 0.88 pore volumes for the soil column without the silicate fertilizer treatment. Soil analysis made after water percolation revealed that 1.5 pore volumes of water could leach down large amount of the water soluble silicate but not the sodium acetate extractable silicate, from top 3-6 cm soil layer.

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